CN100357378C - Insulating mold coating and its uses - Google Patents
Insulating mold coating and its uses Download PDFInfo
- Publication number
- CN100357378C CN100357378C CNB2005100001490A CN200510000149A CN100357378C CN 100357378 C CN100357378 C CN 100357378C CN B2005100001490 A CNB2005100001490 A CN B2005100001490A CN 200510000149 A CN200510000149 A CN 200510000149A CN 100357378 C CN100357378 C CN 100357378C
- Authority
- CN
- China
- Prior art keywords
- company
- weight parts
- agent
- byk
- thermal insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention relates to heat insulation paint which comprises the components: 15 to 65 weight parts of film forming materials, 3 to 20 weight parts of nanometer multi-hole SiO<2>, 1 to 12 weight parts of nanometer iron oxide yellow, 5 to 30 weight parts of pigments, 3 to 22 weight parts of fillers, 0.4 to 8 weight parts of auxiliary agents and 6 to 30 weight parts of solvents. The heat insulation paint can be widely applied to various devices or buildings, which need temperature reduction and heat insulation, and the heat insulation paint is especially used for outer walls, metal storage tanks, pipelines, instrument devices, transportation, industrial architecture, civil architecture, aircrafts, etc. The coating thickness of 20 mu m can obviously improve the effect of heat insulation and temperature reduction, and the optimal film thickness is from 35 to 45 mu m. The heat insulation paint has high reflectance, high heat insulation efficiency and strong ultraviolet ray resistant capability for solar heat and infrared radiation, and has the advantages of good weather resistance, strong adhesive force and high self-cleaning performance.
Description
Technical field
The present invention relates to a kind of coating, specifically relate to a kind ofly to be widely used in variously needing to lower the temperature, the novel heat-insulation coating of heat insulation device or building and uses thereof.
Background technology
The world today, human consumption sharp increase to the energy makes energy scarcity, thus the price that drives the energy and relevant series product thereof constantly raises.With China is example, and electricity consumption in recent years continues to occur nervous, total nearly 30 provincial power network power cuts to limit consumption in 2004, and a large amount of factories are forced to stop production, and cause a large amount of financial losses.The crude oil consumption of Chinese every day in 2003 increases by 440,000 barrels, and the contribution rate of global crude oil demand growth is reached 35%; To the year two thousand twenty, the following of China's Oil demand is limited to 4.5 hundred million tons, on be limited to 6.1 hundred million tons, the energy demand total amount of China will reach 2,500,000,000 tons of standard coals, this numeral exceeded 90%～152% than 2000, the interdependency of overseas source is reached more than 55% to the major general, about the same with the external interdependency of the present U.S. 58%.Though the mankind constantly attempt tapping a new source of energy, also do not find at present a kind ofly can substitute the new forms of energy that oil, coal, Sweet natural gas etc. are related to national economy fully.Therefore, how to utilize the energy, minimizing energy dissipation just to seem more important efficiently.
Cause the reason of energy dissipation a lot.With heat insulation field is example, during the broiling summer, because the radiation of the sun, the metal of petrochemical complex, brewery and cement storage tank surface temperature up to five or six ten the degree, jar in temperature in addition can be higher, not only cause a large amount of vapour loss, contaminate environment, and can cause danger.Tradition brushing silver paint and use the spray water cooling, wastes energy at etching apparatus, and service life of equipment is short, only has 1 year.The intensification of silo grain depot can be quickened the bad change of grain and infested, and is big with the air-conditioning temperature-reducing power consumption, the cost height.The plant and instrument of aircraft, factory etc. has reduced work-ing life or has reduced tolerance range owing to being subjected to thermal radiation or ir radiation, has caused waste equally.In a word, from the Industrial buildings to covil construction, from storage tank, pipeline, factory building, warehouse, plant and instrument, aircraft to residential building, the Room of selling goods, the phone Room etc. owing to the influence that raying heats up uses conventional methods cooling, all can cause the waste of great amount of manpower and material resources, financial resources.
People have early had recognized that the importance of this problem, and propose and implemented multiple terms of settlement.In existing related techniques, Chinese patent CN1204672A discloses a kind of white modified acroleic acid alcohol acids coating capable of reflecting sun-heat, but its solar heat reflection rate is low, only has 80%, and color is single, and outdoor weatherability is relatively poor.Chinese patent CN1405248A discloses a kind of acrylic resin sun-heat reflecting coating, but its sticking power is relatively poor, and shock strength is not high, and the solar heat specific absorption changes bigger in time, and does not have the performance of reflected infra-red radiation.Chinese patent CN1257897A discloses and a kind ofly can reflect solar heat, the thermal insulating coating of certain heat insulation and automatic cleaning action is arranged again, but effect is not fine.In addition, the reflective coating that Japanese Patent JP98-1209466, German patent DE 19501114, U.S. Pat 5540998, Chinese patent CN1434063A disclose, reflectivity is not high, and heat-insulating efficiency neither be fine.
Summary of the invention
The reflectivity that the objective of the invention is to overcome existing solar heat reflection paint is low, heat-insulating efficiency is not fine and color is single, outdoor weatherability and sticking power is relatively poor, shock strength is not high defective, thereby providing a kind of all has high-reflectivity, heat-insulating efficiency height, anti-uv-ray strong to solar heat and ir radiation, and the novel heat-insulation coating with super-weathering resistance, strong adhesive force and high self-cleaning performance, and uses thereof.
The objective of the invention is to realize by the following technical solutions:
Thermal insulating coating provided by the invention, its composition comprises:
Film forming matter 15～65 weight parts;
Nanoporous SiO
23～20 weight parts;
Nano iron oxide yellow 1～12 weight part;
Pigment 5～30 weight parts;
Filler 3～22 weight parts;
Auxiliary agent 0.4～8 weight part;
Solvent 6～30 weight parts;
Described film forming matter is one or more of vibrin, Synolac, Resins, epoxy, acrylic resin, aminoresin, resol, polyvinyl chloride (PVC) RESINS, organosilicon modified polyester resin, organosilicon modified crylic acid resin, silicone resin and fluorocarbon resin, according to different performance requriementss, select different resins.
Described nanoporous SiO
2Particle diameter be 10～600nm, its preparation method is as follows: add 100ml ethanol in there-necked flask, stir that to add 0.2～1.2ml concentration down be the salt solution of 0.1M and the ethanolic soln of 0.1M polymkeric substance; continue under the room temperature to stir; logical nitrogen is protected, and adds the positive tetraethyl orthosilicate (TEOS) of 0.8～4.2ml again, fully stirs 1～5h; leave standstill; use washing with alcohol after the centrifugation, repeatedly for several times, at last at 230～460 ℃ of following sintering; sieve, promptly obtain nanoporous SiO
2
Wherein, described salt is NaCl, NaI, KBr, KCl, KI, KNO
3, LiCl or CsCl;
Described polymkeric substance is R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y, z=1～65, and molar mass is 1650～2900g/mol.
