CA2963560A1 - Sorbents for recovery of lithium values from brines - Google Patents

Sorbents for recovery of lithium values from brines Download PDF

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Publication number
CA2963560A1
CA2963560A1 CA2963560A CA2963560A CA2963560A1 CA 2963560 A1 CA2963560 A1 CA 2963560A1 CA 2963560 A CA2963560 A CA 2963560A CA 2963560 A CA2963560 A CA 2963560A CA 2963560 A1 CA2963560 A1 CA 2963560A1
Authority
CA
Canada
Prior art keywords
lithium
sorbent
granular
hydroxide
chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2963560A
Other languages
English (en)
French (fr)
Inventor
Chi Hung Cheng
Jan Nieman
Gregory Alan Marus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Corp
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp filed Critical Albemarle Corp
Publication of CA2963560A1 publication Critical patent/CA2963560A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3035—Compressing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Water Treatment By Sorption (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CA2963560A 2014-10-30 2015-10-16 Sorbents for recovery of lithium values from brines Abandoned CA2963560A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462072849P 2014-10-30 2014-10-30
US62/072,849 2014-10-30
PCT/US2015/056095 WO2016069297A2 (en) 2014-10-30 2015-10-16 Sorbents for recovery of lithium values from brines

Publications (1)

Publication Number Publication Date
CA2963560A1 true CA2963560A1 (en) 2016-05-06

Family

ID=55310890

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2963560A Abandoned CA2963560A1 (en) 2014-10-30 2015-10-16 Sorbents for recovery of lithium values from brines

Country Status (8)

Country Link
US (1) US20170333867A1 (enExample)
JP (1) JP2017534444A (enExample)
KR (1) KR20170078617A (enExample)
AR (1) AR102364A1 (enExample)
AU (1) AU2015339757A1 (enExample)
CA (1) CA2963560A1 (enExample)
CL (1) CL2017001045A1 (enExample)
WO (1) WO2016069297A2 (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11655150B2 (en) 2017-12-22 2023-05-23 Posco Co., Ltd Preparation method for lithium phosphate, preparation method for lithium hydroxide, and preparation method for lithium carbonate
CL2020001650A1 (es) 2019-06-18 2021-01-29 Schlumberger Technology Bv Extracción de litio
CN110479228A (zh) * 2019-08-16 2019-11-22 黄冈师范学院 一种失效的离子筛型锰系吸附剂的再生方法
KR102401348B1 (ko) 2019-12-20 2022-05-23 재단법인 포항산업과학연구원 리튬 함유 용액으로부터 리튬 추출 방법
US11904297B1 (en) * 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media
CN113509911B (zh) * 2020-11-25 2023-05-23 中国科学院青海盐湖研究所 一种用于液体锂资源提取的铝系吸附剂颗粒制备方法
CN112691654B (zh) * 2020-12-25 2024-04-02 华东理工大学 一种铝盐锂吸附剂的一步再生方法
CN116888075A (zh) * 2021-01-05 2023-10-13 智利化学和矿业股份有限公司 由氯化锂（LiCl）直接生产氢氧化锂（LiOH）的方法，不需要中间生产碳酸锂或类似物
CN115814465A (zh) * 2021-09-17 2023-03-21 高陵蓝晓科技新材料有限公司 一种含碳酸根或/和硫酸根溶液中锂吸附的方法
CN115837266B (zh) 2021-09-18 2025-01-14 比亚迪股份有限公司 一种铝盐型锂离子吸附剂的液相沉淀合成方法
CN116356144B (zh) * 2021-12-28 2024-10-29 比亚迪股份有限公司 一种盐湖提锂方法
CN114558557B (zh) * 2022-03-22 2022-09-09 北京中科顺谷科技发展有限公司 基于分子筛吸附剂的天然卤水中锂提取吸附颗粒及其制备方法
WO2024151783A1 (en) * 2023-01-11 2024-07-18 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorbents
CN117358196B (zh) * 2023-09-20 2024-03-15 中国地质科学院矿产资源研究所 铝土矿基铝系锂离子吸附剂的制备方法和卤水提锂方法
US20250222435A1 (en) * 2024-01-10 2025-07-10 Iliad Ip Company, Llc Process for producing lithium selective adsorbents using a stoichiometric amount of lithium
CN117902783A (zh) * 2024-03-14 2024-04-19 莱特莱德(上海)技术有限公司 一种铝土矿冶炼废水中锂的回收方法
WO2025226865A1 (en) * 2024-04-26 2025-10-30 Energy Exploration Technologies, Inc. Compositions, systems and methods for adsorbing at least one metal from a solution
WO2026084613A1 (ru) * 2024-10-17 2026-04-23 Общество С Ограниченной Ответственностью "Иркутская Химическая Компания" Гранулированные сорбенты для извлечения лития и способ их подготовки к использованию
KR20260098750A (ko) * 2024-12-19 2026-06-26 포스코홀딩스 주식회사 리튬 흡착제 및 이의 제조 방법

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US3306700A (en) 1964-03-06 1967-02-28 Dow Chemical Co Method of lithium recovery
CH598137A5 (enExample) * 1974-04-19 1978-04-28 Alusuisse
US4221767A (en) * 1978-09-05 1980-09-09 The Dow Chemical Company Recovery of lithium from brines
US4472362A (en) 1980-12-18 1984-09-18 The Dow Chemical Company Regeneration of crystalline lithium aluminates
US4348295A (en) * 1980-12-18 1982-09-07 The Dow Chemical Company Crystalline lithium aluminates
EP0103035A1 (en) * 1982-09-09 1984-03-21 The Dow Chemical Company A process for growing crystalline hydrous alumina within the pores of a porous substrate
JPS6252127A (ja) * 1985-08-29 1987-03-06 ザ　ダウ　ケミカル　カンパニ− 結晶状三層リチウム・アルミネートの製造法
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
US5389349A (en) 1993-05-24 1995-02-14 Bauman; William C. Recovery of lithium values from brines
CN1095807C (zh) * 1995-09-01 2002-12-11 水泽化学工业株式会社 碱金属铝配合氢氧化物碳酸盐、和生产该盐的方法及其应用
US8753594B1 (en) 2009-11-13 2014-06-17 Simbol, Inc. Sorbent for lithium extraction
US8309043B2 (en) 2010-12-06 2012-11-13 Fmc Corporation Recovery of Li values from sodium saturate brine

Also Published As

Publication number Publication date
WO2016069297A3 (en) 2016-06-23
JP2017534444A (ja) 2017-11-24
AU2015339757A1 (en) 2017-04-27
US20170333867A1 (en) 2017-11-23
WO2016069297A2 (en) 2016-05-06
AR102364A1 (es) 2017-02-22
CL2017001045A1 (es) 2017-11-10
KR20170078617A (ko) 2017-07-07

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Effective date: 20220106