CN103589274A - Heat insulation anticorrosive paint and manufacturing method thereof - Google Patents
Heat insulation anticorrosive paint and manufacturing method thereof Download PDFInfo
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Abstract
A heat insulation anticorrosive paint is an energy-saving and environment-friendly paint, which uses nano metal powder, a variety of nano ceramic powders, an infrared powder and a pigment as the main body and is cured at room temperature, anti-infrared, thermal-insulating, wear-resistant and corrosion-resistant. A formula of the paint mainly includes ceramic hollow spheres, ultra-fine mica, kaolin, titanium dioxide, titanium dioxide, nano calcium carbonate, nano aluminium powder, zirconium dioxide, nano alumina, a ceramic powder, a pigment, a filler, epoxy resin, polyethylene and silicon resin. The solid materials are subjected to by nanometer ultrafine treatment to reach a granularity of 10-600 nm. The coating of the paint provided by the invention has excellent wear resistance, corrosion resistance, high temperature resistance, high radiation efficiency and stability, strong adhesion, compactness and stability; therefore, the anticorrosive insulation paint is ideal for building roof and tank, and can be widely applied to the fields of building energy saving, insulation and energy saving of equipment and anticorrosion environmental protection.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of adiabatic heat-insulation protective system and preparation method thereof.
Background technology
Be subject to irradiation and the outdoor infrared thermal radiation of sunlight summer, the surface temperatures such as building roof, storage tank ball are high, and in building body, temperature is also very high, and high temperature strengthens Loss of Oil Evaporation in oil tank, and increase fire alarm and explosion hazard, use in a large number air-conditioning greatly to increase energy consumption and environmental pollution.
Summary of the invention
Object of the present invention, exactly for a kind of adiabatic heat-insulation protective system and preparation method thereof is provided, both environmental protection, economy, easy to produce and use, have again the fabulous performance such as corrosion-resistant, stable, high temperature resistant, wear-resisting, withstand voltage.And have high thermal insulation and anti-infrared property, to reach adiabatic cooling and rot-resistant effect.
In order to achieve the above object, the present invention has adopted following technical scheme: a kind of adiabatic heat-insulation protective system, and its component and weight part proportioning are as follows:
Epoxy resin 100;
Ceramic hollow ball 1~15;
Mica powder 1~8;
Kaolin 1~10;
Titanium dioxide 1~15;
Titanium dioxide 1~15;
Nano-calcium carbonate 1~15;
Nanometer aluminium powder 1~15;
Zirconium dioxide 1~10;
Zircon English 1~10;
Manganese oxide 1~15;
Nano aluminium oxide 1~15;
Nanometer silicon carbide 1~10;
Silica powder 1~15;
Porcelain powder 1~15;
Asbestos powder 1~8;
Graphite Powder 99 1~8;
Color stuffing 1~20;
Polyethylene 1~20;
Silicone resin 1~15;
Dispersion agent 0~4;
Flow agent 0~3;
Mixed organic solvents 1~30;
Wax liquid 1~6.
Described dispersion agent is that polyacrylamide, flow agent are modification acrylate, and described mixed organic solvents is the mixture of acetone and toluene, and the weight proportion of acetone and toluene is 2: 3.
The making method of above-mentioned adiabatic heat-insulation protective system, comprises the following steps:
A, batching: the epoxy resin of take measures as 100 weight parts, accurately take respectively ceramic hollow ball 1~15 weight part, mica powder 1~8 weight part, kaolin 1~10 weight part, titanium dioxide 1~15 weight part, titanium dioxide 1~15 weight part, nano-calcium carbonate 1~15 weight part, nanometer aluminium powder 1~15 weight part, zirconium dioxide 1~10 weight part, zircon English 1~10 weight part, manganese oxide 1~15 weight part, nano aluminium oxide 1~15 weight part, nanometer silicon carbide 1~10 weight part, silica powder 1~15 weight part, porcelain powder 1~15 weight part, asbestos powder 1~8 weight part, Graphite Powder 99 1~8 weight part, color stuffing 1~20 weight part, epoxy resin 100 weight parts, polyethylene 1~20 weight part, silicone resin 1~15 weight part, dispersion agent 0~4 weight part, flow agent 0~3 weight part, mixed organic solvents 1~30 weight part and wax liquid 1~6 weight part,
B, at normal temperatures, the mica powder of dosage, kaolin, titanium dioxide, titanium dioxide, zirconium dioxide, zircon English, manganese oxide, silica powder, porcelain powder, asbestos powder and Graphite Powder 99 are adopted to nanometer ultrafining treatment, make granularity reach 10-600nm, obtain nano-solid powder;
C, step b gained nano-solid powder is mixed with ceramic hollow ball, nano-calcium carbonate, nanometer aluminium powder, nano aluminium oxide, nanometer silicon carbide, color stuffing, epoxy resin, polyethylene, silicone resin, dispersion agent, flow agent, mixed organic solvents and the wax liquid of dosage, and fully disperse to stir, obtain coating work in-process;
D, by step c gained coating work in-process after filtration, canning sealing, obtain coating finished product.
Described dispersion agent is that polyacrylamide, flow agent are modification acrylate, and described mixed organic solvents is the mixture of acetone and toluene, and the weight proportion of acetone and toluene is 2: 3.
Adiabatic heat-insulation protective system of the present invention need not priming paint, can not add special-purpose finish paint uses separately, direct spraying or brushing are in metallic surface at normal temperatures, before spary coating, pre-treatment and derusting by sandblast or hand cleaning need to be carried out in metallic surface and reach metal true qualities, then brush the thick 180-220 μ of this coating m coating, can divide twice brushing, interval 5-10 hour is good.
The coating of adiabatic heat-insulation protective system of the present invention has fabulous wear resistance, erosion resistance, high temperature resistant, high radiant rate and stability, and coating adhesion is strong, closely knit stable, is the corrosion-resistant thermal insulation adiabatic coatings such as desirable building roof, oil tank.
Embodiment
In table 1, listed the formula (weight unit for gram) of 10 embodiment, its making method is all: at normal temperatures, first the mica powder of dosage, kaolin, titanium dioxide, titanium dioxide, zirconium dioxide, zircon English, manganese oxide, silica powder, porcelain powder, asbestos powder and Graphite Powder 99 are ground to 60-100 minute in high-energy mill, and then after meticulous sieving, large-sized mixed powder is continued to fine grinding 5070 minutes, make granularity reach 10-600nm.Again the ceramic hollow ball of the powder of twice grinding and dosage, nano-calcium carbonate, nanometer aluminium powder, nano aluminium oxide, nanometer silicon carbide, color stuffing, epoxy resin, polyethylene, silicone resin, dispersion agent, flow agent, mixed organic solvents and wax liquid are mixed, and fully disperse to stir; Then after filtration, canning sealing forms.
Table 1
Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
Epoxy resin | 1000 | 1000 | 1000 | 1000 | 1000 | 1000 | 1000 | 1000 | 1000 | 1000 |
Ceramic hollow ball | 50 | 40 | 60 | 150 | 70 | 120 | 80 | 10 | 90 | 100 |
Mica powder | 50 | 80 | 25 | 45 | 55 | 35 | 70 | 30 | 60 | 10 |
Kaolin | 50 | 25 | 30 | 90 | 100 | 10 | 60 | 70 | 80 | 20 |
Titanium dioxide | 100 | 130 | 150 | 40 | 80 | 20 | 50 | 30 | 10 | 80 |
Titanium dioxide | 30 | 100 | 50 | 10 | 140 | 120 | 150 | 80 | 60 | 110 |
Nano-calcium carbonate | 50 | 80 | 30 | 100 | 10 | 150 | 90 | 60 | 120 | 70 |
Nanometer aluminium powder | 30 | 150 | 100 | 80 | 80 | 30 | 10 | 50 | 20 | 50 |
Zirconium dioxide | 30 | 50 | 80 | 20 | 60 | 100 | 90 | 10 | 40 | 70 |
Zircon English | 15 | 25 | 30 | 80 | 70 | 10 | 40 | 50 | 100 | 20 |
Manganese oxide | 30 | 80 | 120 | 50 | 80 | 10 | 100 | 150 | 20 | 60 |
Nano aluminium oxide | 10 | 30 | 50 | 60 | 40 | 100 | 150 | 15 | 45 | 120 |
Nanometer silicon carbide | 100 | 15 | 80 | 20 | 35 | 25 | 40 | 30 | 90 | 10 |
Silica powder | 100 | 50 | 10 | 150 | 80 | 60 | 120 | 60 | 30 | 130 |
Porcelain powder | 150 | 30 | 50 | 60 | 100 | 120 | 80 | 90 | 10 | 130 |
Asbestos powder | 60 | 50 | 10 | 80 | 25 | 65 | 75 | 20 | 40 | 55 |
Graphite Powder 99 | 10 | 30 | 80 | 60 | 70 | 55 | 35 | 40 | 65 | 20 |
Color stuffing | 100 | 50 | 200 | 10 | 80 | 150 | 180 | 60 | 30 | 120 |
Polyethylene | 200 | 80 | 10 | 150 | 60 | 180 | 120 | 30 | 50 | 65 |
Silicone resin | 100 | 150 | 120 | 10 | 90 | 130 | 60 | 80 | 50 | 30 |
Dispersion agent | 0 | 15 | 30 | 40 | 25 | 5 | 10 | 15 | 35 | 8 |
Flow agent | 10 | 15 | 8 | 0 | 20 | 30 | 25 | 5 | 3 | 35 |
Acetone | 60 | 66 | 80 | 90 | 84 | 100 | 110 | 92 | 82 | 102 |
Toluene | 90 | 99 | 120 | 135 | 126 | 150 | 165 | 138 | 123 | 153 |
Wax liquid | 10 | 50 | 15 | 60 | 35 | 25 | 45 | 50 | 55 | 30 |
Adiabatic heat-insulation protective system of the present invention need not priming paint, can not add special-purpose finish paint uses separately, direct spraying or brushing are in metallic surface at normal temperatures, before spary coating, pre-treatment and derusting by sandblast or hand cleaning need to be carried out in metallic surface and reach metal true qualities, then brush the thick 200 μ m coatings of this coating, can divide twice brushing.
By aforesaid operations processing step, produce, the environment protecting thermal insulating corrosion protection coating obtaining is carried out to functional performance verification test, test result is as shown in table 2:
Table 2
Paint coatings of the present invention has fabulous wear resistance, erosion resistance, high temperature resistant, high radiant rate and stability, coating adhesion is strong, closely knit stable, be the corrosion-resistant thermal insulation adiabatic coatings such as desirable building roof, oil tank, can be widely applied to the energy-conservation and anticorrosion field of Environment Protections such as building energy conservation, insulation of equipment.
Claims (4)
1. an adiabatic heat-insulation protective system, is characterized in that, its component and weight part proportioning are as follows:
Epoxy resin 100;
Ceramic hollow ball 1~15;
Mica powder 1~8;
Kaolin 1~10;
Titanium dioxide 1~15;
Titanium dioxide 1~15;
Nano-calcium carbonate 1~15;
Nanometer aluminium powder 1~15;
Zirconium dioxide 1~10;
Zircon English 1~10;
Manganese oxide 1~15;
Nano aluminium oxide 1~15;
Nanometer silicon carbide 1~10;
Silica powder 1~15;
Porcelain powder 1~15;
Asbestos powder 1~8;
Graphite Powder 99 1~8;
Color stuffing 1~20;
Polyethylene 1~20;
Silicone resin 1~15;
Dispersion agent 0~4;
Flow agent 0~3;
Mixed organic solvents 1~30;
Wax liquid 1~6.
2. adiabatic heat-insulation protective system according to claim 1, it is characterized in that: described dispersion agent is that polyacrylamide, flow agent are modification acrylate, described mixed organic solvents is the mixture of acetone and toluene, and the weight proportion of acetone and toluene is 2: 3.
3. the making method of adiabatic heat-insulation protective system according to claim 1, is characterized in that, comprises the following steps:
A, batching: the epoxy resin of take measures as 100 weight parts, accurately take respectively ceramic hollow ball 1~15 weight part, mica powder 1~8 weight part, kaolin 1~10 weight part, titanium dioxide 1~15 weight part, titanium dioxide 1~15 weight part, nano-calcium carbonate 1~15 weight part, nanometer aluminium powder 1~15 weight part, zirconium dioxide 1~10 weight part, zircon English 1~10 weight part, manganese oxide 1~15 weight part, nano aluminium oxide 1~15 weight part, nanometer silicon carbide 1~10 weight part, silica powder 1~15 weight part, porcelain powder 1~15 weight part, asbestos powder 1~8 weight part, Graphite Powder 99 1~8 weight part, color stuffing 1~20 weight part, epoxy resin 100 weight parts, polyethylene 1~20 weight part, silicone resin 1~15 weight part, dispersion agent 0~4 weight part, flow agent 0~3 weight part, mixed organic solvents 1~30 weight part and wax liquid 1~6 weight part,
B, at normal temperatures, the mica powder of dosage, kaolin, titanium dioxide, titanium dioxide, zirconium dioxide, zircon English, manganese oxide, silica powder, porcelain powder, asbestos powder and Graphite Powder 99 are adopted to nanometer ultrafining treatment, make granularity reach 100-600nm, obtain nano-solid powder;
C, step b gained nano-solid powder is mixed with ceramic hollow ball, nano-calcium carbonate, nanometer aluminium powder, nano aluminium oxide, nanometer silicon carbide, color stuffing, epoxy resin, polyethylene, silicone resin, dispersion agent, flow agent, mixed organic solvents and the wax liquid of dosage, and fully disperse to stir, obtain coating work in-process;
D, by step c gained coating work in-process after filtration, canning sealing, obtain coating finished product.
4. the making method of adiabatic heat-insulation protective system according to claim 3, it is characterized in that: described dispersion agent is that polyacrylamide, flow agent are modification acrylate, described mixed organic solvents is the mixture of acetone and toluene, and the weight proportion of acetone and toluene is 2: 3.
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CN104312102A (en) * | 2014-10-31 | 2015-01-28 | 合肥鼎雅家具有限责任公司 | Epoxy resin composite material for heat preservation coating and manufacturing method of epoxy resin composite material |
CN105255318A (en) * | 2015-11-10 | 2016-01-20 | 西南石油大学 | Preparation method of wear-resistant nano Al2O3-CaCO3-epoxy composite coating |
CN105315841A (en) * | 2015-09-25 | 2016-02-10 | 洛阳暖盈电子技术有限公司 | Wear-resistant ceramic paint |
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CN108395742A (en) * | 2018-05-12 | 2018-08-14 | 浙江大学 | A kind of aperture is in obturator-type anti-corrosive metal coating, the preparation method and use of normal distribution |
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CN104312102A (en) * | 2014-10-31 | 2015-01-28 | 合肥鼎雅家具有限责任公司 | Epoxy resin composite material for heat preservation coating and manufacturing method of epoxy resin composite material |
CN105315841A (en) * | 2015-09-25 | 2016-02-10 | 洛阳暖盈电子技术有限公司 | Wear-resistant ceramic paint |
CN105255318A (en) * | 2015-11-10 | 2016-01-20 | 西南石油大学 | Preparation method of wear-resistant nano Al2O3-CaCO3-epoxy composite coating |
CN105255318B (en) * | 2015-11-10 | 2018-12-14 | 西南石油大学 | A kind of wear-resisting nanometer Al2O3-CaCO3The preparation method of epoxy composite coating |
CN105567080A (en) * | 2016-03-21 | 2016-05-11 | 苏州天键衡电子信息科技有限公司 | High-temperature-resistant protective paint for ships |
EP3555218B1 (en) * | 2016-11-14 | 2022-10-05 | Mankiewicz Gebr. & Co. (GmbH & Co. KG) | Solar radiation reflecting coating and its use |
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WO2018086661A1 (en) * | 2016-11-14 | 2018-05-17 | Mankiewicz Gebr. & Co. Gmbh & Co. Kg | Coating reflecting solar radiation, and use thereof |
CN108395742A (en) * | 2018-05-12 | 2018-08-14 | 浙江大学 | A kind of aperture is in obturator-type anti-corrosive metal coating, the preparation method and use of normal distribution |
CN109181934A (en) * | 2018-09-30 | 2019-01-11 | 广西秀美壮乡能源环保有限公司 | A kind of Brewing equipment of fen-flavor type white spirit |
CN109468022A (en) * | 2018-11-06 | 2019-03-15 | 苏州环明电子科技有限公司 | Heat radiation coating and preparation method thereof |
CN111171670A (en) * | 2019-12-19 | 2020-05-19 | 湖南太子化工涂料有限公司 | Environment-friendly powder coating for metal substrate and preparation method thereof |
CN112762279A (en) * | 2021-01-14 | 2021-05-07 | 温州赵氟隆有限公司 | Processing method of plastic-coated pipeline with excellent adhesion |
CN113502096A (en) * | 2021-06-18 | 2021-10-15 | 佛山市顺德区博宜防腐涂料科技有限公司 | Low-cost color water-based super high temperature resistant coating prepared by self-crosslinking and sintering crosslinking, and preparation method and use method thereof |
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Application publication date: 20140219 |