CN104194539A - Impact resistant coating with strong adhesive force - Google Patents
Impact resistant coating with strong adhesive force Download PDFInfo
- Publication number
- CN104194539A CN104194539A CN201410508989.7A CN201410508989A CN104194539A CN 104194539 A CN104194539 A CN 104194539A CN 201410508989 A CN201410508989 A CN 201410508989A CN 104194539 A CN104194539 A CN 104194539A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive force
- resistant coating
- impact resistant
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 15
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 15
- 238000000576 coating method Methods 0.000 title abstract description 12
- 239000011248 coating agent Substances 0.000 title abstract description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- 210000003298 dental enamel Anatomy 0.000 claims description 12
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 4
- 229920000137 polyphosphoric acid Polymers 0.000 abstract description 4
- 239000004113 Sepiolite Substances 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000007822 coupling agent Substances 0.000 abstract description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 229910052624 sepiolite Inorganic materials 0.000 abstract description 2
- 235000019355 sepiolite Nutrition 0.000 abstract description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 125000006267 biphenyl group Chemical group 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an impact resistant coating with strong adhesive force. The impact resistant coating comprises the following raw materials in parts by weight: 80 to 83 parts of acrylic resin, 23 to 26 parts of ABS resin, 15 to 18 parts of ketoaldehyde resin KR-120, 4 to 5 parts of lignin fiber, 3.2 to 3.6 parts of sodium stearate, 6.5 to 7 parts of sodium hexametaphosphate, 1.8 to 2.1 parts of a titanate coupling agent, 9 to 12 parts of nano-TiO2, 4 to 5 parts of organic bentonite, 14 to 17 parts of nano sepiolite powder, 25 to 28 parts of talcum powder, 6 to 9 parts of triphenyl phosphine, 12 to 15 parts of polyphosphoric acid, 28 to 31 parts of nano-magnesium hydroxide, 5.2 to 5.6 parts of a flexibilizer, 1.2 to 1.5 parts of a curing agent, 1.5 to 1.8 parts of a defoaming agent, 1.6 to 1.9 parts of a leveling agent, 1 to 1.3 parts of a mildew preventive, 2.2 to 2.5 parts of pigment and 65 to 70 parts of a solvent.
Description
Technical field
The present invention relates to technical field of coatings, relate in particular to a kind of high adhesive force stamping enamel.
Background technology
Coating is coated in after building surface, has function attractive in appearance, and coating, in the middle of application, has proposed very high requirement to the shock-resistance of coating and sticking power.Under atrocious weather, along with rainwater is continual, coating top layer is scrubbed, if paint adhesion is poor, coating can produce fade, problems of crack.Shock-resistance is poor, along with fraction time and extend, the performance of coating also can change.Affect the normal function of coating.Need to find now a kind of shock-resistant and coating high adhesive force that has.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of high adhesive force stamping enamel, has good sticking power and impact resistance, and fire retardancy and corrosion resistance outstanding.
A kind of high adhesive force stamping enamel that the present invention proposes, its raw material comprises by weight:
Preferably, in ABS resin, the content of divinyl is 20-23wt%.
Preferably, the weight ratio of acrylic resin, ABS resin and ketone resin KR-120 is 81-82:24-25:16-17.
Preferably, its raw material comprises by weight:
The present invention is usingd ABS resin, ketone resin KR-120 and acrylic resin blending and modifying as major ingredient, make the present invention there is excellent glossiness, sticking power, levelling property and weathering resistance, corrosion-resistant, oil resistant, cold tolerance have also been improved, and make hardness of the present invention and toughness reach balance, there is larger shock-resistant ability; Nano titanium oxide, organobentonite, nanometer sepiolite powder, talcum powder and nano-sized magnesium hydroxide add in major ingredient and solvent, by assisting of Sodium hexametaphosphate 99 and sodium stearate, can be dispersed in uniformly between major ingredient molecule, by titanate coupling agent, make each component compatibility of raw material good again, significantly improve high temperature resistant, corrosion resistant performance of the present invention, and hydrophobic nature is good, can be widely used in anticorrosion, the leakproof of anticorrosion and ground, the drainage tray etc. of bridge, storage tank, various steel construction pieces; And diphenyl phosphoester, polyphosphoric acid amine, nano-sized magnesium hydroxide coordinate and form flame-retardant system, wherein polyphosphoric acid amine is as phosphorus-nitrogen containing flame retardant, diphenyl phosphoester is as phosphorus flame retardant, the two cooperation has significantly improved oxygen index of the present invention, improve flame retardant properties of the present invention, and nano-sized magnesium hydroxide can decompose generation magnesium oxide and water in the process of burning, not only can suppress smog in combustion processes and form, and magnesium oxide coordinates with diphenyl phosphoester, polyphosphoric acid amine and can further improve heat-resisting and flame retardant properties of the present invention.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of high adhesive force stamping enamel that the present invention proposes, its raw material comprises by weight:
Wherein in ABS resin, the content of divinyl is 20wt%.
Embodiment 2
A kind of high adhesive force stamping enamel that the present invention proposes, its raw material comprises by weight:
Wherein in ABS resin, the content of divinyl is 23wt%.
Embodiment 3
A kind of high adhesive force stamping enamel that the present invention proposes, its raw material comprises by weight:
Wherein in ABS resin, the content of divinyl is 22wt%.
Embodiment 4
A kind of high adhesive force stamping enamel that the present invention proposes, its raw material comprises by weight:
Wherein in ABS resin, the content of divinyl is 21wt%.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; according to technical scheme of the present invention and inventive concept thereof, be equal to replacement or changed, within all should being encompassed in protection scope of the present invention.
