CN100355711C - 获取乙醇的方法 - Google Patents

获取乙醇的方法 Download PDF

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Publication number
CN100355711C
CN100355711C CNB2004800067881A CN200480006788A CN100355711C CN 100355711 C CN100355711 C CN 100355711C CN B2004800067881 A CNB2004800067881 A CN B2004800067881A CN 200480006788 A CN200480006788 A CN 200480006788A CN 100355711 C CN100355711 C CN 100355711C
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China
Prior art keywords
extractant
ethanol
membrane
liquid
feed
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Expired - Fee Related
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CNB2004800067881A
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English (en)
Chinese (zh)
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CN1759086A (zh
Inventor
丹·L·范泽洛
詹姆斯·S·姆罗辛斯基姆
托德·W·约翰逊
布林达·B·拉克希米
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB2004800067881A 2003-03-13 2004-01-22 获取乙醇的方法 Expired - Fee Related CN100355711C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/387,697 2003-03-13
US10/387,697 US7122709B2 (en) 2003-03-13 2003-03-13 Method for obtaining ethanol

Publications (2)

Publication Number Publication Date
CN1759086A CN1759086A (zh) 2006-04-12
CN100355711C true CN100355711C (zh) 2007-12-19

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CNB2004800067881A Expired - Fee Related CN100355711C (zh) 2003-03-13 2004-01-22 获取乙醇的方法

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US (1) US7122709B2 (https=)
EP (2) EP1603855B1 (https=)
JP (1) JP2006520398A (https=)
CN (1) CN100355711C (https=)
AT (1) ATE392405T1 (https=)
AU (1) AU2004221906A1 (https=)
BR (1) BRPI0408224B1 (https=)
CA (1) CA2518849C (https=)
DE (1) DE602004013129T2 (https=)
RU (1) RU2005127414A (https=)
WO (1) WO2004083158A1 (https=)
ZA (1) ZA200508248B (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7105089B2 (en) * 2003-03-13 2006-09-12 3M Innovative Properties Company Liquid—liquid extraction system and method
US7608438B2 (en) * 2005-04-05 2009-10-27 Jessica Laviolette Process for the continuous production of ethanol
US7794593B2 (en) * 2005-11-30 2010-09-14 3M Innovative Properties Company Cross-flow membrane module
CA2747827A1 (en) 2008-12-23 2010-07-01 Poet Research, Inc. System for production of ethanol and co-products
US8652818B2 (en) 2008-12-31 2014-02-18 Poet Research, Inc. Method for extracting protein from a fermentation product
WO2011026690A1 (en) * 2009-09-02 2011-03-10 Huntsman International Llc A method for removing methylene-bridged polyphenyl polyamines from an aqueous stream
BR112012031872A2 (pt) * 2010-06-14 2015-11-24 3M Innovative Properties Co método de remoção de inibidores de biomassa celulósica e de produção de álcoois
DE102012017860A1 (de) 2012-09-11 2014-05-15 Peter Vinz Behandlungsmethode zum Ab- und Anreichern oder Trennen von Flüssigkeitsgemischen
TWI494433B (zh) * 2012-10-15 2015-08-01 Green Cellulosity Corp 製造羧酸及／或醇的方法
US9139803B2 (en) * 2013-07-11 2015-09-22 Poet Research, Inc Ethanol fermentation methods and systems
US10752875B2 (en) * 2014-07-11 2020-08-25 Archer-Daniels-Midland Company System and method for extracting ethanol from a fermentation broth
EP3907209A4 (en) * 2019-01-28 2022-03-30 Sekisui Chemical Co., Ltd. ETHANOL
US12534424B2 (en) 2019-07-29 2026-01-27 Evonik Operations Gmbh Extraction of aliphatic alcohols
US11724213B2 (en) * 2020-02-27 2023-08-15 Lawrence Livermore National Security, Llc Modular, disposable 3D printed microfluidic membrane system for separation and purification

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4306884A (en) * 1980-12-18 1981-12-22 Biohol Corporation Alcohol and fuel production
US4966707A (en) * 1986-05-13 1990-10-30 Celanese Corporation Liquid/liquid extractions with microporous membranes

