CA3031677C - Solid phosphoric acid catalysts - Google Patents

Solid phosphoric acid catalysts Download PDF

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Publication number
CA3031677C
CA3031677C CA3031677A CA3031677A CA3031677C CA 3031677 C CA3031677 C CA 3031677C CA 3031677 A CA3031677 A CA 3031677A CA 3031677 A CA3031677 A CA 3031677A CA 3031677 C CA3031677 C CA 3031677C
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Canada
Prior art keywords
silica
calcined
catalyst composition
range
mixture
Prior art date
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CA3031677A
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English (en)
French (fr)
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CA3031677A1 (en
Inventor
Malati RAGHUNATH
Aaron Miller
Claus G. Lugmair
Anthony Volpe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
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Clariant International Ltd
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Publication of CA3031677A1 publication Critical patent/CA3031677A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/182—Phosphorus; Compounds thereof with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/18—Acids of phosphorus; Salts thereof; Phosphorus oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C07C2527/173—Phosphoric acid or other acids with the formula Hn+2PnO3n+1

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA3031677A 2016-08-04 2017-07-27 Solid phosphoric acid catalysts Active CA3031677C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662370819P 2016-08-04 2016-08-04
US62/370,819 2016-08-04
PCT/US2017/044070 WO2018026617A1 (en) 2016-08-04 2017-07-27 Solid phosphoric acid catalysts

Publications (2)

Publication Number Publication Date
CA3031677A1 CA3031677A1 (en) 2018-02-08
CA3031677C true CA3031677C (en) 2024-02-20

Family

ID=59687007

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3031677A Active CA3031677C (en) 2016-08-04 2017-07-27 Solid phosphoric acid catalysts

Country Status (10)

Country Link
US (1) US10189014B2 (de)
EP (1) EP3493902A1 (de)
JP (1) JP7084376B2 (de)
KR (1) KR102406813B1 (de)
CN (1) CN109562362A (de)
BR (1) BR112019001422B8 (de)
CA (1) CA3031677C (de)
EA (1) EA201990391A1 (de)
WO (1) WO2018026617A1 (de)
ZA (1) ZA201900101B (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016163600A1 (ko) * 2015-04-06 2016-10-13 엘지전자 주식회사 고속 이동 사용자 기기의 이동성 관리
CN112300376B (zh) * 2020-11-20 2022-03-25 中国林业科学研究院林产化学工业研究所 固体酸催化竹屑液化用以制备生物基聚醚多元醇的方法
JP2025087936A (ja) * 2022-03-30 2025-06-11 丸善石油化学株式会社 ブテンオリゴマーの製造方法
CN118724837A (zh) * 2023-03-29 2024-10-01 蔚来电池科技(安徽)有限公司 氟代芳香不饱和氮硫五元杂环化合物及其制备方法和用途

Family Cites Families (29)

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US1993513A (en) 1933-07-03 1935-03-05 Universal Oil Prod Co Treatment of hydrocarbons
US2569092A (en) * 1949-07-01 1951-09-25 Union Oil Co Phosphoric acid or metal phosphate catalysts on precalcined carriers and their preparation
US2824149A (en) * 1951-07-31 1958-02-18 Exxon Research Engineering Co Olefin polymerization catalyst and process
US3044964A (en) 1958-12-15 1962-07-17 Jacque C Morrell Catalyst and process of making the same
US3112350A (en) 1961-06-12 1963-11-26 Universal Oil Prod Co Polymerization of olefins using a solid phosphoric acid catalyst
FR1603512A (de) 1968-10-31 1971-05-03
US3661801A (en) 1970-02-02 1972-05-09 Catalysts & Chem Inc Solid phosphoric acid catalysts
US4280929A (en) * 1979-09-17 1981-07-28 Standard Oil Company Attrition resistant-higher active component fluid bed catalysts
US4334118A (en) * 1981-06-01 1982-06-08 Chevron Research Solid phosphoric acid catalyzed olefin polymerization process
US4619908A (en) 1984-12-24 1986-10-28 Stauffer Chemical Company Non-aged inorganic oxide-containing aerogels and their preparation
SE465706B (sv) 1988-11-22 1991-10-21 Boerje Gevert Metod foer tillverkning av en katalysator baserad paa kiseldioxid och fosforsyra samt anvaendning av densamma
US5059737A (en) 1988-12-23 1991-10-22 Uop Catalytic condensation process
US4946815A (en) 1988-12-23 1990-08-07 Uop Solid phosphoric acid catalyst
US5081086A (en) 1988-12-29 1992-01-14 Uop Solid phosphoric acid catalyst
US4912279A (en) 1988-12-29 1990-03-27 Uop Solid phosphoric acid catalyst
US5043509A (en) 1989-08-18 1991-08-27 Uop Shaped catalyst particles utilizable for the conversion of organic compounds
US5177283A (en) 1992-02-03 1993-01-05 Uop Hydrocarbon conversion process
IT1255755B (it) 1992-05-15 1995-11-15 Procedimento per la preparazione di un catalizzatore solido a base di acido fosforico
CN1078494C (zh) 1998-01-06 2002-01-30 北京燕山石油化工公司研究院 固体磷酸催化剂的制造方法
GB9805107D0 (en) 1998-03-10 1998-05-06 Bp Chem Int Ltd Catalyst and use therof
DE19920830A1 (de) * 1999-05-06 2000-11-09 Ticona Gmbh Trimerisierung von Formaldehyd in der Gasphase
CN1208130C (zh) 2002-12-11 2005-06-29 中国石油化工股份有限公司 用于低碳烯烃齐聚的固体磷酸催化剂的制备方法
JP4366338B2 (ja) * 2004-07-16 2009-11-18 新日本石油株式会社 固体リン酸触媒およびそれを用いたオレフィンの二量化方法
KR101442857B1 (ko) 2006-06-07 2014-09-22 바스프 에스이 올레핀의 공이량체화 방법
US7557060B2 (en) * 2007-06-29 2009-07-07 Sud-Chemie Inc. Solid phosphoric acid with controlled porosity
US20130053599A1 (en) * 2011-08-22 2013-02-28 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US9403149B2 (en) 2011-09-21 2016-08-02 Clariant Corpoation Promoted solid phosphoric acid catalysts and methods of use
AU2013262758B9 (en) 2012-05-17 2015-11-12 Shell Internationale Research Maatschappij B.V. Process for producing volatile organic compounds from biomass material
US9205412B2 (en) 2013-03-01 2015-12-08 Clariant Corporation Catalyst for polyol hydrogenolysis

Also Published As

Publication number Publication date
CA3031677A1 (en) 2018-02-08
BR112019001422B1 (pt) 2021-03-09
JP7084376B2 (ja) 2022-06-14
WO2018026617A1 (en) 2018-02-08
JP2019524435A (ja) 2019-09-05
BR112019001422A2 (pt) 2019-05-07
US10189014B2 (en) 2019-01-29
BR112019001422B8 (pt) 2022-08-30
US20180036720A1 (en) 2018-02-08
ZA201900101B (en) 2019-09-25
EP3493902A1 (de) 2019-06-12
KR20190039141A (ko) 2019-04-10
KR102406813B1 (ko) 2022-06-08
CN109562362A (zh) 2019-04-02
EA201990391A1 (ru) 2019-07-31

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