The particle diameter of described nano iron oxide yellow is 10～500nm, and is disclosed among its preparation method such as the CN200410047955.3.
Described pigment is to be selected from rutile titanium white, phthalocyanine blue, phthalocyanine green, carbon black, red iron oxide, zinc-chrome yellow, medium chrome yellow medium yellow, Lemon chrome yellow, deep chrome yellow, chrome green, the molybdenum red one or more.
Described filler is one or more in zinc oxide, barium sulfate, silicon-dioxide, talcum powder, sericite, light calcium carbonate and the wollastonite powder.
Described auxiliary agent is one or more in dispersion agent, defoamer, flow agent, acid catalyst, anti-settling agent, softening agent, slip(ping)agent, thickening material and the solidifying agent;
Described dispersion agent is BYK-110, BYK-P104 or the Disperbyk-130 of German BYK Chemie company, perhaps is the Efka-766 of Dutch EFKA company, perhaps is Efka Polymer452; Described defoamer is the BYK-065 or the BYK-052 of German BYKChemie company, perhaps is the Efka-20 of Dutch EFKA company, perhaps is the Airex970 of German Tego company); Described flow agent is the BYK-354 or the BYK-300 of German BYK Chemie company, perhaps is the Efka-30 or the Efka-772 of Dutch EFKA company; Described acid catalyst is the BYK-Catalyst450 of German BYK Chemie company, perhaps is the NACURE155,1051 or K-CURE1040 of KIMG INDUSTRIES company; Described anti-settling agent is the anti-settling agent 902 or the 201P of the Taiwan modest trading company of moral, perhaps is the BORCHIGEL THIXO Z of German Bayer company; Described softening agent is the plasticizer DOP or the tributyl phosphate of Shanghai solvent factory, perhaps is the EDENOL of German Henkel company
344; Described slip(ping)agent is 840SL or the AMA that industrial corporation is changed in Taiwan three, perhaps is the A-C6 or the Acumist B-6 of Allied Signal company; Described thickening material is the DEHYSOL of German Henkel company
R or RILANIT
45; Described solidifying agent is KB, KC or the DBTDL curing catalyst of the Taiwan modest trading company of moral, perhaps is the JTY curing catalyst of Taixing, Jiangxi coatings additive(s) factory.
Described solvent is one or more in ethyl acetate, butylacetate, ethylene glycol ether acetate, dimethylbenzene, butyl glycol ether, butanols, methyl iso-butyl ketone (MIBK), propylene glycol methyl ether acetate, sherwood oil, No. 200 varnish makers' and painters' naphtha, pimelinketone, No. 100, aromatic solvent, No. 150, aromatic solvent, No. 200, aromatic solvent or the mixed dibasic acid diester.
Above-mentioned component is mixed, after disperseing, grind, mixing colours, promptly obtain thermal insulating coating of the present invention.
Thermal insulating coating provided by the invention can be widely used in various cooling, heat insulation device or the buildings of needing, especially for exterior wall, metal tank, pipeline, plant and instrument, transport trade, Industrial buildings, covil construction and aircraft etc.The coat-thickness of 20 μ m can obviously improve heat-insulating cooling effect, and best coating thickness is 35～45 μ m.
When being used for exterior wall, storage tank, pipeline, plant and instrument, aircraft etc., novel heat-insulation coating provided by the invention is formed preferred following composition:
Film forming matter 15～50 weight parts;
Nanoporous SiO
24～20 weight parts;
Nano iron oxide yellow 1～9 weight part;
Pigment 5～30 weight parts;
Filler 6～22 weight parts;
Auxiliary agent 0.4～6 weight part;
Solvent 6～25 weight parts.
Be used for factory building, warehouse, during color steel such as the Room of selling goods, the phone Room, novel heat-insulation coating provided by the invention is formed preferred following composition:
Film forming matter 20～65 weight parts;
Nanoporous SiO
23～18 weight parts;
Nano iron oxide yellow 3～12 weight parts;
Pigment 5～30 weight parts;
Filler 3～20 weight parts;
Auxiliary agent 0.6～8 weight part;
Solvent 10～30 weight parts.
Novel heat-insulation coating provided by the invention is compared with existing solar heat reflection paint, and its advantage is: paint adhesion is strong, and antiseptic property is good, good weatherability, and the scratch resistance ability is strong, both can make priming paint and also can make finish paint; And the reflective thermal radiation ability is strong, the heat-insulating efficiency height, and the coat-thickness of 20 μ m can obviously improve heat-insulating cooling effect, and best coating thickness is 35～45 μ m; In addition, this novel heat-insulation coating has good self-cleaning performance simultaneously, and reflectivity changes less in time.
Embodiment
Below in conjunction with example the present invention is further described in detail, but is not limited thereto.
Wherein, described nanoporous SiO
2Be self-control as follows: add 100ml ethanol in there-necked flask, stirring down, adding 0.2～1.2ml concentration is salt solution (NaCl, NaI, KBr, KCl, KI, the KNO of 0.1M
3, LiCl or CsCl) and 0.1M polymkeric substance (R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y; z=1～65, and molar mass is 1650～2900g/mol) ethanolic soln, continues under the room temperature to stir; logical nitrogen is protected, and adds the positive tetraethyl orthosilicate (TEOS) of 0.8～4.2ml again, fully stirs 1～5h; leave standstill; use washing with alcohol after the centrifugation, repeatedly for several times, at last at 230～460 ℃ of following sintering; sieve, promptly obtain nanoporous SiO
2
Disclosed among the preparation method of described nano iron oxide yellow such as the CN200410047955.3.
Embodiment 1, sea blue Synolac novel external wall thermal insulating coating
The prescription of sea blue Synolac novel external wall thermal insulating coating provided by the invention is listed in table 1.
The prescription of table 1, sea blue Synolac novel external wall thermal insulating coating
| Material | Specification | Consumption/Kg | Supplier |
| Synolac nanoporous SiO 2Nanometer iron oxide yellow phthalocyanine blue titanium white carbon black lead chromate yellow blanc fixe sericite wollastonite dispersant defoamer levelling agent thickener slip agent anti-settling agent plasticizer butyl acetate | SintalR05 (oil content 35%) 200nm 300nm R1216-01 BGS R960 N110 lemon chrome 501 1250m 800 orders 800 order BYK-110 BYK-065 Efka-30 DEHYSOLR MW-1875 201P DOP solvent | 25 4 1 3.8 7 0.1 0.13 3 4 2.5 0.8 0.2 0.2 0.2 0.2 0.15 0.15 10 | BYK Chemie company of BYK Chemie company of Multi Resine company self-control self-control Shenzhen Suzhou treasuredization carbon black company of Hua Su chemical company U.S. DuPont company Shanghai one Kechuang chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company Holland Shanghai solvent factory Shanghai east salt chemical engineering company of the modest trading company of Taiwan moral of the modest trading company of Taiwan moral of EFKA company Germany Henkel company |
Embodiment 2, the novel storage tank thermal insulating coating of white acrylic resin
The novel storage tank of white acrylic resin provided by the invention is listed in table 2 with the prescription of thermal insulating coating.
Table 2, the novel storage tank of the white acrylic resin prescription of thermal insulating coating
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin nanoporous SiO 2The antiseized slip agent thickener of nanometer iron oxide yellow titanium white blanc fixe sericite zinc oxide precipitated calcium carbonate dispersant defoamer acid catalyst levelling agent anti-settling agent plasticizer butyl acetate | 4404 (solid content 50 ± 1%) 300nm 350nm R960,1250 orders, 800 order A levels, 99.7% 1250 order BYK-P104 BYK-052 BYK-Catalyst450 Efka-772 840SL DEHYSOLR 201P Acumist B-6 solvent | 35 12 4 24 3 1 12 4 0.7 0.3 1.2 0.2 0.3 0.2 0.2 0.15 15 | Allied Signal company Shanghai east salt chemical engineering company of the industrial corporation Germany modest trading company of Taiwan moral of Henkel company is changed in Xinhua Resin Factory, Shanghai self-control self-control U.S. DuPont company Kechuang chemical company state sharp superfine powder company Liuzhou zinc product company state sharp superfine powder company Germany BYK Chemie company Germany BYK Chemie company Germany BYK Chemie company Holland EFKA company Taiwan three |
Embodiment 3, be used for machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating
The prescription that is used for machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating provided by the invention is listed in table 3.
Table 3, be used for the prescription of machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin nanoporous SiO 2The nanometer iron oxide yellow | 4550 (solid content 55 ± 2%) 150nm 400nm | 50 15 12 | Xinhua Resin Factory, Shanghai's self-control self-control |
| Phthalocyanine blue titanium white carbon black medium chrome yellow blanc fixe sericite wollastonite dispersant defoamer levelling agent curing agent thickener anti-settling agent plasticizer butyl acetate | R1216-01 BGS R960 N115 103 1250 orders 800 orders 800 order Disperbyk-130 Efka-20 BYK-300 DBTDL RILANIT45 BORCHIGEL THIXO Z tributyl phosphate solvents | 3.8 8 0.1 0.13 3 1 2.5 0.5 0.15 0.15 4.6 0.2 0.15 0.15 17 | The modest trading company of Shenzhen Suzhou treasuredization carbon black company of Hua Su chemical company U.S. DuPont company Shanghai one Kechuang chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company Germany BYK Chemie company Holland EFKA company Germany BYK Chemie company Taiwan moral Germany Shanghai solvent factory Shanghai east salt chemical engineering company of Henkel company Germany Bayer company |
Embodiment 4, be used for the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft
The prescription that is used for the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft provided by the invention is listed in table 4.
Table 4, be used for the prescription of the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin | AU-2608 (solid content 60%) | 30 | U.S. Rohm﹠Haas company |
| Silicone resin nanoporous SiO 2Nanometer iron oxide yellow titanium white zinc oxide sericite silicon-dioxide light calcium carbonate | MSE100 (solid content 100%) 30nm 150nm R960 A level 99.7% 800 order 800 orders 1250 orders | 12 17 10 11 3 1 3 1 | Germany Wacker company self-control self-control U.S. DuPont company Liuzhou zinc product company state sharp superfine powder company state sharp superfine powder company state sharp superfine powder company |
| Dispersant defoamer slip agent levelling agent thickener anti-settling agent plasticizer curing agent butyl acetate | Efka Polymer452 Airex970 Ceraflour960 Efka-30 RILANIT 45 902 EDENOL 344 KC solvents | 1 0.2 0.1 0.2 0.15 0.15 0.2 4 15 | The Holland modest trading company of Taiwan moral of the EFKA company Germany Tego company Germany BYK Chemie company Holland EFKA company Germany Henkel company Germany modest trading company of Taiwan moral of Henkel company Shanghai east salt chemical engineering company |
Novel heat-insulation coating to embodiment 1～4 preparation carries out performance test, lists in table 5.
Table 5, the test of novel heat-insulation coating property
| Test item | Technical indicator | Testing standard |
| Condition in container solids content % surface drying time/h time of doing solid work/h viscosity (being coated with-4 glasss/23 ℃)/s adhesive force rank resistance to water 96h acid resistance 24h5% hydrochloric acid alkali resistance 48h10%NaOH efflorescence/level (500h) variable color/level (500h) abrasion resistance/time ultraviolet resistance 2000h artificial accelerated aging 2000h thermal conductivity w/ (mk) contact angle solar reflectivity | Even no lump 〉=65≤0.5≤24 90～120 1 grades of intact unchanged 0 grade of 0 grade 〉=10000 intact unchanged paint films of paint film intact unchanged 0.048 〉=105 ° 〉=0.92 of the intact unchanged paint film of the intact unchanged paint film of paint film | The outer committee of the outer detection of entrusting of range estimation GB1725-79 (89) GB1728-79 (89) GB1728-79 (89) GB1725-99 GB1720-79 (89) actual measurement GB1763-79 (89) GB1865-79 (89) detects and surveys the detection of the outer committee of GB1865-80 (89) GB10294 actual measurement |
Embodiment 5, silver grey polyester coiled material finish paint novel heat-insulation coating
The prescription of silver grey polyester coiled material finish paint novel heat-insulation coating provided by the invention is listed in table 6.
