CN1800283A - Insulating mold coating and its uses - Google Patents
Insulating mold coating and its uses Download PDFInfo
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- CN1800283A CN1800283A CN 200510000149 CN200510000149A CN1800283A CN 1800283 A CN1800283 A CN 1800283A CN 200510000149 CN200510000149 CN 200510000149 CN 200510000149 A CN200510000149 A CN 200510000149A CN 1800283 A CN1800283 A CN 1800283A
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Abstract
The invention relates to a insulating coating whose constituents include film forming substance 15-65 weight parts, nano porous SiO2 3-20 weight parts, nano iron oxide yellow 1-12 weight parts, dyestuff 5-30 weight parts, gasket material 3-22 weight parts, auxiliary agent 0.4-8 weight parts, and dissolvent 6-30 weight parts.
Description
Technical field
The present invention relates to a kind of coating, specifically relate to a kind ofly to be widely used in variously needing to lower the temperature, the novel heat-insulation coating of heat insulation device or building and uses thereof.
Background technology
The world today, human consumption sharp increase to the energy makes energy scarcity, thus the price that drives the energy and relevant series product thereof constantly raises.With China is example, and electricity consumption in recent years continues to occur nervous, total nearly 30 provincial power network power cuts to limit consumption in 2004, and a large amount of factories are forced to stop production, and cause a large amount of financial losses.The crude oil consumption of Chinese every day in 2003 increases by 440,000 barrels, and the contribution rate of global crude oil demand growth is reached 35%; To the year two thousand twenty, the following of China's Oil demand is limited to 4.5 hundred million tons, on be limited to 6.1 hundred million tons, the energy demand total amount of China will reach 2,500,000,000 tons of standard coals, this numeral exceeded 90%～152% than 2000, the interdependency of overseas source is reached more than 55% to the major general, about the same with the external interdependency of the present U.S. 58%.Though the mankind constantly attempt tapping a new source of energy, also do not find at present a kind ofly can substitute the new forms of energy that oil, coal, Sweet natural gas etc. are related to national economy fully.Therefore, how to utilize the energy, minimizing energy dissipation just to seem more important efficiently.
Cause the reason of energy dissipation a lot.With heat insulation field is example, during the broiling summer, because the radiation of the sun, the metal of petrochemical complex, brewery and cement storage tank surface temperature up to five or six ten the degree, jar in temperature in addition can be higher, not only cause a large amount of vapour loss, contaminate environment, and can cause danger.Tradition brushing silver paint and use the spray water cooling, wastes energy at etching apparatus, and service life of equipment is short, only has 1 year.The intensification of silo grain depot can be quickened the bad change of grain and infested, and is big with the air-conditioning temperature-reducing power consumption, the cost height.The plant and instrument of aircraft, factory etc. has reduced work-ing life or has reduced tolerance range owing to being subjected to thermal radiation or ir radiation, has caused waste equally.In a word, from the Industrial buildings to covil construction, from storage tank, pipeline, factory building, warehouse, plant and instrument, aircraft to residential building, the Room of selling goods, the phone Room etc. owing to the influence that raying heats up uses conventional methods cooling, all can cause the waste of great amount of manpower and material resources, financial resources.
People have early had recognized that the importance of this problem, and propose and implemented multiple terms of settlement.In existing related techniques, Chinese patent CN1204672A discloses a kind of white modified acroleic acid alcohol acids coating capable of reflecting sun-heat, but its solar heat reflection rate is low, only has 80%, and color is single, and outdoor weatherability is relatively poor.Chinese patent CN1405248A discloses a kind of acrylic resin sun-heat reflecting coating, but its sticking power is relatively poor, and shock strength is not high, and the solar heat specific absorption changes bigger in time, and does not have the performance of reflected infra-red radiation.Chinese patent CN1257897A discloses and a kind ofly can reflect solar heat, the thermal insulating coating of certain heat insulation and automatic cleaning action is arranged again, but effect is not fine.In addition, the reflective coating that Japanese Patent JP98-1209466, German patent DE 19501114, U.S. Pat 5540998, Chinese patent CN1434063A disclose, reflectivity is not high, and heat-insulating efficiency neither be fine.
Summary of the invention
The reflectivity that the objective of the invention is to overcome existing solar heat reflection paint is low, heat-insulating efficiency is not fine and color is single, outdoor weatherability and sticking power is relatively poor, shock strength is not high defective, thereby providing a kind of all has high-reflectivity, heat-insulating efficiency height, anti-uv-ray strong to solar heat and ir radiation, and the novel heat-insulation coating with super-weathering resistance, strong adhesive force and high self-cleaning performance, and uses thereof.
