CN100397994C - Insect and mite killer with vegetable oil as base - Google Patents
Insect and mite killer with vegetable oil as base Download PDFInfo
- Publication number
- CN100397994C CN100397994C CNB2006100349639A CN200610034963A CN100397994C CN 100397994 C CN100397994 C CN 100397994C CN B2006100349639 A CNB2006100349639 A CN B2006100349639A CN 200610034963 A CN200610034963 A CN 200610034963A CN 100397994 C CN100397994 C CN 100397994C
- Authority
- CN
- China
- Prior art keywords
- rotenone
- oil
- agent
- vegetable oil
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the field of agricultural insecticide, and specifically discloses an insect and mite killer by using vegetable oil as a base. The insect and mite killer by using vegetable oil as a base of the present invention specifically comprises the following substances by weight percentage of 5 to 75 percent of turpentine, 0 to 55 percent of wintergreen oil and 0.01 to 5 percent of rotenone, and the surplus are additives. The present invention is the insect and mite killer by using vegetable oil as a base, which is processed by utilizing vegetable oil to replace benzene series solvents in conventional missible oil. The present invention overcomes the defects that the toxicity of the existing rotenone and the benzene series solvents existing in compounding conventional pesticide missible oil thereof for mammals is high, the environmental pollution is serious, plenty of organic solvent resources are consumed, a certain resistance risk exists, the light stability of the rotenone and phoxim is poor, and the effective period is short. The insect and mite killer by using vegetable oil as a base searched and produced by the present invention has the characteristics of high efficiency, low toxicity, no environment pollution, good green, reproducing property and light stability of vegetable oil base resources, simple production process, low cost and small resistance risk.
Description
Technical field
The present invention relates to field of agricultural pesticide, be specifically related to a kind of plant oil based insecticidal/acaricidal agent.
Background technology
Rotenone is famous selective vegetable source insecticidal/acaricidal agent, and hundreds of agriculturals and sanitary insect pest are had good result, has particularly brought into play important function in recent years on control resistant insect (as diamond-back moth), is comparatively ideal medicament in the insect comprehensive regulation.Phoxim is efficient, wide spectrum, low toxicity insecticidal/acaricidal agent, can effectively prevent and treat insect, evil mite on the various crop such as paddy rice, tealeaves, fruit tree, vegetables, cotton.The main body solvent is toluene or dimethylbenzene (the two all contains a spot of benzene) in existing rotenone or rotenone and the phoxim compound missible oil, it exists, and (benzene is courageous and upright poisonous substance greatly to mammalian toxicity, and has a strong cytogenetics effect, can cause not distortion of various dyeing, toluene, dimethylbenzene mainly influences the neural function of contactee, long-term contact benzene series thing may cause elevation of blood pressure and leukopenia, influential and have a development toxicity to contactee's reproduction function), environmental pollution is serious, (China processing missible oil will expend 250,000 t every year to expend the defective of ample resources, be worth 7.5～900,000,000 yuan organic solvent), and benzene series thing solvent has faced disabled trend in developed country, especially vegetables, use conventional (making solvent) missible oil to suffer strong resistance on the fruit tree, thereby impel the continual renovation and the development of pesticidal preparations with the benzene series thing.Above problem demanding prompt solution based on conventional missible oil formulation existence, most agricultural chemicals circle experts propose following formulations of pesticide processing and turn to main countermeasure with water base, as be processed into suspending agent, water dispersible granules, microemulsion, aqueous emulsion, microcapsule suspending agent etc., it is relatively harsher that but these water baseization formulations require process equipment and process technology, and the old brand agricultural chemicals enterprise that is unfavorable for the current numerous production missible oil of China breaks away from the predicament of aspects such as fund that the foreseeable future, conventional missible oil was brought by cut-off and technical bottleneck.
