CH618206A5 - Process for the preparation of thermoplastic resins by injection-moulding based on saturated polyesters - Google Patents
Process for the preparation of thermoplastic resins by injection-moulding based on saturated polyesters Download PDFInfo
- Publication number
- CH618206A5 CH618206A5 CH1446173A CH1446173A CH618206A5 CH 618206 A5 CH618206 A5 CH 618206A5 CH 1446173 A CH1446173 A CH 1446173A CH 1446173 A CH1446173 A CH 1446173A CH 618206 A5 CH618206 A5 CH 618206A5
- Authority
- CH
- Switzerland
- Prior art keywords
- sodium
- polyester
- molding compositions
- linear
- compositions according
- Prior art date
Links
- 229920000728 polyester Polymers 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 8
- 229920006395 saturated elastomer Polymers 0.000 title claims description 5
- 238000001746 injection moulding Methods 0.000 title description 6
- 238000002360 preparation method Methods 0.000 title description 2
- 229920005992 thermoplastic resin Polymers 0.000 title description 2
- -1 sulphonate compound Chemical class 0.000 claims description 21
- 239000011734 sodium Substances 0.000 claims description 15
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 14
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 14
- 239000002667 nucleating agent Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 10
- 238000002425 crystallisation Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 230000008025 crystallization Effects 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 229910003480 inorganic solid Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical class [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- PWWJJDVDTKXWOF-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O PWWJJDVDTKXWOF-UHFFFAOYSA-M 0.000 claims description 2
- PLQISZLZPSPBDP-UHFFFAOYSA-M sodium;pentadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCS([O-])(=O)=O PLQISZLZPSPBDP-UHFFFAOYSA-M 0.000 claims description 2
- 229960003080 taurine Drugs 0.000 claims description 2
- 240000007049 Juglans regia Species 0.000 claims 1
- 235000009496 Juglans regia Nutrition 0.000 claims 1
- HWQXBVHZYDELQG-UHFFFAOYSA-L disodium 2,2-bis(6-methylheptyl)-3-sulfobutanedioate Chemical compound C(CCCCC(C)C)C(C(C(=O)[O-])S(=O)(=O)O)(C(=O)[O-])CCCCCC(C)C.[Na+].[Na+] HWQXBVHZYDELQG-UHFFFAOYSA-L 0.000 claims 1
- 238000009757 thermoplastic moulding Methods 0.000 claims 1
- 235000020234 walnut Nutrition 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- 239000008187 granular material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 238000001816 cooling Methods 0.000 description 7
- 238000006068 polycondensation reaction Methods 0.000 description 5
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- IMLXCKIOFHIZJR-UHFFFAOYSA-N [Na].CC(C)CCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC(C)C Chemical compound [Na].CC(C)CCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC(C)C IMLXCKIOFHIZJR-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229950000886 isetionate Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- VJWGHGJYLCJIEK-UHFFFAOYSA-N 1,4-bis(6-methylheptoxy)-1,4-dioxobutane-2-sulfonic acid Chemical compound CC(C)CCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC(C)C VJWGHGJYLCJIEK-UHFFFAOYSA-N 0.000 description 1
- 101100443311 Caenorhabditis elegans dlg-1 gene Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001279 adipic acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000007931 coated granule Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical class O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Chemical class 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- TWBKZBJAVASNII-UHFFFAOYSA-N pentadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCS(O)(=O)=O TWBKZBJAVASNII-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/88—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT3038672A IT968878B (it) | 1972-10-12 | 1972-10-12 | Resine termoplastiche per stampag gio ad iniezione a base di polie steri saturi |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH618206A5 true CH618206A5 (en) | 1980-07-15 |
