CH136257A - Process for the production of a new dye. - Google Patents

Process for the production of a new dye.

Info

Publication number
CH136257A
CH136257A CH136257DA CH136257A CH 136257 A CH136257 A CH 136257A CH 136257D A CH136257D A CH 136257DA CH 136257 A CH136257 A CH 136257A
Authority
CH
Switzerland
Prior art keywords
production
parts
new dye
violet
new
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH136257A publication Critical patent/CH136257A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00—Preparation of azo dyes from other azo compounds
    • C09B43/08—Preparation of azo dyes from other azo compounds by reduction
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
    • C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
    • C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
    • C09B29/3647—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms
    • C09B29/3652—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles
    • C09B29/366—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles containing hydroxy-1,2-diazoles, e.g. pyrazolone

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

  

  Verfahren zur Herstellung eines neuen     Farbstoffes.       Es wurde gefunden,     dass    ein neuer Farb  stoff entsteht, wenn man     1-Amino-4-nitro-          #        a        nthrachinan        diazotiert,        hierauf        mit        1.-Phe-          nyl-3-methyl-5-pyrazolon    kuppelt     and    das  so erhaltene Produkt mit Reduktionsmitteln  behandelt.  



  Der neue Farbstoff bildet ein dunkel  violettes Pulver, das sich in konzentrierter       I        ehwefelsäure    mit gelbbrauner und in     Toluol     mit     violettroter    Farbe löst. Er färbt die       Aceta,tseide    in reinen     rötlielivioletten    Tö  nen an.  



  <I>Beispiel:</I>  <B>13,5</B> Teile     1-Amino-4-nitroanthrachinoTt     werden in der     zehnfaehen    Menge Schwefel  säure gelöst, bei<B>10</B> bis 20<B>'</B> mit<B>3,6</B> Teilen       Natriumnitrit    versetzt und 48 Stunden bei  Zimmertemperatur gerührt.  



       Die    so erhaltene     Lö,%,ung    wird auf  400 Teile Eis ausgetragen, der kristallin     ab-          cileselliedene        Diazokörper    abgesaugt und mit  einer zirka, 40     '/oigen    Schwefelsäure ge  waschen. Der     Diazakörper    wird hierauf in    <B>8,00</B> Teilen Eiswasser gelöst, von eventuellen  unlöslichen Anteilen     abfiltriert    und mit  einer Lösung von<B>6</B> Teilen     1-Plienyl-3-methyl-          5-pyrazolo-n    in 200 Teilen Wasser,<B>100</B> Tei  len Eis und 20 Teilen     Natriumearbonat    ver  einigt.

   Nach mehrstündigem Rühren -wird  abgesaugt und neutral gewaschen. Der so  hergestellte     Nitroazokörper    bildet getrocknet  ein rotbraunes Pulver, das sieh in konzen  trierter     Sehwefelsäure    orange, in     Tolual     braunorange, löst.  



  Die feuchte Paste des Nitrokörpers wird  nun mit 200 Teilen Wasser verrührt und  mit<B>15</B> Teilen     Natriumsulfliydrat    während  einer halben bis einer Stunde bei<B>60'</B> nicht  übersteigender Temperatur behandelt. Hier  auf wird abgesaugt, neutral gewaschen und  gegebenenfalls in bekannter Weise     ver-          pastet.   <B>-</B>



  Process for the production of a new dye. It has been found that a new dye is produced when 1-amino-4-nitro- # a nthraquinane is diazotized, then coupled with 1.-phenyl-3-methyl-5-pyrazolone and the product thus obtained with reducing agents treated.



  The new dye forms a dark purple powder which dissolves in concentrated sulfuric acid with a yellow-brown color and in toluene with a purple-red color. He colors the Aceta, silk in pure reddish violet tones.



  <I> Example: </I> <B> 13.5 </B> parts of 1-amino-4-nitroanthraquinone are dissolved in ten times the amount of sulfuric acid, at <B> 10 </B> to 20 <B> '</B> mixed with <B> 3.6 </B> parts of sodium nitrite and stirred for 48 hours at room temperature.



       The solution obtained in this way is poured onto 400 parts of ice, and the crystalline ab- cileselliedene diazo body is filtered off with suction and washed with about 40% sulfuric acid. The diazo body is then dissolved in <B> 8.00 </B> parts of ice water, any insoluble constituents are filtered off and treated with a solution of <B> 6 </B> parts of 1-plienyl-3-methyl-5-pyrazolo- n in 200 parts of water, <B> 100 </B> parts of ice and 20 parts of sodium carbonate combined.

   After several hours of stirring, it is filtered off with suction and washed neutral. The nitroazo body produced in this way forms a red-brown powder when dried, which dissolves orange in concentrated sulfuric acid and brown-orange in tolual.



  The moist paste of the nitro body is then stirred with 200 parts of water and treated with <B> 15 </B> parts of sodium sulfide hydrate for half an hour to one hour at a temperature not exceeding 60 °. Here it is suctioned off, washed neutral and, if necessary, pasted in a known manner. <B> - </B>

Claims (1)

PATENTANSPRUCII: Verfahren zur Herstellung eines neuen Fa,rbs-üo,ffe,s, dadurch gekennzeichnet, dass man 1-Amino-4-nitroanthraehinon diazotiert, hierauf mit 1-Phenyl-3-methyl-5-pyrazolon kuppelt und das so erhaltene Produkt mit Reduktionsmitteln behandelt. Der neue Farbstoff bildet ein dunkel violettes Pulver,- das siA in konzentrierter Schwefelsä,ure mit gelbbrauner und in Toluol mit violettroter Farbe löst. PATENT CLAIM: Process for the production of a new Fa, rbs-üo, ffe, s, characterized in that 1-amino-4-nitroanthraehinone is diazotized, then coupled with 1-phenyl-3-methyl-5-pyrazolone and the product thus obtained treated with reducing agents. The new dye forms a dark violet powder - which dissolves in concentrated sulfuric acid with a yellow-brown color and in toluene with a violet-red color. Er färbt die Acetatseide in reinen rütlichvioletten TÖ'- nen an. He colors the acetate silk in pure red-violet tones.
CH136257D 1928-04-04 1928-04-04 Process for the production of a new dye. CH136257A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH136257T 1928-04-04
CH134943T 1928-04-04

Publications (1)

Publication Number Publication Date
CH136257A true CH136257A (en) 1929-10-31

Family

ID=25712400

Family Applications (1)

Application Number Title Priority Date Filing Date
CH136257D CH136257A (en) 1928-04-04 1928-04-04 Process for the production of a new dye.

Country Status (1)

Country Link
CH (1) CH136257A (en)

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