CN100425665C - 天然彩色木器漆 - Google Patents
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Abstract
天然彩色木器漆，由天然树脂，稀释剂、颜料、填料配制而得，其中天然树脂由植物油和植物固体树脂制得，稀释剂为从植物汁液中提炼的天然植物溶剂，颜料为天然颜料或天然物加工颜料。本发明各组成成分均为天然制品，不含苯、甲苯等有毒化学类溶剂及汞、铝、镉、铅等重金属离子，无毒无害，无刺激性气味，无氟酸酯毒气挥发，健康环保，性能优异，施工简单，适用面广。
Description
技术领域
本发明属于木器漆技术领域，具体涉及一种天然彩色木器漆。
背景技术
化学合成漆大多含苯、甲醛、重金属等，大量使用容易造成大气、土地污染和空气质量下降，给人们的居住环境和身体健康带来严重的影响。随着社会对环境意识的加强，人们越来越注重生存的这个环境，为了限制有害物质对人类生态环境的污染，我国政府颁发了GB18581-2001《室内装修材料溶剂型木器涂料中有害物质限量》、GB18582-2001《室内装修材料内墙涂料中有害物质限量》等国家标准。标准的制定在一定程度上限制和减少了有害物质的污染，但能达标的产品中是仍含有一定量的重金属、甲醛、烷烯烃有机物、异氰酸酯等有害物质。传统彩色聚氨酯家具漆会散发有毒的刺激性气体，危害人体健康，且工艺复杂，须专业人员施工，自己动手施工不便。而很多环保型涂料为了达到环保，油漆成膜后的一些性能不能得到保证。
发明内容
本发明要解决的就是现有的化学合成漆因大多含苯、甲醛、重金属等容易造成环境污染，影响人体健康的问题，提供一种不含化学类溶剂及汞、铝、镉等重金属离子，无毒无害无刺激性气味，且施工简便，适用面广的天然彩色木器漆。
本发明由天然树脂，稀释剂、颜料、填料配制而得，各组分的重量配比为：天然树脂58-62％，颜料8-12％，填料10-15％，稀释剂15-20％，其中天然树脂由植物油和植物固体树脂制得，稀释剂为从植物汁液中提炼的天然植物溶剂，颜料为天然颜料或天然物加工颜料。
本发明采用的天然树脂由下列成分按重量比在280℃-290℃下热炼而得：亚麻油60-63％，桐油14-16％，松香11-13％，松节油9-11％，其中亚麻油为精漂型，桐油、松香、松节油均为国一级。
本发明采用的稀释剂为松节油或薄荷油；颜料选用天然颜料或天然物加工颜料，如钛白粉，有机中黄；填料可用碳酸钙、滑石粉、重钙等，为达到良好的消光效果，优选碳酸钙，为方便木器漆的配制，优选超细碳酸钙。
本发明具有如下优点：
1、各组成成分均为天然制品，不含苯、甲苯等有毒化学类溶剂及汞、铝、镉、铅等重金属离子，即不含任何有毒有害化学物质；
2、能散发出天然植物香味；
3、无毒无害，无刺激性气味，无氟酸酯毒气挥发，健康环保；
4、性能优异，干燥快、色彩多样、颜色鲜艳、装饰性强、附着力好、硬度高、遮盖力高、柔韧性好，漆膜丰满、坚硬，耐湿耐擦洗。
5、本发明施工简单，适用面广，可涂刷在钢铁、木器、水泥墙面上，漆膜丰满、坚硬，耐湿耐擦洗，流平性极佳，手感细腻，不易变黄，尤其对木制家具能起到很好的保护作用。
表1为本发明使用的稀释剂检的测结果，其中苯、甲苯和二甲苯总和的检出限为0.001％：
| 检测项目 | 技术指标 | 检验结果 |
| 苯％ | ≤0.5 | 未检出 |
| 甲苯和二甲苯总和％ | ≤10 | 未检出 |
表1
表2为本发明天然彩色木器漆环保性检测结果，其中苯、甲苯和二甲苯总和的检出限为0.001％，可溶性铅的检出限为0.5mg/kg，可溶性镉和可溶性铬的检出限为0.3mg/kg，可溶性汞的检出限为0.01mg/kg：
| 检验项目 | 技术指标 | 检验结果 | 本项结论 |
| 挥发性有机化合物(VOC)g/L | ≤550 | 422 | 合格 |
| 苯％ | ≤0.5 | 未检出 | 合格 |
| 甲苯和二甲苯总和％ | ≤10 | 未检出 | 合格 |
| 重金属：可溶性铅(Pb)可溶性镉(Cd)可溶性铬(Cr)可溶性汞(Hg) | ≤90≤75≤60≤60 | 未检出未检出未检出未检出 | 合格合格合格合格 |
表2
表3为本发明木器漆性能检测结果：
表3
具体实施方式
实施例1
将亚麻油600kg、桐油140kg投入反应釜中，搅拌升温至280℃-290℃，然后保温至粘度达到涂-4杯150-160S/(25±2)℃。降温到260℃-270℃，加入松香110kg，再加热，在280℃时继续保温至粘度涂-4杯300-320S/(25±2)℃。然后降温至260℃，出釜用松节油90kg兑稀，达到需要的粘度：涂-4杯180-200S/(25±2)℃。经过滤达到细度≤30μm后，检验入罐备用。
取天然树脂580kg，钛白粉80kg，细度为325目的超细碳酸钙100kg，松节油150kg。将300kg天然树脂投入料锅中，加入钛白粉80kg、超细碳酸钙100kg，再加入100kg松节油研磨，研磨40-60分钟，研磨时间由所需的油漆细度来定。剩余的280kg天然树脂和50kg松节油在油漆检测达到细度≤35μm后，再根据所需粘度指标逐量加入，继续研磨保持细度≤35μm，细度、粘度均达到指标后灌装，得到白色木器漆，外观为均匀白色流体。
实施例2
将原料亚麻油624kg、桐油156kg投入反应釜中，搅拌升温至280℃-290℃，然后保温至粘度达到涂-4杯150-160S/(25±2)℃。降温至260℃-270℃后加入松香120kg，再加热，在280℃时继续保温至粘度涂-4杯300-320S/(25±2)℃。然后降温至260℃，出釜用松节油100kg兑稀，达到需要的粘度涂-4杯180-200S/(25±2)℃。经过滤达到细度≤30μm后，检验入罐备用。
取600kg天然树脂，有机中黄100kg，细度为325目的超细碳酸钙125kg，松节油175kg。将400kg天然树脂投入料锅中，加入有机中黄100kg、超细碳酸钙125kg，再加入100kg松节油研磨40-60分钟，研磨时间由所需的油漆细度来定。剩余的200kg天然树脂和75kg松节油在油漆检测达到细度≤35μm后，再根据所需粘度指标逐量加入，继续研磨保持细度≤35μm，细度、粘度均达到指标后灌装，得到黄色木器漆。
实施例3
将原料亚麻油630kg、桐油145kg投入反应釜中，搅拌升温至280℃-290℃，然后保温至粘度达到涂-4杯150-160S/(25±2)℃。降温至260℃-270℃后加入松香130kg，再加热，在280℃时继续保温至粘度涂-4杯300-320S/(25±2)℃。然后降温至260℃，出釜用松节油95kg兑稀，达到需要的粘度涂-4杯180-200S/(25±2)℃。经过滤达到细度≤30μm后，检验入罐备用。
取600kg天然树脂，酞菁蓝100kg，细度为325目的超细碳酸钙125kg，松节油175kg。将400kg天然树脂投入料锅中，加入酞菁蓝100kg、超细碳酸钙125kg，再加入100kg松节油研磨40-60分钟，研磨时间由所需的油漆细度来定。剩余的200kg天然树脂和75kg松节油在油漆检测达到细度≤35μm后，再根据所需粘度指标逐量加入，继续研磨保持细度≤35μm，细度、粘度均达到指标后灌装，得到蓝色木器漆。
本发明为单组分配方，粘度70-90S/25℃，使用时不需添加其它原料，可直接涂刷。
Claims (5)
1、天然彩色木器漆，其特征在于由天然树脂、稀释剂、颜料、填料配制而得，各组分基于木器漆中各组分总重量的重量配比为：天然树脂58-62％，颜料8-12％，填料10-15％，稀释剂15-20％，其中天然树脂由亚麻油、桐油、松香、松节油在280℃-290℃下热炼而得，且天然树脂各成分基于天然树脂中各成分总重量的重量配比为：亚麻油60-63％，桐油14-16％，松香11-13％，松节油9-11％，稀释剂为从植物汁液中提炼的天然植物溶剂，颜料为天然颜料或天然物加工颜料。
2、根据权利要求1所述的天然彩色木器漆，其特征在于天然树脂中亚麻油为精漂型，桐油、松香、松节油为国一级。
3、根据权利要求1所述的天然彩色木器漆，其特征在于稀释剂为松节油或薄荷油。
4、根据权利要求1所述的天然彩色木器漆，其特征在于填料为碳酸钙。
5、根据权利要求4所述的天然彩色木器漆，其特征在于碳酸钙细度可通过325目筛。
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| CN102286249A (zh) * | 2010-06-17 | 2011-12-21 | 葛义谦 | 生物油漆及制造方法 |
| CN102585701A (zh) * | 2012-03-16 | 2012-07-18 | 惠州市长润发涂料有限公司 | 一种植物油涂料 |
| CN103740276A (zh) * | 2013-09-30 | 2014-04-23 | 罗新平 | 一种环保漆 |
| CN106752191B (zh) * | 2016-12-30 | 2019-01-22 | 河北晨阳工贸集团有限公司 | 一种水性木器漆基础粘接料及其制备方法 |
| CN110183909A (zh) * | 2019-06-12 | 2019-08-30 | 深圳市前海幸运色彩科技有限公司 | 一种木皮染色材料及其制备工艺 |
| CN111871740A (zh) * | 2020-07-23 | 2020-11-03 | 福建省尤溪县红树林木业有限公司 | 一种改良型的涂装料以及其应用于木板材上涂装工艺 |
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| GB473329A (en) * | 1935-04-05 | 1937-10-06 | Deutsche Hydrierwerke Ag | Improvements in or relating to the production of lacquers, varnishes, coating, impregnating and adhesive agents |
| GB506796A (en) * | 1937-12-01 | 1939-06-01 | George William Johnson | Improvements in coating agents, priming compositions and putties |
| CN1318574A (zh) * | 2001-05-28 | 2001-10-24 | 方忠熙 | 改性天然树脂 |
| CN1494579A (zh) * | 2001-03-16 | 2004-05-05 | 李丙年 | 用于缩短干燥时间的天然油树脂组合物及其制造方法和具有该相同树脂组合物的天然油漆组合物 |
-
2007
- 2007-05-10 CN CNB2007100222327A patent/CN100425665C/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB473329A (en) * | 1935-04-05 | 1937-10-06 | Deutsche Hydrierwerke Ag | Improvements in or relating to the production of lacquers, varnishes, coating, impregnating and adhesive agents |
| GB506796A (en) * | 1937-12-01 | 1939-06-01 | George William Johnson | Improvements in coating agents, priming compositions and putties |
| CN1494579A (zh) * | 2001-03-16 | 2004-05-05 | 李丙年 | 用于缩短干燥时间的天然油树脂组合物及其制造方法和具有该相同树脂组合物的天然油漆组合物 |
| CN1318574A (zh) * | 2001-05-28 | 2001-10-24 | 方忠熙 | 改性天然树脂 |
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| CN101050335A (zh) | 2007-10-10 |
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