CL2017001045A1 - Sorbente para la recuperación de valores de litio a partir de salmueras. - Google Patents

Sorbente para la recuperación de valores de litio a partir de salmueras.

Info

Publication number
CL2017001045A1
CL2017001045A1 CL2017001045A CL2017001045A CL2017001045A1 CL 2017001045 A1 CL2017001045 A1 CL 2017001045A1 CL 2017001045 A CL2017001045 A CL 2017001045A CL 2017001045 A CL2017001045 A CL 2017001045A CL 2017001045 A1 CL2017001045 A1 CL 2017001045A1
Authority
CL
Chile
Prior art keywords
granular
lithium
aluminum hydroxide
brines
sorbent
Prior art date
Application number
CL2017001045A
Other languages
English (en)
Spanish (es)
Inventor
Chi Hung Cheng
Jan Nieman
Gregory Alan Marus
Original Assignee
Albemarle Coporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Coporation filed Critical Albemarle Coporation
Publication of CL2017001045A1 publication Critical patent/CL2017001045A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3035—Compressing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Water Treatment By Sorption (AREA)
CL2017001045A 2014-10-30 2017-04-27 Sorbente para la recuperación de valores de litio a partir de salmueras. CL2017001045A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201462072849P 2014-10-30 2014-10-30

Publications (1)

Publication Number Publication Date
CL2017001045A1 true CL2017001045A1 (es) 2017-11-10

Family

ID=55310890

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2017001045A CL2017001045A1 (es) 2014-10-30 2017-04-27 Sorbente para la recuperación de valores de litio a partir de salmueras.

Country Status (8)

Country Link
US (1) US20170333867A1 (enExample)
JP (1) JP2017534444A (enExample)
KR (1) KR20170078617A (enExample)
AR (1) AR102364A1 (enExample)
AU (1) AU2015339757A1 (enExample)
CA (1) CA2963560A1 (enExample)
CL (1) CL2017001045A1 (enExample)
WO (1) WO2016069297A2 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11655150B2 (en) 2017-12-22 2023-05-23 Posco Co., Ltd Preparation method for lithium phosphate, preparation method for lithium hydroxide, and preparation method for lithium carbonate
AR119183A1 (es) 2019-06-18 2021-12-01 Schlumberger Technology Bv Extracción de litio
CN110479228A (zh) * 2019-08-16 2019-11-22 黄冈师范学院 一种失效的离子筛型锰系吸附剂的再生方法
KR102401348B1 (ko) 2019-12-20 2022-05-23 재단법인 포항산업과학연구원 리튬 함유 용액으로부터 리튬 추출 방법
US11904297B1 (en) * 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media
CN113509911B (zh) * 2020-11-25 2023-05-23 中国科学院青海盐湖研究所 一种用于液体锂资源提取的铝系吸附剂颗粒制备方法
CN112691654B (zh) * 2020-12-25 2024-04-02 华东理工大学 一种铝盐锂吸附剂的一步再生方法
CN115837266B (zh) * 2021-09-18 2025-01-14 比亚迪股份有限公司 一种铝盐型锂离子吸附剂的液相沉淀合成方法
CN114558557B (zh) * 2022-03-22 2022-09-09 北京中科顺谷科技发展有限公司 基于分子筛吸附剂的天然卤水中锂提取吸附颗粒及其制备方法
WO2024151783A1 (en) * 2023-01-11 2024-07-18 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorbents
CN117358196B (zh) * 2023-09-20 2024-03-15 中国地质科学院矿产资源研究所 铝土矿基铝系锂离子吸附剂的制备方法和卤水提锂方法
WO2025151731A1 (en) * 2024-01-10 2025-07-17 Iliad Ip Company, Llc Process for producing lithium selective adsorbents using a stoichiometric amount of lithium
CN117902783A (zh) * 2024-03-14 2024-04-19 莱特莱德(上海)技术有限公司 一种铝土矿冶炼废水中锂的回收方法
WO2025226865A1 (en) * 2024-04-26 2025-10-30 Energy Exploration Technologies, Inc. Compositions, systems and methods for adsorbing at least one metal from a solution

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306700A (en) 1964-03-06 1967-02-28 Dow Chemical Co Method of lithium recovery
CH598137A5 (enExample) * 1974-04-19 1978-04-28 Alusuisse
US4221767A (en) * 1978-09-05 1980-09-09 The Dow Chemical Company Recovery of lithium from brines
US4472362A (en) 1980-12-18 1984-09-18 The Dow Chemical Company Regeneration of crystalline lithium aluminates
US4348295A (en) * 1980-12-18 1982-09-07 The Dow Chemical Company Crystalline lithium aluminates
EP0103035A1 (en) * 1982-09-09 1984-03-21 The Dow Chemical Company A process for growing crystalline hydrous alumina within the pores of a porous substrate
JPS6252127A (ja) * 1985-08-29 1987-03-06 ザ　ダウ　ケミカル　カンパニ− 結晶状三層リチウム・アルミネートの製造法
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
US5389349A (en) * 1993-05-24 1995-02-14 Bauman; William C. Recovery of lithium values from brines
KR100439636B1 (ko) * 1995-09-01 2004-10-26 미즈자와 가가꾸 고교오 가부시기가이샤 알칼리 알루미늄 복합 수산화물 탄산염, 그 제조방법 및 용도
US8753594B1 (en) 2009-11-13 2014-06-17 Simbol, Inc. Sorbent for lithium extraction
US8309043B2 (en) 2010-12-06 2012-11-13 Fmc Corporation Recovery of Li values from sodium saturate brine

Also Published As

Publication number Publication date
CA2963560A1 (en) 2016-05-06
AR102364A1 (es) 2017-02-22
JP2017534444A (ja) 2017-11-24
US20170333867A1 (en) 2017-11-23
AU2015339757A1 (en) 2017-04-27
KR20170078617A (ko) 2017-07-07
WO2016069297A3 (en) 2016-06-23
WO2016069297A2 (en) 2016-05-06

Similar Documents

Publication Publication Date Title
CL2017001045A1 (es) Sorbente para la recuperación de valores de litio a partir de salmueras.
CL2017001153A1 (es) Adsorbente basado en alumina activada porosa para la extracciôn de litio
AR129825A2 (es) Sistema de intercambio iónico para generar una solución de eluato de litio a partir de un recurso líquido
CL2014002473A1 (es) Metodo y disposicion para recuperar carbonato de litio que comprende triturar la materia prima en presencia de agua y carbonato de sodio, lixiviar la lechada en presencia de vapor a alta presion, carbonatar la solucion, separar los solidos de la solucion, purificar la solucion que contiene carbonato de litio y cristalizar.
CL2017002137A1 (es) (divisional nº 2121-2016 ) metodo para tratar minerales que contienen litio.
CY1121970T1 (el) Συσκευες και μεθοδοι για την ανακυκλωση χωρις τηξη μπαταριων μολυβδου/οξεος
EP4424408A3 (en) Processes for preparing lithium hydroxide
EA201491464A1 (ru) Способ получения водного раствора, содержащего по меньшей мере один гидрокарбонат щелочно-земельного металла, и его применение
MX2017009578A (es) Tratamiento de material contenedor de litio incluyendo espuma hcl.
MX2016016926A (es) Sistemas y metodos para aislar un producto en particulas cuando se recicla plomo de baterias de plomo-acido gastadas.
PE20160627A1 (es) Agentes depresores para procesos de separacion
WO2013006390A3 (en) Chilled ammonia based co2 capture system with ammonia recovery and processes of use
MY172961A (en) Purification of carbon dioxide
CL2019000564A1 (es) Método para la fabricación de cloruro de litio y método para la fabricación de carbonato de litio.
PE20151724A1 (es) Recuperacion de urea y aceite a partir de un complejo urea/aceite
CL2017001544A1 (es) Sistema y método para la lixiviación de sulfuros metálicos por arriba de la presión atmosférica
PE20142158A1 (es) Proceso para la produccion de oxido de zinc a partir de mineral
AR110525A1 (es) Método de fabricación de hidróxido de litio a partir de fosfato de litio
BR112016016299A2 (pt) Processo para recuperar líquidos de gás natural de gás natural produzido em locais remotos
WO2015080961A3 (en) Methods to separate brine from invert emulsions used in drilling and completion fluids
WO2016005920A3 (en) Method for recovery of ionic liquid and system thereof
GB2550722A (en) Reclamation of brines with metal contamination using lime
BR112016013645B8 (pt) Método e disposição de processo para separação de índio e arsênico entre si
RU2013149809A (ru) Способ извлечения оксида алюминия из красного шлама
TW201613826A (en) Manufacturing method of infrared absorption powder