CH229352A - Process for the preparation of a direct drawing copper-containing dye. - Google Patents
Process for the preparation of a direct drawing copper-containing dye.Info
- Publication number
- CH229352A CH229352A CH229352DA CH229352A CH 229352 A CH229352 A CH 229352A CH 229352D A CH229352D A CH 229352DA CH 229352 A CH229352 A CH 229352A
- Authority
- CH
- Switzerland
- Prior art keywords
- dye
- copper
- brown
- preparation
- water
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B56/00—Azo dyes containing other chromophoric systems
- C09B56/04—Stilbene-azo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Verfahren zur Darstellung eines direkt ziehenden kupferhaltigen Farbstoffes. Gegenstand des vorliegenden Zusatzpaten tes ist ein Verfahren zur Darstellung eines kupferhaltigen Farbstoffes, dadurch ,gekenn-
EMI0001.0003
kondensiert und das Kondensationsprodukt noch mit kupferabgebenden Mitteln behan delt. Durch Nachbehandeln des Farbstoffes mit oxydierenden Mitteln, wie Ilypochlori- ten, kann die Reinheit des: Farbtones noch gesteigert werden.
<I>Beispiel:</I> 63 Teile des Triazols, erhalten durch Oxydation des Kupplungsproduktes aus diazotierter 4 - Nitro - 4'- amino-.stilben - 2, 2' disulfonsäure und 2-Naphthylamin-6-sulfon- säure, und 28 Teile des durch Kuppeln von zeichnet,
dass man den durch Kupplung von diazotiertem 1-Oxy-2-amino-4-nitrobenzol mit m-Anisidin erhaltenen Aminoazofarbstoff mit einem Triazol der Formel 1-Ogy-2-diazo-4-nitrobenzol mit m-Anisidin hergestellten Aminoazofarbstoffes werden mit 700 Teilen Wasser und 120 Teilen Na tronlauge 36'B6 14-16 Stunden bei Siede temperatur unter Rückfluss kondensiert und in üblicher Weise in eine Kupferverbindung übergeführt.
Der metallisierte Farbstoff stellt ein braunschwarzes Pulver dar; er löst sich in Wasser mit brauner, in konzentrierter Schwe felsäure mit blauer Farbe und färbt Zellu- losefasern in licht- und wasserechten braunen Tönen.
Process for the preparation of a direct drawing copper-containing dye. The subject of the present additional patent is a method for the preparation of a copper-containing dye, thereby marked
EMI0001.0003
condensed and the condensation product still treated with copper releasing agents. By treating the dye with oxidizing agents such as Ilypochlorites, the purity of the color can be increased.
<I> Example: </I> 63 parts of the triazole, obtained by oxidation of the coupling product from diazotized 4 - nitro - 4'-amino-.stilbene - 2, 2 'disulfonic acid and 2-naphthylamine-6-sulfonic acid, and 28 parts of the draws by coupling of,
700 parts of the aminoazo dye obtained by coupling diazotized 1-oxy-2-amino-4-nitrobenzene with m-anisidine with a triazole of the formula 1-Ogy-2-diazo-4-nitrobenzene with m-anisidine are used Water and 120 parts of sodium hydroxide solution 36'B6 condensed for 14-16 hours at boiling temperature under reflux and converted in the usual way into a copper compound.
The metallized dye is a brown-black powder; it dissolves in water with a brown color, in concentrated sulfuric acid with a blue color and dyes cellulose fibers in light- and water-fast brown tones.
Claims (1)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH2394998X | 1941-11-05 | ||
CH561117X | 1941-11-06 | ||
CH229352T | 1941-11-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH229352A true CH229352A (en) | 1943-10-15 |
Family
ID=32110422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH229352D CH229352A (en) | 1941-11-05 | 1941-11-06 | Process for the preparation of a direct drawing copper-containing dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH229352A (en) |
-
1941
- 1941-11-06 CH CH229352D patent/CH229352A/en unknown
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