CA2958915A1 - Laundry detergents and cleaning compositions comprising sulfonate group-containing polymers - Google Patents
Laundry detergents and cleaning compositions comprising sulfonate group-containing polymers Download PDFInfo
- Publication number
- CA2958915A1 CA2958915A1 CA2958915A CA2958915A CA2958915A1 CA 2958915 A1 CA2958915 A1 CA 2958915A1 CA 2958915 A CA2958915 A CA 2958915A CA 2958915 A CA2958915 A CA 2958915A CA 2958915 A1 CA2958915 A1 CA 2958915A1
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- mass
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- detergent
- copolymer
- sulfonate group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 438
- 239000003599 detergent Substances 0.000 title claims abstract description 214
- 238000004140 cleaning Methods 0.000 title claims abstract description 213
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 title claims abstract description 164
- 229920000642 polymer Polymers 0.000 title description 237
- 229920001577 copolymer Polymers 0.000 claims abstract description 347
- 239000007788 liquid Substances 0.000 claims abstract description 69
- 239000002689 soil Substances 0.000 claims abstract description 54
- 239000000178 monomer Substances 0.000 claims description 339
- -1 brighteners Substances 0.000 claims description 142
- 239000004094 surface-active agent Substances 0.000 claims description 83
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 66
- 239000003795 chemical substances by application Substances 0.000 claims description 65
- 239000002253 acid Substances 0.000 claims description 62
- 150000003839 salts Chemical class 0.000 claims description 61
- 239000000975 dye Substances 0.000 claims description 49
- 150000001875 compounds Chemical class 0.000 claims description 44
- 239000007844 bleaching agent Substances 0.000 claims description 42
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 31
- 102000004190 Enzymes Human genes 0.000 claims description 30
- 108090000790 Enzymes Proteins 0.000 claims description 30
- 239000003945 anionic surfactant Substances 0.000 claims description 29
- 239000004927 clay Substances 0.000 claims description 22
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
- 229910052708 sodium Inorganic materials 0.000 claims description 21
- 239000003054 catalyst Substances 0.000 claims description 20
- 239000002304 perfume Substances 0.000 claims description 19
- 239000002736 nonionic surfactant Substances 0.000 claims description 18
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical group [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 16
- 239000002738 chelating agent Substances 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 239000010457 zeolite Substances 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000012190 activator Substances 0.000 claims description 12
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 11
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 11
- 229910052700 potassium Inorganic materials 0.000 claims description 11
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 238000012546 transfer Methods 0.000 claims description 10
- 238000004061 bleaching Methods 0.000 claims description 9
- 239000003093 cationic surfactant Substances 0.000 claims description 9
- 238000004851 dishwashing Methods 0.000 claims description 9
- 239000004519 grease Substances 0.000 claims description 9
- 125000006353 oxyethylene group Chemical group 0.000 claims description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims description 8
- 230000000087 stabilizing effect Effects 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 125000000962 organic group Chemical group 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 239000012459 cleaning agent Substances 0.000 claims description 4
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 122
- 238000000034 method Methods 0.000 abstract description 61
- 238000012423 maintenance Methods 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 10
- 230000008901 benefit Effects 0.000 abstract description 9
- 239000000243 solution Substances 0.000 description 171
- 230000000052 comparative effect Effects 0.000 description 130
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 99
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 78
- 238000006116 polymerization reaction Methods 0.000 description 70
