CH194096A - Process for the preparation of a new anthraquinone dye. - Google Patents
Process for the preparation of a new anthraquinone dye.Info
- Publication number
- CH194096A CH194096A CH194096DA CH194096A CH 194096 A CH194096 A CH 194096A CH 194096D A CH194096D A CH 194096DA CH 194096 A CH194096 A CH 194096A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- dye
- new
- anthraquinone dye
- new anthraquinone
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/50—Amino-hydroxy-anthraquinones; Ethers and esters thereof
- C09B1/54—Amino-hydroxy-anthraquinones; Ethers and esters thereof etherified
- C09B1/545—Anthraquinones with aliphatic, cycloaliphatic or araliphatic ether groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
- C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 189647. Verfahren zur Darstellung eines neuen Anthr achinonfarbstoffes. Das vorliegende Verfahren betrifft die Herstellung eines neuen Arithrachinonfarb- stoffes und ist dadurch gekennzeichnet, dass man 1-Amino-4(2', 6'-dimethylanilido-) anthra- chinorr-2-sulfonsäur-e in Gegenwart von Ätz natron mit Glycerin kondensiert und die er haltene Verbindung mit Schwefelsäure be handelt.
<I>Beispiel:</I> Man löst in 100 Teilen Glycerin 10 Teile Ätznatron und fügt zur warmen Lösung 10 Teile des Farbstoffes der Formel
EMI0001.0013
Nach einstündigem Rühren bei 120 lässt man auf 80<B>0</B> abkühlen und verdünnt mit Alkohol, worauf die Base kristallisiert aus fällt. Sie wird gewaschen, getrocknet und hierauf in der 5fachen Menge konzentrierter Schwefelsäure bei<B>150</B> C gelöst. Nach kurzem Rühren ist eine Probe vollständig wasser löslich. Man giesst auf Eis-Salzwassermischung, saugt den Farbstoff ab, stellt ihn in Wasser neutral und salzt mit Kochsalz aus.
Der erhaltene Farbstoff besitzt die Formel
EMI0001.0015
und färbt Wolle in lebhaften rotvioletten Tönen an.
Additional patent to main patent no. 189647. Process for the preparation of a new anthracinone dye. The present process relates to the preparation of a new arithraquinone dye and is characterized in that 1-amino-4 (2 ', 6'-dimethylanilido) anthraquinor-2-sulfonic acid is condensed with glycerol in the presence of caustic soda and the compound he retained is treated with sulfuric acid.
<I> Example: </I> 10 parts of caustic soda are dissolved in 100 parts of glycerine and 10 parts of the dye of the formula are added to the warm solution
EMI0001.0013
After stirring for one hour at 120, the mixture is allowed to cool to 80 <B> 0 </B> and diluted with alcohol, whereupon the base crystallizes out. It is washed, dried and then dissolved in 5 times the amount of concentrated sulfuric acid at 150 C. A sample is completely water-soluble after brief stirring. It is poured onto a mixture of ice and salt water, the dye is suctioned off, made neutral in water and salted out with table salt.
The dye obtained has the formula
EMI0001.0015
and dyes wool in vivid red-violet tones.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH194096T | 1936-06-18 | ||
CH189647T | 1936-06-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH194096A true CH194096A (en) | 1937-11-15 |
Family
ID=25721823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH194096D CH194096A (en) | 1936-06-18 | 1936-06-18 | Process for the preparation of a new anthraquinone dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH194096A (en) |
-
1936
- 1936-06-18 CH CH194096D patent/CH194096A/en unknown
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