CN102504673A - Priming-finishing integrated rust protection paint - Google Patents
Priming-finishing integrated rust protection paint Download PDFInfo
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- CN102504673A CN102504673A CN2011103745188A CN201110374518A CN102504673A CN 102504673 A CN102504673 A CN 102504673A CN 2011103745188 A CN2011103745188 A CN 2011103745188A CN 201110374518 A CN201110374518 A CN 201110374518A CN 102504673 A CN102504673 A CN 102504673A
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Abstract
The invention relates to priming-finishing integrated rust protection paint which comprises the following components by part by weight: 20 to 60 parts of epoxy ester resin, 5 to 40 parts of anti-corrosion pigment, 10 to 55 parts of anti-corrosion filling material, 1 to 30 parts of solvent, and 0.01 to 10 parts of additive. Compared with the prior art, the invention has the advantages as follows: 1, the classification of priming paint and finishing paint is broken through, and the integration of the priming paint and the finishing paint is realized, so as to facilitate construction; 2, the rust protection performance is good; and 3, the traditional epoxy ester coating is lusterless coating material, while the priming-finishing integrated rust protection paint has high glossiness, can be used as the finishing paint and has a better decoration effect.
Description
Technical field
The present invention relates to paint field, particularly, the present invention relates to a kind of bottom surface unification rust-inhibiting paint.
Background technology
The corrosion of various items is from the medium that is contacted, and the one, natural condition form, and mainly are meant atmosphere, water, soil and seawater etc.; Other are the corrosive mediums that produce in the industrial production, for example acid, alkali, salt and various organic cpds.Etching condition is that the composite factor by complicacy constitutes, and like the contaminated big G&W in manufacturing district, contains the soil of soda acid etc., and the corrosion of existing natural condition has the corrosion of the medium that production process produces again.
Protective system is to be used in body surface can be used for protecting interior of articles not receive one type of coating of corrosive.Anticorrosive coating is that departments such as modern industry, traffic, the energy, oceanographic engineering use a kind of very widely function (special type) property coating.By the corrosion-resistant degree and the request for utilization of its coating rete, usually anticorrosive coating is divided into two types of universal (or light-duty) and heavy anti-corrosive types, there is the people also to propose one type of overweight anti-corrosive type recently.According to the situation of environment for use corrosive medium, select dissimilar anticorrosive coatings for use.Anticorrosive coating is a veriety of coating, and therefore, it also should possess following characteristics except basic physics with coating, mechanical property:
(1) high anti-corrosion: be not corroded medium swelling, dissolving, destruction, decomposition are in steady state;
(2) high-weatherability: adapt to the outdoor environment variation of temperature and have ultraviolet light ability preferably;
(3) high-durability: coating long service life;
(4) it is thicker to be coated with rete.Coating ventilation property and water permeability are little.Coat-thickness is generally: universal 150 μ m~200 μ m, heavy anti-corrosive type 200 μ m~300 μ m, overweight anti-corrosive type 300 μ m~500 μ m;
(5) workability and matching performance preferably.
At present, domestic existing anticorrosive coating system adopts the composite anti-corrosive coating system of priming paint, intermediate coat, finish paint or priming paint and finish paint mostly.The main effect of priming paint is on ground, to lay a solid foundation, and ground is had good adhesion, has rustless property; The main effect of intermediate coat is to increase thickness, thereby plays more efficiently shielding effect, also will make surfacing, helps the finish paint application; The finish paint significant feature is to prevent deleterious corrosive medium in the external environment, like the influence of oxygen, steam, sulfur monoxide and chemical atmosphere, has attractive, decorative property simultaneously.
But these two kinds of composite anti-corrosive coating system long construction periods, operation sequence is complicated, and the cost cost is higher, also need consider respectively to be coated with the matching capacity problem of interlayer simultaneously, in case the interlayer combination is bad, matching capacity is bad, causes whole coating system downgrade.Therefore the primer-topcoat integrated anticorrosive lacquer obtains more research in recent years.
CN 102108250A provides a kind of water-based primer-topcoat integrated anticorrosive lacquer, comprises following component in percentage by weight: waterborne polyurethane modified epoxy resin 20%~60%, deionized water 5%~25%, dispersion agent 0.5%~5%; Skimmer 0.1%~5%, base material wetting agent 0.1%~5%, color stuffing are 10%~40%; PH regulator agent 0.5%~10%; Thixotropic agent 0.5%~10%, film coalescence aid 0.5%~5%, photostabilizer 1%~5%; Dodge corrosion inhibitor 0.5%~5%, salt spray resistance auxiliary agent 0%~10%.
CN 101864236A discloses a kind of aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish.Be that component by following weight part constitutes: aqueous acrylic modified epoxy ester resin 45-65; Aminoresin 2-20; Pigment 5-35; Filler 0-15; Aqueous dispersion type siccative 1-3; PH regulator agent 0.1-0.55; Softening water 5-15; Dispersion agent 0.2-0.4 part; Wetting agent 0.3-0.5 part, flow agent 0.15-0.25 part, skimmer 0.3-0.5 part, sanitas and mould inhibitor 0.2-0.3 part.
CN 101838489A discloses a kind of primer-topcoat integrated anticorrosive lacquer, comprises 20~30 parts of HCPEs, 10~20 parts of chlorinated rubber resins, 10~20 parts of maleficent acid resins, 6~10 parts of epoxy resin, 20~40 parts of YLENE, 10~15 parts of N-BUTYL ACETATEs, 8~15 parts of white titanium pigments, 8~15 parts of aluminium triphosphates, 3~10 parts in softening agent, 2~7 parts of UV light absorbers.
Bottom surface unification rust-inhibiting paint not only serves as priming paint but also serve as finish paint, therefore requires it to have excellent rustless property and higher glossiness, but existing bottom surface unification rust-inhibiting paint far can not reach this requirement.
Summary of the invention
To the deficiency of prior art, one of the object of the invention is to provide a kind of bottom surface unification rust-inhibiting paint.Said bottom surface unification rust-inhibiting paint comprises following component according to parts by weight:
Preferably, said bottom surface unification rust-inhibiting paint comprises following component according to parts by weight:
Preferably; Said anti-corrosion paint is a kind or at least 2 kinds combination in red lead, modification barium borate, chromate pigment, zn phosphate, iron mica, iron oxide red powder, basic lead chromate silicate, poly aluminium phosphate, zinc molybdate, zinc borate, other phosphoric acid salts and phosphorous rust-stabilising pigment, cyanogen amination lead, cyanogen amination zinc, IX rust-stabilising pigment, glass flake, the aluminum paste; Said combination typical case but the example of non-limit have: the combination of red lead, modification barium borate; The combination of zn phosphate, iron oxide red powder, basic lead chromate silicate; The combination of poly aluminium phosphate, zinc molybdate; The combination of phosphoric acid salt, cyanogen amination zinc, the combination of iron oxide red powder, glass flake, aluminum paste, the combination of IX rust-stabilising pigment, glass flake etc.; Further preferred said protective system is a kind or at least 2 kinds combination in modification barium borate, zn phosphate, iron oxide red powder, poly aluminium phosphate, zinc molybdate, zinc borate, other phosphoric acid salts and phosphorous rust-stabilising pigment, cyanogen amination zinc, IX rust-stabilising pigment, glass flake, the aluminum paste; More preferably iron oxide red powder and/or aluminum paste, preferred especially iron oxide red powder and/or non-floating type aluminum paste.
Preferably; Said anticorrosive packing is a kind or at least 2 kinds combination in kaolin, silica powder, WHITE CARBON BLACK, talcum powder, mica powder, sericite in powder, process white, the wilkinite; Said combination typical case but the instance of non-limit have: the combination of kaolin, silica powder; The combination of WHITE CARBON BLACK, talcum powder, mica powder; Sericite in powder, process white, bentonitic combination, the combination of talcum powder, sericite in powder, process white etc. further are preferably a kind or at least 2 kinds combination in talcum powder, sericite in powder, the process white.
