CA3018497A1 - Improved method of making carbon molecular sieve membranes - Google Patents
Improved method of making carbon molecular sieve membranes Download PDFInfo
- Publication number
- CA3018497A1 CA3018497A1 CA3018497A CA3018497A CA3018497A1 CA 3018497 A1 CA3018497 A1 CA 3018497A1 CA 3018497 A CA3018497 A CA 3018497A CA 3018497 A CA3018497 A CA 3018497A CA 3018497 A1 CA3018497 A1 CA 3018497A1
- Authority
- CA
- Canada
- Prior art keywords
- gas
- molecular sieve
- carbon molecular
- furnace
- pyrolysis temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 89
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 42
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 38
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000007789 gas Substances 0.000 claims abstract description 101
- 238000000197 pyrolysis Methods 0.000 claims abstract description 65
- 238000000034 method Methods 0.000 claims abstract description 48
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 34
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 34
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- 239000004642 Polyimide Substances 0.000 claims abstract description 30
- 238000001816 cooling Methods 0.000 claims abstract description 30
- 229920001721 polyimide Polymers 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002243 precursor Substances 0.000 claims abstract description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005977 Ethylene Substances 0.000 claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 230000001590 oxidative effect Effects 0.000 claims abstract description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000001294 propane Substances 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- 239000012465 retentate Substances 0.000 claims description 8
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 239000001273 butane Substances 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 26
- 238000000926 separation method Methods 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 19
- 239000012510 hollow fiber Substances 0.000 description 13
- 239000012466 permeate Substances 0.000 description 13
- 239000011261 inert gas Substances 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000010926 purge Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000035699 permeability Effects 0.000 description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical compound C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 2
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 101100208473 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) lcm-2 gene Proteins 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 2
- 239000012704 polymeric precursor Substances 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007158 vacuum pyrolysis Methods 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- UENRXLSRMCSUSN-UHFFFAOYSA-N 3,5-diaminobenzoic acid Chemical compound NC1=CC(N)=CC(C(O)=O)=C1 UENRXLSRMCSUSN-UHFFFAOYSA-N 0.000 description 1
- LFBALUPVVFCEPA-UHFFFAOYSA-N 4-(3,4-dicarboxyphenyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C(C(O)=O)=C1 LFBALUPVVFCEPA-UHFFFAOYSA-N 0.000 description 1
- MBJAPGAZEWPEFB-UHFFFAOYSA-N 5-amino-2-(4-amino-2-sulfophenyl)benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1C1=CC=C(N)C=C1S(O)(=O)=O MBJAPGAZEWPEFB-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- YTVNOVQHSGMMOV-UHFFFAOYSA-N naphthalenetetracarboxylic dianhydride Chemical compound C1=CC(C(=O)OC2=O)=C3C2=CC=C2C(=O)OC(=O)C1=C32 YTVNOVQHSGMMOV-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0083—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
- B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
- B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/22—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
- B01D2323/081—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
- B01D2323/082—Cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/50—Control of the membrane preparation process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/28—Degradation or stability over time
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Carbon And Carbon Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662310836P | 2016-03-21 | 2016-03-21 | |
| US62/310,836 | 2016-03-21 | ||
| PCT/US2017/020432 WO2017165098A1 (en) | 2016-03-21 | 2017-03-02 | Improved method of making carbon molecular sieve membranes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA3018497A1 true CA3018497A1 (en) | 2017-09-28 |
Family
ID=58398259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3018497A Pending CA3018497A1 (en) | 2016-03-21 | 2017-03-02 | Improved method of making carbon molecular sieve membranes |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11084000B2 (enExample) |
| EP (1) | EP3433009A1 (enExample) |
| JP (1) | JP6966464B2 (enExample) |
| KR (1) | KR102339473B1 (enExample) |
| CN (1) | CN109070009A (enExample) |
| BR (1) | BR112018067665A2 (enExample) |
| CA (1) | CA3018497A1 (enExample) |
| WO (1) | WO2017165098A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112018011094B1 (pt) * | 2015-12-17 | 2023-03-07 | Dow Global Technologies Llc | Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás |
| US11517857B2 (en) | 2017-08-14 | 2022-12-06 | Dow Global Technologies Llc | Method to make carbon molecular sieve hollow fiber membranes |
| CN111225736B (zh) * | 2017-10-30 | 2023-03-31 | 陶氏环球技术有限责任公司 | 含第13族金属的碳分子筛膜和其制造方法 |
| DE102018216163A1 (de) | 2018-09-21 | 2020-03-26 | Forschungszentrum Jülich GmbH | CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US12036518B2 (en) | 2019-01-25 | 2024-07-16 | Dow Global Technologies Llc | Carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend |
| CN112044273B (zh) * | 2019-06-05 | 2023-04-25 | 中国石油天然气股份有限公司 | 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用 |
| CN112337320A (zh) * | 2019-08-08 | 2021-02-09 | 中国石油天然气股份有限公司 | 一种碳分子筛膜的密封方法 |
| CN110743389B (zh) * | 2019-12-07 | 2023-03-24 | 中化泉州能源科技有限责任公司 | 一种碳分子筛膜及其制备方法 |
| US20230311073A1 (en) * | 2020-08-26 | 2023-10-05 | King Abdullah University Of Science And Technology | Carbon molecular sieve membranes based on oxygen-free polymeric precursors |
| CN115945079B (zh) * | 2022-12-29 | 2025-10-10 | 太原理工大学 | 一种含氟可交联聚酰亚胺基碳分子筛膜的制备方法及应用 |
| CN119680406B (zh) * | 2024-12-17 | 2025-09-23 | 大连理工大学 | 一种具备高气体分离性能的含氟特罗格碱基炭分子筛膜制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69102350T2 (de) | 1990-04-27 | 1995-01-19 | Ube Industries | Asymmetrische Hohlfadenmembran aus Kohlenstoff und Verfahren zu deren Herstellung. |
| JPH07121344B2 (ja) * | 1990-04-27 | 1995-12-25 | 宇部興産株式会社 | 非対称性中空糸炭素膜及びその製法 |
| US5288304A (en) | 1993-03-30 | 1994-02-22 | The University Of Texas System | Composite carbon fluid separation membranes |
| KR100263333B1 (ko) * | 1997-12-31 | 2000-08-01 | 이영무 | 다공성 탄소분자체 분리막의 제조방법 |
| JP4081956B2 (ja) * | 1999-03-05 | 2008-04-30 | 宇部興産株式会社 | 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法 |
| US6299669B1 (en) | 1999-11-10 | 2001-10-09 | The University Of Texas System | Process for CO2/natural gas separation |
| PT103453B (pt) * | 2006-03-24 | 2008-05-28 | Univ Do Porto | Dispositivo de separação de olefinas de parafinas e de purificação de olefinas e sua utilização |
| US8486179B2 (en) | 2009-10-29 | 2013-07-16 | Georgia Tech Research Corporation | Method for producing carbon molecular sieve membranes in controlled atmospheres |
| SG181276A1 (en) * | 2010-12-03 | 2012-06-28 | Univ Singapore | Method of fabricating a carbon molecular sieve membrane |
| EP2683473A1 (en) * | 2011-03-07 | 2014-01-15 | Georgia Tech Research Corporation | Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations |
| AU2012354175B2 (en) * | 2011-12-20 | 2015-04-30 | Air Liquide Advanced Technologies U.S., Llc | Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes |
| CN102527259A (zh) * | 2012-02-10 | 2012-07-04 | 南京工业大学 | 一种复合碳分子筛膜及其制备方法和应用 |
| EP2844368B1 (en) * | 2012-05-01 | 2019-08-07 | Dow Global Technologies LLC | Use of a hollow fiber carbon molecular sieve membrane |
| US8999037B2 (en) * | 2012-05-30 | 2015-04-07 | Georgia Tech Research Corporation | Carbon molecular sieve membrane (CMSM) performance tuning by dual temperature secondary oxygen doping (DTSOD) |
| EP2911769A4 (en) | 2012-10-29 | 2016-06-15 | Georgia Tech Res Inst | CARBON MOLECULAR SIEVE MEMBRANES FOR NITROGEN / METHANE SEPARATION |
| WO2015100161A1 (en) * | 2013-12-26 | 2015-07-02 | L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude | Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers |
| BR112018011094B1 (pt) * | 2015-12-17 | 2023-03-07 | Dow Global Technologies Llc | Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás |
-
2017
- 2017-03-02 KR KR1020187028432A patent/KR102339473B1/ko active Active
- 2017-03-02 CA CA3018497A patent/CA3018497A1/en active Pending
- 2017-03-02 WO PCT/US2017/020432 patent/WO2017165098A1/en not_active Ceased
- 2017-03-02 CN CN201780015488.7A patent/CN109070009A/zh active Pending
- 2017-03-02 EP EP17712883.2A patent/EP3433009A1/en not_active Ceased
- 2017-03-02 US US16/086,621 patent/US11084000B2/en active Active
- 2017-03-02 BR BR112018067665A patent/BR112018067665A2/pt not_active Application Discontinuation
- 2017-03-02 JP JP2018545916A patent/JP6966464B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20190099722A1 (en) | 2019-04-04 |
| WO2017165098A1 (en) | 2017-09-28 |
| US11084000B2 (en) | 2021-08-10 |
| EP3433009A1 (en) | 2019-01-30 |
| CN109070009A (zh) | 2018-12-21 |
| KR20190033464A (ko) | 2019-03-29 |
| JP6966464B2 (ja) | 2021-11-17 |
| BR112018067665A2 (pt) | 2019-01-08 |
| JP2019510624A (ja) | 2019-04-18 |
| KR102339473B1 (ko) | 2021-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11084000B2 (en) | Method of making carbon molecular sieve membranes | |
| CA3008242C (en) | Method of making carbon molecular sieve membranes | |
| US11666865B2 (en) | Method of making carbon molecular sieve membranes | |
| JP7262454B2 (ja) | 第１３族金属を含有する炭素分子ふるい膜およびそれらを作製する方法 | |
| WO2023004022A1 (en) | Reverse selective/surface flow polyimide derived cms membrane for gas separation | |
| EP4373604A1 (en) | Methods for manufacturing hollow fiber carbon membranes | |
| US11420154B2 (en) | Method of making carbon molecular sieve membranes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |
|
| EEER | Examination request |
Effective date: 20220302 |