Claims (4)
1. a high adhesive force stamping enamel, is characterized in that, its raw material comprises by weight:
2. high adhesive force stamping enamel according to claim 1, is characterized in that, in ABS resin, the content of divinyl is 20-23wt%.
3. according to high adhesive force stamping enamel described in claim 1 or 2, it is characterized in that, the weight ratio of acrylic resin, ABS resin and ketone resin KR-120 is 81-82:24-25:16-17.
4. according to high adhesive force stamping enamel described in claim 1-3 any one, it is characterized in that, its raw material comprises by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410508989.7A CN104194539B (en) | 2014-09-28 | 2014-09-28 | A kind of high adhesive force stamping enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410508989.7A CN104194539B (en) | 2014-09-28 | 2014-09-28 | A kind of high adhesive force stamping enamel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104194539A true CN104194539A (en) | 2014-12-10 |
| CN104194539B CN104194539B (en) | 2016-04-20 |
Family
ID=52079917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410508989.7A Active CN104194539B (en) | 2014-09-28 | 2014-09-28 | A kind of high adhesive force stamping enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104194539B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861813A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High tenacity high adhesive force decontaminating coating |
| CN104895297A (en) * | 2015-05-29 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Anti-bacterial, anti-static and anti-corrosive rubber floor |
| CN110142841A (en) * | 2019-05-21 | 2019-08-20 | 临沂优彩新能源环保科技有限公司 | A kind of home decoration plate and coating process |
| CN110484071A (en) * | 2019-08-29 | 2019-11-22 | 河南浩丰铝业科技发展有限公司 | A kind of aluminum paste metallic paint and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001049779A2 (en) * | 2000-01-07 | 2001-07-12 | Rathor Ag | Composition which can be foamed from a pressurized container for producing insulating foams |
| CN1397614A (en) * | 2002-08-15 | 2003-02-19 | 东莞东成发化工有限公司 | Plastic paint and its preparing process |
| CN102977665A (en) * | 2012-11-02 | 2013-03-20 | 铜陵市明诚铸造有限责任公司 | Metal antirust paint containing modified pure acrylic emulsion, and its preparation method |
| CN103319983A (en) * | 2013-05-31 | 2013-09-25 | 安徽国电能源设备工程有限公司 | Powder paint with high bending resistance |
| CN104024343A (en) * | 2011-10-05 | 2014-09-03 | 水晶美国股份公司 | Infrared-reflective clusters |
| CN104046175A (en) * | 2014-06-22 | 2014-09-17 | 青岛启源振东电气有限公司 | Fireproof coating material |
-
2014
- 2014-09-28 CN CN201410508989.7A patent/CN104194539B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001049779A2 (en) * | 2000-01-07 | 2001-07-12 | Rathor Ag | Composition which can be foamed from a pressurized container for producing insulating foams |
| CN1397614A (en) * | 2002-08-15 | 2003-02-19 | 东莞东成发化工有限公司 | Plastic paint and its preparing process |
| CN104024343A (en) * | 2011-10-05 | 2014-09-03 | 水晶美国股份公司 | Infrared-reflective clusters |
| CN102977665A (en) * | 2012-11-02 | 2013-03-20 | 铜陵市明诚铸造有限责任公司 | Metal antirust paint containing modified pure acrylic emulsion, and its preparation method |
| CN103319983A (en) * | 2013-05-31 | 2013-09-25 | 安徽国电能源设备工程有限公司 | Powder paint with high bending resistance |
| CN104046175A (en) * | 2014-06-22 | 2014-09-17 | 青岛启源振东电气有限公司 | Fireproof coating material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861813A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High tenacity high adhesive force decontaminating coating |
| CN104895297A (en) * | 2015-05-29 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Anti-bacterial, anti-static and anti-corrosive rubber floor |
| CN110142841A (en) * | 2019-05-21 | 2019-08-20 | 临沂优彩新能源环保科技有限公司 | A kind of home decoration plate and coating process |
| CN110484071A (en) * | 2019-08-29 | 2019-11-22 | 河南浩丰铝业科技发展有限公司 | A kind of aluminum paste metallic paint and preparation method thereof |
| CN110484071B (en) * | 2019-08-29 | 2021-05-04 | 河南浩丰铝业科技发展有限公司 | Aluminum paste metal coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104194539B (en) | 2016-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sheng Shiyong Inventor before: Hu Changti |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170608 Address after: Room 303, innovation building, Science Park, Anhui University, 2 Tianda Road, Hefei hi tech Zone, Anhui, 230088 Patentee after: Hefei gather HowNet Information Technology Co., Ltd. Address before: Wuhu County Industrial Park, 241100 Anhui Huaqiao city in Wuhu Province Patentee before: WUHU SHUANGBAO BUILDING MATERIAL CO., LTD. |
|
| CB03 | Change of inventor or designer information |
Inventor after: Liu Shanjiang Inventor after: Liu Zhanchuan Inventor after: Mei Shaofeng Inventor after: Hu Zhongyuan Inventor after: Dong Lizhi Inventor before: Sheng Shiyong |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171024 Address after: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1 Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: Room 303, innovation building, Science Park, Anhui University, 2 Tianda Road, Hefei hi tech Zone, Anhui, 230088 Patentee before: Hefei gather HowNet Information Technology Co., Ltd. |
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| TR01 | Transfer of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20160420 |
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| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20160420 |
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| PD01 | Discharge of preservation of patent |