Turpentine oil is the terpenes mixture, and Main Ingredients and Appearance is australene and nopinene, belongs to the alicyclic hydrocarbon compounds, is one of green renewable forest products essential oil of China's output maximum.Turpentine oil is low evil reagent to body, and what do not belong to national regulation causes occupational disease medicine category; Its boiling point is 139.1 ℃, index of refraction [nd
20] be 1.472 and dimethylbenzene approaching, these data have satisfied the specification requirement that turpentine oil can substituted dimethyl benzene.Existing being reported in the pathological section replaces the dimethylbenzene dewaxing with turpentine oil, exempted the human injury of dimethylbenzene to the pathology technician, protected that the staff's is healthy.Other has document announcement, and turpentine oil can be used for the synthetic pesticide synergist and has desinsection, weeding, bactericidal activity and have repellent and the chemical substance of attracting action at pesticide field.Wintergreen (gaultherolin) is a kind of nontoxic, colourless and dulcet liquid, now extensively be used in and made solvent, preservative in the fine chemistry industry, also be used as the spices of beverage, food, toothpaste, cosmetics etc., and be used to produce analgesic, insecticide, polish etc.China produces turpentine oil 60,000 t per year, and the deep processing and utilization rate only is 25%, on proportion of utilization and kind with obvious gap is abroad arranged.Wintergreen obtains except extracting the Chinese ilex plant leaf blade of extensively planting from the south of the lower reaches of the Yangtze River, and also available chemical method is synthetic.Two kinds of essential oils of turpentine oil and wintergreen are the green renewable resources of wide material sources in summary, have the resource base of abundant deep exploitation.
Summary of the invention
The object of the invention is to provide a kind of with mixture replacing rotenone of plant oil based solvent turpentine oil or turpentine oil and wintergreen or the benzene series thing solvent in rotenone and the conventional missible oil of phoxim compound at the deficiencies in the prior art, and a kind ofly be used to prevent and treat various agricultural insect, evil mite by what add that auxiliary agent is processed into, especially be fit to the environment friendly agricultural preparation of control phytophagous mites, aphid and prodenia litura.
Plant oil based insecticidal/acaricidal agent of the present invention, plant oil based solvent are the mixture of turpentine oil or turpentine oil and wintergreen, and active ingredient is the compound of rotenone or rotenone and phoxim.Specifically contain following material and percentage by weight: turpentine oil 5～75%, wintergreen 0～55%, rotenone 0.01～5%, surplus is an auxiliary agent.
In above-mentioned plant oil based insecticidal/acaricidal agent: the terebinthine preferred content of plant oil based solvent is 25～60%, and the preferred content of wintergreen is 0～45%; The rotenone preferred content is 0.1～2%.
In above-mentioned plant oil based insecticidal/acaricidal agent, also can contain phoxim, the weight of phoxim is 20～25 times of rotenone.
In above-mentioned plant oil based insecticidal/acaricidal agent, described auxiliary agent and percentage by weight thereof are respectively cosolvent 0～10%, emulsifier 3～15%, natural short bleeding agent 0～20%, bleeding agent 0～5%, ultra-violet absorber 0～5%, antioxidant 0～5%, antifreezing agent 0～5%.
In above-mentioned plant oil based insecticidal/acaricidal agent, the preferred weight percent of described auxiliary agent is respectively cosolvent 0～5%, emulsifier 5～10%, natural short bleeding agent 5～15%, bleeding agent 0.2～2%, ultra-violet absorber 0.5～2%, antioxidant 0.5～2%, antifreezing agent 0～3%.
In above-mentioned plant oil based insecticidal/acaricidal agent, described cosolvent is an ethyl acetate, described emulsifier is the compound of agricultural newborn 500# (calcium dodecyl benzene sulfonate) and OP-10 (octylphenol polyethylene oxyethylene group ether), described natural short bleeding agent is a fevergum oil, described bleeding agent is JFC (a bay alcohol radical polyoxyethylene groups ether), described ultra-violet absorber is UV-P[2-(2 '-hydroxyl-5 '-aminomethyl phenyl) BTA], described antioxidant is Jiao's property oil gallate-based, described antifreezing agent is a glycerine.
Plant oil based Insecticiding-miticiding agent and process for producing same of the present invention is: each component by prescription weighing medicament, is added successively and mixes, and stir in mulser, through quality inspection, make finished product at last.
Plant oil based insecticidal/acaricidal agent of the present invention is compared with matching convention missible oil, has following beneficial effect:
1. to have low toxicity, environmental friendliness, used plant oil based solvent be the characteristic of green renewable resources to the plant oil based insecticidal/acaricidal agent of green preparation of the present invention development, benzene series thing solvent toxicity and problem of environmental pollution in the matching convention missible oil have been avoided, sheltered simultaneously the bad smell of Phoxim original medicine in rotenone and the phoxim compound missible oil effectively, be adapted at fully applying in the ecological agriculture and the non-environmental pollution control technology, have extremely remarkable economical, society and ecological benefits.