The prescription of table 6, silver grey polyester coiled material finish paint novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Polyester resin nano porous SiO 2No. 100 ethylene glycol ether acetates of the antiseized slip agent levelling agent of nanometer iron oxide yellow titanium white carbon black iron oxide yellow phthalocyanine blue zinc oxide sericite wollastonite precipitated calcium carbonate dispersant defoamer slip agent thickener acid catalyst curing agent anti-settling agent plasticizer cyclohexane ketone aromatic solvent | Desmophen 650 (solid content 65%) 400nm 30nm R960 N115 S313 R1216-01 BGS A level, 99.7% 800 order 800 orders 1250 order Efka-766 Airex970 Ceraflour960 AMA BYK-354 RILANIT45 1051 JTY 201P EDENOL 344 solvent solvent solvents | 50 7.5 4 23 0.5 2 0.1 4 3 2 2 0.8 0.2 0.1 0.1 0.2 0.2 1.1 5 0.25 0.2 8.5 5 12 | Germany Bayer company self-control self-control U.S. DuPont Suzhou treasuredization carbon black company Shanghai one Liuzhou zinc product company of Shenzhen Hua Su chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company state sharp superfine powder company Holland EFKA company Germany Tego company Germany BYK Chemie company Taiwan three is changed Rui'an City enterprise of the modest trading company of Taiwan moral of industrial corporation Germany BYK Chemie company Germany KING INDUSTRIES company Jiangxi Taixing coating additive factory of Henkel company Germany Henkel company and is levied Yangzhou Hua Lun chemical company of chemical company Jiangsu auxiliary reagent factory |
Embodiment 6, aminoresin curing polyester coiled material novel heat-insulation coating
The prescription of aminoresin curing polyester coiled material novel heat-insulation coating provided by the invention is listed in table 7.
The prescription of table 7, aminoresin curing polyester coiled material novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Vibrin aminoresin nano porous SiO 2No. 100, No. 200 paint naphtha ethylene glycol ether acetates of nanometer iron oxide yellow titanium white zinc oxide precipitated calcium carbonate sericite dispersant defoamer acid catalyst levelling agent thickener slip agent anti-settling agent plasticizer aromatic solvent | Desmophen 1100 (solid content 100%) Resimene747 (solid content＞98%) 550nm 500nm R960 A level, 99.7% 800 order 800 order Disperbyk-130 Airex970 K-CURE1040 Efka-30 DEHYSOLR Acumist B-6 902 EDENOL 344 solvent solvent solvents | 60 5 11 5 22 3 4 4 0.8 0.2 0.3 0.2 0.2 0.1 0.15 0.15 8 12 10 | The Germany Bayer company U.S. Solutia.Inc. company self-control self-control U.S. DuPont company Liuzhou zinc product company state sharp superfine powder company state sharp superfine powder company Germany BYK Chemie company Germany modest trading company of Taiwan moral of Allied Signal company of KIMG INDUSTRIES company of Tego company Holland EFKA company Germany Henkel company Germany Henkel company Maoming City Yongjia chemical company Jiangsu auxiliary reagent factory Yangzhou Hua Lun chemical company |
Color steel to embodiment 5,6 preparations carries out performance test with novel coiled material thermal insulating coating, lists in table 8.
Table 8, the test of novel heat-insulation coating property
| Test item | Technical indicator | Testing standard |
| Fineness/μ m viscosity (being coated with-4 glasss/23 ℃)/s solid part/% curing performance/s (℃) 60 ° of gloss/% T curved shock-resistant/Kg.cm tack/anti-MEK of level pencil hardness/time salt spray resistance (2000h) wet-heat resisting (2000h) ultraviolet resistance (2000h) artificial accelerated aging (2000h) thermal conductivity w/ (mk) contact angle Solar reflectance | ≤ 20 80～110 〉=60 30～60 (224～232) (PMT) 〉=the intact unchanged paint film of the intact unchanged paint film of the intact unchanged paint film of 85≤3T 〉=80 0 〉=H 〉=120 paint films intact unchanged 0.048 〉=105 ° 〉=0.92 | GB1724-79 (89) GB1725-99 GB1725-79 (89) detects by the outer committee of the GB9754-88 of anti-solvent GB/T13448-92 ASTM2794-93 GB/T1732-93 GB/T6739-96 ASTMD5402 GB1771-91 GB/T1740-79 (89) actual measurement GB1865-80 (89) GB10294 actual measurement |
Embodiment 7, performance test 1
When the heat-proof quality of novel heat-insulation coating provided by the invention is tested, be that to be placed on wind little, fine, sun-drenched outdoor carrying out, this method is applied widely, all can test small-sized or large-scale experiment sample.
Get three blocks of sheet iron plates, size is 150mm * 150mm, wherein the surface of plate II, plate III respectively brushing thickness be the novel heat-insulation coating of the commercially available green shield solar heat reflection paint LD-RFS of 40 μ m and the embodiment of the invention 4 preparations, another piece plate I does not brush any coating in contrast.Sun-drenched outdoor the test, the surface temperature of iron sheet plate adopts infrared thermometer to measure, and temperature adopts J207-1-100 ± 0.1 a ℃ type thermometer to measure, and detects data and lists in table 9.
Table 9, sheet iron board test data
The fine wind speed of 2004-07-15≤2 grades
| Time | Temperature (℃) | Iron sheet plate I (℃) | Iron sheet plate II (℃) | Iron sheet plate III (℃) |
| 10:00 11:00 12:00 13:00 14:00 15:00 16:00 | 27.6 30.5 33.4 36.1 37.2 34.4 31.6 | 37 41.3 44.8 50.0 51.6 47.3 42.6 | 31.4 34.7 37.1 41.2 42.3 38.5 34.2 | 29.0 32.3 35.7 39.6 40.1 37.0 32.6 |
This shows, compare with the plate I that does not brush any coating, the cooling-down effect of iron sheet plate of plate II, plate III of novel heat-insulation coating of having brushed 4 preparations of commercially available green shield solar heat reflection paint LD-RFS and the embodiment of the invention is obvious, especially brushed the plate III of novel heat-insulation coating of the present invention, its effect of heat insulation is particularly evident.
And because the iron plate of test usefulness is little, influence factor is many, and flat plate radiation is fast, so the temperature difference is not very big.If the reduction influence factor is tested with the encloses container of high surface area, novel heat-insulation coating provided by the invention also can obtain more obvious cooling effect, and with to shine upon the area that contacts big more, cooling-down effect is good more.
Embodiment 8, performance test 2
The gasoline can of 200L under empty bucket condition, is used the novel heat-insulation coating brushing of the embodiment of the invention 6 preparations, numbering first bucket; Use commercially available green shield solar heat reflection paint LD-RFS brushing, numbering second bucket.Top and test with infrared thermometer apart from the staving side temperature at bottom 80cm place, all test surfaces are side to light, and temperature, staving is inner to adopt J207-1-100 ± 0.1 ℃ type thermometer test.Test result is listed in table 10.