Family Cites Families (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB155713A (en) 1919-12-31 1920-12-30 Masch Werke Zu Frankfurt A M Improvements in and relating to surface measuring machines
US3332746A (en) * 1963-03-29 1967-07-25 Single Cell Res Foundation Inc Pulsatile membrane oxygenator apparatus
US3428553A (en) * 1966-02-03 1969-02-18 Chyn Duog Shiah Separating primary solvent with a secondary solvent
US3801404A (en) * 1970-10-28 1974-04-02 Celanese Corp Novel open-celled microporous film
US3839516A (en) * 1971-06-25 1974-10-01 Res Triangle Inst Process for the preparation of opencelled microporous films
BE792941A (fr) * 1971-12-20 1973-06-18 Sandoz Sa Dialyseur, notamment pour l'epuration du sang
US3956112A (en) * 1973-01-02 1976-05-11 Allied Chemical Corporation Membrane solvent extraction
US3843761A (en) * 1973-05-30 1974-10-22 Celanese Corp Process for preparing a thermoplastic microporous film involving a cold stretching step and multiple hot stretching steps
CH569501A5 (https=) * 1973-06-19 1975-11-28 Schleiffer Louis Ag
US3872014A (en) * 1974-03-11 1975-03-18 Aerojet General Co Membrane separation apparatus
JPS5215627A (en) * 1975-07-09 1977-02-05 Mitsubishi Rayon Co Ltd Porous polypropylene hollow fibers and a process for manufacturing the m
US4532347A (en) * 1978-07-28 1985-07-30 Varen Technology Membrane solvent extraction process
US4257997A (en) * 1979-06-01 1981-03-24 Celanese Corporation Solvent stretch process for preparing a microporous film
US4276179A (en) * 1979-06-01 1981-06-30 Celanese Corporation Removing halogenated hydrocarbons from aqueous media by utilizing a polyolefinic microporous adsorbent
US4255376A (en) * 1979-06-01 1981-03-10 Celanese Corporation Solvent stretch process for preparing microporous films from precursor films of controlled crystalline structure
FI71573C (fi) * 1979-06-15 1987-01-19 Akzo Nv Foerfarande och anordning foer minskning av jaesta dryckers alkoholhalt genom dialys.
US4251231A (en) * 1979-09-13 1981-02-17 Artisan Industries Inc. Direct process for the production of gasohol from fermentation mixtures
US4340475A (en) * 1980-01-22 1982-07-20 A.T. Ramot Plastics Ltd. Membrane separation cell
US4298693A (en) * 1980-07-29 1981-11-03 Wallace Michael W Fermentation apparatus
US4441891A (en) * 1980-12-18 1984-04-10 Biohol Corporation Gasoline-aided production of alcohol and fuel
US4369112A (en) * 1981-03-18 1983-01-18 Gelman Sciences Inc. Filter device
US4517298A (en) * 1981-05-08 1985-05-14 Georgia Tech Research Corporation Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation
US4510242A (en) * 1981-07-15 1985-04-09 Georgia Tech Research Corporation Process for producing fuel grade alcohol by solvent extraction and carrier gas stripping
US4692432A (en) * 1981-07-15 1987-09-08 Georgia Tech Research Corporation Two cycle process for producing fuel-grade ethanol from dilute aqueous mixtures
US4399000A (en) * 1981-10-07 1983-08-16 Georgia Tech Research Institute Process for producing absolute alcohol by solvent extraction and vacuum distillation
US4405688A (en) * 1982-02-18 1983-09-20 Celanese Corporation Microporous hollow fiber and process and apparatus for preparing such fiber
US4520213A (en) * 1982-05-03 1985-05-28 Institute Of Gas Technology Method for solvent recovery in solvent separation of ethanol from water
US4997569A (en) * 1984-08-28 1991-03-05 The Trustees Of The Stevens Institute Of Technology Immobilized-interface solute-transfer process
US4789468A (en) * 1984-08-28 1988-12-06 The Trustees Of The Stevens Institute Of Technology Immobilized-interface solute-transfer apparatus
