CN104449136A - Flame-retardant wear-resisting modified acrylic resin coating - Google Patents

Flame-retardant wear-resisting modified acrylic resin coating Download PDF

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CN104449136A
CN104449136A CN201410679797.2A CN201410679797A CN104449136A CN 104449136 A CN104449136 A CN 104449136A CN 201410679797 A CN201410679797 A CN 201410679797A CN 104449136 A CN104449136 A CN 104449136A
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parts
acrylic resin
powder
flame
stir
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王和山
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Tianchang Kailin Chemical Co Ltd
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Tianchang Kailin Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a flame-retardant wear-resisting modified acrylic resin coating which comprises the following raw materials in parts by weight: 68-71 parts of acrylic resin, 12-15 parts of polyurethane resin, 16-19 parts of aldehyde ketone resin, 7-10 parts of powdery ethylene propylene diene monomer, 6-9 parts of hollow glass beads, 5-7 parts of organic bentonite, 3-5 parts of talcum powder, 7-9 parts of zeolite powder, 12-15 parts of modified yttrium oxide, 5-7 parts of mica powder, 2.5-3 parts of diisononyl phthalate, 5-8 parts of epoxy xanthium sibiricum butyl oleate, 3-6 parts of sodium laurate, 3-5 parts of (1,3-dichloro-2-propyl) phosphotriester, 13-16 parts of nano-magnesium hydroxide, 4-6 parts of antimony trioxide, 8-11 parts of a drying catalyst, 12-15 parts of a pigment, 3-4 parts of a toughening agent, 1.5-2 parts of an antifoaming agent, 2-3 parts of a leveling agent and 1-2 parts of a mould inhibitor. The flame-retardant wear-resisting modified acrylic resin coating has excellent flame retardancy and wear resistance and high curing speed.

Description

The acrylic resin modified coating of a kind of flame-proof abrasion-resistant
Technical field
The present invention relates to technical field of coatings, particularly relate to the acrylic resin modified coating of a kind of flame-proof abrasion-resistant.
Background technology
At present wood materials and coating consumption cumulative year after year in interior decoration, due to combustibility and the inflammableness of wood materials and some coating itself, certainly exists disaster hidden-trouble.In recent years, due to a large amount of uses of finishing material, this fire is in rising trend.Prepare novel not fire, difficult combustion finishing material, be subject to the great attention of national departments concerned.Therefore anti-flaming dope becomes the focus of research, but existing anti-flaming dope still also exists some shortcomings, done in order to realize the prior art fire-retardant to base material by the catalysis carbon-forming of film, the dehydration catalyst decomposition temperature of employing is higher and low temperature active is poor, and the flame retardant properties of coating is not good enough.Because when fire occurs, filmogen, often prior to dehydration catalyst decomposes, produces more flammable volatile organic compounds, affects formation and the structure of layer of charcoal, and then the provide protection of impact to base material.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes the acrylic resin modified coating of a kind of flame-proof abrasion-resistant, there is excellent fire-retardant and wear resisting property, and curing speed is fast.
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 68-71 part, urethane resin 12-15 part, aldehyde ketone resin 16-19 part, powder terpolymer EP rubber 7-10 part, hollow glass micropearl 6-9 part, organobentonite 5-7 part, talcum powder 3-5 part, zeolite powder 7-9 part, modified oxidized yttrium 12-15 part, mica powder 5-7 part, diisononyl phthalate 2.5-3 part, epoxy Siberian cocklebur butyl oleate 5-8 part, sodium laurate 3-6 part, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3-5 part, nano-sized magnesium hydroxide 13-16 part, antimonous oxide 4-6 part, siccative 8-11 part, pigment 12-15 part, toughner 3-4 part, defoamer 1.5-2 part, advection agent 2-3 part, mould inhibitor 1-2 part.
Preferably, the ethylene, propylene of powder terpolymer EP rubber is than being 65-70:30-35.
Preferably, talcum powder and zeolite powder are 700-800 order.