- 239000004744 fabric Substances 0.000 description 66
- 239000007787 solid Substances 0.000 description 61
- 238000006386 neutralization reaction Methods 0.000 description 57
- 238000012360 testing method Methods 0.000 description 53
- 125000000217 alkyl group Chemical group 0.000 description 52
- 230000015572 biosynthetic process Effects 0.000 description 48
- 238000003786 synthesis reaction Methods 0.000 description 46
- 125000004432 carbon atom Chemical group C* 0.000 description 45
- 239000000463 material Substances 0.000 description 44
- 239000000047 product Substances 0.000 description 42
- 238000006243 chemical reaction Methods 0.000 description 41
- 235000019441 ethanol Nutrition 0.000 description 40
- 125000005702 oxyalkylene group Chemical group 0.000 description 39
- 238000011282 treatment Methods 0.000 description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 35
- 239000011521 glass Substances 0.000 description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 29
- 230000000379 polymerizing effect Effects 0.000 description 28
- 239000000562 conjugate Substances 0.000 description 27
- 229940088598 enzyme Drugs 0.000 description 27
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 26
- 229910001385 heavy metal Inorganic materials 0.000 description 26
- 235000011121 sodium hydroxide Nutrition 0.000 description 26
- 230000001976 improved effect Effects 0.000 description 25
- 238000003756 stirring Methods 0.000 description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 24
- 239000011734 sodium Substances 0.000 description 24
- 230000003750 conditioning effect Effects 0.000 description 23
- 150000002500 ions Chemical class 0.000 description 23
- 239000002904 solvent Substances 0.000 description 23
- 150000001412 amines Chemical class 0.000 description 22
- 239000003505 polymerization initiator Substances 0.000 description 20
- 229920001296 polysiloxane Polymers 0.000 description 20
- 239000004615 ingredient Substances 0.000 description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 18
- 102000035195 Peptidases Human genes 0.000 description 18
- 108091005804 Peptidases Proteins 0.000 description 18
- 150000001298 alcohols Chemical class 0.000 description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 17
- 239000004365 Protease Substances 0.000 description 17
- MQLVWQSVRZVNIP-UHFFFAOYSA-L ferrous ammonium sulfate hexahydrate Chemical compound [NH4+].[NH4+].O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MQLVWQSVRZVNIP-UHFFFAOYSA-L 0.000 description 17
- 125000002947 alkylene group Chemical group 0.000 description 16
- 238000010992 reflux Methods 0.000 description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 15
- 229940048053 acrylate Drugs 0.000 description 15
- 125000002091 cationic group Chemical group 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
- 125000000129 anionic group Chemical group 0.000 description 14
- 239000012986 chain transfer agent Substances 0.000 description 14
- 239000011162 core material Substances 0.000 description 14
- 229940117927 ethylene oxide Drugs 0.000 description 14
- 239000000945 filler Substances 0.000 description 14
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 description 13
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 12
- 229920002749 Bacterial cellulose Polymers 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 12
- 239000005016 bacterial cellulose Substances 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 229920002678 cellulose Polymers 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
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- 229910052742 iron Inorganic materials 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 150000004965 peroxy acids Chemical class 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 229920000058 polyacrylate Polymers 0.000 description 12
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 12
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 12
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 12
- 229920006317 cationic polymer Polymers 0.000 description 11
- 239000001913 cellulose Substances 0.000 description 11
- 238000007334 copolymerization reaction Methods 0.000 description 11
- 235000011187 glycerol Nutrition 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 125000003277 amino group Chemical group 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 239000000049 pigment Substances 0.000 description 10
