CA3057714C - Adsorptive gas separation employing steam for regeneration - Google Patents
Adsorptive gas separation employing steam for regeneration Download PDFInfo
- Publication number
- CA3057714C CA3057714C CA3057714A CA3057714A CA3057714C CA 3057714 C CA3057714 C CA 3057714C CA 3057714 A CA3057714 A CA 3057714A CA 3057714 A CA3057714 A CA 3057714A CA 3057714 C CA3057714 C CA 3057714C
- Authority
- CA
- Canada
- Prior art keywords
- stream
- steam
- regeneration
- contactor
- adsorptive gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000000274 adsorptive effect Effects 0.000 title claims abstract description 497
- 238000000926 separation method Methods 0.000 title claims abstract description 347
- 238000011069 regeneration method Methods 0.000 title claims description 352
- 230000008929 regeneration Effects 0.000 title claims description 344
- 239000007789 gas Substances 0.000 claims abstract description 519
- 239000000446 fuel Substances 0.000 claims abstract description 112
- 239000012530 fluid Substances 0.000 claims abstract description 71
- 239000000567 combustion gas Substances 0.000 claims abstract description 56
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 230000003750 conditioning effect Effects 0.000 claims description 98
- 238000000034 method Methods 0.000 claims description 88
- 230000008569 process Effects 0.000 claims description 86
- 239000003463 adsorbent Substances 0.000 claims description 64
- 239000000463 material Substances 0.000 claims description 62
- 238000010992 reflux Methods 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 239000007800 oxidant agent Substances 0.000 claims description 37
- 230000001590 oxidative effect Effects 0.000 claims description 37
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 20
- 230000009467 reduction Effects 0.000 claims description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052815 sulfur oxide Inorganic materials 0.000 claims description 9
- 230000001939 inductive effect Effects 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 abstract description 65
- 239000002826 coolant Substances 0.000 description 38
- 238000001179 sorption measurement Methods 0.000 description 30
- 238000010586 diagram Methods 0.000 description 19
- 239000007788 liquid Substances 0.000 description 16
- 238000009833 condensation Methods 0.000 description 15
- 230000005494 condensation Effects 0.000 description 15
- 239000007787 solid Substances 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- 239000003546 flue gas Substances 0.000 description 11
- 239000012080 ambient air Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- 239000002028 Biomass Substances 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 6
- 239000003350 kerosene Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000010248 power generation Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000003570 air Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000012621 metal-organic framework Substances 0.000 description 1
- 229920003146 methacrylic ester copolymer Polymers 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Treating Waste Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662316486P | 2016-03-31 | 2016-03-31 | |
| US62/316,486 | 2016-03-31 | ||
| PCT/CA2017/050396 WO2017165977A1 (en) | 2016-03-31 | 2017-03-31 | Adsorptive gas separation employing steam for regeneration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3057714A1 CA3057714A1 (en) | 2017-10-05 |
| CA3057714C true CA3057714C (en) | 2023-09-26 |
Family
ID=59962380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3057714A Active CA3057714C (en) | 2016-03-31 | 2017-03-31 | Adsorptive gas separation employing steam for regeneration |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US11117088B2 (enExample) |
| EP (1) | EP3426381B1 (enExample) |
| JP (2) | JP6957497B2 (enExample) |
| KR (1) | KR102346019B1 (enExample) |
| CN (1) | CN109310941B (enExample) |
| AU (1) | AU2017244045B2 (enExample) |
| BR (1) | BR112018070204B1 (enExample) |
| CA (1) | CA3057714C (enExample) |
| SA (1) | SA518400150B1 (enExample) |
| WO (1) | WO2017165977A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102476305B1 (ko) * | 2020-12-17 | 2022-12-09 | 한국생산기술연구원 | 저에너지형 이산화탄소 탈거방법 및 이산화탄소 탈거장치 |
| JP2024530997A (ja) * | 2021-05-11 | 2024-08-28 | スヴァンテ インコーポレイテッド | 高速循環式ガス分離デバイスにおいて第３の成分の吸着を用いて浄化済みの第１の成分の脱着を促進する吸着性ガス分離プロセスおよびシステム |
| US11577191B1 (en) | 2021-09-09 | 2023-02-14 | ColdStream Energy IP, LLC | Portable pressure swing adsorption method and system for fuel gas conditioning |
| JP2023108268A (ja) * | 2022-01-25 | 2023-08-04 | エア・ウォーター株式会社 | Ｃｏ２回収方法およびｃｏ２回収装置 |
| US12440807B2 (en) | 2022-05-10 | 2025-10-14 | Hydron Energy Inc. | System and process for gas upgrading |
| CN115608347B (zh) * | 2022-10-12 | 2024-03-29 | 普沃思环保科技无锡有限公司 | 一种蒸汽节能加热器和除湿系统 |