Preferably, the weight ratio of acrylic resin, urethane resin, aldehyde ketone resin and powder terpolymer EP rubber is 69-70:13-14:17-18:8-9.
Preferably, its raw material comprises by weight: acrylic resin 69-70 part, urethane resin 13-14 part, aldehyde ketone resin 17-18 part, powder terpolymer EP rubber 8-9 part, hollow glass micropearl 7-8 part, organobentonite 5.6-6.7 part, 700-800 order talcum powder 3.3-4.5 part, 700-800 order zeolite powder 7.5-8.3 part, modified oxidized yttrium 13-14 part, mica powder 5.6-6.2 part, diisononyl phthalate 2.7-2.9 part, epoxy Siberian cocklebur butyl oleate 6-7 part, sodium laurate 4-5 part, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3.4-4.1 part, nano-sized magnesium hydroxide 14-15 part, antimonous oxide 4.8-5.6 part, siccative 9-10 part, pigment 13-14 part, toughner 3.5-3.8 part, defoamer 1.6-1.8 part, advection agent 2.2-2.6 part, mould inhibitor 1.1-1.4 part.
Preferably, its raw material comprises by weight: acrylic resin 69 parts, urethane resin 14 parts, aldehyde ketone resin 17 parts, powder terpolymer EP rubber 9 parts, hollow glass micropearl 7 parts, organobentonite 6 parts, 750 order talcum powder 4 parts, 750 order zeolite powders 8 parts, modified oxidized yttrium 13.3 parts, mica powder 6 parts, diisononyl phthalate 2.8 parts, epoxy Siberian cocklebur butyl oleate 6.7 parts, sodium laurate 4.5 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 4 parts, nano-sized magnesium hydroxide 14.5 parts, antimonous oxide 5 parts, siccative 9.4 parts, pigment 13.4 parts, toughner 3.7 parts, defoamer 1.7 parts, advection agent 2.5 parts, mould inhibitor 1.3 parts.
Preferably, the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, then after adding nano yttrium oxide, continue after intensification to stir, then vacuum-drying obtains the first mixture; Stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir; After the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
The present invention adopts tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester, nano-sized magnesium hydroxide and antimonous oxide coordinate formation flame-retardant system, significantly improve heat-proof combustion-resistant performance of the present invention, wherein tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester is as phosphorus flame retardant, and nano-sized magnesium hydroxide is in the process of heated combustion, decomposable asymmetric choice net generates water and magnesium oxide, not only can suppress the generation of smog, resistance to elevated temperatures of the present invention can also be improved further, antimonous oxide and tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) chlorine element in ester complements each other to form synergistic effect, further increase heat-proof combustion-resistant performance of the present invention, coordinate as filmogen using acrylic resin, urethane resin, aldehyde ketone resin and powder terpolymer EP rubber, the present invention is made to have excellent sticking power, water-fast, oil resistant, weather-proof and heat-proof combustion-resistant performance, also improve heat-resisting, light fastness, especially when the ethylene, propylene of powder terpolymer EP rubber is than when being 65-70:30-35, improve wear resisting property of the present invention, hollow glass micropearl, organobentonite, talcum powder, zeolite powder, modified oxidized yttrium and mica powder cooperatively interact and add in filmogen, improve of the present invention high temperature resistant, corrosion resistant performance and anti-thixotroping ability, be aided with diisononyl phthalate and epoxy Siberian cocklebur butyl oleate again, hollow glass micropearl can be impelled, organobentonite, talcum powder, zeolite powder, modified oxidized yttrium and mica powder are uniformly dispersed dispersion in filmogen, plasticity of the present invention can also be improved, and add sodium laurate as tensio-active agent, not only improve hollow glass micropearl, organobentonite, talcum powder, zeolite powder, modified oxidized yttrium, the consistency of mica powder and filmogen, and can be combined by the organic polymer in filmogen, change amphipathic property of the present invention, for carrier of the present invention is selected to improve more selection, modified oxidized yttrium is by adopting hyperbranched polyphosphoramidate by aluminum-zirconium coupling agent grafting yttrium oxide, making curing activation energy of the present invention reduce, also reduce solidification rate constant, cooperatively interact with siccative, reduce solidification temperature required, improve the speed of solidification.