Further preferred, said bottom surface unification rust-inhibiting paint comprises following component according to parts by weight:
More preferably, said bottom surface unification rust-inhibiting paint comprises following component according to parts by weight:
Preferably, said solvent is a kind or at least 2 kinds combination in alcohols, ester class, ethers, aromatics, the ketone, further is preferably C
1-C
10Alcohols, C
2-C
10Ethers, benzene class, C
3-C
101 kind or at least 2 kinds combination in the ketone; 1 kind in mibk, YLENE, propylene glycol monomethyl ether, pimelinketone, Benzene Chloride, toluene, ethanol, butanols, the methylethylketone or at least 2 kinds combination more preferably; Said combination typical case but the instance of non-limit have: the combination of mibk, YLENE, propylene glycol monomethyl ether; The combination of pimelinketone, toluene, Benzene Chloride, the combination of butanols, methylethylketone etc. are preferably pimelinketone and/or YLENE especially.
Preferred especially, said bottom surface unification rust-inhibiting paint comprises following component according to parts by weight:
One of ordinary skill in the art can add other auxiliary agent according to the expertise of its grasp in said bottom surface unification rust-inhibiting paint; For example; 1 kind or at least 2 kinds combination in dispersion agent, flow agent, skimmer, anti, solidifying agent, softening agent, antistatic agent, the ultraviolet absorbers; It makes up the typical case but the instance of non-limit has: the combination of dispersion agent, flow agent, skimmer, anti; The combination of dispersion agent, flow agent, skimmer, ultraviolet absorbers etc.; Contain a kind or at least 2 kinds combination in dispersion agent, flow agent, skimmer, the anti in further preferred said other auxiliary agent, preferred especially said other auxiliary agent contains dispersion agent, flow agent, skimmer, anti.
Preferably, said non-floating type aluminum paste is below 1000 orders, and like 900 orders, 850 orders, 490 orders, 450 orders, 300 orders etc., further preferred said non-floating type aluminum paste is below 500 orders, and more preferably 100 orders~300 orders are preferably 250 orders especially.
Preferably; Said sericite in powder is more than 100 orders, like 100 orders, 150 orders, 200 orders, 350 orders, 800 orders, 850 orders, 900 orders, 950 orders, 1000 orders etc., further is preferably 300 orders~700 orders; More preferably 300 orders~500 orders are preferably 400 orders especially.
Preferably, said talcum powder is more than 100 orders, like 100 orders, 150 orders, 200 orders, 350 orders, 800 orders, 850 orders, 900 orders, 950 orders, 1000 orders etc., further is preferably 300 orders~700 orders, and more preferably 300 orders~500 orders are preferably 400 orders especially.
Preferably, said process white is more than 500 orders, like 550 orders, 600 orders, 650; Order, 700 orders, 750 orders, 1600 orders, 1700 orders, 1800 orders, 1900 orders, 1950 orders etc.; Further be preferably 800 orders~2000 orders, more preferably 1000 orders~1500 orders are preferably 1250 orders especially.
Raw material described in the present invention all can obtain through commercially available, and those skilled in that art can prepare through the technology/new technology of its grasp.
One of the object of the invention also is to provide a kind of purposes of said bottom surface unification rust-inhibiting paint.
Said bottom surface unification rust-inhibiting paint is preferred for the X-former tailor-made paint.
Unification rust-inhibiting paint in bottom surface according to the invention all is the method preparations according to the prior art record, for example obtains through simple hybrid technique.
Unification rust-inhibiting paint in bottom surface according to the invention can use separately, also can be used with other coating.
Compared with prior art, unification rust-inhibiting paint in bottom surface according to the invention has following characteristics:
(1) breaks through the classification that coat with lacquer the bottom surface, realize bottom surface lacquer two-in-one, convenient construction;
(2) good antirust property;
(3) traditional epoxy ester coating is matt(e)coating, and this project product glossiness is high, can be used as finish paint and uses, and has ornamental preferably.
Embodiment
For ease of understanding the present invention, it is following that the present invention enumerates embodiment.Those skilled in the art should understand, and said embodiment helps to understand the present invention, should not be regarded as concrete restriction of the present invention.
Embodiment one
Than preparation bottom surface unification rust-inhibiting paint, its composition according to parts by weight is according to following set of dispense:
Embodiment two
Than preparation bottom surface unification rust-inhibiting paint, its composition according to parts by weight is according to following set of dispense:
Embodiment three
Than preparation bottom surface unification rust-inhibiting paint, its composition according to parts by weight is according to following set of dispense:
Embodiment four
Than preparation bottom surface unification rust-inhibiting paint, its composition according to parts by weight is according to following set of dispense:
Embodiment five
Than preparation bottom surface unification rust-inhibiting paint, its composition according to parts by weight is according to following set of dispense:
Above embodiment all is the method preparations according to the prior art record, for example obtains through simple hybrid technique.
With embodiment one~embodiment five preparation bottom surfaces unifications rust-inhibiting paint according to standard: HG/T 2244-1991 " lathe priming paint " tests, and the result is following:
Applicant's statement; The present invention explains detailed process equipment of the present invention and technical process through the foregoing description; But the present invention is not limited to above-mentioned detailed process equipment and technical process, does not mean that promptly the present invention must rely on above-mentioned detailed process equipment and technical process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
3. according to claim 1 or claim 2 bottom surface unification rust-inhibiting paint; It is characterized in that; Said anti-corrosion paint is preferably a kind or at least 2 kinds combination in red lead, modification barium borate, chromate pigment, zn phosphate, iron mica, iron oxide red powder, basic lead chromate silicate, poly aluminium phosphate, zinc molybdate, zinc borate, other phosphoric acid salts and phosphorous rust-stabilising pigment, cyanogen amination lead, cyanogen amination zinc, IX rust-stabilising pigment, glass flake, the aluminum paste; Further preferred said protective system is a kind or at least 2 kinds combination in modification barium borate, zn phosphate, iron oxide red powder, poly aluminium phosphate, zinc molybdate, zinc borate, other phosphoric acid salts and phosphorous rust-stabilising pigment, cyanogen amination zinc, IX rust-stabilising pigment, glass flake, the aluminum paste; More preferably iron oxide red powder and/or aluminum paste, preferred especially iron oxide red powder and/or non-floating type aluminum paste;
Preferably; Said anticorrosive packing is a kind or at least 2 kinds combination in kaolin, silica powder, WHITE CARBON BLACK, talcum powder, mica powder, sericite in powder, process white, the wilkinite, further is preferably a kind or at least 2 kinds combination in talcum powder, sericite in powder, the process white.
6. like each described bottom surface unification rust-inhibiting paint of claim 1-5, it is characterized in that said solvent is preferably a kind or at least 2 kinds combination in alcohols, ester class, ethers, aromatics, the ketone, further is preferably C
1-C
10Alcohols, C
2-C
10Ethers, benzene class, C
3-C
101 kind or at least 2 kinds combination in the ketone, more preferably a kind in mibk, YLENE, propylene glycol monomethyl ether, pimelinketone, Benzene Chloride, toluene, ethanol, butanols, the methylethylketone or at least 2 kinds combination are preferably pimelinketone and/or YLENE especially.
8. like each described bottom surface unification rust-inhibiting paint of claim 1-7; It is characterized in that; Said other auxiliary agents preferably contain a kind or at least 2 kinds combination in dispersion agent, flow agent, skimmer, anti, solidifying agent, softening agent, antistatic agent, the ultraviolet absorbers; Contain a kind or at least 2 kinds combination in dispersion agent, flow agent, skimmer, the anti in further preferred said other auxiliary agent, preferred especially said other auxiliary agent contains dispersion agent, flow agent, skimmer, anti.
9. like each described bottom surface unification rust-inhibiting paint of claim 1-7; It is characterized in that said non-floating type aluminum paste is preferably below 1000 orders, further preferred said non-floating type aluminum paste is below 500 orders; More preferably 100 orders~300 orders are preferably 250 orders especially;
Preferably, said sericite in powder is more than 100 orders, further is preferably 300 orders~700 orders, and more preferably 300 orders~500 orders are preferably 400 orders especially;
Preferably, said talcum powder is more than 100 orders, further is preferably 300 orders~700 orders, and more preferably 300 orders~500 orders are preferably 400 orders especially;
Preferably, said process white is more than 500 orders, further is preferably 800 orders~2000 orders, and more preferably 1000 orders~1500 orders are preferably 1250 orders especially.
10. the purposes like the said bottom surface unification of claim 1-9 rust-inhibiting paint is characterized in that, said bottom surface unification rust-inhibiting paint is preferably used as the X-former tailor-made paint.