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- 235000013772 propylene glycol Nutrition 0.000 description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 239000008233 hard water Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 238000004900 laundering Methods 0.000 description 9
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 9
- 229940068984 polyvinyl alcohol Drugs 0.000 description 9
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 8
- 101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 8
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
- 239000002585 base Substances 0.000 description 8
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
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- 239000003999 initiator Substances 0.000 description 8
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- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 7
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- NJGWOFRZMQRKHT-UHFFFAOYSA-N surfactin Natural products CC(C)CCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-UHFFFAOYSA-N 0.000 description 1
- NJGWOFRZMQRKHT-WGVNQGGSSA-N surfactin C Chemical compound CC(C)CCCCCCCCC[C@@H]1CC(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-WGVNQGGSSA-N 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000007885 tablet disintegrant Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 150000001911 terphenyls Chemical class 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 description 1
- RILFGEIJJMTZLZ-UHFFFAOYSA-J tetrapotassium;dioxido-oxo-phosphonato-$l^{5}-phosphane Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)P([O-])([O-])=O RILFGEIJJMTZLZ-UHFFFAOYSA-J 0.000 description 1
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 description 1
- SDVHRXOTTYYKRY-UHFFFAOYSA-J tetrasodium;dioxido-oxo-phosphonato-$l^{5}-phosphane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)P([O-])([O-])=O SDVHRXOTTYYKRY-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- LKHDXIBHVSGUHN-UHFFFAOYSA-N thiadiazole 1,1-dioxide Chemical class O=S1(=O)C=CN=N1 LKHDXIBHVSGUHN-UHFFFAOYSA-N 0.000 description 1
- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 1
- 229940035024 thioglycerol Drugs 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical class C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 150000003732 xanthenes Chemical class 0.000 description 1
- 229940030186 xpect Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical class C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/16—Monomers containing no hetero atoms other than the ether oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Dispersion Chemistry (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2014/087376 WO2016045026A1 (en) | 2014-09-25 | 2014-09-25 | Laundry detergents and cleaning compositions comprising sulfonate group-containing polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2958915A1 true CA2958915A1 (en) | 2016-03-31 |
Family
ID=55580074
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2958915A Pending CA2958915A1 (en) | 2014-09-25 | 2014-09-25 | Laundry detergents and cleaning compositions comprising sulfonate group-containing polymers |
| CA2959188A Abandoned CA2959188A1 (en) | 2014-09-25 | 2015-09-15 | Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers |
| CA2959190A Expired - Fee Related CA2959190C (en) | 2014-09-25 | 2015-09-15 | Cleaning compositions comprising amphiphilic graft copolymers and sulfonate group-containing copolymers |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2959188A Abandoned CA2959188A1 (en) | 2014-09-25 | 2015-09-15 | Cleaning compositions comprising alkoxylated polyalkyleneimines and sulfonate group-containing copolymers |
| CA2959190A Expired - Fee Related CA2959190C (en) | 2014-09-25 | 2015-09-15 | Cleaning compositions comprising amphiphilic graft copolymers and sulfonate group-containing copolymers |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9809784B2 (enExample) |
| EP (3) | EP3197995B1 (enExample) |
| JP (1) | JP6571171B2 (enExample) |
| CN (3) | CN106715665B (enExample) |
| AR (3) | AR102346A1 (enExample) |
| BR (3) | BR112017003432A2 (enExample) |
| CA (3) | CA2958915A1 (enExample) |
| MX (3) | MX2017003974A (enExample) |
| WO (3) | WO2016045026A1 (enExample) |
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| US8968047B1 (en) | 2011-05-09 | 2015-03-03 | Balloon Innovations, LLC | Balloon display system with inflatable balloon, balloon holder cup and flexible rod with mounting pole |
| US10005205B1 (en) | 2013-03-07 | 2018-06-26 | Balloon Innovations, Inc. | Reflective helium-free balloon system |
| US10124268B1 (en) | 2014-06-18 | 2018-11-13 | Balloon Innovations Inc. | Self-adjusting support plate |
| JP6513442B2 (ja) * | 2015-03-20 | 2019-05-15 | 株式会社日本触媒 | 酸基含有重合体、及び、酸基含有重合体の保存方法 |
| US9399176B1 (en) | 2015-06-16 | 2016-07-26 | Balloon Innovations, Inc. | Helium free balloon support bracket system |
| US10232544B2 (en) | 2015-07-31 | 2019-03-19 | Balloon Innovations, Inc. | Method of manufacturing a helium-free balloon |
| US10679529B1 (en) | 2016-02-18 | 2020-06-09 | Balloon Innovations Inc. | Modular pole display assembly |
| CN108779416B (zh) | 2016-04-08 | 2021-01-05 | 荷兰联合利华有限公司 | 洗衣洗涤剂组合物 |
| RU2767404C2 (ru) | 2016-04-13 | 2022-03-17 | МОНОСОЛ, ЭлЭлСи | Водорастворимые пленки, пакеты и контейнерные системы |
| CN106281749B (zh) * | 2016-07-15 | 2019-07-02 | 广州蓝月亮实业有限公司 | 一种洗涤剂组合物 |
| USD813316S1 (en) | 2016-07-26 | 2018-03-20 | Balloon Innovations, Inc. | Balloon stem handle |
| DE102017210141A1 (de) * | 2017-06-16 | 2018-12-20 | Henkel Ag & Co. Kgaa | Portion zur Bereitstellung tensidhaltiger Flotten |
| US20180216038A1 (en) * | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Detergent particle comprising polymer and surfactant |
| US11390713B2 (en) * | 2017-02-13 | 2022-07-19 | Basf Se | Process for making an alkoxylated polyalkylenimine |
| CN113015783B (zh) * | 2018-12-13 | 2024-07-05 | 陶氏环球技术有限责任公司 | 清洁助剂 |
| JP7102408B2 (ja) | 2019-01-15 | 2022-07-19 | ザ プロクター アンド ギャンブル カンパニー | 孔又は穴を有する多層溶解性固体物品 |
| EP3911293A1 (en) * | 2019-01-15 | 2021-11-24 | The Procter & Gamble Company | Flexible and dissolvable solid sheet article |
| US12180438B2 (en) * | 2019-05-30 | 2024-12-31 | Rohm And Haas Company | Dispersant polymer for automatic dishwashing |
| WO2020251766A1 (en) | 2019-06-14 | 2020-12-17 | Dow Global Technologies Llc | Liquid laundry detergent with cleaning booster |
| US12129450B2 (en) | 2019-06-14 | 2024-10-29 | Dow Global Technologies Llc | Detergent formulation for liquid laundry |
| BR112021022611A2 (pt) | 2019-06-14 | 2022-01-04 | Dow Global Technologies Llc | Aditivo líquido para lavagem de roupas |
| WO2020251765A1 (en) | 2019-06-14 | 2020-12-17 | Dow Global Technologies Llc | A polymer for cleaning boosting |
| US11427786B2 (en) * | 2019-08-15 | 2022-08-30 | Henkel Ag & Co. Kgaa | Detergent composition including a functional material encapsulated in polyvinyl alcohol particles |
| EP4100449A4 (en) * | 2020-02-05 | 2024-04-10 | Itaconix Corporation | COPOLYMER FORMULATIONS OF POLY(ITACONIC ACID-CO-2-ACRYLAMIDO-2-METHYLPROPANESULPHONIC ACID) FOR DISHWASHER COMPOSITIONS |
| EP4157983B1 (en) * | 2020-05-27 | 2024-02-14 | Unilever IP Holdings B.V. | Fabric softener composition |
| US20230266670A1 (en) * | 2020-07-17 | 2023-08-24 | Lam Research Corporation | Metal chelators for development of metal-containing photoresist |
| UY39668A (es) * | 2021-03-11 | 2022-10-31 | Suzano Sa | Estructura de matriz para una composición de detergente para ropa, composición sólida de detergente para ropa, proceso para producir una composición sólida de detergente para ropa, forma de detergente de dosificación unitaria, uso de celulosa microfibrilada |
| CN115957592B (zh) * | 2021-10-13 | 2024-11-29 | 中国石油化工股份有限公司 | 脱碱精制剂及其制备方法和在干气脱碱性杂质中的应用 |
| EP4194536A1 (en) * | 2021-12-08 | 2023-06-14 | The Procter & Gamble Company | Laundry treatment cartridge |
| CN114316133B (zh) * | 2022-03-11 | 2022-06-10 | 河南博源新材料有限公司 | 一种具有增强配位作用的聚丙烯酰胺组合物 |
| CN114680140B (zh) * | 2022-04-22 | 2024-01-26 | 宁波市农业科学研究院 | 一种提高瓜类嫁接成效的药剂及其制备方法和应用 |
| CN116286224B (zh) * | 2023-02-22 | 2023-11-24 | 广东优凯科技有限公司 | 一种去异味的超浓缩液体洗涤剂组合物及其制备方法 |
| JP7769144B2 (ja) | 2023-03-17 | 2025-11-12 | ラム リサーチ コーポレーション | Ｅｕｖパターニングのための乾式現像およびエッチングプロセスの単一プロセスチャンバへの統合 |
| CN116924507B (zh) * | 2023-09-14 | 2023-12-15 | 杭州尚善若水环保科技有限公司 | 一种多功能混合药剂 |
| CN117447648B (zh) * | 2023-11-23 | 2024-04-02 | 滨州乾坤化工机械有限公司 | 一种稠油降粘剂及其制备方法 |
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| BRPI0813361A2 (pt) * | 2007-06-29 | 2016-07-12 | Procter & Gamble | composições detergentes para lavagem de roupas que compreendem polímeros de enxerto anfifílicos à base de óxidos de polialquileno e ésteres vinílicos. |
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| WO2010024448A1 (ja) * | 2008-09-01 | 2010-03-04 | 株式会社日本触媒 | 疎水基含有共重合体及びその製造方法 |
| WO2010024469A1 (en) * | 2008-09-01 | 2010-03-04 | The Procter & Gamble Company | Hydrophobic group-containing copolymer and process for the production thereof |
| WO2010024468A1 (en) | 2008-09-01 | 2010-03-04 | The Procter & Gamble Company | Sulfonate group-containing copolymers and manufacturing method thereof |
| US8779184B2 (en) | 2008-09-12 | 2014-07-15 | Nippon Shokubai Co., Ltd. | Manufacturing method for sulfonic acid group-containing ether compound |
| JP5235615B2 (ja) * | 2008-11-07 | 2013-07-10 | 株式会社日本触媒 | スルホン酸基含有共重合体およびその製造方法 |
| US20120101018A1 (en) * | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
| EP2643370B1 (de) * | 2010-11-23 | 2019-07-03 | Basf Se | Copolymere, die carbonsäuregruppen, sulfonsäuregruppen und polyalkylenoxidgruppen enthalten, als belagsinhibierender zusatz zu wasch- und reinigungsmitteln |
| WO2014032269A1 (en) * | 2012-08-31 | 2014-03-06 | The Procter & Gamble Company | Laundry detergents and cleaning compositions comprising carboxyl group-containing polymers |
| CN104540932B (zh) | 2012-08-31 | 2017-11-17 | 株式会社日本触媒 | 含有羧基的聚合物及含有该聚合物的组合物 |
| MX2016002494A (es) * | 2013-08-26 | 2016-05-31 | Procter & Gamble | Composiciones que comprenden poliaminas alcoxiladas que tienen puntos de fusion bajos. |
| EP3110933B1 (en) * | 2014-02-26 | 2019-07-31 | The Procter and Gamble Company | Cleaning compositions comprising alkoxylated polyalkyleneimine, organomodified silicone and siloxane-based diluent |
| DE112014006990T5 (de) | 2014-09-25 | 2017-06-08 | Nippon Shokubai Co., Ltd. | Sulfonatgruppenhaltiges polymer und verfahren zur herstellung hiervon |
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2014
- 2014-09-25 CN CN201480082175.XA patent/CN106715665B/zh active Active
- 2014-09-25 CA CA2958915A patent/CA2958915A1/en active Pending
- 2014-09-25 JP JP2017513198A patent/JP6571171B2/ja active Active
- 2014-09-25 MX MX2017003974A patent/MX2017003974A/es unknown
- 2014-09-25 WO PCT/CN2014/087376 patent/WO2016045026A1/en not_active Ceased
- 2014-09-25 EP EP14902632.0A patent/EP3197995B1/en active Active
- 2014-09-25 BR BR112017003432A patent/BR112017003432A2/pt not_active Application Discontinuation
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2015
- 2015-09-15 EP EP15843869.7A patent/EP3197998A1/en not_active Withdrawn
- 2015-09-15 MX MX2017003975A patent/MX2017003975A/es unknown
- 2015-09-15 CA CA2959188A patent/CA2959188A1/en not_active Abandoned
- 2015-09-15 CA CA2959190A patent/CA2959190C/en not_active Expired - Fee Related
- 2015-09-15 MX MX2017003976A patent/MX2017003976A/es unknown
- 2015-09-15 BR BR112017004033A patent/BR112017004033A2/pt not_active Application Discontinuation
- 2015-09-15 CN CN201580049580.6A patent/CN106715667A/zh active Pending
- 2015-09-15 EP EP15843494.4A patent/EP3197997A1/en not_active Withdrawn
- 2015-09-15 BR BR112017005812A patent/BR112017005812A2/pt not_active Application Discontinuation
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- 2015-09-24 AR ARP150103075A patent/AR102346A1/es unknown
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Also Published As
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|---|---|
| WO2016045519A1 (en) | 2016-03-31 |
| MX2017003974A (es) | 2017-06-30 |
| US20160090553A1 (en) | 2016-03-31 |
| US9809784B2 (en) | 2017-11-07 |
| CA2959190C (en) | 2020-06-16 |
| AR102346A1 (es) | 2017-02-22 |
| CA2959190A1 (en) | 2016-03-31 |
| JP6571171B2 (ja) | 2019-09-04 |
| BR112017003432A2 (pt) | 2017-11-28 |
| CN106715665A (zh) | 2017-05-24 |
| AR102074A1 (es) | 2017-02-01 |
| CN106795462A (zh) | 2017-05-31 |
| CN106715665B (zh) | 2019-10-01 |
| EP3197997A1 (en) | 2017-08-02 |
| EP3197995A1 (en) | 2017-08-02 |
| BR112017004033A2 (pt) | 2017-12-05 |
| BR112017005812A2 (pt) | 2017-12-19 |
| MX2017003975A (es) | 2017-05-30 |
| WO2016045518A1 (en) | 2016-03-31 |
| WO2016045026A1 (en) | 2016-03-31 |
| JP2017532407A (ja) | 2017-11-02 |
| AR102072A1 (es) | 2017-02-01 |
| CN106715667A (zh) | 2017-05-24 |
| EP3197998A1 (en) | 2017-08-02 |
| MX2017003976A (es) | 2017-05-30 |
| EP3197995B1 (en) | 2018-12-19 |
| CA2959188A1 (en) | 2016-03-31 |
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