Table 10, gasoline can test data
The fine wind speed of 2004-07-28≤2 grades
| The test duration test event | 10:00 first and second | 11:00 first and second | 12:00 first and second | 13:00 first and second | 14:00 first and second | 15:00 first and second | 16:00 first and second | |||||||
| Temperature | 28.8 | 30.5 | 32.2 | 35.0 | 36.2 | 34.4 | 33.0 | |||||||
| Side ℃ | 30.1 | 32.1 | 33.1 | 35.4 | 35.3 | 38.7 | 38.8 | 43.1 | 39.8 | 44.5 | 38.0 | 42.1 | 36.7 | 39.8 |
| Temperature head ℃ | 2.0 | 2.3 | 3.4 | 4.3 | 4.7 | 4.1 | 3.1 | |||||||
| Top ℃ | 31.5 | 34.9 | 35.6 | 39.0 | 38.9 | 42.6 | 41.6 | 46. | 42.7 | 47.9 | 42.0 | 47.0 | 40.2 | 44.4 |
| Temperature head ℃ | 3.4 | 3.4 | 3.7 | 4.5 | 5.2 | 5.0 | 4.2 | |||||||
| Inner ℃ | 29.6 | 30.4 | 31.8 | 33.1 | 34.6 | 36.7 | 36.9 | 39.6 | 39.0 | 42.5 | 36.8 | 39.9 | 35.6 | 37.9 |
| Temperature head ℃ | 0.8 | 1.3 | 2.1 | 2.7 | 3.5 | 3.1 | 2.3 | |||||||
This shows, compare that the cooling-down effect of first bucket of novel heat-insulation coating of having brushed the embodiment of the invention 6 preparations is more remarkable, and the high more cooling of sun direct projection temperature is obvious more with the second bucket of having brushed commercially available green shield solar heat reflection paint LD-RFS.
Embodiment 9, performance test 3
With certain 250m of brewery
3The empty wine jar of stainless steel uses the novel storage tank thermal insulating coating brushing of the embodiment of the invention 2 preparations, numbering first jar; The brushing of use silver powder, numbering second jar.This thermometric is under the slack tank condition, and all test surfaces are side to light; The tank surface temperature adopts the infrared thermometer test, and the tank interior temperature adopts J207-1-100 ± 0.1 ℃ thermometer test.Test result is listed in table 11.
Table 11,250m
3The empty wine jar of stainless steel test data
The fine wind speed of 2004-08-03≤2 grades
| The test duration test event | 9:00 | 10:00 | 11:00 | 12:00 | 13:00 | 14:00 | 15:00 |
| First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | |
| Temperature (℃) | 31 | 32 | 33 | 33 | 34 | 34 | 34 |
| Humidity (%) | 63 | ||||||
| The tank body side (℃) | 34.2 45.3 | 35.4 46.7 | 37 47.1 | 38 46.8 | 38.6 44.5 | 39 43.9 | 40.5 44 |
| Temperature head (℃) | 11.1 | 11.3 | 10.1 | 8.8 | 5.9 | 4.9 | 3.5 |
| The tank body end face (℃) | 37.1 54.2 | 38.5 55.6 | 41.7 59.3 | 42.3 61.9 | 43.7 66.2 | 43.2 68.3 | 44 66.6 |
| Temperature head (℃) | 15.3 | 17.1 | 17.6 | 19.6 | 22.5 | 25.1 | 22.6 |
| Tank interior apart from tank deck 1m place (℃) | 33.5 42.6 | 35.4 45.8 | 35.7 49.4 | 36.4 53.1 | 37.2 53.8 | 37.4 55.2 | 37.5 55 |
| Temperature head (℃) tank interior apart from tank deck 5m place (℃) | 9.1 32.8 41.2 | 10.4 34.6 43.4 | 13.7 34.9 44.2 | 16.7 35.5 46.4 | 16.6 36.4 48.7 | 17.8 36.8 50 | 17.5 37 51.3 |
| Temperature head (℃) | 8.4 | 8.8 | 9.3 | 10.9 | 12.3 | 13.2 | 14.3 |
| Tank interior apart from tank deck 8m place (℃) | 32.6 40.4 | 34.2 41.8 | 34.6 42.4 | 35 44.1 | 35.9 44.5 | 36 45.1 | 36.3 46.8 |
| Temperature head (℃) | 7.8 | 7.6 | 7.8 | 9.1 | 8.6 | 9.1 | 10.5 |
The test experiments data show, compare with brushing silver paint second jar, the novel storage tank of white acrylic resin of having brushed the embodiment of the invention 2 preparations is all more obvious with the first jar appearance and the internal temperature decline of thermal insulating coating, can replace the existing silver paint that is coated with fully and add the method that spray water is lowered the temperature, and long service life, greatly reduce cost.
Claims (9)
1, a kind of thermal insulating coating, its composition comprises:
Film forming matter 15～65 weight parts;
Nanoporous SiO
23～20 weight parts;
Nano iron oxide yellow 1～12 weight part;
Pigment 5～30 weight parts;
Filler 3～22 weight parts;
Auxiliary agent 0.4～8 weight part;
Solvent 6～30 weight parts;
Described film forming matter is one or more in vibrin, Synolac, Resins, epoxy, acrylic resin, aminoresin, resol, polyvinyl chloride (PVC) RESINS, organosilicon modified polyester resin, organosilicon modified crylic acid resin, silicone resin and the fluorocarbon resin;
Described filler is selected from one or more in zinc oxide, barium sulfate, silicon-dioxide, talcum powder, sericite, light calcium carbonate and the wollastonite powder;
Described auxiliary agent is one or more in dispersion agent, defoamer, flow agent, acid catalyst, anti-settling agent, softening agent, slip(ping)agent, thickening material and the solidifying agent;
Above-mentioned component is mixed, after disperseing, grind, mixing colours, promptly obtain thermal insulating coating of the present invention;
Described nanoporous SiO
2For making: in there-necked flask, add 100ml ethanol by following method; adding 0.2～1.2ml concentration under stirring is the salt solution of 0.1M and the ethanolic soln of 0.1M polymkeric substance, continues under the room temperature to stir, and logical nitrogen is protected; the positive tetraethyl orthosilicate that adds 0.8～4.2ml again; fully stir 1～5h, leave standstill, use washing with alcohol after the centrifugation; repeatedly for several times; at 230～460 ℃ of following sintering, sieve at last, promptly obtain nanoporous SiO
2
Wherein, described salt is NaCl, NaI, KBr, KCl, KI, KNO
3, LiCl or CsCl;
Described polymkeric substance is R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or be HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y, z=1～65, and molar mass is 1650～2900g/mol.
2, thermal insulating coating as claimed in claim 1 is characterized in that: described nanoporous SiO
2Particle diameter be 10～600nm.