The objective of the invention is to realize by the following technical solutions:
Thermal insulating coating provided by the invention, its composition comprises:
Film forming matter 15～65 weight parts;
Nanoporous SiO
23～20 weight parts;
Nano iron oxide yellow 1～12 weight part;
Pigment 5～30 weight parts;
Filler 3～22 weight parts;
Auxiliary agent 0.4～8 weight part;
Solvent 6～30 weight parts;
Described film forming matter comprises vibrin, Synolac, Resins, epoxy, acrylic resin, aminoresin, resol, polyvinyl chloride (PVC) RESINS, organosilicon modified polyester resin, organosilicon modified crylic acid resin, silicone resin, fluorocarbon resin, according to different performance requriementss, select different resins.
Described nanoporous SiO
2Particle diameter be 10～600nm, its preparation method is as follows: add 100ml ethanol in there-necked flask, stir that to add 0.2～1.2ml concentration down be the salt solution of 0.1M and the ethanolic soln of 0.1M polymkeric substance; continue under the room temperature to stir; logical nitrogen is protected, and adds the positive tetraethyl orthosilicate (TEOS) of 0.8～4.2ml again, fully stirs 1～5h; leave standstill; use washing with alcohol after the centrifugation, repeatedly for several times, at last at 230～460 ℃ of following sintering; sieve, promptly obtain nanoporous SiO
2
Wherein, described salt comprises NaCl, NaI, KBr, KCl, KI, KNO
3, LiCl, CsCl etc.;
Described polymkeric substance is R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y, z=1～65, and molar mass is 1650～2900g/mol.
The particle diameter of described nano iron oxide yellow is 10～500nm, and is disclosed among its preparation method such as the CN200410047955.3.
Described pigment is to be selected from rutile titanium white, phthalocyanine blue, phthalocyanine green, carbon black, red iron oxide, zinc-chrome yellow, medium chrome yellow medium yellow, Lemon chrome yellow, deep chrome yellow, chrome green, the molybdenum red one or more.
Described filler is to be selected from zinc oxide, barium sulfate, silicon-dioxide, talcum powder, sericite, light calcium carbonate, the wollastonite powder one or more.
Described auxiliary agent comprises that dispersion agent is (as BYK-110, BYK-P104, the Disperbyk-130 of German BYK Chemie company; Efka-766, the Efka Polymer452 of Holland EFKA company), defoamer is (as BYK-065, the BYK-052 of German BYKChemie company; The Efka-20 of Holland EFKA company; The Airex970 of Germany Tego company), flow agent is (as BYK-354, the BYK-300 of German BYK Chemie company; Efka-30, the Efka-772 of Holland EFKA company), acid catalyst (as German BYK Chemie company BYK-Catalyst450; NACURE155,1051, the K-CURE1040 of KIMG INDUSTRIES company), anti-settling agent is (as anti-settling agent 902, the 201P of the modest trading company of Taiwan moral; The BORCHIGEL THIXO Z of Germany Bayer company etc.), softening agent is (as plasticizer DOP, the tributyl phosphate of Shanghai solvent factory; The EDENOL of Germany Henkel company
344), slip(ping)agent (is changed 840SL, the AMA of industrial corporation as Taiwan three; The A-C6 of Allied Signal company, Acumist B-6), thickening material is (as the DEHYSOL of German Henkel company
R, RILANIT
45), solidifying agent is (as KB, KC, the DBTDL curing catalyst of the modest trading company of Taiwan moral; The JTY curing catalyst of Taixing, Jiangxi coatings additive(s) factory) one or more in.
Described solvent is selected from one or more in ethyl acetate, butylacetate, ethylene glycol ether acetate, dimethylbenzene, butyl glycol ether, butanols, methyl iso-butyl ketone (MIBK), propylene glycol methyl ether acetate, sherwood oil, No. 200 varnish makers' and painters' naphtha, pimelinketone, No. 100, aromatic solvent, No. 150, aromatic solvent, No. 200, aromatic solvent, the mixed dibasic acid diester.
Above-mentioned component is mixed, after disperseing, grind, mixing colours, promptly obtain thermal insulating coating of the present invention.
Thermal insulating coating provided by the invention can be widely used in various cooling, heat insulation device or the buildings of needing, especially for exterior wall, metal tank, pipeline, plant and instrument, transport trade, Industrial buildings, covil construction and aircraft etc.The coat-thickness of 20 μ m can obviously improve heat-insulating cooling effect, and best coating thickness is 35～45 μ m.
When being used for exterior wall, storage tank, pipeline, plant and instrument, aircraft etc., novel heat-insulation coating provided by the invention is formed preferred following composition:
Film forming matter 15～50 weight parts;
Nanoporous SiO
24～20 weight parts;
Nano iron oxide yellow 1～9 weight part;
Pigment 5～30 weight parts;
Filler 6～22 weight parts;
Auxiliary agent 0.4～6 weight part;
Solvent 6～25 weight parts.
Be used for factory building, warehouse, during color steel such as the Room of selling goods, the phone Room, novel heat-insulation coating provided by the invention is formed preferred following composition:
Film forming matter 20～65 weight parts;
Nanoporous SiO
23～18 weight parts;
Nano iron oxide yellow 3～12 weight parts;
Pigment 5～30 weight parts;
Filler 3～20 weight parts;
Auxiliary agent 0.6～8 weight part;
Solvent 10～30 weight parts.
Novel heat-insulation coating provided by the invention is compared with existing solar heat reflection paint, and its advantage is: paint adhesion is strong, and antiseptic property is good, good weatherability, and the scratch resistance ability is strong, both can make priming paint and also can make finish paint; And the reflective thermal radiation ability is strong, the heat-insulating efficiency height, and the coat-thickness of 20 μ m can obviously improve heat-insulating cooling effect, and best coating thickness is 35～45 μ m; In addition, this novel heat-insulation coating has good self-cleaning performance simultaneously, and reflectivity changes less in time.
Embodiment
Below in conjunction with example the present invention is further described in detail, but is not limited thereto.
Wherein, described nanoporous SiO
2Be self-control as follows: add 100ml ethanol in there-necked flask, stirring down, adding 0.2～1.2ml concentration is salt solution (NaCl, NaI, KBr, KCl, KI, the KNO of 0.1M
3, LiCl or CsCl) and 0.1M polymkeric substance (R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y; z=1～65, and molar mass is 1650～2900g/mol) ethanolic soln, continues under the room temperature to stir; logical nitrogen is protected, and adds the positive tetraethyl orthosilicate (TEOS) of 0.8～4.2ml again, fully stirs 1～5h; leave standstill; use washing with alcohol after the centrifugation, repeatedly for several times, at last at 230～460 ℃ of following sintering; sieve, promptly obtain nanoporous SiO
2
Disclosed among the preparation method of described nano iron oxide yellow such as the CN200410047955.3.
Embodiment 1, sea blue Synolac novel external wall thermal insulating coating
The prescription of sea blue Synolac novel external wall thermal insulating coating provided by the invention is listed in table 1.
The prescription of table 1, sea blue Synolac novel external wall thermal insulating coating
| Material | Specification | Consumption/Kg | Supplier |
| Synolac nanoporous SiO 2Nanometer iron oxide yellow phthalocyanine blue titanium white carbon black lead chromate yellow blanc fixe sericite wollastonite dispersant defoamer levelling agent thickener slip agent anti-settling agent plasticizer butyl acetate | SintalR05 (oil content 35%) 200nm 300nm R1216-01BGS R960 N110 lemon chrome 501 1250m 800 orders 800 order BYK-110 BYK-065 Efka-30 DEHYSOLR MW-1875 201P DOP solvent | 25 4 1 3.8 7 0.1 0.13 3 4 2.5 0.8 0.2 0.2 0.2 0.2 0.15 0.15 10 | BYK Chemie company of BYK Chemie company of Multi Resine company self-control self-control Shenzhen Suzhou treasuredization carbon black company of Hua Su chemical company U.S. DuPont company Shanghai one Kechuang chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company Holland Shanghai solvent factory Shanghai east salt chemical engineering company of the modest trading company of Taiwan moral of the modest trading company of Taiwan moral of EFKA company Germany Henkel company |
Embodiment 2, the novel storage tank thermal insulating coating of white acrylic resin
The novel storage tank of white acrylic resin provided by the invention is listed in table 2 with the prescription of thermal insulating coating.
Table 2, the novel storage tank of the white acrylic resin prescription of thermal insulating coating
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin nanoporous SiO 2The antiseized slip agent thickener of nanometer iron oxide yellow titanium white blanc fixe sericite zinc oxide precipitated calcium carbonate dispersant defoamer acid catalyst levelling agent anti-settling agent plasticizer butyl acetate | 4404 (solid content 50 ± 1%) 300nm 350nm R960,1250 orders, 800 order A levels, 99.7% 1250 order BYK-P104 BYK-052 BYK-Catalyst450 Efka-772 840SL DEHYSOLR 201P Acumist B-6 solvent | 35 12 4 24 3 1 12 4 0.7 0.3 1.2 0.2 0.3 0.2 0.2 0.15 15 | Allied Signal company Shanghai east salt chemical engineering company of the industrial corporation Germany modest trading company of Taiwan moral of Henkel company is changed in Xinhua Resin Factory, Shanghai self-control self-control U.S. DuPont company Kechuang chemical company state sharp superfine powder company Liuzhou zinc product company state sharp superfine powder company Germany BYK Chemie company Germany BYK Chemie company Germany BYK Chemie company Holland EFKA company Taiwan three |
Embodiment 3, be used for machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating
The prescription that is used for machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating provided by the invention is listed in table 3.
Table 3, be used for the prescription of machinery equipment anti-infrared radiating acrylic resin novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin nanoporous SiO 2The nanometer iron oxide yellow | 4550 (solid content 55 ± 2%) 150nm 400nm | 50 15 12 | Xinhua Resin Factory, Shanghai's self-control self-control |
| Phthalocyanine blue titanium white carbon black medium chrome yellow blanc fixe sericite wollastonite dispersant defoamer levelling agent curing agent thickener anti-settling agent plasticizer butyl acetate | R1216-01 BGS R960 N115 103 1250 orders 800 orders 800 order Disperbyk-130 Efka-20 BYK-300 DBTDL RILANIT45 BORCHIGEL THIXO Z tributyl phosphate solvents | 3.8 8 0.1 0.13 3 1 2.5 0.5 0.15 0.15 4.6 0.2 0.15 0.15 17 | The modest trading company of Shenzhen Suzhou treasuredization carbon black company of Hua Su chemical company U.S. DuPont company Shanghai one Kechuang chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company Germany BYK Chemie company Holland EFKA company Germany BYK Chemie company Taiwan moral Germany Shanghai solvent factory Shanghai east salt chemical engineering company of Henkel company Germany Bayer company |
Embodiment 4, be used for the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft
The prescription that is used for the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft provided by the invention is listed in table 4.
Table 4, be used for the prescription of the inferior light organosilicon modified crylic acid resin novel heat-insulation coating of aircraft
| Material | Specification | Consumption/Kg | Supplier |
| Acrylic resin | AU-2608 (solid content 60%) | 30 | U.S. Rohm﹠Haas company |
| Silicone resin nanoporous SiO 2Nanometer iron oxide yellow titanium white zinc oxide sericite silicon-dioxide light calcium carbonate | MSE100 (solid content 100%) 30nm 150nm R960 A level 99.7% 800 order 800 orders 1250 orders | 12 17 10 11 3 1 3 1 | Germany Wacker company self-control self-control U.S. DuPont company Liuzhou zinc product company state sharp superfine powder company state sharp superfine powder company state sharp superfine powder company |
| Dispersant defoamer slip agent levelling agent thickener anti-settling agent plasticizer curing agent butyl acetate | Efka Polymer452 Airex970 Ceraflour960 Efka-30 RILANIT 45 902 EDENOL 344 KC solvents | 1 0.2 0.1 0.2 0.15 0.15 0.2 4 15 | The Holland modest trading company of Taiwan moral of the EFKA company Germany Tego company Germany BYK Chemie company Holland EFKA company Germany Henkel company Germany modest trading company of Taiwan moral of Henkel company Shanghai east salt chemical engineering company |
Novel heat-insulation coating to embodiment 1～4 preparation carries out performance test, lists in table 5.
Table 5, the test of novel heat-insulation coating property
| Test item | Technical indicator | Testing standard |
| Condition in container solids content % surface drying time/h time of doing solid work/h viscosity (being coated with-4 glasss/23 ℃)/s adhesive force rank resistance to water 96h acid resistance 24h 5% hydrochloric acid alkali resistance 48h10%NaOH efflorescence/level (500h) variable color/level (500h) abrasion resistance/time ultraviolet resistance 2000h artificial accelerated aging 2000h thermal conductivity w/ (mk) contact angle solar reflectivity | Even no lump 〉=65≤0.5≤24 90～120 1 grades of intact unchanged 0 grade of 0 grade 〉=10000 intact unchanged paint films of paint film intact unchanged 0.048 〉=105 ° 〉=0.92 of the intact unchanged paint film of the intact unchanged paint film of paint film | The outer committee of the outer detection of entrusting of range estimation GB1725-79 (89) GB1728-79 (89) GB1728-79 (89) GB1725-99 GB1720-79 (89) actual measurement GB1763-79 (89) GB1865-79 (89) detects and surveys the detection of the outer committee of GB1865-80 (89) GB10294 actual measurement |
Embodiment 5, silver grey polyester coiled material finish paint novel heat-insulation coating
The prescription of silver grey polyester coiled material finish paint novel heat-insulation coating provided by the invention is listed in table 6.
The prescription of table 6, silver grey polyester coiled material finish paint novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Polyester resin nano porous SiO 2No. 100 ethylene glycol ether acetates of the antiseized slip agent levelling agent of nanometer iron oxide yellow titanium white carbon black iron oxide yellow phthalocyanine blue zinc oxide sericite wollastonite precipitated calcium carbonate dispersant defoamer slip agent thickener acid catalyst curing agent anti-settling agent plasticizer cyclohexane ketone aromatic solvent | Desmophen 650 (solid content 65%) 400nm 30nm R960 N115 S313 R1216-01BGS A level, 99.7% 800 order 800 orders 1250 order Efka-766 Airex970 Ceraflour960 AMA BYK-354 RILANIT45 1051 JTY 201P EDENOL 344 solvent solvent solvents | 50 7.5 4 23 0.5 2 0.1 4 3 2 2 0.8 0.2 0.1 0.1 0.2 0.2 1.1 5 0.25 0.2 8.5 5 12 | Germany Bayer company self-control self-control U.S. DuPont Suzhou treasuredization carbon black company Shanghai one Liuzhou zinc product company of Shenzhen Hua Su chemical company of product pigment company state sharp superfine powder company state sharp superfine powder company state sharp superfine powder company Holland EFKA company Germany Tego company Germany BYK Chemie company Taiwan three is changed Rui'an City enterprise of the modest trading company of Taiwan moral of industrial corporation Germany BYK Chemie company Germany KING INDUSTRIES company Jiangxi Taixing coating additive factory of Henkel company Germany Henkel company and is levied Yangzhou Hua Lun chemical company of chemical company Jiangsu auxiliary reagent factory |
Embodiment 6, aminoresin curing polyester coiled material novel heat-insulation coating
The prescription of aminoresin curing polyester coiled material novel heat-insulation coating provided by the invention is listed in table 7.
The prescription of table 7, aminoresin curing polyester coiled material novel heat-insulation coating
| Material | Specification | Consumption/Kg | Supplier |
| Vibrin aminoresin nano porous SiO 2No. 100, No. 200 paint naphtha ethylene glycol ether acetates of nanometer iron oxide yellow titanium white zinc oxide precipitated calcium carbonate sericite dispersant defoamer acid catalyst levelling agent thickener slip agent anti-settling agent plasticizer aromatic solvent | Desmophen 1100 (solid content 100%) Resimene747 (solid content＞98%) 550nm 500nm R960 A level, 99.7% 800 order 800 order Disperbyk-130 Airex970 K-CURE1040 Efka-30 DEHYSOLR Acumist B-6 902 EDENOL 344 solvent solvent solvents | 60 5 11 5 22 3 4 4 0.8 0.2 0.3 0.2 0.2 0.1 0.15 0.15 8 12 10 | The Germany Bayer company U.S. Solutia.Inc. company self-control self-control U.S. DuPont company Liuzhou zinc product company state sharp superfine powder company state sharp superfine powder company Germany BYK Chemie company Germany modest trading company of Taiwan moral of Allied Signal company of KIMG INDUSTRIES company of Tego company Holland EFKA company Germany Henkel company Germany Henkel company Maoming City Yongjia chemical company Jiangsu auxiliary reagent factory Yangzhou Hua Lun chemical company |
Color steel to embodiment 5,6 preparations carries out performance test with novel coiled material thermal insulating coating, lists in table 8.
Table 8, the test of novel heat-insulation coating property
| Test item | Technical indicator | Testing standard |
| Fineness/μ m viscosity (being coated with-4 glasss/23 ℃)/s solid part/% curing performance/s (℃) 60 ° of gloss/% T curved shock-resistant/Kg.cm tack/anti-MEK of level pencil hardness/time salt spray resistance (2000h) wet-heat resisting (2000h) ultraviolet resistance (2000h) artificial accelerated aging (2000h) thermal conductivity w/ (mk) contact angle Solar reflectance | ≤ 20 80～110 〉=60 30～60 (224～232) (PMT) 〉=the intact unchanged paint film of the intact unchanged paint film of the intact unchanged paint film of 85≤3T 〉=80 0 〉=H 〉=120 paint films intact unchanged 0.048 〉=105 ° 〉=0.92 | GB1724-79 (89) GB1725-99 GB1725-79 (89) detects by the outer committee of the GB9754-88 of anti-solvent GB/T13448-92 ASTM2794-93 GB/T1732-93 GB/T6739-96 ASTMD5402 GB1771-91 GB/T1740-79 (89) actual measurement GB1865-80 (89) GB10294 actual measurement |
Embodiment 7, performance test 1
When the heat-proof quality of novel heat-insulation coating provided by the invention is tested, be that to be placed on wind little, fine, sun-drenched outdoor carrying out, this method is applied widely, all can test small-sized or large-scale experiment sample.
Get three blocks of sheet iron plates, size is 150mm * 150mm, wherein the surface of plate II, plate III respectively brushing thickness be the novel heat-insulation coating of the commercially available green shield solar heat reflection paint LD-RFS of 40 μ m and the embodiment of the invention 4 preparations, another piece plate I does not brush any coating in contrast.Sun-drenched outdoor the test, the surface temperature of iron sheet plate adopts infrared thermometer to measure, and temperature adopts J207-1-100 ± 0.1 a ℃ type thermometer to measure, and detects data and lists in table 9.
Table 9, sheet iron board test data
The fine wind speed of 2004-07-15≤2 grades
| Time | Temperature (℃) | Iron sheet plate I (℃) | Iron sheet plate II (℃) | Iron sheet plate III (℃) |
| 10:00 11:00 12:00 13:00 14:00 15:00 16:00 | 27.6 30.5 33.4 36.1 37.2 34.4 31.6 | 37 41.3 44.8 50.0 51.6 47.3 42.6 | 31.4 34.7 37.1 41.2 42.3 38.5 34.2 | 29.0 32.3 35.7 39.6 40.1 37.0 32.6 |
This shows, compare with the plate I that does not brush any coating, the cooling-down effect of iron sheet plate of plate II, plate III of novel heat-insulation coating of having brushed 4 preparations of commercially available green shield solar heat reflection paint LD-RFS and the embodiment of the invention is obvious, especially brushed the plate III of novel heat-insulation coating of the present invention, its effect of heat insulation is particularly evident.
And because the iron plate of test usefulness is little, influence factor is many, and flat plate radiation is fast, so the temperature difference is not very big.If the reduction influence factor is tested with the encloses container of high surface area, novel heat-insulation coating provided by the invention also can obtain more obvious cooling effect, and with to shine upon the area that contacts big more, cooling-down effect is good more.
Embodiment 8, performance test 2
The gasoline can of 200L under empty bucket condition, is used the novel heat-insulation coating brushing of the embodiment of the invention 6 preparations, numbering first bucket; Use commercially available green shield solar heat reflection paint LD-RFS brushing, numbering second bucket.Top and test with infrared thermometer apart from the staving side temperature at bottom 80cm place, all test surfaces are side to light, and temperature, staving is inner to adopt J207-1-100 ± 0.1 ℃ type thermometer test.Test result is listed in table 10.
Table 10, gasoline can test data
The fine wind speed salt of 2004-07-28≤2 grades
| The test duration test event | 10:00 first and second | 11:00 first and second | 12:00 first and second | 13:00 first and second | 14:00 first and second | 15:00 first and second | 16:00 first and second | |||||||
| Temperature | 28.8 | 30.5 | 32.2 | 35.0 | 36.2 | 34.4 | 33.0 | |||||||
| Side ℃ | 30.1 | 32.1 | 33.1 | 35.4 | 35.3 | 38.7 | 38.8 | 43.1 | 39.8 | 44.5 | 38.0 | 42.1 | 36.7 | 39.8 |
| Temperature head ℃ | 2.0 | 2.3 | 3.4 | 4.3 | 4.7 | 4.1 | 3.1 | |||||||
| Top ℃ | 31.5 | 34.9 | 35.6 | 39.0 | 38.9 | 42.6 | 41.6 | 46.1 | 42.7 | 47.9 | 42.0 | 47.0 | 40.2 | 44.4 |
| Temperature head ℃ | 3.4 | 3.4 | 3.7 | 4.5 | 5.2 | 5.0 | 4.2 | |||||||
| Inner ℃ | 29.6 | 30.4 | 31.8 | 33.1 | 34.6 | 36.7 | 36.9 | 39.6 | 39.0 | 42.5 | 36.8 | 39.9 | 35.6 | 37.9 |
| Temperature head ℃ | 0.8 | 1.3 | 2.1 | 2.7 | 3.5 | 3.1 | 2.3 | |||||||
This shows, compare that the cooling-down effect of first bucket of novel heat-insulation coating of having brushed the embodiment of the invention 6 preparations is more remarkable, and the high more cooling of sun direct projection temperature is obvious more with the second bucket of having brushed commercially available green shield solar heat reflection paint LD-RFS.
Embodiment 9, performance test 3
With certain 250m of brewery
3The empty wine jar of stainless steel uses the novel storage tank thermal insulating coating brushing of the embodiment of the invention 2 preparations, numbering first jar; The brushing of use silver powder, numbering second jar.This thermometric is under the slack tank condition, and all test surfaces are side to light; The tank surface temperature adopts the infrared thermometer test, and the tank interior temperature adopts J207-1-100 ± 0.1 ℃ thermometer test.Test result is listed in table 11.
Table 11,250m
3The empty wine jar of stainless steel test data
The fine wind speed of 2004-08-03≤2 grades
| The test duration test event | 9:00 | 10:00 | 11:00 | 12:00 | 13:00 | 14:00 | 15:00 |
| First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | First and second jars of jars | |
| Temperature (℃) | 31 | 32 | 33 | 33 | 34 | 34 | 34 |
| Humidity (%) | 63 | ||||||
| The tank body side (℃) | 34.2 45.3 | 35.4 46.7 | 37 47.1 | 384 6.8 | 38.6 44.5 | 39 43.9 | 40.5 44 |
| Temperature head (℃) | 11.1 | 11.3 | 10.1 | 8.8 | 5.9 | 4.9 | 3.5 |
| The tank body end face (℃) | 37.1 54.2 | 38.5 55.6 | 41.7 59.3 | 42.3 61.9 | 43.7 66.2 | 43.2 68.3 | 44 66.6 |
| Temperature head (℃) | 15.3 | 17.1 | 17.6 | 19.6 | 22.5 | 25.1 | 22.6 |
| Tank interior apart from tank deck 1m place (℃) | 33.5 42.6 | 35.4 45.8 | 35.7 49.4 | 36.4 53.1 | 37.2 53.8 | 37.4 55.2 | 37.5 55 |
| Temperature head (℃) tank interior apart from tank deck 5m place (℃) | 9.1 32.8 41.2 | 10.4 34.6 43.4 | 13.7 34.9 44.2 | 16.7 35.5 46.4 | 16.6 36.4 48.7 | 17.8 36.8 50 | 17.5 37 51.3 |
| Temperature head (℃) | 8.4 | 8.8 | 9.3 | 10.9 | 12.3 | 13.2 | 14.3 |
| Tank interior apart from tank deck 8m place (℃) | 32.6 40.4 | 34.2 41.8 | 34.6 42.4 | 35 44.1 | 35.9 44.5 | 36 45.1 | 36.3 46.8 |
| Temperature head (℃) | 7.8 | 7.6 | 7.8 | 9.1 | 8.6 | 9.1 | 10.5 |
The test experiments data show, compare with brushing silver paint second jar, the novel storage tank of white acrylic resin of having brushed the embodiment of the invention 2 preparations is all more obvious with the first jar appearance and the internal temperature decline of thermal insulating coating, can replace the existing silver paint that is coated with fully and add the method that spray water is lowered the temperature, and long service life, greatly reduce cost.
Claims (10)
1, a kind of thermal insulating coating, its composition comprises:
Film forming matter 15～65 weight parts;
Nanoporous SiO
23～20 weight parts;
Nano iron oxide yellow 1～12 weight part;
Pigment 5～30 weight parts;
Filler 3～22 weight parts;
Auxiliary agent 0.4～8 weight part;
Solvent 6～30 weight parts;
Described film forming matter comprises vibrin, Synolac, Resins, epoxy, acrylic resin, aminoresin, resol, polyvinyl chloride (PVC) RESINS, organosilicon modified polyester resin, organosilicon modified crylic acid resin, silicone resin, fluorocarbon resin;
Described filler is to be selected from zinc oxide, barium sulfate, silicon-dioxide, talcum powder, sericite, light calcium carbonate, the wollastonite powder one or more;
Described auxiliary agent comprises one or more in dispersion agent, defoamer, flow agent, acid catalyst, anti-settling agent, softening agent, slip(ping)agent, thickening material, the solidifying agent;
Above-mentioned component is mixed, after disperseing, grind, mixing colours, promptly obtain thermal insulating coating of the present invention.
2, thermal insulating coating as claimed in claim 1 is characterized in that: described nanoporous SiO
2Particle diameter be 10～600nm.
3, thermal insulating coating as claimed in claim 1 or 2 is characterized in that: described nanoporous SiO
2For making: in there-necked flask, add 100ml ethanol by following method; adding 0.2～1.2ml concentration under stirring is the salt solution of 0.1M and the ethanolic soln of 0.1M polymkeric substance, continues under the room temperature to stir, and logical nitrogen is protected; the positive tetraethyl orthosilicate that adds 0.8～4.2ml again; fully stir 1～5h, leave standstill, use washing with alcohol after the centrifugation; repeatedly for several times; at 230～460 ℃ of following sintering, sieve at last, promptly obtain nanoporous SiO
2
Wherein, described salt comprises NaCl, NaI, KBr, KCl, KI, KNO
3, LiCl, CsCl;
Described polymkeric substance is R
aO (CH
2CH
2O)
bH, R
aBe C
6～C
18Alkyl, b=3～15; Or HO (CH
2CH
2O) x (CH (CH
3) CH
2O) y (CH
2CH
2O) zH, x, y, z=1～65, and molar mass is 1650～2900g/mol.
4, thermal insulating coating as claimed in claim 1 is characterized in that: the particle diameter of described nano iron oxide yellow is 10～500nm.
5, thermal insulating coating as claimed in claim 1 is characterized in that: described pigment is to be selected from rutile titanium white, phthalocyanine blue, phthalocyanine green, carbon black, red iron oxide, zinc-chrome yellow, medium chrome yellow medium yellow, Lemon chrome yellow, deep chrome yellow, chrome green, the molybdenum red one or more.
6, thermal insulating coating as claimed in claim 1 is characterized in that: described dispersion agent is Efka-766, the EfkaPolymer452 of BYK-110, BYK-P104, the Disperbyk-130 of German BYK Chemie company, Dutch EFKA company;
Described defoamer is the Efka-20 of BYK-065, the BYK-052 of German BYK Chemie company, Dutch EFKA company; The Airex970 of Germany Tego company;
Described flow agent is Efka-30, the Efka-772 of BYK-354, the BYK-300 of German BYK Chemie company, Dutch EFKA company;
Described acid catalyst be German BYK Chemie company BYK-Catalyst450, NACURE155,1051, the K-CURE1040 of KIMGINDUSTRIES company;
Described anti-settling agent is the BORCHIGEL THIXO Z of the anti-settling agent 902,201P of the Taiwan modest trading company of moral, German Bayer company;
Described softening agent is the EDENOL of the plasticizer DOP, tributyl phosphate of Shanghai solvent factory, German Henkel company
344;
Described slip(ping)agent is 840SL, the AMA that industrial corporation is changed in Taiwan three; The A-C6 of Allied Signal company, Acumist B-6;
Described thickening material is the DEHYSOL of German Henkel company
R, RILANIT
45;
Described solidifying agent is KB, KC, the DBTDL curing catalyst of the Taiwan modest trading company of moral, the JTY curing catalyst of Taixing, Jiangxi coatings additive(s) factory.
7, thermal insulating coating as claimed in claim 1 is characterized in that: described solvent is selected from one or more in ethyl acetate, butylacetate, ethylene glycol ether acetate, dimethylbenzene, butyl glycol ether, butanols, methyl iso-butyl ketone (MIBK), propylene glycol methyl ether acetate, sherwood oil, No. 200 varnish makers' and painters' naphtha, pimelinketone, No. 100, aromatic solvent, No. 150, aromatic solvent, No. 200, aromatic solvent, the mixed dibasic acid diester.
8, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 15～50 weight parts;
Nanoporous SiO
24～20 weight parts;
Nano iron oxide yellow 1～9 weight part;
Pigment 5～30 weight parts;
Filler 6～22 weight parts;
Auxiliary agent 0.4～6 weight part;
Solvent 6～25 weight parts.
9, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 20～65 weight parts;
Nanoporous SiO
23～18 weight parts;
Nano iron oxide yellow 3～12 weight parts;
Pigment 5～30 weight parts;
Filler 3～20 weight parts;
Auxiliary agent 0.6～8 weight part;
Solvent 10～30 weight parts.
10, claim 1,8 or 9 described thermal insulating coatings variously need to lower the temperature, heat insulation device or architectural application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100001490A CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100001490A CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1800283A true CN1800283A (en) | 2006-07-12 |
| CN100357378C CN100357378C (en) | 2007-12-26 |
Family
ID=36810504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100001490A Expired - Fee Related CN100357378C (en) | 2005-01-05 | 2005-01-05 | Insulating mold coating and its uses |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100357378C (en) |
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