Family
ID=11229657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH1446173A CH618206A5 (en) | 1972-10-12 | 1973-10-10 | Process for the preparation of thermoplastic resins by injection-moulding based on saturated polyesters |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5760376B2 (en, 2012) |
| AT (1) | AT339611B (en, 2012) |
| BE (1) | BE805936A (en, 2012) |
| CA (1) | CA1026884A (en, 2012) |
| CH (1) | CH618206A5 (en, 2012) |
| DE (1) | DE2350781A1 (en, 2012) |
| FR (1) | FR2202913B1 (en, 2012) |
| GB (1) | GB1451945A (en, 2012) |
| IT (1) | IT968878B (en, 2012) |
| NL (1) | NL7313803A (en, 2012) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2639428C2 (de) * | 1976-09-02 | 1986-01-30 | Bayer Ag, 5090 Leverkusen | Schnell kristallisierende Polyestermassen |
| EP0021648B1 (en) * | 1979-06-19 | 1984-03-21 | Imperial Chemical Industries Plc | Fast crystallising polyester compositions |
| US4368288A (en) | 1979-09-21 | 1983-01-11 | Imperial Chemical Industries Limited | Fast crystallizing polyester compositions |
| EP0031201A3 (en) * | 1979-12-12 | 1981-07-15 | Imperial Chemical Industries Plc | Fast crystallising polyester compositions |
| US4539356A (en) * | 1984-10-17 | 1985-09-03 | Gaf Corporation | Polyethylene terephthalate molding composition |
| DE602005008006D1 (de) * | 2004-01-20 | 2008-08-21 | Takemoto Oil & Fat Co Ltd | Zusammensetzung auf basis von aliphatischem polyesterharz, formkörper aus aliphatischem polyesterharz und verfahren zur herstellung des formkörpers aus aliphatischem polyesterharz |
| CN113831700B (zh) * | 2021-11-04 | 2022-07-01 | 深圳市金志成塑胶科技有限公司 | 一种pet聚酯复合材料及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1151569A (en) * | 1965-10-22 | 1969-05-07 | Celanese Corp | Metal Salts of Organic Sulphonic Acids and Polymer Compositions containing them |
| NL6608999A (en, 2012) * | 1965-11-20 | 1967-02-27 | ||
| DE1933969C3 (de) * | 1969-07-04 | 1980-11-13 | Hoechst Ag, 6000 Frankfurt | Thermoplastische Formmassen auf Basis gesättigter Polyester |
| BE754116A (fr) * | 1969-07-29 | 1971-01-29 | Hoechst Ag | Matieres a mouler thermoplastiques a base de polyesters |
| BE755832A (fr) * | 1969-09-05 | 1971-03-08 | Hoechst Ag | Matieres a mouler thermoplastiques a base de polyesters satures |
| BE755830A (fr) * | 1969-09-05 | 1971-03-08 | Hoechst Ag | Matieres a mouler thermoplastiques a base de polyesters satures |
| DE2004382A1 (de) * | 1970-01-31 | 1971-10-14 | Basf Ag | Formkörper aus linearen Polyäthylen terephthalaten |
-
1972
- 1972-10-12 IT IT3038672A patent/IT968878B/it active
-
1973
- 1973-10-08 NL NL7313803A patent/NL7313803A/xx not_active Application Discontinuation
- 1973-10-09 FR FR7336025A patent/FR2202913B1/fr not_active Expired
- 1973-10-09 AT AT857773A patent/AT339611B/de not_active IP Right Cessation
- 1973-10-09 GB GB4711973A patent/GB1451945A/en not_active Expired
- 1973-10-10 DE DE19732350781 patent/DE2350781A1/de active Granted
- 1973-10-10 CA CA182,991A patent/CA1026884A/en not_active Expired
- 1973-10-10 CH CH1446173A patent/CH618206A5/it not_active IP Right Cessation
- 1973-10-11 BE BE136563A patent/BE805936A/xx not_active IP Right Cessation
- 1973-10-11 JP JP11336173A patent/JPS5760376B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE805936A (fr) | 1974-04-11 |
| DE2350781C2 (en, 2012) | 1988-04-21 |
| IT968878B (it) | 1974-03-20 |
| FR2202913B1 (en, 2012) | 1976-10-01 |
| JPS5760376B2 (en, 2012) | 1982-12-18 |
| ATA857773A (de) | 1977-02-15 |
| FR2202913A1 (en, 2012) | 1974-05-10 |
| AT339611B (de) | 1977-10-25 |
| GB1451945A (en) | 1976-10-06 |
| DE2350781A1 (de) | 1974-04-25 |
| NL7313803A (en, 2012) | 1974-04-16 |
| CA1026884A (en) | 1978-02-21 |
| JPS4997080A (en, 2012) | 1974-09-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |