CA3071434A1 - Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture - Google Patents

Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture Download PDF

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Publication number
CA3071434A1
CA3071434A1 CA3071434A CA3071434A CA3071434A1 CA 3071434 A1 CA3071434 A1 CA 3071434A1 CA 3071434 A CA3071434 A CA 3071434A CA 3071434 A CA3071434 A CA 3071434A CA 3071434 A1 CA3071434 A1 CA 3071434A1
Authority
CA
Canada
Prior art keywords
adsorption
adsorption material
emm
desorption
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3071434A
Other languages
English (en)
French (fr)
Inventor
Jeffrey R. Long
Simon Christopher Weston
Phillip J. Milner
Rebecca L. Siegelman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California San Diego UCSD
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
University of California San Diego UCSD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co, University of California San Diego UCSD filed Critical ExxonMobil Research and Engineering Co
Publication of CA3071434A1 publication Critical patent/CA3071434A1/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
CA3071434A 2017-08-04 2018-08-03 Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture Pending CA3071434A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762541616P 2017-08-04 2017-08-04
US62/541,616 2017-08-04
PCT/US2018/045259 WO2019028421A1 (en) 2017-08-04 2018-08-03 ORGANOMETALLIC STRUCTURES ADDED TO CYCLIC DIAMINES FOR CAPTURING CARBON DIOXIDE

Publications (1)

Publication Number Publication Date
CA3071434A1 true CA3071434A1 (en) 2019-02-07

Family

ID=63371776

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3071434A Pending CA3071434A1 (en) 2017-08-04 2018-08-03 Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture

Country Status (9)

Country Link
US (1) US10780388B2 (enExample)
EP (1) EP3661644A1 (enExample)
JP (1) JP7246367B2 (enExample)
KR (1) KR102675365B1 (enExample)
CN (1) CN111093824B (enExample)
AU (1) AU2018309168B2 (enExample)
CA (1) CA3071434A1 (enExample)
SG (1) SG11202000934TA (enExample)
WO (1) WO2019028421A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116472112A (zh) * 2020-08-13 2023-07-21 埃克森美孚技术与工程公司 合成和再循环金属有机骨架体系的方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019108847A1 (en) 2017-11-29 2019-06-06 The Regents Of The University Of California A vanadium metal-organic framework for selective adsorption
US11097250B2 (en) * 2018-09-28 2021-08-24 The Regents Of The University Of California Metal-organic framework phase and crystallite shape control
JP7638223B2 (ja) * 2019-04-26 2025-03-03 エクソンモービル テクノロジー アンド エンジニアリング カンパニー 選択的ｃｏ２回収のための混合金属混合有機フレームワーク系
EP3999227A1 (en) 2019-07-15 2022-05-25 ExxonMobil Research and Engineering Company Metal-organic frameworks having localized defects for gas separations
US12403446B2 (en) * 2020-01-30 2025-09-02 Korea University Research And Business Foundation Alkanolamine/amine-grafted metal-organic framework-based carbon dioxide adsorbent
AU2021320985A1 (en) * 2020-08-06 2023-03-09 ExxonMobil Technology and Engineering Company Metal-organic frameworks for carbon dioxide capture
US20220370984A1 (en) * 2021-05-21 2022-11-24 ExxonMobil Technology and Engineering Company Polymeric sorbent fiber compositions incorporating metal organic frameworks
CN113663649A (zh) * 2021-08-05 2021-11-19 华东师范大学 一种mof成型材料应用于低温二氧化碳捕获
CN116693866A (zh) * 2022-02-25 2023-09-05 中国科学院福建物质结构研究所 一种钛基金属有机框架材料及其制备方法和应用
CN114644888B (zh) * 2022-04-01 2022-10-21 飞思仪表（深圳）有限公司 一种改性湿敏材料及其制备方法及应用、湿度传感器
GB202206101D0 (en) * 2022-04-27 2022-06-08 Mof Tech Limited Method and apparatus for carbon dioxide separation
WO2024202759A1 (ja) * 2023-03-29 2024-10-03 ウシオ電機株式会社 二酸化炭素の回収方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101247877B (zh) * 2005-08-09 2012-08-22 埃克森美孚研究工程公司 用于酸气涤气工艺的受阻环状多胺和其盐
US8916722B2 (en) 2009-06-19 2014-12-23 The Regents Of The University Of California Complex mixed ligand open framework materials
CN101816924A (zh) * 2010-04-13 2010-09-01 东南大学 用于co2吸附与分离的金属有机骨架材料及其制备方法
KR20120029586A (ko) * 2010-09-17 2012-03-27 한국전력공사 혼합가스 중 산성가스 분리용 흡수제 및 이를 이용한 분리방법
JP2015504000A (ja) 2011-10-18 2015-02-05 ザ レジェンツ オブ ザ ユニヴァーシティー オブ カリフォルニア 混合ガス分離用アルキルアミン官能化金属有機骨格
CN102962036B (zh) * 2012-10-30 2016-06-29 中国科学院大连化学物理研究所 基于过渡金属钴的多孔金属有机骨架材料及其制备方法
CA3209245A1 (en) 2014-04-22 2015-10-29 The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
US9421517B2 (en) * 2015-01-20 2016-08-23 Chung Yuan Christian University Metal-organic framework polymer for solid-phase microextraction
US20180272314A1 (en) * 2015-09-30 2018-09-27 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116472112A (zh) * 2020-08-13 2023-07-21 埃克森美孚技术与工程公司 合成和再循环金属有机骨架体系的方法

Also Published As

Publication number Publication date
US10780388B2 (en) 2020-09-22
AU2018309168A1 (en) 2020-02-27
SG11202000934TA (en) 2020-02-27
JP2020531249A (ja) 2020-11-05
KR102675365B1 (ko) 2024-06-13
JP7246367B2 (ja) 2023-03-27
AU2018309168B2 (en) 2022-09-29
CN111093824B (zh) 2023-05-26
WO2019028421A1 (en) 2019-02-07
US20190039015A1 (en) 2019-02-07
CN111093824A (zh) 2020-05-01
KR20200038273A (ko) 2020-04-10
EP3661644A1 (en) 2020-06-10

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