CH182605A - Process for the preparation of a complexed metal-containing dye. - Google Patents

Process for the preparation of a complexed metal-containing dye.

Info

Publication number
CH182605A
CH182605A CH182605DA CH182605A CH 182605 A CH182605 A CH 182605A CH 182605D A CH182605D A CH 182605DA CH 182605 A CH182605 A CH 182605A
Authority
CH
Switzerland
Prior art keywords
diazotized
mole
preparation
nitro
phenol
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH182605A publication Critical patent/CH182605A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/24—Disazo or polyazo compounds
    • C09B45/32—Disazo or polyazo compounds containing other metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Paper (AREA)

Description

  

  <B>Zusatzpatent</B> zum Hauptpatent Nr. 178542.    Verfahren zur Herstellung eines komplex gebundenes Metall enthaltenden Farbstoffs.         Es    wurde gefunden, dass man einen kom  plex gebundenes Metall enthaltenden Farb  stoff herstellen kann, wenn man 1     Mol        diazo-          tiertes        4-Nitro-2-amino-l-phenol,    1     Mol        diazo-          tierte        1-Aminobenzol-4-sulfonsäure,    1     Mol     1 .     3-Dioxybenzol    und ein Eisen abgebendes       Mittel    aufeinander     einwirken    lässt.

    



  Der erhaltene Farbstoff stellt     ein    in  Wasser mit brauner Farbe leicht lösliches  schwarzes Pulver dar. Er löst sich in kon  zentrierter Schwefelsäure mit     braunstichig     oranger Farbe und färbt     Leder    in gelb  braunen Tönen von sehr guten     Echtheits-          eigenschaften.       Das Verfahren kann beispielsweise derart  ausgeführt werden,

       da.ss    man auf das Ein  wirkungsprodukt aus 1     Mol        diazotiertem          4-Nitro-2-amino-l-phenol    und 1     Mol        1.3-          Dioxybenzolein    Eisen abgebendes Mittel und  hierauf 1     Mol        diazotierte        1-Aminobenzol-4-          sulfonsäure    einwirken lässt.

      <I>Beispiel:</I>  <B>31,6</B> Teile der Eisenverbindung des Farb  stoffes aus     diazotiertem        4-Nitro-2-amino-l-          phenol    und 1.     3-Dioxybenzol    werden in 200  Teilen Wasser und 27 Teilen 30 %     iger    Natron  lauge in .der Kälte gelöst und bei 10 bis 12'  mit der in üblicher Weise hergestellten     Diazo-          verbindung    aus<B>17,3</B> Teilen     1-Aminobenzol-          4-sulfonsäure    gekuppelt.

   Nach     vier-    bis sechs  stündigem Rühren ist die Kupplung beendet  Man neutralisiert mit verdünnter Salzsäure,  fällt den Farbstoff mit     Kochsalz    aus und  trocknet.



  <B> Additional patent </B> to main patent no. 178542. Process for the production of a dye containing complexed metal. It has been found that a complex metal-containing dye can be produced if 1 mol of diazotized 4-nitro-2-amino-1-phenol, 1 mol of diazotized 1-aminobenzene-4-sulfonic acid, 1 Mole 1. 3-Dioxybenzene and an iron releasing agent can interact.

    



  The dye obtained is a black powder which is easily soluble in water with a brown color. It dissolves in concentrated sulfuric acid with a brownish orange color and dyes leather in yellow-brown shades with very good fastness properties. The method can be carried out, for example,

       da.ss is allowed to act on the product of action of 1 mole of diazotized 4-nitro-2-amino-1-phenol and 1 mole of 1,3-dioxybenzene iron releasing agent and then 1 mole of diazotized 1-aminobenzene-4-sulfonic acid.

      <I> Example: </I> <B> 31.6 </B> parts of the iron compound of the dye from diazotized 4-nitro-2-amino-1-phenol and 1. 3-dioxybenzene in 200 parts of water and 27 parts of 30% sodium hydroxide solution dissolved in the cold and coupled at 10 to 12 'with the conventionally prepared diazo compound from 17.3 parts of 1-aminobenzenes-4-sulfonic acid.

   The coupling is complete after four to six hours of stirring. The mixture is neutralized with dilute hydrochloric acid, the dye is precipitated with sodium chloride and dried.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines komplex gebundenes Metall enthaltenden Farbstoffes, dadurch gekennzeichnet, dass man 1 Mol diazotiertes 4-Nitro-2-amino-l-phenol, 1 Mol diazotierte 1- Aminobenzol - 4 - sulfonsäure, 1 Hol 1. 3-Dioxybenzol und ein Eisen ab gebendes Mittel aufeinander einwirken lässt. Der erhaltene Farbstoff stellt ein in Wasser mit brauner Farbe leicht lösliches schwarzes Pulver dar. Claim: A process for the preparation of a complexed metal-containing dye, characterized in that 1 mol of diazotized 4-nitro-2-amino-1-phenol, 1 mol of diazotized 1-aminobenzene-4-sulfonic acid, 1 hol 1,3-dioxybenzene and lets an iron-releasing agent act on one another. The dye obtained is a black powder which is easily soluble in water with a brown color. Er löst sich in kon zentrierter Schwefelsäure mit braunstichig oranger Farbe und färbt Leder in gelb braunen Tönen von sehr guten Echtheits eigenschaften. UNTERANSPRUCH: Verfahren nach Patentanspruch, .dadurch gekennzeichnet, dass man auf das Einwir kungsprodukt aus 1 Mol diazotiertem 4-Nitro- 2-amino-l-phenol und 1 Mol 1. It dissolves in concentrated sulfuric acid with a brownish orange color and dyes leather in yellow-brown tones with very good fastness properties. SUBCLAIM: Process according to claim, characterized in that one mole of diazotized 4-nitro-2-amino-1-phenol and 1 mole of 1. 3-Diogyben- zol ein Eisen abgebendes Mittel und hierauf 1 Mol diazotierte 1-Aminobenzol-4-sulfon- säure einwirken lässt. 3-diogybenzene is an iron releasing agent and 1 mole of diazotized 1-aminobenzene-4-sulfonic acid is allowed to act on it.
CH182605D 1934-08-11 1934-08-11 Process for the preparation of a complexed metal-containing dye. CH182605A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH182605T 1934-08-11
CH178542T 1934-08-11

Publications (1)

Publication Number Publication Date
CH182605A true CH182605A (en) 1936-02-15

Family

ID=25720164

Family Applications (1)

Application Number Title Priority Date Filing Date
CH182605D CH182605A (en) 1934-08-11 1934-08-11 Process for the preparation of a complexed metal-containing dye.

Country Status (1)

Country Link
CH (1) CH182605A (en)

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