US4617127A (en) * 1985-05-20 1986-10-14 Allied Corporation Production of low alcoholic content beverages
US4717482A (en) * 1985-05-20 1988-01-05 Allied Corporation Production of low alcoholic content beverages
ZA865173B (en) * 1985-07-31 1987-03-25 Celanese Corp Immobilized liquid membrane
US5036005A (en) * 1987-05-22 1991-07-30 Georgia Tech Research Corporation Alcohol recovery by continuous fermentation
US5215902A (en) * 1985-08-12 1993-06-01 Georgia Tech Research Corporation Process for recovering alcohol with energy integration
US4865973A (en) * 1985-09-13 1989-09-12 Queen's University At Kingston Process for extractive fermentation
JPS6279808A (ja) 1985-10-04 1987-04-13 Nitto Electric Ind Co Ltd 有機溶剤に溶解する物質の抽出方法およびその装置
US4933198A (en) * 1985-10-11 1990-06-12 Lee Eric K L Production of low-ethanol beverage by membrane extraction
US4778688A (en) * 1985-10-11 1988-10-18 Sepracor, Inc. Production of low-ethanol beverages by membrane extraction
US4921612A (en) * 1985-10-22 1990-05-01 The Trustees Of Stevens Institute Of Technology Asymmetrically-wettable porous membrane process
EP0254758B1 (en) * 1986-07-29 1991-06-26 GFT Gesellschaft für Trenntechnik mbH Pervaporation process and membrane
JPS6380802A (ja) 1986-09-25 1988-04-11 Kurita Water Ind Ltd 平膜型抽出装置
US4726989A (en) * 1986-12-11 1988-02-23 Minnesota Mining And Manufacturing Microporous materials incorporating a nucleating agent and methods for making same
JPS63209704A (ja) 1987-02-27 1988-08-31 Kurita Water Ind Ltd 平膜型抽出装置
DK641887D0 (da) * 1987-12-07 1987-12-07 Danske Sukkerfab Apparat til fraktionering af en vaeske i to fraktioner ved membranfiltrering
SE457605B (sv) 1988-01-18 1989-01-16 Gambro Ab Anordning foer diffusion av aemnen mellan tvaa fluida
DE3804236A1 (de) * 1988-02-11 1989-08-24 Gft Ges Fuer Trenntechnik Verfahren zur reduktion des alkoholgehaltes von alkoholischen getraenken
US4976867A (en) * 1989-04-05 1990-12-11 Hoechst Celanese Corporation Systems and methods for predetermining maximum pressure differentials for microporous hollow fibers employed in liquid-liquid extractions
US5104532A (en) 1989-09-15 1992-04-14 Exxon Research And Engineering Company Flat stack permeator
US5120594A (en) * 1989-11-20 1992-06-09 Minnesota Mining And Manufacturing Company Microporous polyolefin shaped articles with patterned surface areas of different porosity
US5238623A (en) * 1989-11-20 1993-08-24 Minnesota Mining And Manufacturing Company Method for preparing microporous polyolefin shaped articles
CA2003539C (en) 1989-11-21 1999-04-27 Oleh Kutowy A fluid fractionating, stacked permeable membrane envelope assembly, and a fluid distributing and permeable membrane sealing collar
US5096584A (en) * 1990-01-29 1992-03-17 The Dow Chemical Company Spiral-wound membrane separation device with feed and permeate/sweep fluid flow control
SE9002652L (sv) 1990-08-15 1992-02-16 Asea Brown Boveri Filterplatta
US5041227A (en) 1990-10-09 1991-08-20 Bend Research, Inc. Selective aqueous extraction of organics coupled with trapping by membrane separation
US5120900A (en) * 1990-12-05 1992-06-09 Exxon Research And Engineering Company Integrated solvent extraction/membrane extraction with retentate recycle for improved raffinate yield
US5114582A (en) 1991-04-12 1992-05-19 W. R. Grace & Co.-Conn. Filter element and spiral-wound membrane cartridge containing same
US5449457A (en) * 1991-04-22 1995-09-12 Hoechst Celanese Corporation Liquid membrane modules with minimal effective membrane thickness and methods of making the same
JP2637890B2 (ja) * 1992-03-20 1997-08-06 モンサント カンパニー 水性溶液から有機化合物を除去する方法
IL101906A0 (en) 1992-05-18 1992-12-30 Yissum Res Dev Co Extraction of electrolytes from aqueous solutions
GB9210980D0 (en) * 1992-05-22 1992-07-08 Dow Danmark Cassette membrane system and method of use for low pressure separations
JP2937678B2 (ja) 1993-01-14 1999-08-23 株式会社ユアサコーポレーション 濾過モジュール
JP3264028B2 (ja) 1993-03-26 2002-03-11 栗田工業株式会社 膜分離装置
JPH06327946A (ja) 1993-05-21 1994-11-29 Yuasa Corp 濾過モジュール
US5614286A (en) * 1993-10-20 1997-03-25 Minnesota Mining And Manufacturing Company Conformable cube corner retroreflective sheeting
DE4342485C1 (de) 1993-12-13 1995-03-30 Gore W L & Ass Gmbh Vorrichtung zur Entfernung von gasförmigen Stoffen aus einem Gasstrom
TW255835B (en) 1994-01-07 1995-09-01 Kubota Kk Filtration membrane module
JPH07313847A (ja) 1994-05-25 1995-12-05 Yuasa Corp 濾過モジュール
PT707884E (pt) * 1994-10-21 2001-09-28 Rochem Ultra Systeme Gesel Fur Dispositivo para a filtracao e separacao em especial de meios correntes biocogico-organicos por meio de elementos de filtro formados por almofadas de membranas
JP4015187B2 (ja) * 1994-10-22 2007-11-28 ブリティッシュ ニュークリア フュエルズ パブリック リミティド カンパニー 不混和性流体間の拡散移動のための方法及び装置
ATE235292T1 (de) 1994-10-22 2003-04-15 Central Research Lab Ltd Verfahren und vorichtung fur diffusionsaustausch zwischen nicht mischbare flüssigkeiten
JPH08131783A (ja) 1994-11-10 1996-05-28 Nitto Denko Corp 膜分離装置
US5580452A (en) * 1994-12-02 1996-12-03 Lsr Technologies, Inc. Moving liquid membrane modules
JPH08155278A (ja) 1994-12-05 1996-06-18 Nitto Denko Corp 膜エレメントの製作方法
JPH0929076A (ja) 1995-07-21 1997-02-04 Nitto Denko Corp 液体の分離方法及び液体分離用膜エレメント
JPH0957070A (ja) 1995-08-24 1997-03-04 Kubota Corp 浸漬型膜カートリッジおよびその製造方法
US5711882A (en) * 1995-09-29 1998-01-27 Membrane Technology And Research, Inc. Gas separation membrane module and process
US5714072A (en) 1995-11-06 1998-02-03 Hoechst Celanese Corporation Method for solvent extraction using a dual-skinned asymmetric microporous membrane
GB9608129D0 (en) * 1996-04-19 1996-06-26 Central Research Lab Ltd Method and apparatus for diffusive transfer between immiscible fluids
JP3575916B2 (ja) 1996-05-20 2004-10-13 日東電工株式会社 逆浸透膜スパイラルエレメントおよびそれを用いた処理システム
US6086769A (en) * 1996-09-16 2000-07-11 Commodore Separation Technologies, Inc. Supported liquid membrane separation
JP3879224B2 (ja) 1998-01-27 2007-02-07 栗田工業株式会社 雨水等の処理方法
DE69942763D1 (de) * 1998-06-18 2010-10-28 Toray Industries Spiralförmiges umkehrosmosemembranelement, verwendung in einem umkehrosmosemembranmodul, vorrichtung und verfahren zur umkehrosmosetrennung unter verwendung des moduls
US6533937B1 (en) 1999-01-22 2003-03-18 Nitto Denko Corporation Methods of running and washing spiral wound membrane modules
GB2352715B (en) 1999-07-30 2002-01-09 Membrane Extraction Tech Ltd Recovery of aromatic amines dissolved in aqueous fluids

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4306884A (en) * 1980-12-18 1981-12-22 Biohol Corporation Alcohol and fuel production
US4966707A (en) * 1986-05-13 1990-10-30 Celanese Corporation Liquid/liquid extractions with microporous membranes

Also Published As

Publication number Publication date
DE602004013129D1 (de) 2008-05-29
WO2004083158A1 (en) 2004-09-30
EP1878715B1 (en) 2013-02-27
ZA200508248B (en) 2007-03-28
CN1759086A (zh) 2006-04-12
CA2518849A1 (en) 2004-09-30
BRPI0408224A (pt) 2006-02-21
DE602004013129T2 (de) 2009-05-20
AU2004221906A1 (en) 2004-09-30
CA2518849C (en) 2012-05-29
EP1603855B1 (en) 2008-04-16
EP1603855A1 (en) 2005-12-14
RU2005127414A (ru) 2006-03-20
BRPI0408224B1 (pt) 2013-09-10
EP1878715A1 (en) 2008-01-16
ATE392405T1 (de) 2008-05-15
US20040181101A1 (en) 2004-09-16
JP2006520398A (ja) 2006-09-07
US7122709B2 (en) 2006-10-17

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Granted publication date: 20071219

Termination date: 20170122