3, thermal insulating coating as claimed in claim 1 is characterized in that: the particle diameter of described nano iron oxide yellow is 10～500nm.
4, thermal insulating coating as claimed in claim 1 is characterized in that: described pigment is to be selected from rutile titanium white, phthalocyanine blue, phthalocyanine green, carbon black, red iron oxide, zinc-chrome yellow, medium chrome yellow medium yellow, Lemon chrome yellow, deep chrome yellow, chrome green, the molybdenum red one or more.
5, thermal insulating coating as claimed in claim 1, it is characterized in that: described dispersion agent is a kind of among BYK-110, the BYK-P104 of German BYK Chemie company and the Disperbyk-130, perhaps is a kind of among the Efka-766 of Dutch EFKA company and the Efka Polymer452;
Described defoamer is a kind of among the BYK-065 of German BYK Chemie company and the BYK-052, perhaps is the Efka-20 of Dutch EFKA company, perhaps is the Airex970 of German Tego company;
Described flow agent is a kind of among the BYK-354 of German BYK Chemie company and the BYK-300; Perhaps be a kind of among the Efka-30 of Dutch EFKA company and the Efka-772;
Described acid catalyst is the BYK-Catalyst450 of German BYK Chemie company, perhaps be KIMGINDUSTRIES company NACURE155,1051 and K-CURE1040 in a kind of;
Described anti-settling agent is a kind of among the anti-settling agent 902 of the Taiwan modest trading company of moral and the 201P, perhaps is the BORCHIGEL THIXO Z of German Bayer company;
Described softening agent is a kind of in the plasticizer DOP of Shanghai solvent factory and the tributyl phosphate, perhaps is the EDENOL of German Henkel company
344;
Described slip(ping)agent is that a kind of among the 840SL of industrial corporations and the AMA changed in Taiwan three, perhaps is a kind of among the A-C6 of AlliedSignal company and the Acumist B-6;
Described thickening material is the DEHYSOL of German Henkel company
R and RILANIT
A kind of in 45;
Described solidifying agent is a kind of in KB, the KC of the Taiwan modest trading company of moral and the DBTDL curing catalyst, perhaps is the JTY curing catalyst of Taixing, Jiangxi coatings additive(s) factory.
6, thermal insulating coating as claimed in claim 1 is characterized in that: described solvent is selected from one or more in ethyl acetate, butylacetate, ethylene glycol ether acetate, dimethylbenzene, butyl glycol ether, butanols, methyl iso-butyl ketone (MIBK), propylene glycol methyl ether acetate, sherwood oil, No. 200 varnish makers' and painters' naphtha, pimelinketone, No. 100, aromatic solvent, No. 150, aromatic solvent, No. 200, aromatic solvent, the mixed dibasic acid diester.
7, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 15～50 weight parts;
Nanoporous SiO
24～20 weight parts;
Nano iron oxide yellow 1～9 weight part;
Pigment 5～30 weight parts;
Filler 6～22 weight parts;
Auxiliary agent 0.4～6 weight part;
Solvent 6～25 weight parts.
8, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 20～65 weight parts;
Nanoporous SiO
23～18 weight parts;
Nano iron oxide yellow 3～12 weight parts;
Pigment 5～30 weight parts;
Filler 3～20 weight parts;
Auxiliary agent 0.6～8 weight part;
Solvent 10～30 weight parts.
9, claim 1,7 or 8 described thermal insulating coatings variously need to lower the temperature, heat insulation device or architectural application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100001490A CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100001490A CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1800283A CN1800283A (en) | 2006-07-12 |
| CN100357378C true CN100357378C (en) | 2007-12-26 |
Family
ID=36810504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100001490A Expired - Fee Related CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100357378C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011000172A1 (en) * | 2009-07-01 | 2011-01-06 | 中山泰腾灯饰有限公司 | Diffuse reflection coating |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100371402C (en) * | 2006-10-16 | 2008-02-27 | 陈东东 | Infrared resistant coating and preparation process |
| CN100462395C (en) * | 2006-10-20 | 2009-02-18 | 南京工业大学 | Transparent heat-insulating film and its preparing process |
| CN101328377B (en) * | 2007-06-20 | 2013-03-06 | 铜联商务咨询（上海）有限公司 | Copper heat interchanger anti-corrosive paint for gas fittings and processing method thereof |
| CN101368019B (en) * | 2007-08-16 | 2011-08-31 | 张振彬 | Novel watersoluble fluorine paint |
| CN101235243B (en) * | 2008-01-23 | 2011-05-18 | 陈树望 | Multifunctional protection composite coating material |
| CN101747828B (en) * | 2008-12-15 | 2013-05-01 | 鞍钢股份有限公司 | Alcohol-based coating and preparation method thereof |
| CN102234466A (en) * | 2010-04-27 | 2011-11-09 | 北京航材百慕新材料技术工程股份有限公司 | Long-acting solar heat reflection fluorocarbon coating |
| CN102382546A (en) * | 2010-09-06 | 2012-03-21 | 张子鹏 | Special modified solvent-free epoxy paint for glass reinforced plastic |
| CN101921517B (en) * | 2010-09-08 | 2012-07-18 | 沈阳建筑大学 | Dark colour-system reflection-type outer wall thermal insulation coating and preparation method thereof |
| CN102838895A (en) * | 2011-06-23 | 2012-12-26 | 江苏考普乐新材料股份有限公司 | High performance coating composition |
| CN102337071A (en) * | 2011-10-09 | 2012-02-01 | 常州豪邦纳米科技涂料有限公司 | Priming paint for bakelite handle |
| CN103059720B (en) * | 2011-10-20 | 2015-07-08 | 无锡灵煌科技有限公司 | Preparation method of transparent thermal insulation self-cleaning coating |
| CN102492339B (en) * | 2011-12-15 | 2013-08-28 | 西南科技大学 | Preparation method for high-wave permeability super-hydrophobic moisture-proofing coating for antenna housing material |
| CN102816519A (en) * | 2012-07-25 | 2012-12-12 | 江苏科技大学 | Inorganic-organic high temperature-resistant coating and preparation method thereof |
