CN104356901A - Easily-cured flame-retardant corrosion-resistant coating - Google Patents
Easily-cured flame-retardant corrosion-resistant coating Download PDFInfo
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- CN104356901A CN104356901A CN201410571073.6A CN201410571073A CN104356901A CN 104356901 A CN104356901 A CN 104356901A CN 201410571073 A CN201410571073 A CN 201410571073A CN 104356901 A CN104356901 A CN 104356901A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an easily-cured flame-retardant corrosion-resistant coating. The easily-cured flame-retardant corrosion-resistant coating comprises the following raw materials in part by weight: 50-53 parts of glycerol alkyd resin, 45-48 parts of melamine formaldehyde resin, 5-8 parts of terpene resin, 5-6 parts of nano-montmorillonite, 17-20 parts of sepiolite powder, 15-18 parts of talcum powder, 9-12 parts of mica powder, 1.1-1.4 parts of monoalkoxy titanate coupling agent, 2.5-2.8 parts of dioctyl azelate, 5-9 parts of phenyl petroleum sulfonate, 0.5-0.8 part of manganese abietate, 1.2-1.5 parts of dibutyl zirconium dilaurate, 8-11 parts of melamine phosphate, 13-16 parts of zinc borate, 12-15 parts of nano-magnesium hydroxide, 4.3-4.7 parts of toughening agent, 1.1-1.4 parts of curing agent, 1.5-1.8 parts of defoamer, 1.3-1.6 parts of leveling agent, 1-1.3 parts of mildew preventive, 12-15 parts of pigment and 58-61 parts of solvent.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of easily cured flame-retardant corrosion resistant coating.
Background technology
Along with the development of industrial technology, the use of metallic substance is more and more extensive, and the etching problem of metal and component thereof, throughout the every field of national economy, causes massive losses to human society.In order to reduce the loss of corrosion; people take a lot of safeguard procedures; but sfgd. general, most economical, the most practical up to now or coating protection; in various anticorrosion technique; the anticorrosion technique of coating is most widely used general, anticorrosion with coat erosion with its easy construction, economic and practical, not by device area, shape the feature such as constraint and be widely used.Now need a kind of coating of corrosion-resistant, heat-resistant fireproof excellent performance, to meet the actual production life requirement day by day improved.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of easily cured flame-retardant corrosion resistant coating, have excellent flame-resistant high-temperature-resistant, corrosion resistant performance, and sticking power is good, curing speed is fast.
The easy cured flame-retardant corrosion resistant coating of one that the present invention proposes, its raw material comprises by weight: glyptal 50-53 part, terpolycyantoamino-formaldehyde resin 45-48 part, terpine resin 5-8 part, nano imvite 5-6 part, sepiolite powder 17-20 part, talcum powder 15-18 part, mica powder 9-12 part, monoalkoxy type titanate coupling agent 1.1-1.4 part, dioctyl azelate 2.5-2.8 part, phenyl alkylsulfonate 5-9 part, manganese rosinate 0.5-0.8 part, di lauric dibutyl zirconium 1.2-1.5 part, melamine phosphate 8-11 part, zinc borate 13-16 part, nano-sized magnesium hydroxide 12-15 part, toughner 4.3-4.7 part, solidifying agent 1.1-1.4 part, defoamer 1.5-1.8 part, advection agent 1.3-1.6 part, mould inhibitor 1-1.3 part, pigment 12-15 part, solvent 58-61 part.
Preferably, the weight ratio of glyptal, terpolycyantoamino-formaldehyde resin, terpine resin is 51-52:46-47:6-7.
Preferably, the weight ratio of nano imvite, sepiolite powder, talcum powder and mica powder is 5.2-5.6:18-19:16-17:10-11.
Preferably, its raw material comprises by weight: glyptal 51-52 part, terpolycyantoamino-formaldehyde resin 46-47 part, terpine resin 6-7 part, nano imvite 5.2-5.6 part, sepiolite powder 18-19 part, talcum powder 16-17 part, mica powder 10-11 part, monoalkoxy type titanate coupling agent 1.2-1.3 part, dioctyl azelate 2.6-2.7 part, phenyl alkylsulfonate 6-8 part, manganese rosinate 0.6-0.7 part, di lauric dibutyl zirconium 1.3-1.4 part, melamine phosphate 9-10 part, zinc borate 14-15 part, nano-sized magnesium hydroxide 13-14 part, toughner 4.4-4.6 part, solidifying agent 1.2-1.3 part, defoamer 1.6-1.7 part, advection agent 1.4-1.5 part, mould inhibitor 1.1-1.2 part, pigment 13-14 part, solvent 59-60 part.
Adopt glyptal, terpolycyantoamino-formaldehyde resin, terpine resin as filmogen in the present invention, significantly improve fire-retardant, water-fast and wear resisting property of the present invention, and make that sticking power of the present invention is good, curing speed is fast; Manganese rosinate and di lauric dibutyl zirconium are combined to form curing system, greatly improve curing speed of the present invention, and the in-situ hybridization that organic and inorganic occurs in the curing process is cross-linked to form three-dimensional netted crosslinking structure, because nano imvite, sepiolite powder, talcum powder and mica powder have very high specific surface area, impel crosslinking structure of the present invention extremely tight, significantly improve corrosion resistance of the present invention; Nano imvite, sepiolite powder, talcum powder and mica powder match, dioctyl azelate and phenyl alkylsulfonate auxiliary under, can be dispersed in filmogen more uniformly, again by monoalkoxy type titanate coupling agent and filmogen grafting, improve the consistency between above-mentioned each raw material further; Because nano imvite, sepiolite powder, talcum powder and mica powder have abundant surface anticorrosive functional group, significantly improve corrosion resistance of the present invention; Melamine phosphate is as phosphorus, nitrogenated flame retardant, with zinc borate, nano-sized magnesium hydroxide with the use of, substantially increase oxygen index of the present invention, improve flame retardant properties of the present invention, and zinc borate and nano-sized magnesium hydroxide burning process in not only can absorb a large amount of heat energy, also decomposable asymmetric choice net produces water, thus suppresses the smog in combustion processes to be formed.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The easy cured flame-retardant corrosion resistant coating of one that the present invention proposes, its raw material comprises by weight: glyptal 50 parts, terpolycyantoamino-formaldehyde resin 48 parts, terpine resin 5 parts, nano imvite 6 parts, sepiolite powder 17 parts, talcum powder 18 parts, mica powder 9 parts, monoalkoxy type titanate coupling agent 1.4 parts, dioctyl azelate 2.5 parts, phenyl alkylsulfonate 9 parts, manganese rosinate 0.5 part, di lauric dibutyl zirconium 1.5 parts, melamine phosphate 8 parts, zinc borate 16 parts, nano-sized magnesium hydroxide 12 parts, toughner 4.7 parts, 1.1 parts, solidifying agent, defoamer 1.8 parts, advection agent 1.3 parts, mould inhibitor 1.3 parts, pigment 12 parts, solvent 61 parts.
Embodiment 2
The easy cured flame-retardant corrosion resistant coating of one that the present invention proposes, its raw material comprises by weight: glyptal 52 parts, terpolycyantoamino-formaldehyde resin 46 parts, terpine resin 7 parts, nano imvite 5.2 parts, sepiolite powder 19 parts, talcum powder 16 parts, mica powder 11 parts, monoalkoxy type titanate coupling agent 1.2 parts, dioctyl azelate 2.7 parts, phenyl alkylsulfonate 6 parts, manganese rosinate 0.7 part, di lauric dibutyl zirconium 1.3 parts, melamine phosphate 10 parts, zinc borate 14 parts, nano-sized magnesium hydroxide 14 parts, toughner 4.4 parts, 1.3 parts, solidifying agent, defoamer 1.6 parts, advection agent 1.5 parts, mould inhibitor 1.1 parts, pigment 14 parts, solvent 59 parts.
Embodiment 3
The easy cured flame-retardant corrosion resistant coating of one that the present invention proposes, its raw material comprises by weight: glyptal 53 parts, terpolycyantoamino-formaldehyde resin 45 parts, terpine resin 8 parts, nano imvite 5 parts, sepiolite powder 20 parts, talcum powder 15 parts, mica powder 12 parts, monoalkoxy type titanate coupling agent 1.1 parts, dioctyl azelate 2.8 parts, phenyl alkylsulfonate 5 parts, manganese rosinate 0.8 part, di lauric dibutyl zirconium 1.2 parts, melamine phosphate 11 parts, zinc borate 13 parts, nano-sized magnesium hydroxide 15 parts, toughner 4.3 parts, 1.4 parts, solidifying agent, defoamer 1.5 parts, advection agent 1.6 parts, mould inhibitor 1 part, pigment 15 parts, solvent 58 parts.
Embodiment 4
The easy cured flame-retardant corrosion resistant coating of one that the present invention proposes, its raw material comprises by weight: glyptal 51 parts, terpolycyantoamino-formaldehyde resin 47 parts, terpine resin 6 parts, nano imvite 5.6 parts, sepiolite powder 18 parts, talcum powder 17 parts, mica powder 10 parts, monoalkoxy type titanate coupling agent 1.3 parts, dioctyl azelate 2.6 parts, phenyl alkylsulfonate 8 parts, manganese rosinate 0.6 part, di lauric dibutyl zirconium 1.4 parts, melamine phosphate 9 parts, zinc borate 15 parts, nano-sized magnesium hydroxide 13 parts, toughner 4.6 parts, 1.2 parts, solidifying agent, defoamer 1.7 parts, advection agent 1.4 parts, mould inhibitor 1.2 parts, pigment 13 parts, solvent 60 parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (4)
1. an easy cured flame-retardant corrosion resistant coating, it is characterized in that, its raw material comprises by weight: glyptal 50-53 part, terpolycyantoamino-formaldehyde resin 45-48 part, terpine resin 5-8 part, nano imvite 5-6 part, sepiolite powder 17-20 part, talcum powder 15-18 part, mica powder 9-12 part, monoalkoxy type titanate coupling agent 1.1-1.4 part, dioctyl azelate 2.5-2.8 part, phenyl alkylsulfonate 5-9 part, manganese rosinate 0.5-0.8 part, di lauric dibutyl zirconium 1.2-1.5 part, melamine phosphate 8-11 part, zinc borate 13-16 part, nano-sized magnesium hydroxide 12-15 part, toughner 4.3-4.7 part, solidifying agent 1.1-1.4 part, defoamer 1.5-1.8 part, advection agent 1.3-1.6 part, mould inhibitor 1-1.3 part, pigment 12-15 part, solvent 58-61 part.
2. easy cured flame-retardant corrosion resistant coating according to claim 1, it is characterized in that, the weight ratio of glyptal, terpolycyantoamino-formaldehyde resin, terpine resin is 51-52:46-47:6-7.
3. easy cured flame-retardant corrosion resistant coating according to claim 1 or 2, is characterized in that, the weight ratio of nano imvite, sepiolite powder, talcum powder and mica powder is 5.2-5.6:18-19:16-17:10-11.
4. easy cured flame-retardant corrosion resistant coating according to any one of claim 1-3, it is characterized in that, its raw material comprises by weight: glyptal 51-52 part, terpolycyantoamino-formaldehyde resin 46-47 part, terpine resin 6-7 part, nano imvite 5.2-5.6 part, sepiolite powder 18-19 part, talcum powder 16-17 part, mica powder 10-11 part, monoalkoxy type titanate coupling agent 1.2-1.3 part, dioctyl azelate 2.6-2.7 part, phenyl alkylsulfonate 6-8 part, manganese rosinate 0.6-0.7 part, di lauric dibutyl zirconium 1.3-1.4 part, melamine phosphate 9-10 part, zinc borate 14-15 part, nano-sized magnesium hydroxide 13-14 part, toughner 4.4-4.6 part, solidifying agent 1.2-1.3 part, defoamer 1.6-1.7 part, advection agent 1.4-1.5 part, mould inhibitor 1.1-1.2 part, pigment 13-14 part, solvent 59-60 part.
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CN201410571073.6A CN104356901A (en) | 2014-10-23 | 2014-10-23 | Easily-cured flame-retardant corrosion-resistant coating |
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CN201410571073.6A CN104356901A (en) | 2014-10-23 | 2014-10-23 | Easily-cured flame-retardant corrosion-resistant coating |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105949834A (en) * | 2016-03-28 | 2016-09-21 | 江苏经贸职业技术学院 | Thermal-resistant chemical-resistance coating for exhaust equipment |
CN106433252A (en) * | 2016-06-30 | 2017-02-22 | 太仓市金新涂料有限公司 | Environment-friendly corrosion-resistant two-component air-dry paint and preparation method thereof |
CN107163781A (en) * | 2017-06-15 | 2017-09-15 | 苏州莱特复合材料有限公司 | A kind of preparation method that coating is lost for steel surface fire retardant, anticorrosive |
CN109251528A (en) * | 2018-09-25 | 2019-01-22 | 合肥巧织纺织科技有限公司 | A kind of environmental protection flame retardant automatic foot-mat |
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CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
CN103073975A (en) * | 2012-10-15 | 2013-05-01 | 怀远县巨龙机械制造有限公司 | Alkyd resin vehicle primer and preparation method thereof |
CN103555158A (en) * | 2013-09-30 | 2014-02-05 | 青岛市高科专利技术转移平台有限公司 | High-efficiency alkyd resin anticorrosion paint |
CN103881543A (en) * | 2012-12-24 | 2014-06-25 | 青岛宣威涂层材料有限公司 | Weathering resistance and corrosion resistance coating material |
-
2014
- 2014-10-23 CN CN201410571073.6A patent/CN104356901A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
CN103073975A (en) * | 2012-10-15 | 2013-05-01 | 怀远县巨龙机械制造有限公司 | Alkyd resin vehicle primer and preparation method thereof |
CN103881543A (en) * | 2012-12-24 | 2014-06-25 | 青岛宣威涂层材料有限公司 | Weathering resistance and corrosion resistance coating material |
CN103555158A (en) * | 2013-09-30 | 2014-02-05 | 青岛市高科专利技术转移平台有限公司 | High-efficiency alkyd resin anticorrosion paint |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105949834A (en) * | 2016-03-28 | 2016-09-21 | 江苏经贸职业技术学院 | Thermal-resistant chemical-resistance coating for exhaust equipment |
CN106433252A (en) * | 2016-06-30 | 2017-02-22 | 太仓市金新涂料有限公司 | Environment-friendly corrosion-resistant two-component air-dry paint and preparation method thereof |
CN107163781A (en) * | 2017-06-15 | 2017-09-15 | 苏州莱特复合材料有限公司 | A kind of preparation method that coating is lost for steel surface fire retardant, anticorrosive |
CN109251528A (en) * | 2018-09-25 | 2019-01-22 | 合肥巧织纺织科技有限公司 | A kind of environmental protection flame retardant automatic foot-mat |
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