CA3002650C - Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore - Google Patents

Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore Download PDF

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CA3002650C
CA3002650C CA3002650A CA3002650A CA3002650C CA 3002650 C CA3002650 C CA 3002650C CA 3002650 A CA3002650 A CA 3002650A CA 3002650 A CA3002650 A CA 3002650A CA 3002650 C CA3002650 C CA 3002650C
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phosphorous oxide
lithium metal
materials
oxide material
metal phosphorous
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CA3002650A1 (fr
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Chun-Chieh Chang
Tsun Yu Chang
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Changs Ascending Enterprise Co Ltd
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Changs Ascending Enterprise Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/30—Alkali metal phosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/043—Processes of manufacture in general involving compressing or compaction
    • H01M4/0435—Rolling or calendering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Il est décrit certaines réalisations dun procédé de synthèse chimique novateur prévu pour des applications liées aux batteries au lithium-ion. Par conséquent, diverses réalisations mettent laccent sur la synthèse dune nouvelle matière active en utilisant de loxyde de lithium-nickel-manganèse-cobalt (NMC) comme précurseur dun matériau phosphaté ayant une structure cristalline en couches. La génération partielle de phosphate dans le matériau ayant une structure en couches stabilise le matériau sans nuire à la nature du matériau ayant une structure en couches qui lui offre une grande capacité. Il est possible de produire des matériaux dont la composition est représentée par Lix Ni1/4 Mn1/4 Co1/4 P(1/4-y )O2, dans lequel 0 <= x <= 1 et 0,001 <= y <= 0,25, et par LixX(2/3+y)P(1/3-y)O2, dans lequel 0 <= x <= 1, 0,001 <= y <= 0,33, et X est du nickel ou une combinaison déléments de métal de transition.
CA3002650A 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore Active CA3002650C (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA3002650A CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA2956032A CA2956032C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore
CA3002650A CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore
PCT/IB2014/001067 WO2016012823A1 (fr) 2014-07-24 2014-07-24 Synthèse et caractérisation d'oxyde de lithium-nickel-manganèse-cobalt phosphoré

Related Parent Applications (1)

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CA2956032A Division CA2956032C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

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CA3002650A1 CA3002650A1 (fr) 2016-01-28
CA3002650C true CA3002650C (fr) 2022-04-12

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CA3002650A Active CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore
CA2956032A Active CA2956032C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

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WO (1) WO2016012823A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL235260B1 (pl) 2016-05-23 2020-06-15 Univ Jagiellonski Materiały katodowe LKMNO i sposób ich wytwarzania
CN114256451A (zh) * 2021-11-29 2022-03-29 广东邦普循环科技有限公司 一种钠离子电池正极材料及其制备方法和应用

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4425915B2 (ja) * 2004-11-02 2010-03-03 日鉱金属株式会社 リチウム二次電池用正極材料及びその製造方法
WO2008054547A2 (fr) * 2006-05-31 2008-05-08 Uchicago Argonne, Llc Électrodes stabilisées en surface pour des batteries au lithium
JP5268042B2 (ja) * 2006-11-24 2013-08-21 国立大学法人九州大学 正極活物質の製造方法およびそれを用いた非水電解質電池
TW201219981A (en) * 2010-09-21 2012-05-16 Basf Se Process for producing electrode materials
KR101475922B1 (ko) * 2012-12-27 2014-12-23 전자부품연구원 망간 인산화물이 코팅된 리튬 이차전지용 양극 활물질 및 그의 제조 방법

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Publication number Publication date
WO2016012823A1 (fr) 2016-01-28
KR101884142B1 (ko) 2018-07-31
KR20170074847A (ko) 2017-06-30
CA3002650A1 (fr) 2016-01-28
CA2956032A1 (fr) 2016-01-28
CA2956032C (fr) 2019-04-16

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