| JP6055276B2 (en) * | 2012-11-05 | 2016-12-27 | クラリアント・インターナシヨナル・リミテツド | Black pigment composition for thermal barrier paint, thermal barrier paint using the same, and use thereof for toning and painting |
| CN103013290A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Elastic coating of heat-insulating anticorrosion external protection layer |
| CN103275535B (en) * | 2013-05-24 | 2015-12-23 | 苏州市德莱尔建材科技有限公司 | A kind of Polyvinyl chloride waterproof paint for wood material |
| CN103509462A (en) * | 2013-09-24 | 2014-01-15 | 上海纳米技术及应用国家工程研究中心有限公司 | Heat insulation coating, preparation method and application thereof |
| CN103540211A (en) * | 2013-09-30 | 2014-01-29 | 安徽华印机电股份有限公司 | Organosilicon modifying acrylic resin fireproof coating |
| CN103555023A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | High-temperature yellowing resistant impregnating varnish and preparation method thereof |
| CN103587210B (en) * | 2013-10-30 | 2015-09-23 | 溧阳市哈大成果转化中心有限公司 | The cated aircraft wing shell of a kind of tool |
| CN103694858A (en) * | 2013-11-29 | 2014-04-02 | 蚌埠市正园电子科技有限公司 | High temperature-resistant acid-resistant anti-corrosion priming paint |
| CN103694868A (en) * | 2013-11-29 | 2014-04-02 | 安徽祈艾特电子科技有限公司 | Heat-resistant and flame-retardant anti-ultraviolet aging paint |
| CN103694843A (en) * | 2013-11-29 | 2014-04-02 | 安徽祈艾特电子科技有限公司 | Environment-friendly anticorrosive yellowing-resistant amino resin paint |
| CN104693982A (en) * | 2013-12-10 | 2015-06-10 | 常州之友梦琦涂料有限公司 | Method for recycling and processing waste powder of powder coating into solvent type coating |
| CN103788810A (en) * | 2014-01-26 | 2014-05-14 | 南通苏通分离工程科技有限公司 | High temperature resistant anticorrosive paint and preparation process thereof |
| CN103756488B (en) * | 2014-01-26 | 2016-01-13 | 南通广泰生化制品有限公司 | A kind of preparation method of microporous nano coating |
| CN104119739B (en) * | 2014-06-26 | 2016-06-29 | 青岛橡胶谷知识产权有限公司 | A kind of packaging facilities coating and preparation method thereof |
| CN104194624A (en) * | 2014-09-18 | 2014-12-10 | 山东大学 | Yellow near-infrared high reflective coating and preparation method thereof |
| CN104293012A (en) * | 2014-09-26 | 2015-01-21 | 无锡七点建材有限公司 | Heat-reflecting thermal insulation coating and preparation method thereof |
| CN104327654B (en) * | 2014-10-20 | 2016-04-20 | 浙江华特实业集团华特化工有限公司 | Sun reflection thermal insulating coating and preparation method thereof |
| CN104403445A (en) * | 2014-11-14 | 2015-03-11 | 无锡中洁能源技术有限公司 | Solar cell backboard reflection paint and preparation method thereof |
| CN104327676A (en) * | 2014-11-26 | 2015-02-04 | 江苏博腾新材料股份有限公司 | Anti-scratch wall paint |
| CN104513559A (en) * | 2014-11-28 | 2015-04-15 | 蚌埠南自仪表有限公司 | Electric power equipment cabinet use anti yellowing thermal insulation noise reduction paint and preparation method thereof |
| CN104403434A (en) * | 2014-12-02 | 2015-03-11 | 苏州Ppg包装涂料有限公司 | Coating composition |
| CN104497805A (en) * | 2014-12-08 | 2015-04-08 | 成都锦汇科技有限公司 | Heat-resistant steel plate and preparation process thereof |
| CN104403521B (en) * | 2014-12-08 | 2016-12-28 | 顾玉奎 | A kind of anti weathering steel |
| CN104449260A (en) * | 2014-12-08 | 2015-03-25 | 成都锦汇科技有限公司 | Heat-resisting steel plate |
| CN104693985A (en) * | 2015-02-12 | 2015-06-10 | 福建省台华化学工业有限公司 | Solvent-type double-component coating and preparation method thereof |
| CN104877491B (en) * | 2015-06-02 | 2017-12-19 | 柳州龙溪化工有限公司 | A kind of anti-hot heat insulation type automobile paint gloss oil and metallized finish |
| CN105295688A (en) * | 2015-12-08 | 2016-02-03 | 常熟市裕茗企业管理咨询有限公司 | Displacement measurement and detection device |
| CN105400301A (en) * | 2015-12-24 | 2016-03-16 | 南京理工大学常熟研究院有限公司 | Architectural thermal insulation coating |
| CN105694545A (en) * | 2016-01-30 | 2016-06-22 | 欧阳杰 | Quantum resonance coating and construction process thereof |
| CN105862443B (en) * | 2016-05-27 | 2018-03-27 | 襄阳宏伟航空器有限责任公司 | A kind of balloon material for fire balloon and preparation method thereof |
| CN106118390A (en) * | 2016-06-29 | 2016-11-16 | 明光市永德包装有限公司 | A kind of metal packaging coating |
| CN106118467A (en) * | 2016-07-29 | 2016-11-16 | 江苏仁通节能科技有限公司 | A kind of aqueous thermal-resistant thermal insulation coatings and its preparation method and application |
| CN106147548A (en) * | 2016-08-14 | 2016-11-23 | 安庆市沁之源电器有限公司 | A kind of electric fan sound deadening coating and preparation method thereof |
| CN106047101A (en) * | 2016-08-14 | 2016-10-26 | 安庆市沁之源电器有限公司 | Gas stove anti-scratch coating and preparation method thereof |
| CN106554704A (en) * | 2016-10-08 | 2017-04-05 | 江苏大使同丰涂料有限公司 | A kind of solar energy reflective insulation coating and preparation method thereof |
| CN106634256A (en) * | 2016-10-11 | 2017-05-10 | 安徽卡塔门窗有限公司 | Aluminum alloy door-window easy to clean and preparation method of aluminum alloy door-window easy to clean |
| CN106752643A (en) * | 2016-12-17 | 2017-05-31 | 吴德炳 | A kind of insulating moulding coating and preparation method thereof |
| CN107189559B (en) * | 2017-07-16 | 2019-05-24 | 镇江市神龙电器管件有限公司 | A kind of cable testing bridge with fire-proof function |
| CN107163695A (en) * | 2017-07-16 | 2017-09-15 | 镇江市神龙电器管件有限公司 | A kind of fireproof coating for high security tray type cable bridge |
| KR101917149B1 (en) * | 2018-05-17 | 2018-11-09 | 주식회사 대수하이테크 | Anti-fouling coating composition having excellent weatherability |
| CN108610725B (en) * | 2018-06-04 | 2020-02-21 | 丹阳市银海镍铬化工有限公司 | Multi-band and multi-layer electromagnetic matching camouflage paint system and application thereof |
| CN109021638A (en) * | 2018-06-22 | 2018-12-18 | 宁波蒙曼生物科技有限公司 | A kind of low-cost environment-friendly water paint and its preparation and application |
| CN108753074A (en) * | 2018-07-13 | 2018-11-06 | 芜湖多辉建设有限公司 | A kind of heat-resistant antifriction modified on outer wall coating |
| CN109135371A (en) * | 2018-07-24 | 2019-01-04 | 张家港市五湖新材料技术开发有限公司 | A kind of formula of anti-ultraviolet coating |
| CN110396340A (en) * | 2019-08-27 | 2019-11-01 | 惠州市鸿泰建筑工程有限公司 | A kind of uvioresistant exterior coating of wet-heat resisting and preparation method thereof |
| CN110564286A (en) * | 2019-09-26 | 2019-12-13 | 青岛天地彩涂料工程应用有限公司 | self-conversion curing exterior wall coating and manufacturing method thereof |
| CN114410219A (en) * | 2021-12-08 | 2022-04-29 | 中国科学技术大学先进技术研究院 | Radiation cooling coating and preparation method thereof |
| CN114538880B (en) * | 2022-01-27 | 2024-04-12 | 环秀(青岛)建材科技有限公司 | Preparation and construction method of inorganic wear-resistant terrace coating |
| CN115181469B (en) * | 2022-09-14 | 2022-12-06 | 北京汉诺威自控技术有限公司 | Protective coating for rubber oil seal and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073700A (en) * | 1992-06-30 | 1993-06-30 | 李成章 | Novel composition of insulating mold coating |
| JPH10120946A (en) * | 1996-10-18 | 1998-05-12 | Fuji Titan Kogyo Kk | Shielding material of infrared ray |
| US6017981A (en) * | 1995-01-17 | 2000-01-25 | Hugo; Gerd | Coating material with reflective properties in two wavelength ranges, and absorbent properties in a third wavelength range |
| CN1363636A (en) * | 2001-01-02 | 2002-08-14 | 顾晓鸣 | Energy-saving ultraviolet and infrared resistant paint |
| CN1405248A (en) * | 2002-01-30 | 2003-03-26 | 北京京安固特化工有限责任公司 | Acrylic resin sun-heat reflecting coating |
| CN1552785A (en) * | 2003-06-05 | 2004-12-08 | 上海祥雅涂料有限公司 | Orthobutyl titanate modified organic specific condensate coating material and its preparation |
| KR100454110B1 (en) * | 1997-01-13 | 2005-01-15 | 주식회사 코오롱 | Preparation method of nylon film by primary coating solution comprising aqueous urethane resin, aqueous epoxy curing agent and amine-based compound, and drying, drawing to at least one direction and heat treating the coated one |
-
2005
- 2005-01-05 CN CNB2005100001490A patent/CN100357378C/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073700A (en) * | 1992-06-30 | 1993-06-30 | 李成章 | Novel composition of insulating mold coating |
| US6017981A (en) * | 1995-01-17 | 2000-01-25 | Hugo; Gerd | Coating material with reflective properties in two wavelength ranges, and absorbent properties in a third wavelength range |
| JPH10120946A (en) * | 1996-10-18 | 1998-05-12 | Fuji Titan Kogyo Kk | Shielding material of infrared ray |
| KR100454110B1 (en) * | 1997-01-13 | 2005-01-15 | 주식회사 코오롱 | Preparation method of nylon film by primary coating solution comprising aqueous urethane resin, aqueous epoxy curing agent and amine-based compound, and drying, drawing to at least one direction and heat treating the coated one |
| CN1363636A (en) * | 2001-01-02 | 2002-08-14 | 顾晓鸣 | Energy-saving ultraviolet and infrared resistant paint |
| CN1405248A (en) * | 2002-01-30 | 2003-03-26 | 北京京安固特化工有限责任公司 | Acrylic resin sun-heat reflecting coating |
| CN1552785A (en) * | 2003-06-05 | 2004-12-08 | 上海祥雅涂料有限公司 | Orthobutyl titanate modified organic specific condensate coating material and its preparation |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011000172A1 (en) * | 2009-07-01 | 2011-01-06 | 中山泰腾灯饰有限公司 | Diffuse reflection coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1800283A (en) | 2006-07-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100357378C (en) | Insulating mold coating and its uses | |
| CN101585992B (en) | Heat insulating reflecting anticorrosive paint | |
| CN103849293A (en) | Anticorrosion thermal insulation heat reflecting paint for storage tank and preparation method thereof | |
| CN101712835A (en) | Heat reflection paint with hollow glass microballoon | |
| KR101779826B1 (en) | Manufacturing method for aqueous ceramic paint for steel bridge painting and steel bridge painting method using the same | |
| CN102559024A (en) | Aqueous polyurethane heat reflection coating and application thereof | |
| CN102504673A (en) | Priming-finishing integrated rust protection paint | |
| CN102888176A (en) | Heat reflection type epoxy anti-corrosion coating | |
| CN101735699A (en) | Fluororesin modified acrylic acid durable heat-insulating anti-corrosive coating | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN102391757A (en) | Water-borne acrylic thermal insulating coating and preparation method thereof | |
| CN104140746A (en) | Composite type functional infrared reflection engineering machine powder coating and production technology thereof | |
| CN110527370A (en) | A kind of polyurea modified fluorine carbon reflective heat-insulation paint and preparation method thereof | |
| CN101693801A (en) | Rare earth modification exterior wall water-borne fluorocarbon coating and preparation method thereof | |
| CN112375483A (en) | Long-acting heavy-duty reflective heat-insulating coating and preparation method thereof | |
| CN1434063A (en) | Aqueous epoxy modified acrylic heat-reflecting thermo-insulating coating | |
| CN110964388A (en) | Polyurea modified anti-pollution coating and preparation method and application thereof | |
| CN113736333B (en) | Cerium oxide reflective heat-insulation coating and preparation method thereof | |
| CN1176119C (en) | Nanometer acrylic acid microemulsion, water-thinned heat reflecting and isolating paint and their production process | |
| CN109971319A (en) | A kind of weather-proof anticorrosion polyester type powder paint containing glass fibre and clay mineral | |
| CN102702867B (en) | Modified high chlorinated polythene long-acting anti-corrosive paint and preparation method thereof | |
| CN107523187B (en) | Enhanced thermal insulation reflective coating | |
| CN101130662A (en) | Aquosity metallic protective paint and method for producing the same | |
| CN105238151A (en) | Environment-friendly marine coating and manufacturing method thereof | |
| CN101585996B (en) | Heat reflecting ship hull paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071226 Termination date: 20220105 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |