JP7246367B2 - 二酸化炭素回収のために環状ジアミンを付加した金属有機骨格 - Google Patents

二酸化炭素回収のために環状ジアミンを付加した金属有機骨格 Download PDF

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JP7246367B2
JP7246367B2 JP2020505866A JP2020505866A JP7246367B2 JP 7246367 B2 JP7246367 B2 JP 7246367B2 JP 2020505866 A JP2020505866 A JP 2020505866A JP 2020505866 A JP2020505866 A JP 2020505866A JP 7246367 B2 JP7246367 B2 JP 7246367B2
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adsorption
adsorbent material
dobpdc
metal
emm
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JP2020531249A5 (enExample
JP2020531249A (ja
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ジェフリー・アール・ロング
サイモン・クリストファー・ウエストン
フィリップ・ジェイ・ミルナー
レベッカ・エル・シーゲルマン
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University of California San Diego UCSD
ExxonMobil Technology and Engineering Co
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ExxonMobil Technology and Engineering Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
JP2020505866A 2017-08-04 2018-08-03 二酸化炭素回収のために環状ジアミンを付加した金属有機骨格 Active JP7246367B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762541616P 2017-08-04 2017-08-04
US62/541,616 2017-08-04
PCT/US2018/045259 WO2019028421A1 (en) 2017-08-04 2018-08-03 ORGANOMETALLIC STRUCTURES ADDED TO CYCLIC DIAMINES FOR CAPTURING CARBON DIOXIDE

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JP2020531249A JP2020531249A (ja) 2020-11-05
JP2020531249A5 JP2020531249A5 (enExample) 2021-09-09
JP7246367B2 true JP7246367B2 (ja) 2023-03-27

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US (1) US10780388B2 (enExample)
EP (1) EP3661644A1 (enExample)
JP (1) JP7246367B2 (enExample)
KR (1) KR102675365B1 (enExample)
CN (1) CN111093824B (enExample)
AU (1) AU2018309168B2 (enExample)
CA (1) CA3071434A1 (enExample)
SG (1) SG11202000934TA (enExample)
WO (1) WO2019028421A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11311856B2 (en) 2017-11-29 2022-04-26 The Regents Of The University Of California Vanadium metal-organic framework for selective adsorption
EP3856748B1 (en) * 2018-09-28 2024-03-06 The Regents of The University of California Metal-organic framework phase and crystallite shape control
CA3136079A1 (en) * 2019-04-26 2020-10-29 Exxonmobil Research And Engineering Company Mixed-metal mixed-organic framework systems for selective co2 capture
JP7504190B2 (ja) * 2019-07-15 2024-06-21 エクソンモービル テクノロジー アンド エンジニアリング カンパニー 局所的欠陥を有するガス分離用金属有機構造体
WO2021153933A1 (ko) * 2020-01-30 2021-08-05 고려대학교 산학협력단 알카놀아민/아민 접지 금속-유기골격체 기반 이산화탄소 흡착제
KR20230037038A (ko) * 2020-08-06 2023-03-15 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 이산화탄소 포집을 위한 금속 유기 골격구조
US11891407B2 (en) 2020-08-13 2024-02-06 ExxonMobil Technology and Engineering Company Methods of synthesizing and recycling metal-organic framework systems
CA3213770A1 (en) * 2021-05-21 2022-11-24 ExxonMobil Technology and Engineering Company Polymeric sorbent fiber compositions incorporating metal organic frameworks
CN113663649A (zh) * 2021-08-05 2021-11-19 华东师范大学 一种mof成型材料应用于低温二氧化碳捕获
CN116693866A (zh) * 2022-02-25 2023-09-05 中国科学院福建物质结构研究所 一种钛基金属有机框架材料及其制备方法和应用
CN114644888B (zh) * 2022-04-01 2022-10-21 飞思仪表（深圳）有限公司 一种改性湿敏材料及其制备方法及应用、湿度传感器
GB202206101D0 (en) * 2022-04-27 2022-06-08 Mof Tech Limited Method and apparatus for carbon dioxide separation
WO2024202759A1 (ja) * 2023-03-29 2024-10-03 ウシオ電機株式会社 二酸化炭素の回収方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012530718A (ja) 2009-06-19 2012-12-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 錯体混合リガンド開骨格材料
US20140294709A1 (en) 2011-10-18 2014-10-02 The Regents Of The University Of California Alkylamine functionalized metal-organic frameworks for composite gas separations
WO2017059130A2 (en) 2015-09-30 2017-04-06 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks
JP2017518169A (ja) 2014-04-22 2017-07-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 官能化された金属−有機フレームワーク内における酸性ガスの協同化学吸着

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ATE495813T1 (de) * 2005-08-09 2011-02-15 Exxonmobil Res & Eng Co Gehinderte cyclische polyamine und ihre salze für ein säuregaswäscheverfahren
CN101816924A (zh) * 2010-04-13 2010-09-01 东南大学 用于co2吸附与分离的金属有机骨架材料及其制备方法
KR20120029586A (ko) * 2010-09-17 2012-03-27 한국전력공사 혼합가스 중 산성가스 분리용 흡수제 및 이를 이용한 분리방법
CN102962036B (zh) * 2012-10-30 2016-06-29 中国科学院大连化学物理研究所 基于过渡金属钴的多孔金属有机骨架材料及其制备方法
US9421517B2 (en) * 2015-01-20 2016-08-23 Chung Yuan Christian University Metal-organic framework polymer for solid-phase microextraction

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JP2012530718A (ja) 2009-06-19 2012-12-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 錯体混合リガンド開骨格材料
US20140294709A1 (en) 2011-10-18 2014-10-02 The Regents Of The University Of California Alkylamine functionalized metal-organic frameworks for composite gas separations
JP2017518169A (ja) 2014-04-22 2017-07-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 官能化された金属−有機フレームワーク内における酸性ガスの協同化学吸着
WO2017059130A2 (en) 2015-09-30 2017-04-06 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks

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AU2018309168B2 (en) 2022-09-29
CN111093824B (zh) 2023-05-26
CN111093824A (zh) 2020-05-01
KR20200038273A (ko) 2020-04-10
SG11202000934TA (en) 2020-02-27
US20190039015A1 (en) 2019-02-07
CA3071434A1 (en) 2019-02-07
WO2019028421A1 (en) 2019-02-07
EP3661644A1 (en) 2020-06-10
US10780388B2 (en) 2020-09-22
KR102675365B1 (ko) 2024-06-13
AU2018309168A1 (en) 2020-02-27
JP2020531249A (ja) 2020-11-05

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