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 70 parts, urethane resin 13 parts, aldehyde ketone resin 18 parts, powder terpolymer EP rubber 8 parts, hollow glass micropearl 8 parts, organobentonite 5.6 parts, 800 order talcum powder 3.3 parts, 800 order zeolite powders 7.5 parts, modified oxidized yttrium 14 parts, mica powder 5.6 parts, diisononyl phthalate 2.9 parts, epoxy Siberian cocklebur butyl oleate 6 parts, sodium laurate 5 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3.4 parts, nano-sized magnesium hydroxide 15 parts, antimonous oxide 4.8 parts, siccative 10 parts, pigment 13 parts, toughner 3.8 parts, defoamer 1.6 parts, advection agent 2.6 parts, mould inhibitor 1.1 parts, wherein the ethylene, propylene of powder terpolymer EP rubber is than being 70:30, the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, after adding nano yttrium oxide again, continue after intensification to stir, then vacuum-drying obtains the first mixture, stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir, after the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
Embodiment 2
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 68 parts, urethane resin 15 parts, aldehyde ketone resin 16 parts, powder terpolymer EP rubber 10 parts, hollow glass micropearl 6 parts, organobentonite 7 parts, talcum powder 3 parts, zeolite powder 9 parts, modified oxidized yttrium 12 parts, mica powder 7 parts, diisononyl phthalate 2.5 parts, epoxy Siberian cocklebur butyl oleate 8 parts, sodium laurate 3 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 5 parts, nano-sized magnesium hydroxide 13 parts, antimonous oxide 6 parts, siccative 8 parts, pigment 15 parts, toughner 3 parts, defoamer 2 parts, advection agent 2 parts, mould inhibitor 2 parts, wherein the ethylene, propylene of powder terpolymer EP rubber is than being 65:35, the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, after adding nano yttrium oxide again, continue after intensification to stir, then vacuum-drying obtains the first mixture, stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir, after the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
Embodiment 3
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 71 parts, urethane resin 12 parts, aldehyde ketone resin 19 parts, powder terpolymer EP rubber 7 parts, hollow glass micropearl 9 parts, organobentonite 5 parts, talcum powder 5 parts, zeolite powder 7 parts, modified oxidized yttrium 15 parts, mica powder 5 parts, diisononyl phthalate 3 parts, epoxy Siberian cocklebur butyl oleate 5 parts, sodium laurate 6 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3 parts, nano-sized magnesium hydroxide 16 parts, antimonous oxide 4 parts, siccative 11 parts, pigment 12 parts, toughner 4 parts, defoamer 1.5 parts, advection agent 3 parts, mould inhibitor 1 part, wherein the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, then after adding nano yttrium oxide, continue after intensification to stir, then vacuum-drying obtains the first mixture, stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir, after the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
Embodiment 4