| DE102022133103A1 (de) * | 2022-12-13 | 2024-06-13 | NE3T (Nexus of Energy Efficiency and Environment Technologies) GmbH | Verfahren zum Abscheiden von Schadstoffen aus einem Rauchgasstrom |
| WO2025238601A1 (en) * | 2024-05-15 | 2025-11-20 | Svante Technologies Inc. | Integrated sorptive gas separation process and system with gas cooling |
Family Cites Families (51)
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|---|---|---|---|---|
| US2545194A (en) | 1945-11-14 | 1951-03-13 | Allan P Colburn | Adsorption process for removal of carbon dioxide from the atmosphere of a submarine |
| USRE29941E (en) * | 1974-03-12 | 1979-03-20 | Petrocarbon Developments Ltd. | Method and apparatus for separating gases |
| JPS5922625A (ja) | 1982-07-27 | 1984-02-04 | Osaka Oxgen Ind Ltd | 一酸化炭素ガス及び窒素ガスを含む混合ガスより窒素ガスを吸着法により除去する方法 |
| US5176722A (en) * | 1990-06-19 | 1993-01-05 | The Boc Group, Inc. | Pressure swing adsorption method for separating gaseous mixtures |
| US5256295A (en) | 1990-12-28 | 1993-10-26 | Membrane Technology & Research | Two-stage membrane process and apparatus |
| US5507857A (en) * | 1995-01-19 | 1996-04-16 | The Boc Group, Inc. | Pressure swing adsorption process for fractionating a multi-component mixture |
| US5906673A (en) * | 1997-05-15 | 1999-05-25 | Nitrotec Corporation | Pressure swing system with auxiliary adsorbent bed |
| FR2786110B1 (fr) * | 1998-11-23 | 2001-01-19 | Air Liquide | Procede de separation par adsorption modulee en pression d'un melange de gaz et installation pour sa mise en oeuvre |
| WO2000074819A1 (en) | 1999-06-04 | 2000-12-14 | Flair Corporation | Rotating drum adsorber process and system |
| JP3983440B2 (ja) * | 1999-11-08 | 2007-09-26 | 月島環境エンジニアリング株式会社 | 溶剤回収における活性炭層の冷却方法 |
| US6322612B1 (en) * | 1999-12-23 | 2001-11-27 | Air Products And Chemicals, Inc. | PSA process for removal of bulk carbon dioxide from a wet high-temperature gas |
| US7291271B2 (en) | 2003-12-09 | 2007-11-06 | Separation Design Group, Llc | Meso-frequency traveling wave electro-kinetic continuous adsorption system |
| US7166149B2 (en) | 2004-01-12 | 2007-01-23 | Uop Llc | Adsorption process for continuous purification of high value gas feeds |
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| CN1287886C (zh) * | 2004-06-11 | 2006-12-06 | 成都天立化工科技有限公司 | 一种改进的两段变压吸附制富氧方法 |
| CN1250321C (zh) * | 2004-06-11 | 2006-04-12 | 成都天立化工科技有限公司 | 一种两段全回收变压吸附气体分离方法 |
| EP2035116A2 (en) | 2006-05-05 | 2009-03-18 | Separation Design Group, LLC | Sorption method, device, and system |
| US7736416B2 (en) | 2007-02-26 | 2010-06-15 | Hamilton Sundstrand Corporation | Thermally linked molecular sieve beds for CO2 removal |
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| KR102055975B1 (ko) | 2013-10-09 | 2019-12-13 | 릴라이언스 인더스트리즈 리미티드 | 이산화 탄소를 포집하기 위한 다중 압축 시스템 및 공정 |
| US9308486B2 (en) | 2013-11-20 | 2016-04-12 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method of using a structured adsorbent bed for capture of CO2 from low pressure and low pressure concentration sources |
| US9314731B2 (en) | 2013-11-20 | 2016-04-19 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | RTSA method using adsorbent structure for CO2 capture from low pressure and low concentration sources |
| JP6351403B2 (ja) * | 2014-06-30 | 2018-07-04 | リファインホールディングス株式会社 | 揮発性有機化合物回収方法、及び揮発性有機化合物回収装置 |
| TWI657195B (zh) | 2014-07-08 | 2019-04-21 | 美商八河資本有限公司 | 加熱再循環氣體流的方法、生成功率的方法及功率產出系統 |
| WO2016005226A1 (en) | 2014-07-10 | 2016-01-14 | Climeworks Ag | Steam assisted vacuum desorption process for carbon dioxide capture |
| US20160010852A1 (en) | 2014-07-10 | 2016-01-14 | Babcock & Wilcox Power Generation Group, Inc. | Energy recovery for waste gas capture systems |
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2017
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- 2017-03-31 AU AU2017244045A patent/AU2017244045B2/en not_active Ceased
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2018
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2021
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| SA518400150B1 (ar) | 2023-01-08 |
| CA3057714A1 (en) | 2017-10-05 |
| US20210354074A1 (en) | 2021-11-18 |
| CN109310941B (zh) | 2022-07-22 |
| AU2017244045A1 (en) | 2018-11-01 |
| JP2022020030A (ja) | 2022-01-28 |
| KR102346019B1 (ko) | 2021-12-30 |
| EP3426381A4 (en) | 2019-11-13 |
| KR20180122477A (ko) | 2018-11-12 |
| AU2017244045B2 (en) | 2023-02-09 |
| EP3426381B1 (en) | 2023-05-03 |
| US20190105596A1 (en) | 2019-04-11 |
| US11117088B2 (en) | 2021-09-14 |
| JP6957497B2 (ja) | 2021-11-02 |
| BR112018070204A2 (pt) | 2019-01-29 |
| JP7210674B2 (ja) | 2023-01-23 |
| JP2019511360A (ja) | 2019-04-25 |
| CN109310941A (zh) | 2019-02-05 |
| BR112018070204B1 (pt) | 2023-01-31 |
| EP3426381A1 (en) | 2019-01-16 |
| WO2017165977A1 (en) | 2017-10-05 |
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