CH115042A - Process for the manufacture of a borneol. - Google Patents

Process for the manufacture of a borneol.

Info

Publication number
CH115042A
CH115042A CH115042DA CH115042A CH 115042 A CH115042 A CH 115042A CH 115042D A CH115042D A CH 115042DA CH 115042 A CH115042 A CH 115042A
Authority
CH
Switzerland
Prior art keywords
borneol
manufacture
acid
camphene
ether
Prior art date
Application number
Other languages
French (fr)
Inventor
Chimiques Societe Als Produits
Original Assignee
Alsacienne De Produits Chimiqu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alsacienne De Produits Chimiqu filed Critical Alsacienne De Produits Chimiqu
Publication of CH115042A publication Critical patent/CH115042A/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Procédé pour la fabrication d'un     bornéol.       L'objet de la     revendication    du brevet  principal est un procédé pour la     fabrication     d'un     bornéol,    suivant lequel on condense du       pinène    avec de l'acide     benzoylebenzoïque     pour produire un éther     bornéolique    facile  ment     saponifiable.     



  Or, il a été trouvé     qu'on    peut remplacer  dans ce procédé le     pinène    par le     camphène    et  l'acide     benzoylebenzoïque    par de l'acide     té-          traehlorbenzoylebenzoïque,    tout en obtenant  un résultat analogue à celui du procédé du  brevet principal, l'éther     bornéolique        obtenu     étant facilement saponifiable au moyen de  soude     caustique    aqueuse.  



  <I>Exemple:</I>  100 kg de     camphène    sont chauffés avec  50 kg d'acide     tétrachlorbenzoylebenzoïque    à    140   C. Après 9 heures, plus de 80 % de  l'acide sont transformés en éther     isobornéoli-          que.    L'excès de     camphène    est alors distillé  à la vapeur d'eau, le résidu est chauffé avec  de la lessive de soude à 20 % jusqu'à saponi  fication complète et     l'isobornéol    est séparé à  la vapeur d'eau.



  Process for the manufacture of a borneol. The object of the main patent claim is a process for the manufacture of borneol, wherein pinene is condensed with benzoylbenzoic acid to produce an easily saponifiable borneol ether.



  Now, it has been found that, in this process, pinene can be replaced by camphene and benzoylbenzoic acid by tetrahlorbenzoylebenzoic acid, while obtaining a result analogous to that of the process of the main patent, ether. borneol obtained being easily saponifiable by means of aqueous caustic soda.



  <I> Example: </I> 100 kg of camphene are heated with 50 kg of tetrachlorbenzoylebenzoic acid at 140 C. After 9 hours, more than 80% of the acid is converted into isoborneolic ether. The excess camphene is then distilled off with water vapor, the residue is heated with 20% sodium hydroxide solution until complete saponification and the isoborneol is separated with water vapor.

Claims (1)

REVENDICATION Procédé pour la fabrication d'un bornéol, suivant lequel on condense du camphène avec de l'acide tétrachlorbenzoylebenzoïque pour produire un éther bornéolique que l'on sa ponifie. CLAIM Process for the manufacture of a borneol, according to which camphene is condensed with tetrachlorbenzoylebenzoic acid to produce a borneol ether which is ponified.
CH115042D 1924-03-28 1925-03-18 Process for the manufacture of a borneol. CH115042A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR115042X 1924-03-28
CH114702T 1925-03-18

Publications (1)

Publication Number Publication Date
CH115042A true CH115042A (en) 1926-06-01

Family

ID=25708376

Family Applications (1)

Application Number Title Priority Date Filing Date
CH115042D CH115042A (en) 1924-03-28 1925-03-18 Process for the manufacture of a borneol.

Country Status (1)

Country Link
CH (1) CH115042A (en)

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