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 69 parts, urethane resin 14 parts, aldehyde ketone resin 17 parts, powder terpolymer EP rubber 9 parts, hollow glass micropearl 7 parts, organobentonite 6.7 parts, 700 order talcum powder 4.5 parts, 700 order zeolite powders 8.3 parts, modified oxidized yttrium 13 parts, mica powder 6.2 parts, diisononyl phthalate 2.7 parts, epoxy Siberian cocklebur butyl oleate 7 parts, sodium laurate 4 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 4.1 parts, nano-sized magnesium hydroxide 14 parts, antimonous oxide 5.6 parts, siccative 9 parts, pigment 14 parts, toughner 3.5 parts, defoamer 1.8 parts, advection agent 2.2 parts, mould inhibitor 1.4 parts, wherein the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, then after adding nano yttrium oxide, continue after intensification to stir, then vacuum-drying obtains the first mixture, stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir, after the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
Embodiment 5
The acrylic resin modified coating of a kind of flame-proof abrasion-resistant that the present invention proposes, its raw material comprises by weight: acrylic resin 69 parts, urethane resin 14 parts, aldehyde ketone resin 17 parts, powder terpolymer EP rubber 9 parts, hollow glass micropearl 7 parts, organobentonite 6 parts, 750 order talcum powder 4 parts, 750 order zeolite powders 8 parts, modified oxidized yttrium 13.3 parts, mica powder 6 parts, diisononyl phthalate 2.8 parts, epoxy Siberian cocklebur butyl oleate 6.7 parts, sodium laurate 4.5 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 4 parts, nano-sized magnesium hydroxide 14.5 parts, antimonous oxide 5 parts, siccative 9.4 parts, pigment 13.4 parts, toughner 3.7 parts, defoamer 1.7 parts, advection agent 2.5 parts, mould inhibitor 1.3 parts, wherein the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, then after adding nano yttrium oxide, continue after intensification to stir, then vacuum-drying obtains the first mixture, stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir, after the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (7)

1. the acrylic resin modified coating of flame-proof abrasion-resistant, it is characterized in that, its raw material comprises by weight: acrylic resin 68-71 part, urethane resin 12-15 part, aldehyde ketone resin 16-19 part, powder terpolymer EP rubber 7-10 part, hollow glass micropearl 6-9 part, organobentonite 5-7 part, talcum powder 3-5 part, zeolite powder 7-9 part, modified oxidized yttrium 12-15 part, mica powder 5-7 part, diisononyl phthalate 2.5-3 part, epoxy Siberian cocklebur butyl oleate 5-8 part, sodium laurate 3-6 part, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3-5 part, nano-sized magnesium hydroxide 13-16 part, antimonous oxide 4-6 part, siccative 8-11 part, pigment 12-15 part, toughner 3-4 part, defoamer 1.5-2 part, advection agent 2-3 part, mould inhibitor 1-2 part.
2. the acrylic resin modified coating of flame-proof abrasion-resistant according to claim 1, is characterized in that, the ethylene, propylene of powder terpolymer EP rubber is than being 65-70:30-35.
3. the acrylic resin modified coating of flame-proof abrasion-resistant according to claim 1 or 2, it is characterized in that, talcum powder and zeolite powder are 700-800 order.
4. the acrylic resin modified coating of flame-proof abrasion-resistant according to any one of claim 1-3, is characterized in that, the weight ratio of acrylic resin, urethane resin, aldehyde ketone resin and powder terpolymer EP rubber is 69-70:13-14:17-18:8-9.
5. the acrylic resin modified coating of flame-proof abrasion-resistant according to any one of claim 1-4, it is characterized in that, its raw material comprises by weight: acrylic resin 69-70 part, urethane resin 13-14 part, aldehyde ketone resin 17-18 part, powder terpolymer EP rubber 8-9 part, hollow glass micropearl 7-8 part, organobentonite 5.6-6.7 part, 700-800 order talcum powder 3.3-4.5 part, 700-800 order zeolite powder 7.5-8.3 part, modified oxidized yttrium 13-14 part, mica powder 5.6-6.2 part, diisononyl phthalate 2.7-2.9 part, epoxy Siberian cocklebur butyl oleate 6-7 part, sodium laurate 4-5 part, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 3.4-4.1 part, nano-sized magnesium hydroxide 14-15 part, antimonous oxide 4.8-5.6 part, siccative 9-10 part, pigment 13-14 part, toughner 3.5-3.8 part, defoamer 1.6-1.8 part, advection agent 2.2-2.6 part, mould inhibitor 1.1-1.4 part.
