CA2963560A1 - Sorbents for recovery of lithium values from brines - Google Patents
Sorbents for recovery of lithium values from brines Download PDFInfo
- Publication number
- CA2963560A1 CA2963560A1 CA2963560A CA2963560A CA2963560A1 CA 2963560 A1 CA2963560 A1 CA 2963560A1 CA 2963560 A CA2963560 A CA 2963560A CA 2963560 A CA2963560 A CA 2963560A CA 2963560 A1 CA2963560 A1 CA 2963560A1
- Authority
- CA
- Canada
- Prior art keywords
- lithium
- sorbent
- granular
- hydroxide
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 85
- 239000002594 sorbent Substances 0.000 title claims abstract description 80
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 238000011084 recovery Methods 0.000 title description 11
- 238000000034 method Methods 0.000 claims abstract description 56
- 230000008569 process Effects 0.000 claims abstract description 42
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 41
- 239000002245 particle Substances 0.000 claims abstract description 38
- 239000012267 brine Substances 0.000 claims abstract description 35
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 35
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 31
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 31
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims abstract description 19
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000003513 alkali Substances 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 44
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 32
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 22
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000009830 intercalation Methods 0.000 claims description 13
- 150000001450 anions Chemical group 0.000 claims description 12
- 230000006835 compression Effects 0.000 claims description 10
- 238000007906 compression Methods 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 229910001679 gibbsite Inorganic materials 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 239000000243 solution Substances 0.000 description 29
- 238000011068 loading method Methods 0.000 description 18
- 239000007787 solid Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229910013470 LiC1 Inorganic materials 0.000 description 11
- 238000006386 neutralization reaction Methods 0.000 description 11
- 230000002687 intercalation Effects 0.000 description 9
- 239000008188 pellet Substances 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000000706 filtrate Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 108091006629 SLC13A2 Proteins 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- 229910001680 bayerite Inorganic materials 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 238000004255 ion exchange chromatography Methods 0.000 description 2
- -1 lithium aluminates Chemical class 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 229910001682 nordstrandite Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- IMRYETFJNLKUHK-UHFFFAOYSA-N traseolide Chemical compound CC1=C(C(C)=O)C=C2C(C(C)C)C(C)C(C)(C)C2=C1 IMRYETFJNLKUHK-UHFFFAOYSA-N 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- BGEBZHIAGXMEMV-UHFFFAOYSA-N 5-methoxypsoralen Chemical compound O1C(=O)C=CC2=C1C=C1OC=CC1=C2OC BGEBZHIAGXMEMV-UHFFFAOYSA-N 0.000 description 1
- 240000000736 Amomum maximum Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- VXASJZQYXZPHGS-UHFFFAOYSA-L aluminum lithium chloride hydroxide Chemical compound [Cl-].[OH-].[Li+].[Al+3] VXASJZQYXZPHGS-UHFFFAOYSA-L 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- MHFMYGHRYRSFIG-UHFFFAOYSA-L dilithium;dihydroxide Chemical compound [Li+].[Li+].[OH-].[OH-] MHFMYGHRYRSFIG-UHFFFAOYSA-L 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3035—Compressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Water Treatment By Sorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462072849P | 2014-10-30 | 2014-10-30 | |
| US62/072,849 | 2014-10-30 | ||
| PCT/US2015/056095 WO2016069297A2 (en) | 2014-10-30 | 2015-10-16 | Sorbents for recovery of lithium values from brines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2963560A1 true CA2963560A1 (en) | 2016-05-06 |
Family
ID=55310890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2963560A Abandoned CA2963560A1 (en) | 2014-10-30 | 2015-10-16 | Sorbents for recovery of lithium values from brines |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20170333867A1 (enExample) |
| JP (1) | JP2017534444A (enExample) |
| KR (1) | KR20170078617A (enExample) |
| AR (1) | AR102364A1 (enExample) |
| AU (1) | AU2015339757A1 (enExample) |
| CA (1) | CA2963560A1 (enExample) |
| CL (1) | CL2017001045A1 (enExample) |
| WO (1) | WO2016069297A2 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11655150B2 (en) | 2017-12-22 | 2023-05-23 | Posco Co., Ltd | Preparation method for lithium phosphate, preparation method for lithium hydroxide, and preparation method for lithium carbonate |
| AR119183A1 (es) | 2019-06-18 | 2021-12-01 | Schlumberger Technology Bv | Extracción de litio |
| CN110479228A (zh) * | 2019-08-16 | 2019-11-22 | 黄冈师范学院 | 一种失效的离子筛型锰系吸附剂的再生方法 |
| KR102401348B1 (ko) | 2019-12-20 | 2022-05-23 | 재단법인 포항산업과학연구원 | 리튬 함유 용액으로부터 리튬 추출 방법 |
| US11904297B1 (en) * | 2023-01-11 | 2024-02-20 | Iliad Ip Company, Llc | Process for manufacturing lithium selective adsorption/separation media |
| CN113509911B (zh) * | 2020-11-25 | 2023-05-23 | 中国科学院青海盐湖研究所 | 一种用于液体锂资源提取的铝系吸附剂颗粒制备方法 |
| CN112691654B (zh) * | 2020-12-25 | 2024-04-02 | 华东理工大学 | 一种铝盐锂吸附剂的一步再生方法 |
| CN115837266B (zh) * | 2021-09-18 | 2025-01-14 | 比亚迪股份有限公司 | 一种铝盐型锂离子吸附剂的液相沉淀合成方法 |
| CN114558557B (zh) * | 2022-03-22 | 2022-09-09 | 北京中科顺谷科技发展有限公司 | 基于分子筛吸附剂的天然卤水中锂提取吸附颗粒及其制备方法 |
| WO2024151783A1 (en) * | 2023-01-11 | 2024-07-18 | Iliad Ip Company, Llc | Process for manufacturing lithium selective adsorbents |
| CN117358196B (zh) * | 2023-09-20 | 2024-03-15 | 中国地质科学院矿产资源研究所 | 铝土矿基铝系锂离子吸附剂的制备方法和卤水提锂方法 |
| WO2025151731A1 (en) * | 2024-01-10 | 2025-07-17 | Iliad Ip Company, Llc | Process for producing lithium selective adsorbents using a stoichiometric amount of lithium |
| CN117902783A (zh) * | 2024-03-14 | 2024-04-19 | 莱特莱德(上海)技术有限公司 | 一种铝土矿冶炼废水中锂的回收方法 |
| WO2025226865A1 (en) * | 2024-04-26 | 2025-10-30 | Energy Exploration Technologies, Inc. | Compositions, systems and methods for adsorbing at least one metal from a solution |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3306700A (en) | 1964-03-06 | 1967-02-28 | Dow Chemical Co | Method of lithium recovery |
| CH598137A5 (enExample) * | 1974-04-19 | 1978-04-28 | Alusuisse | |
| US4221767A (en) * | 1978-09-05 | 1980-09-09 | The Dow Chemical Company | Recovery of lithium from brines |
| US4472362A (en) | 1980-12-18 | 1984-09-18 | The Dow Chemical Company | Regeneration of crystalline lithium aluminates |
| US4348295A (en) * | 1980-12-18 | 1982-09-07 | The Dow Chemical Company | Crystalline lithium aluminates |
| EP0103035A1 (en) * | 1982-09-09 | 1984-03-21 | The Dow Chemical Company | A process for growing crystalline hydrous alumina within the pores of a porous substrate |
| JPS6252127A (ja) * | 1985-08-29 | 1987-03-06 | ザ ダウ ケミカル カンパニ− | 結晶状三層リチウム・アルミネートの製造法 |
| US5599516A (en) | 1993-05-24 | 1997-02-04 | Fmc Corporation | Recovery of lithium values from brines |
| US5389349A (en) * | 1993-05-24 | 1995-02-14 | Bauman; William C. | Recovery of lithium values from brines |
| KR100439636B1 (ko) * | 1995-09-01 | 2004-10-26 | 미즈자와 가가꾸 고교오 가부시기가이샤 | 알칼리 알루미늄 복합 수산화물 탄산염, 그 제조방법 및 용도 |
| US8753594B1 (en) | 2009-11-13 | 2014-06-17 | Simbol, Inc. | Sorbent for lithium extraction |
| US8309043B2 (en) | 2010-12-06 | 2012-11-13 | Fmc Corporation | Recovery of Li values from sodium saturate brine |
-
2015
- 2015-10-16 US US15/522,829 patent/US20170333867A1/en not_active Abandoned
- 2015-10-16 KR KR1020177010350A patent/KR20170078617A/ko not_active Withdrawn
- 2015-10-16 AU AU2015339757A patent/AU2015339757A1/en not_active Abandoned
- 2015-10-16 CA CA2963560A patent/CA2963560A1/en not_active Abandoned
- 2015-10-16 WO PCT/US2015/056095 patent/WO2016069297A2/en not_active Ceased
- 2015-10-16 JP JP2017519850A patent/JP2017534444A/ja not_active Ceased
- 2015-10-19 AR ARP150103384A patent/AR102364A1/es unknown
-
2017
- 2017-04-27 CL CL2017001045A patent/CL2017001045A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR102364A1 (es) | 2017-02-22 |
| JP2017534444A (ja) | 2017-11-24 |
| US20170333867A1 (en) | 2017-11-23 |
| AU2015339757A1 (en) | 2017-04-27 |
| CL2017001045A1 (es) | 2017-11-10 |
| KR20170078617A (ko) | 2017-07-07 |
| WO2016069297A3 (en) | 2016-06-23 |
| WO2016069297A2 (en) | 2016-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20170333867A1 (en) | Sorbents for Recovery of Lithium Values from Brines | |
| US5599516A (en) | Recovery of lithium values from brines | |
| US10829676B2 (en) | Treated geothermal brine compositions with reduced concentration of silica, iron and lithium | |
| US5389349A (en) | Recovery of lithium values from brines | |
| CN107250049B (zh) | 用于锂提取的多孔活化的氧化铝基吸附剂 | |
| AU2015380289B2 (en) | Processing of lithium containing material including HCL sparge | |
| US4540509A (en) | Crystalline 3-layer lithium aluminates | |
| US8309043B2 (en) | Recovery of Li values from sodium saturate brine | |
| US20120207656A1 (en) | System and Method for Recovery of Scandium Values From Scandium-Containing Ores | |
| CN110354796A (zh) | 一种铝盐型锂吸附剂及其制备方法与应用 | |
| CN113926419A (zh) | 一种Keggin链式结构铝系锂吸附剂的制备方法 | |
| EP0819098B1 (en) | Process for the production of cesium compounds | |
| RU2455063C2 (ru) | Способ получения гранулированного сорбента для извлечения лития из литийсодержащих рассолов | |
| JP5336932B2 (ja) | 水質浄化材料、水質浄化方法、リン酸肥料前駆体及びリン酸肥料前駆体の製造方法 | |
| US20250303388A1 (en) | Sorbent Comprising High-Hydration Lithium-Incorporated-Aluminum-Hydroxide Composition | |
| EP3190087A1 (en) | Method for producing crystalline silicotitanate | |
| JP2748334B2 (ja) | 食塩水中の硫酸イオンを除去する方法 | |
| US20230085171A1 (en) | Treated geothermal brine compositions with reduced concentration of silica, iron and lithium | |
| US12337309B2 (en) | Method of manufacturing inorganic ion exchanger for the selective extraction of lithium from lithium-containing natural and technological brines | |
| KR102082873B1 (ko) | 고순도 수산화마그네슘의 제조방법 | |
| JP4228077B2 (ja) | ハイドロタルサイトの脱炭酸イオンによる、イオン交換性のある陰イオンを有する層状水酸化物の製造方法 | |
| Xu et al. | Development of barium@ alginate adsorbents for sulfate removal in lithium refining | |
| EP4643989A1 (en) | Shaped material for extracting lithium from a lithium-containing aqueous solution, method for preparing the same, and method for extracting lithium from a lithium-containing aqueous solution | |
| CN111979427A (zh) | 一种回收硫代硫酸盐浸金溶液中金离子的方法 | |
| Peng et al. | Direct lithium extraction from α-spodumene ore via alkali leaching-Li/Al co-precipitation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20220106 |
|
| FZDE | Discontinued |
Effective date: 20220106 |