Background technology
The application of hot-spraying techniques, it is an important application in material protection and sufacing field, by carrying out thermospray at material surface, form alloy coat, material is formed to supercoat, but due to the reason of conventional hot-spraying techniques due to technology itself, be difficult to form fully dense alloy coat, the existence of hole gains to some extent for the wear resisting property of golden sprayed coating, because hole can effectively reduce the friction that is coated with interlayer, but for corrosion-resistant be but a large defect, we should reduce the hole of coating as much as possible, to reach acid, alkali, the object that salt and base material are isolated.
Exist in the market hole sealing agent ubiquity poor heat resistance, cost high, harmful to environment, for these problems, be necessary existing technology to improve.
Summary of the invention
The defect that object of the present invention exists for solving prior art just, provides that a kind of energy is high temperature resistant, low-cost, the fire resistant anticorrosive organic coating of environmental sound.
To achieve these goals, the present invention adopts following technical scheme:
A fire resistant anticorrosive organic coating, it comprises following raw materials by weight portion preparation gained:
A component: modifying epoxy resin by organosilicon: 40-65; Glass powder with low melting point: 10-30; Mica powder: 6-15; Asbestos powder: 3-15; Carbon black: 2-6; Nano silicon: 1-4; KH-560:1-4;
B component: aromatic amine curing agent: be the 1-5 ‰ of A component gross weight; DMP-30: be the 3-12% of the weight of aromatic amine curing agent.
Described modifying epoxy resin by organosilicon is one or more in epoxy resin 900, epoxy resin 1000, epoxy resin 1200.
This coating adopts modifying epoxy resin by organosilicon for substantially adding materials, therefore it has good heat resistance energy and acid-proof alkaline, glass powder with low melting point is that softening temperature is in 400 degree left and right, it can be again 400 degree hot mastications and to form enamel shape coating with modifying epoxy resin by organosilicon and other color stuffings be so-called two-step film forming, can under high-temperature condition, during decomposed, allow coating bear more lasting even higher temperature at organic-silicon-modified resin; Mica powder can significantly improve paint film intensity and resistance to chalking; The thermostability of asbestos powder is high, and can improve the resistance to cracking under paint film high temperature; Carbon black is mainly to make black pigment, and has good thermotolerance; Nano silicon can form reticulated structure fast, the ageing-resistant performance of raising paint film, paint film intensity, smooth finish etc.Nano material forms fine and close coating can improve that impermeability and antiultraviolet absorb, anti-thermal ageing ability.KH-560, as connecting organic and inorganic bridge, plays the effect that increases bonding strength, plays the moistening and good dispersive ability to nanometer color stuffing simultaneously.B component aromatic amine curing agent, carry out crosslinking curing film forming with organic-silicon-modified resin; DMP-30 is curing catalyst, shortens set time.
Beneficial effect of the present invention:
Coating provided by the invention, good heat resistance, cost are low, easy to operate, environmental sound, change coating formula and allow to adopt different forms of construction work in certain scope, and cold spray, brushing, roller coat, can obtain great operating efficiency.
Embodiment
Below in conjunction with example, the present invention is described further:
A component: modifying epoxy resin by organosilicon: 40-65; Glass powder with low melting point: 10-30; Mica powder: 6-15; Asbestos powder: 3-15; Carbon black: 2-6; Nano silicon: 1-4; KH-560:1-4;
B component: aromatic amine curing agent: be the 1-5 ‰ of A component gross weight; DMP-30: be the 3-12% of the weight of aromatic amine curing agent.
Example one
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 60; Glass powder with low melting point: 20; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
The resin of above-mentioned A component and color stuffing are thought mixed rear even by stirrer dispersed with stirring, with soluble silicate mix and blend and get final product, it is basic framework that the present invention has adopted modifying epoxy resin by organosilicon, added glass powder with low melting point, mica powder, asbestos powder, nano silicon etc., have increased the thermotolerance of coating and the physical strength of paint film and impermeability, compactness.Then add B component, stir and can construct.This coating is fast setting at normal temperatures, and organic materials has good thermal conductivity, by the tight fine and close coating system of formation of filler, makes firmly fine and close hard coatings and substrate material combine.The corrosion of protection steel and iron member.Product of the present invention detects after testing: use temperature (℃): 400 degree are with interior, thickness (mm): 0.3-1;
30%H
2sO
4solution 2 hours is without considerable change; 10%HCl solution 72 hours is without considerable change; 30%NaCl solution 72 hours is without considerable change; 30%NaOH solution 72 hours is without considerable change.
Example two
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 63; Glass powder with low melting point: 17; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1 thousand;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make the high temperature resistant compact inorganic hole sealing agent of high temperature resistive connection of the present invention coating.
Example three
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 50; Glass powder with low melting point: 30; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 1 ‰ of A component gross weight; DMP-30: be 3% of the weight of aromatic amine curing agent.
By the method identical with example 1, make the high temperature resistant compact inorganic hole sealing agent of high temperature resistive connection of the present invention coating.
Example four
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 65; Glass powder with low melting point: 15; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 5 ‰ of A component gross weight; DMP-30: be 12% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.
Example five
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 40; Glass powder with low melting point: 10; Mica powder: 6; Asbestos powder: 3; Carbon black: 2; Nano silicon: 1; KH-560:1;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.
Example six
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 65; Glass powder with low melting point: 30; Mica powder: 15; Asbestos powder: 15; Carbon black: 6; Nano silicon: 4; KH-560:4;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.