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Cited By (18)
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CN102719153A (en) * | 2012-06-28 | 2012-10-10 | 福建百花化学股份有限公司 | Reflective heat insulation coating and preparation method thereof |
CN103509415A (en) * | 2012-06-26 | 2014-01-15 | 禹州市金彩家纳米乳胶漆有限公司 | Aqueous acrylic acid flashrust resistance bottom surface two-in-one antirust paint |
CN103525145A (en) * | 2013-09-28 | 2014-01-22 | 芜湖中集瑞江汽车有限公司 | Basic lead silicochromate anti-rust paint and preparation method thereof |
CN103666192A (en) * | 2013-11-07 | 2014-03-26 | 安徽省智汇电气技术有限公司 | Multifunctional anti-rust paint and preparation method thereof |
CN103694876A (en) * | 2013-12-12 | 2014-04-02 | 青岛海洋新材料科技有限公司 | Marine anticorrosive paint |
CN104059511A (en) * | 2013-03-18 | 2014-09-24 | 福建省腾龙工业公司 | Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof |
CN104231868A (en) * | 2014-09-19 | 2014-12-24 | 苏州云舒新材料科技有限公司 | High-temperature-resistant heavy-duty corrosion-resistant intermediate paint and preparation method thereof |
CN104449166A (en) * | 2014-11-21 | 2015-03-25 | 无锡市虎皇漆业有限公司 | Single-component primer-topcoat paint commonly used on stainless steel, galvanized sheet and aluminum alloy and preparation method of single-component primer-topcoat paint commonly used on stainless steel, galvanized sheet and aluminum alloy |
CN104830204A (en) * | 2015-05-22 | 2015-08-12 | 山东奔腾漆业股份有限公司 | High-performance low-VOC industrial anticorrosive coating and preparation method thereof |
CN105086752A (en) * | 2015-08-05 | 2015-11-25 | 安徽岍汧漆业有限公司 | Antifouling iron red epoxy antirust paint and preparation method thereof |
CN105086751A (en) * | 2015-08-05 | 2015-11-25 | 安徽岍汧漆业有限公司 | Quick-drying and rapid-hardening epoxy mica iron rust preventing paint and preparing method thereof |
CN105925147A (en) * | 2016-06-12 | 2016-09-07 | 欧振云 | Multifunctional epoxy corrosion-resistant coating |
CN106085107A (en) * | 2016-06-14 | 2016-11-09 | 平高集团有限公司 | A kind of epoxy coating and preparation method thereof, coating process |
CN106366847A (en) * | 2016-08-29 | 2017-02-01 | 江南载福粉末涂料(张家港)有限公司 | Outdoor paint with extra weather resistance and corrosion resistance |
CN107163781A (en) * | 2017-06-15 | 2017-09-15 | 苏州莱特复合材料有限公司 | A kind of preparation method that coating is lost for steel surface fire retardant, anticorrosive |
CN108250876A (en) * | 2017-12-13 | 2018-07-06 | 中国特种飞行器研究所 | A kind of black brake baking vanish of bottom surface unification and preparation method thereof |
WO2019052071A1 (en) * | 2017-09-14 | 2019-03-21 | 常熟市方塔涂料化工有限公司 | Energy-saving and efficiency-increasing primer-topcoat anti-corrosion coating and preparation method therefor |
CN114921143A (en) * | 2022-06-09 | 2022-08-19 | 广东天朗化工实业有限公司 | Water-based antirust primer-topcoat paint and preparation method and application thereof |
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CN103666192A (en) * | 2013-11-07 | 2014-03-26 | 安徽省智汇电气技术有限公司 | Multifunctional anti-rust paint and preparation method thereof |
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CN105925147A (en) * | 2016-06-12 | 2016-09-07 | 欧振云 | Multifunctional epoxy corrosion-resistant coating |
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CN106366847A (en) * | 2016-08-29 | 2017-02-01 | 江南载福粉末涂料(张家港)有限公司 | Outdoor paint with extra weather resistance and corrosion resistance |
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CN114921143A (en) * | 2022-06-09 | 2022-08-19 | 广东天朗化工实业有限公司 | Water-based antirust primer-topcoat paint and preparation method and application thereof |
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Application publication date: 20120620 |