2. the plant oil based insecticidal/acaricidal agent of the present invention's development is remarkable to phytophagy evil mite, aphid and prodenia litura synergistic effect.
3. photostability raising, lasting period suit, and can reduce dispenser frequency and control cost, and help further alleviating the pressure to environment.
4. by conventional missible oil being transformed into the green preparation of plant oil based novel missible oil,, and will promote the innovation of China's turpentine oil and wintergreen deep processing and utilization approach for conventional missible oil manufacturing enterprise brings new survival and development opportunity.
Embodiment
The plant oil based Insecticiding-miticiding agent prescription of embodiment 1～9 embodiment 1～9 sees Table 1, and each components contents all by weight percentage in the prescription.Each component by prescription weighing medicament, is added successively and mixes, and stir in mulser,, make finished product at last through quality inspection.Wherein rotenone, the female oil of phoxim, plant oil based solvent turpentine oil and wintergreen, cosolvent ethyl acetate, emulsifier (compound of agricultural newborn 500# and OP-10), natural short bleeding agent fevergum oil, penetrating agent JFC, Ultraviolet Absorber UV-P, antioxidant pyrogallic acid, antifreezing agent glycerine are commercially available product.
The plant oil based insecticidal/acaricidal agent formulation Example of table 1
Annotate: this component is not added in "-" expression in the table.
Embodiment 10 plant oil based insecticidal/acaricidal agents and conventional missible oil compare the virulence of citrus red mite (crm)
Measure 2.5% plant oil based rotenone insecticidal/acaricidal agent (embodiment 1) and the virulence of conventional missible oil with reference to the slide infusion process that FAO recommends to citrus red mite (crm), two medicaments are diluted to 5 concentration through prerun respectively with running water, every concentration repeats for three times, whenever, repeat at least 30 female one-tenth mites, to try mite and in each concentration liquid, flood 5s, blot mite body remaining soup all around rapidly with filter paper, to try mite after finishing dealing with and place T=(25 ± 1) ℃, RH=(60 ± 10) %, L: D=14: cultivate in 10 the biochemical incubator, contrast and be clear water.Result's (seeing Table 2) shows, this plant oil based insecticidal/acaricidal agent of 24h is significantly higher than conventional missible oil to the virulence of citrus red mite (crm) behind the medicine, the two differs 1.83 times, and it is remarkable to prove that this plant oil based insecticidal/acaricidal agent and the conventional missible oil of identical active constituent content compare the citrus red mite (crm) synergistic effect.
Plant oil based insecticidal/acaricidal agent of table 2 and conventional missible oil compare the virulence of citrus red mite (crm)
| Rotenone emulsifiable solution | The 24h virulence regression equation | Correlation coefficient (r) | LC 50 (μg/mL) | LC 95 (μg/mL) | LC 5095% confidence interval |
| Plant oil based insecticidal/acaricidal agent | Y＝4.8202+1.8204x | 0.9969 | 1.26 | 10.05 | 0.91～ 1.72 |
| Conventional | Y＝4.2897+1.9584x | 0.9976 | 2.31 | 15.94 | 1.78～ 2.98 |
Embodiment 11 plant oil based rotenone and phoxim compound insecticidal/acaricidal agent and conventional missible oil compare the virulence of prodenia litura third-instar larvae
With the blade infusion process measure 18% plant oil based rotenone and phoxim compound insecticidal/acaricidal agent (embodiment 6) and conventional missible oil to 3 age Spodoptera litura larvae virulence, two medicaments are diluted to 5 concentration through prerun respectively with running water, every concentration repeats for three times, every repeat at least 10 the examination worms, get fresh nontoxic cassava blade and in each concentration liquid, flood 5s, to try worm after finishing dealing with and place T=(25 ± 1) ℃, RH=(60 ± 10) %, L: D=14: cultivate in 10 the biochemical incubator, contrast and be clear water.Result's (seeing Table 3) shows, behind the medicine this insecticidal/acaricidal agent of 24h to 3 age Spodoptera litura larvae virulence be significantly higher than conventional missible oil, the two differs 2.23 times, and it is remarkable to prove that this insecticidal/acaricidal agent and the conventional missible oil of identical active constituent content compare the prodenia litura synergistic effect.
Table 3 18% plant oil based insecticidal/acaricidal agent and conventional missible oil to 3 age Spodoptera litura larvae virulence relatively
| Rotenone and phoxim compound missible oil | The 24h virulence regression equation | Correlation coefficient (r) | LC 50 (μg/mL) | LC 95 (μg/mL) | LC 5095% confidence interval |
| Plant oil based insecticidal/acaricidal agent | Y＝1.8780+2.6836x | 0.9892 | 14.57 | 59.75 | 11.98～ 17.70 |
| Conventional | Y＝1.7881+2.1250x | 0.9914 | 32.47 | 193.00 | 25.72～ 40.99 |
Embodiment 12 plant oil based rotenone and phoxim compound insecticidal/acaricidal agent and conventional missible oil compare the virulence of radish aphid
Take potter spray-on process relatively 18% plant oil based rotenone and phoxim compound insecticidal/acaricidal agent (embodiment 6) and the virulence of conventional missible oil to radish aphid, two medicaments are diluted to 5 concentration through prerun respectively with running water, every concentration repeats for three times, whenever, repeat at least 30 aptery one-tenth aphids, the 1mL soup is sprayed in every processing blade positive and negative, will try worm after finishing dealing with and place T=(25 ± 1) ℃, R=(60 ± 10) %, L: D=14: cultivate in 10 the biochemical incubator, contrast and be clear water.Result's (seeing Table 4) shows that apparently higher than conventional missible oil, the two differs 1.63 times to this insecticidal/acaricidal agent of 24h to the virulence of radish aphid behind the medicine, and it is remarkable that this insecticidal/acaricidal agent and the conventional missible oil of identical active constituent content compare the radish aphid synergistic effect.
Table 4 18% plant oil based insecticidal/acaricidal agent and conventional missible oil compare the virulence of radish aphid
| Rotenone and phoxim compound missible oil | The 24h virulence regression equation | Correlation coefficient (r) | LC 50 (μg/mL) | LC 95 (μg/mL) | LC 5095% confidence interval |
| Plant oil based insecticidal/acaricidal agent | Y＝3.8645+1.8922x | 0.9972 | 3.98 | 29.47 | 3.03～ 5.24 |
| Conventional | Y＝3.4689+1.8856x | 0.9963 | 6.49 | 48.35 | 4.96～ 8.49 |
Embodiment 13 plant oil based rotenone and phoxim compound insecticidal/acaricidal agent and conventional missible oil compare the virulence of Tetranychus cinnabarinus
The slide infusion process of recommending with reference to FAO is measured 18% plant oil based rotenone and phoxim compound insecticidal/acaricidal agent (embodiment 6) and conventional missible oil to the female virulence that becomes mite of Tetranychus cinnabarinus, two medicaments are diluted to 5 concentration through prerun respectively with running water, every concentration repeats for three times, whenever, repeat at least 30 female one-tenth mites, blot mite body remaining soup all around rapidly with filter paper, to try worm after finishing dealing with and place T=(25 ± 1) ℃, RH=(60 ± 10) %, L: D=14: cultivate in 10 the biochemical incubator, contrast and be clear water.Result's (seeing Table 5) shows that this insecticidal/acaricidal agent of 24h is significantly higher than conventional missible oil to the virulence of the female one-tenth mite of Tetranychus cinnabarinus behind the medicine, and the two differs 2.25 times, and it is remarkable that this insecticidal/acaricidal agent and the conventional missible oil of identical active constituent content compare the Tetranychus cinnabarinus synergistic effect.
Table 5 18% plant oil based insecticidal/acaricidal agent and conventional missible oil compare the virulence of Tetranychus cinnabarinus
| Rotenone and phoxim compound missible oil | The 24h virulence regression equation | Correlation coefficient (r) | LC 50 (μg/mL) | LC 95 (μg/mL) | LC 5095% confidence interval |
| Plant oil based insecticidal/acaricidal agent | Y＝1.8780+2.6836x | 0.9964 | 16.78 | 157.47 | 12.50～ 22.54 |
| Conventional | Y＝2.5296+1.5660x | 0.9895 | 37.80 | 424.48 | 27.51～ 51.95 |
Embodiment 14 plant oil based rotenone and rotenone and phoxim compound Insecticiding-miticiding agent emulsifiable solution photostability are measured
Adopt potted plant residual effect method to add relatively that (embodiment 2,6) with add not that (embodiment 1,5) the photostability difference of plant oil based 2.5% rotenone of stabilizing agent and 18% rotenone and phoxim compound insecticidal/acaricidal agent, should plant oil based 2.5% rotenone and 18% rotenone and phoxim compound insecticidal/acaricidal agent be diluted to 25 μ g/mL and 100 μ g/mL soups respectively with running water, be sprayed on plantation respectively in the solarium not on the cassava blade of contacted medicament, 0d behind medicine, 3d, 5d win blade feed citrus red mite (crm) and three age Spodoptera litura larvae, to try mite after finishing dealing with or try worm to place T=(25 ± 1) ℃, RH=(60 ± 10) %, L: D=14: cultivate in 10 the biochemical incubator, contrast and be clear water.Result's (seeing Table 6) shows that the photostability of 3d, 5d is significantly increased after the plant oil based rotenone insecticidal/acaricidal agent dispenser of interpolation light stabilizer; Plant oil based rotenone and phoxim compound insecticidal/acaricidal agent photostability obtain the utmost point especially and significantly improve, the 24h corrected mortality that 3d, 5d two handle behind the spray medicine is respectively 80.91% and 65.12%, the two is remarkable with contrast inequality heteropole, and the contrast medicament is almost completely degraded behind the spray medicine 5d, proof by add an amount of ultra-violet absorber and antioxidant can significantly improve rotenone and with the photostability of phoxim compound insecticidal/acaricidal agent, play the proper extension lasting period and reduce medication number of times and cost, and help the harmful effect to environment is minimized.
The plant oil based insecticidal/acaricidal agent photostability of table 6 result of the test
Annotate: above result is the mean value that repeats three times, indicates " * " expression in the table after the same column data through t check significant difference (p＜0.05), and " * * " expression difference is (P＜0.01) extremely significantly.
Claims (4)
1. plant oil based insecticidal/acaricidal agent, contain following component and percentage by weight: turpentine oil 5～75%, wintergreen 0～55%, rotenone 0.01～5%, cosolvent 0～5%, emulsifier 5～10%, natural short bleeding agent 5～15%, bleeding agent 0.2～2%, ultra-violet absorber 0.5～2%, antioxidant 0.5～2%, antifreezing agent 0～3%.
2. plant oil based insecticidal/acaricidal agent according to claim 1 is characterized in that, contains following component and percentage by weight: turpentine oil 25～60%, and wintergreen 0～45%, rotenone 0.1～2%, surplus is an auxiliary agent.
3. plant oil based insecticidal/acaricidal agent according to claim 2 is characterized in that, also can contain phoxim, and its weight is 20～25 times of rotenone.
4. plant oil based insecticidal/acaricidal agent according to claim 1, it is characterized in that, described cosolvent is an ethyl acetate, described emulsifier is the mixture of agricultural newborn 500# and OP-10, described natural short bleeding agent is a fevergum oil, and described bleeding agent is JFC, and described ultra-violet absorber is UV-P, described antioxidant is Jiao's property oil gallate-based, and described antifreezing agent is a glycerine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100349639A CN100397994C (en) | 2006-04-13 | 2006-04-13 | Insect and mite killer with vegetable oil as base |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100349639A CN100397994C (en) | 2006-04-13 | 2006-04-13 | Insect and mite killer with vegetable oil as base |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1826903A CN1826903A (en) | 2006-09-06 |
| CN100397994C true CN100397994C (en) | 2008-07-02 |
Family
ID=36945602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100349639A Expired - Fee Related CN100397994C (en) | 2006-04-13 | 2006-04-13 | Insect and mite killer with vegetable oil as base |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100397994C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101849556A (en) * | 2010-05-28 | 2010-10-06 | 杨凌农科大无公害农药研究服务中心 | Plant source synergistic complex acaricide and preparation method thereof |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755739A (en) * | 2009-10-22 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Pesticide emulsion in water and preparation method thereof |
