CN103642362A - High-temperature-resistant anticorrosive organic coating - Google Patents

High-temperature-resistant anticorrosive organic coating Download PDF

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Publication number
CN103642362A
CN103642362A CN201310673031.9A CN201310673031A CN103642362A CN 103642362 A CN103642362 A CN 103642362A CN 201310673031 A CN201310673031 A CN 201310673031A CN 103642362 A CN103642362 A CN 103642362A
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parts
component
coating
epoxy resin
curing agent
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CN201310673031.9A
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CN103642362B (en
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不公告发明人
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Jiangxi Hengda High Tech Co.,Ltd.
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JIANGXI HENGDA ADVANCED TECHNOLOGY Co Ltd
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Abstract

The invention relates to a coating, and particularly relates to a high-temperature-resistant anticorrosive organic coating for pores of closed gold spraying coats. The high-temperature-resistant anticorrosive organic coating is prepared from the following raw materials in parts by weight: a component A consisting of 40-65 parts of organic silicone modified epoxy resin, 10-30 parts of low-melting-point glass powder, 6-15 parts of mica powder, 3-15 parts of asbestos powder, 2-6 parts of carbon black, 1-4 parts of nano silica and 1-4 parts of KH-560, and a component B consisting of an aromatic amine curing agent accounting for 1-5% of the total weight of the component A and DMP-30 accounting for 3-12% of the weight of the aromatic amine curing agent. The coating provided by the invention is good in heat resistance, low in cost, convenient to operate, and harmless to the environment; the proportioning of the coating is changed within a certain range, and different construction modes such as cold spraying, brushing and roller painting are allowed to be adopted, so that great construction efficiency can be achieved.

Description

A kind of fire resistant anticorrosive organic coating
Technical field
The present invention relates to a kind of coating, specifically for the fire resistant anticorrosive organic coating that seals golden sprayed coating hole.
Background technology
The application of hot-spraying techniques, it is an important application in material protection and sufacing field, by carrying out thermospray at material surface, form alloy coat, material is formed to supercoat, but due to the reason of conventional hot-spraying techniques due to technology itself, be difficult to form fully dense alloy coat, the existence of hole gains to some extent for the wear resisting property of golden sprayed coating, because hole can effectively reduce the friction that is coated with interlayer, but for corrosion-resistant be but a large defect, we should reduce the hole of coating as much as possible, to reach acid, alkali, the object that salt and base material are isolated.
Exist in the market hole sealing agent ubiquity poor heat resistance, cost high, harmful to environment, for these problems, be necessary existing technology to improve.
Summary of the invention
The defect that object of the present invention exists for solving prior art just, provides that a kind of energy is high temperature resistant, low-cost, the fire resistant anticorrosive organic coating of environmental sound.
To achieve these goals, the present invention adopts following technical scheme:
A fire resistant anticorrosive organic coating, it comprises following raw materials by weight portion preparation gained:
A component: modifying epoxy resin by organosilicon: 40-65; Glass powder with low melting point: 10-30; Mica powder: 6-15; Asbestos powder: 3-15; Carbon black: 2-6; Nano silicon: 1-4; KH-560:1-4;
B component: aromatic amine curing agent: be the 1-5 ‰ of A component gross weight; DMP-30: be the 3-12% of the weight of aromatic amine curing agent.
Described modifying epoxy resin by organosilicon is one or more in epoxy resin 900, epoxy resin 1000, epoxy resin 1200.
This coating adopts modifying epoxy resin by organosilicon for substantially adding materials, therefore it has good heat resistance energy and acid-proof alkaline, glass powder with low melting point is that softening temperature is in 400 degree left and right, it can be again 400 degree hot mastications and to form enamel shape coating with modifying epoxy resin by organosilicon and other color stuffings be so-called two-step film forming, can under high-temperature condition, during decomposed, allow coating bear more lasting even higher temperature at organic-silicon-modified resin; Mica powder can significantly improve paint film intensity and resistance to chalking; The thermostability of asbestos powder is high, and can improve the resistance to cracking under paint film high temperature; Carbon black is mainly to make black pigment, and has good thermotolerance; Nano silicon can form reticulated structure fast, the ageing-resistant performance of raising paint film, paint film intensity, smooth finish etc.Nano material forms fine and close coating can improve that impermeability and antiultraviolet absorb, anti-thermal ageing ability.KH-560, as connecting organic and inorganic bridge, plays the effect that increases bonding strength, plays the moistening and good dispersive ability to nanometer color stuffing simultaneously.B component aromatic amine curing agent, carry out crosslinking curing film forming with organic-silicon-modified resin; DMP-30 is curing catalyst, shortens set time.
Beneficial effect of the present invention:
Coating provided by the invention, good heat resistance, cost are low, easy to operate, environmental sound, change coating formula and allow to adopt different forms of construction work in certain scope, and cold spray, brushing, roller coat, can obtain great operating efficiency.
Embodiment
Below in conjunction with example, the present invention is described further:
A component: modifying epoxy resin by organosilicon: 40-65; Glass powder with low melting point: 10-30; Mica powder: 6-15; Asbestos powder: 3-15; Carbon black: 2-6; Nano silicon: 1-4; KH-560:1-4;
B component: aromatic amine curing agent: be the 1-5 ‰ of A component gross weight; DMP-30: be the 3-12% of the weight of aromatic amine curing agent.
Example one
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 60; Glass powder with low melting point: 20; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
The resin of above-mentioned A component and color stuffing are thought mixed rear even by stirrer dispersed with stirring, with soluble silicate mix and blend and get final product, it is basic framework that the present invention has adopted modifying epoxy resin by organosilicon, added glass powder with low melting point, mica powder, asbestos powder, nano silicon etc., have increased the thermotolerance of coating and the physical strength of paint film and impermeability, compactness.Then add B component, stir and can construct.This coating is fast setting at normal temperatures, and organic materials has good thermal conductivity, by the tight fine and close coating system of formation of filler, makes firmly fine and close hard coatings and substrate material combine.The corrosion of protection steel and iron member.Product of the present invention detects after testing: use temperature (℃): 400 degree are with interior, thickness (mm): 0.3-1;
30%H 2sO 4solution 2 hours is without considerable change; 10%HCl solution 72 hours is without considerable change; 30%NaCl solution 72 hours is without considerable change; 30%NaOH solution 72 hours is without considerable change.
Example two
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 63; Glass powder with low melting point: 17; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1 thousand;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make the high temperature resistant compact inorganic hole sealing agent of high temperature resistive connection of the present invention coating.
Example three
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 50; Glass powder with low melting point: 30; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 1 ‰ of A component gross weight; DMP-30: be 3% of the weight of aromatic amine curing agent.
By the method identical with example 1, make the high temperature resistant compact inorganic hole sealing agent of high temperature resistive connection of the present invention coating.
Example four
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 65; Glass powder with low melting point: 15; Mica powder: 8; Asbestos powder: 5; Carbon black: 4; Nano silicon: 2; KH-560:1;
B component: aromatic amine curing agent: be 5 ‰ of A component gross weight; DMP-30: be 12% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.
Example five
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 40; Glass powder with low melting point: 10; Mica powder: 6; Asbestos powder: 3; Carbon black: 2; Nano silicon: 1; KH-560:1;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.
Example six
It comprises following raw materials by weight portion preparation gained:
Get A component: modifying epoxy resin by organosilicon: 65; Glass powder with low melting point: 30; Mica powder: 15; Asbestos powder: 15; Carbon black: 6; Nano silicon: 4; KH-560:4;
B component: aromatic amine curing agent: be 3 ‰ of A component gross weight; DMP-30: be 5% of the weight of aromatic amine curing agent.
By the method identical with example 1, make fire resistant anticorrosive organic coating of the present invention.This example is applicable to brushing or round brush technique.

Claims (2)

1. a fire resistant anticorrosive organic coating, is characterized in that: it comprises following raw materials by weight portion preparation gained:
A component: modifying epoxy resin by organosilicon: 40-65; Glass powder with low melting point: 10-30; Mica powder: 6-15; Asbestos powder: 3-15; Carbon black: 2-6; Nano silicon: 1-4; KH-560:1-4;
B component: aromatic amine curing agent: be the 1-5 ‰ of A component gross weight; DMP-30: be the 3-12% of the weight of aromatic amine curing agent.
2. fire resistant anticorrosive organic coating according to claim 1, is characterized in that: described modifying epoxy resin by organosilicon is one or more in epoxy resin 900, epoxy resin 1000, epoxy resin 1200.
CN201310673031.9A 2013-12-12 2013-12-12 A kind of fire resistant anticorrosive organic coating Active CN103642362B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263224A (en) * 2014-10-29 2015-01-07 芜湖县双宝建材有限公司 Cold-resistant and water-proof damping coating
CN104277663A (en) * 2014-10-20 2015-01-14 江苏常明电力设备有限公司 Novel metal-armor mobile open-type switchgear
CN104877523A (en) * 2015-06-25 2015-09-02 刘朝辉 Solvent-free organosilicone modified epoxy sealing prime paint and preparing method thereof
CN106433440B (en) * 2016-11-29 2018-06-01 滁州市瑞景园林建设有限公司 A kind of fire resistant water-based coating
CN108411241A (en) * 2018-05-31 2018-08-17 合肥宸翊商贸有限公司 The method for being intended to improve bathroom cabinet board weather resistance
CN111073503A (en) * 2019-12-24 2020-04-28 洛阳嘉德节能科技有限公司 High-temperature-resistant high-emissivity anticorrosive paint
CN112300661A (en) * 2020-11-02 2021-02-02 刘超 High-temperature-resistant coating and application thereof
CN112358795A (en) * 2020-11-20 2021-02-12 山东国铭球墨铸管科技有限公司 Method for manufacturing low-resistance corrosion-resistant heat distribution pipeline

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JPS6028464A (en) * 1983-07-28 1985-02-13 Sumitomo Bakelite Co Ltd Highly heat-resistant electrical insulating powder coating composition
CN101705074A (en) * 2008-12-30 2010-05-12 北方涂料工业研究设计院 High temperature screw thread fastening glue and production method thereof
CN101935497A (en) * 2010-09-21 2011-01-05 中国人民解放军国防科学技术大学 Epoxy modified high-temperature-resistant anticorrosive paint
CN102585696A (en) * 2012-02-13 2012-07-18 江苏大学 Methyl phenyl silicone resin base high-temperature-resistant coating and preparation method thereof
CN103342958A (en) * 2013-06-05 2013-10-09 浙江华彩化工有限公司 High temperature resistant powder coating

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JPS6028464A (en) * 1983-07-28 1985-02-13 Sumitomo Bakelite Co Ltd Highly heat-resistant electrical insulating powder coating composition
CN101705074A (en) * 2008-12-30 2010-05-12 北方涂料工业研究设计院 High temperature screw thread fastening glue and production method thereof
CN101935497A (en) * 2010-09-21 2011-01-05 中国人民解放军国防科学技术大学 Epoxy modified high-temperature-resistant anticorrosive paint
CN102585696A (en) * 2012-02-13 2012-07-18 江苏大学 Methyl phenyl silicone resin base high-temperature-resistant coating and preparation method thereof
CN103342958A (en) * 2013-06-05 2013-10-09 浙江华彩化工有限公司 High temperature resistant powder coating

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277663A (en) * 2014-10-20 2015-01-14 江苏常明电力设备有限公司 Novel metal-armor mobile open-type switchgear
CN104263224A (en) * 2014-10-29 2015-01-07 芜湖县双宝建材有限公司 Cold-resistant and water-proof damping coating
CN104877523A (en) * 2015-06-25 2015-09-02 刘朝辉 Solvent-free organosilicone modified epoxy sealing prime paint and preparing method thereof
CN106433440B (en) * 2016-11-29 2018-06-01 滁州市瑞景园林建设有限公司 A kind of fire resistant water-based coating
CN108411241A (en) * 2018-05-31 2018-08-17 合肥宸翊商贸有限公司 The method for being intended to improve bathroom cabinet board weather resistance
CN111073503A (en) * 2019-12-24 2020-04-28 洛阳嘉德节能科技有限公司 High-temperature-resistant high-emissivity anticorrosive paint
CN112300661A (en) * 2020-11-02 2021-02-02 刘超 High-temperature-resistant coating and application thereof
CN112358795A (en) * 2020-11-20 2021-02-12 山东国铭球墨铸管科技有限公司 Method for manufacturing low-resistance corrosion-resistant heat distribution pipeline

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Effective date of registration: 20180625

Address after: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee after: Jiangxi Hengda Engineering Technology Co., Ltd.

Address before: 330096 Jinlu North Road, Nanchang hi tech Zone, Jiangxi Province, No. 88

Patentee before: Jiangxi Hengda Advanced Technology Co., Ltd.

CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee after: Jiangxi Hengda High Tech Co.,Ltd.

Address before: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee before: JIANGXI HENGDA ENGINEERING TECHNOLOGY Co.,Ltd.