6. the acrylic resin modified coating of flame-proof abrasion-resistant according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight: acrylic resin 69 parts, urethane resin 14 parts, aldehyde ketone resin 17 parts, powder terpolymer EP rubber 9 parts, hollow glass micropearl 7 parts, organobentonite 6 parts, 750 order talcum powder 4 parts, 750 order zeolite powders 8 parts, modified oxidized yttrium 13.3 parts, mica powder 6 parts, diisononyl phthalate 2.8 parts, epoxy Siberian cocklebur butyl oleate 6.7 parts, sodium laurate 4.5 parts, tricresyl phosphate (1, the chloro-2-propyl group of 3-bis-) ester 4 parts, nano-sized magnesium hydroxide 14.5 parts, antimonous oxide 5 parts, siccative 9.4 parts, pigment 13.4 parts, toughner 3.7 parts, defoamer 1.7 parts, advection agent 2.5 parts, mould inhibitor 1.3 parts.
7. the acrylic resin modified coating of flame-proof abrasion-resistant according to any one of claim 1-6, it is characterized in that, the preparation method of modified oxidized yttrium is: added in methylene dichloride by aluminum-zirconium coupling agent TL-4 and stir, after adding nano yttrium oxide again, continue after intensification to stir, then vacuum-drying obtains the first mixture; Stir after hyperbranched polyphosphoramidate being added methylene dichloride, then after adding the first mixture, heating in water bath obtains the second mixture, do not stop in heating in water bath process to stir; After the second mixture suction filtration, vacuum-drying obtains modified oxidized yttrium.
CN201410679797.2A 2014-11-24 2014-11-24 Flame-retardant wear-resisting modified acrylic resin coating Pending CN104449136A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105255349A (en) * 2015-11-09 2016-01-20 江苏有能电力自动化有限公司 Corrosion-resistant and wear-resistant multi-ported valve
CN105348931A (en) * 2015-11-09 2016-02-24 江苏有能电力自动化有限公司 High-efficiency chromatography heating device
CN107629559A (en) * 2017-09-22 2018-01-26 深圳市晟腾企业管理有限公司 A kind of building coating with flameproof effect and preparation method thereof
CN107903011A (en) * 2017-12-01 2018-04-13 钱理 A kind of environmental-friendly construction material of antimycotic antiseptic

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504146A (en) * 2011-11-18 2012-06-20 广东工业大学 Preparation method and application of coupled modified nanometer yttrium oxide
CN103360605A (en) * 2013-06-13 2013-10-23 上海交通大学 Hyperbranched polyphosphate amide ester as well as preparation method and application thereof
CN103571292A (en) * 2013-10-16 2014-02-12 青岛华瑞胶业设备有限公司 Acrylic water-proof composite coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504146A (en) * 2011-11-18 2012-06-20 广东工业大学 Preparation method and application of coupled modified nanometer yttrium oxide
CN103360605A (en) * 2013-06-13 2013-10-23 上海交通大学 Hyperbranched polyphosphate amide ester as well as preparation method and application thereof
CN103571292A (en) * 2013-10-16 2014-02-12 青岛华瑞胶业设备有限公司 Acrylic water-proof composite coating

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
全国一级注册建筑师职业资格考试研究组: "《建筑材料与构造》", 31 January 2014, 北京科学技术出版社 *
刘嘉等: "《航空橡胶与密封材料》", 30 November 2011, 国防工业出版社 *
刘登良: "《涂层失效分析的方法和工作程序》", 31 October 2003, 化学工业出版社材料科学与工程出版中心 *
和丽秋等: "《消防燃烧学》", 30 June 2014, 机械工业出版社 *
秦浩正等: "《中学生学习辞典 化学卷》", 30 September 2012, 世界图书出版社 *
陈作璋等: "《新型建筑涂料涂装及标准化》", 31 July 2010, 化学工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105255349A (en) * 2015-11-09 2016-01-20 江苏有能电力自动化有限公司 Corrosion-resistant and wear-resistant multi-ported valve
CN105348931A (en) * 2015-11-09 2016-02-24 江苏有能电力自动化有限公司 High-efficiency chromatography heating device
CN107629559A (en) * 2017-09-22 2018-01-26 深圳市晟腾企业管理有限公司 A kind of building coating with flameproof effect and preparation method thereof
CN107903011A (en) * 2017-12-01 2018-04-13 钱理 A kind of environmental-friendly construction material of antimycotic antiseptic

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Application publication date: 20150325