| CN102283254A (en) * | 2010-03-17 | 2011-12-21 | 钟韬 | Plant source environmentally-friendly pesticide preparation |
| CN102626116B (en) * | 2011-06-23 | 2013-09-04 | 北京亚戈农生物药业有限公司 | Plant pesticide and its preparation method |
| CN102239828A (en) * | 2011-07-07 | 2011-11-16 | 湖北蕲农化工有限公司 | Azadirachtin insecticide and preparation method thereof |
| CN102524314B (en) * | 2011-11-28 | 2014-02-26 | 宁夏农林科学院 | Euphorbia esula plant pest-killing emulsion in water |
| CN102863284B (en) * | 2012-09-24 | 2014-07-09 | 华南农业大学 | Organic fertilizer and preparation method thereof and method for controlling soil borne disease |
| CN103947654A (en) * | 2014-01-26 | 2014-07-30 | 华南农业大学 | Insecticide and preparation method thereof |
| CN104041504A (en) * | 2014-05-08 | 2014-09-17 | 中国农业科学院茶叶研究所 | Behavior control agent for control tea tree and leaf empoasca vitis and dendrothrips minowai priesner |
| CN105994425A (en) * | 2016-06-16 | 2016-10-12 | 太仓市雅丰农场专业合作社 | Environment-friendly miticide and preparing method thereof |
| CN106614797A (en) * | 2016-12-20 | 2017-05-10 | 重庆医学检验试剂研究所 | Composition for preventing and controlling red spiders and phyllocoptruta oleivora, and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107293A (en) * | 1994-02-23 | 1995-08-30 | 郑树勤 | Multifunctional emulsified insecticide |
| CN1223800A (en) * | 1997-12-25 | 1999-07-28 | 李安君 | Biological source insecticide |
-
2006
- 2006-04-13 CN CNB2006100349639A patent/CN100397994C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107293A (en) * | 1994-02-23 | 1995-08-30 | 郑树勤 | Multifunctional emulsified insecticide |
| CN1223800A (en) * | 1997-12-25 | 1999-07-28 | 李安君 | Biological source insecticide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101849556A (en) * | 2010-05-28 | 2010-10-06 | 杨凌农科大无公害农药研究服务中心 | Plant source synergistic complex acaricide and preparation method thereof |
| CN101849556B (en) * | 2010-05-28 | 2012-09-26 | 杨凌农科大无公害农药研究服务中心 | Plant source synergistic complex acaricide and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1826903A (en) | 2006-09-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100397994C (en) | Insect and mite killer with vegetable oil as base | |
| US20230172208A1 (en) | Preparation Method of Eucalyptol Emulsion and Application Thereof in Biopesticides | |
| CN106922728B (en) | A kind of suspension seed-coating agent for preventing brassicaceous vegetable phyllotreta striolata | |
| CN102224830B (en) | Plant source synergistic complex acaricide and preparation method thereof | |
| CN101278683A (en) | Pollution-free plant source pesticide rotenone emulsifiable solution formulation and method of preparing the same | |
| CN110833076A (en) | Rosemary essential oil microemulsion for preventing and treating plant diseases and insect pests and preparation method thereof | |
| CN104488918A (en) | Phytogenic synergistic compound insecticide containing tea polyphenol and dioscin | |
| CN101843268B (en) | Botanical synergistic compound aphicide and preparation method thereof | |
| CN103494886B (en) | Spray type beriberi liquid containing vinegar liquid and essential oil of bamboo and wood, nano-grade manufacturing method, and applications thereof | |
| CN103947655B (en) | A kind of Pesticidal combination comprising ivermectin and spiral shell mite ester | |
| CN101233856A (en) | Emamectin-benzoate and cyhalothrin microemulsion | |
| KR102099825B1 (en) | Compositions for controlling poultry red mite comprising extracts derived from natural materials and preparation method of the same | |
| CN105746584A (en) | Insecticidal composition containing metarhizium anisopliae and cyromazine and preparation method and application of insecticidal composition | |
| CN106561657B (en) | A kind of Pesticidal combination containing Celastrus angulatus and ethyl pleocidin | |
| CN106561656B (en) | A kind of Pesticidal combination containing Celastrus angulatus and multiple killing teichomycin | |
| EP0003318A2 (en) | Processing of foodstuffs and composition for the protection of microorganisms used in foodstuff-processing | |
| CN114680120A (en) | Insecticidal composition containing emamectin benzoate and cinnamaldehyde | |
| CN103931621A (en) | Pesticide composition containing tolfenpyrad and cyflumetofen | |
| CN1178580C (en) | Multiple preparation type pesticide for killing insects and acarids | |
| CN109221261A (en) | New application of the oil of badian as agricultural acaricides | |
| CN107094802A (en) | A kind of Pesticidal combination containing cyflumetofen and Celastrus angulatus | |
| CN102657215A (en) | Missible oil containing phoxim and fenvalerate and its preparation method and use | |
| CN106376571A (en) | Insecticidal composition containing celastrus angulatus and chlorantraniliprole | |
| CN106359420A (en) | Pesiticidal composition comprising dichloro oxadiazole and pyraclostrobin | |
| CN104782647A (en) | Acaricidal composition containing thiacloprid and spirodiclofen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080702 Termination date: 20180413 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |