CA2941844A1 - Catalyseur d'hydrotraitement, procede de production du catalyseur, et procede d'hydrotraitement pour huile hydrocarbure utilisant le catalyseur - Google Patents
Catalyseur d'hydrotraitement, procede de production du catalyseur, et procede d'hydrotraitement pour huile hydrocarbure utilisant le catalyseur Download PDFInfo
- Publication number
- CA2941844A1 CA2941844A1 CA2941844A CA2941844A CA2941844A1 CA 2941844 A1 CA2941844 A1 CA 2941844A1 CA 2941844 A CA2941844 A CA 2941844A CA 2941844 A CA2941844 A CA 2941844A CA 2941844 A1 CA2941844 A1 CA 2941844A1
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- Prior art keywords
- catalyst
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- metal
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- 238000000034 method Methods 0.000 title claims abstract description 34
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- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 26
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- 230000008569 process Effects 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 13
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- 230000000737 periodic effect Effects 0.000 claims abstract description 46
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- 238000006243 chemical reaction Methods 0.000 claims description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
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- 239000007858 starting material Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 description 1
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- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
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- 238000001935 peptisation Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
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- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
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- 238000002459 porosimetry Methods 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
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- 239000005720 sucrose Substances 0.000 description 1
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- 239000011275 tar sand Substances 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
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- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Nanotechnology (AREA)
Abstract
La présente invention concerne un catalyseur ayant des performances d'hydrotraitement (hydrogénation, désulfuration et dénitrification) qui sont égales ou supérieures à l'art antérieur, en tant que catalyseur d'hydrotraitement pour des huiles hydrocarbures, et un procédé d'hydrotraitement pour des huiles hydrocarbures au moyen du catalyseur. Le catalyseur comprend 10 à 40 % en masse d'au moins un élément du groupe 6 de la table périodique, 0,5 à 15 % en masse d'au moins un élément des groupes 8 à 10 de la table périodique sur la base des catalyseurs d'oxyde, et une quantité de 0,05 à 3 fois d'un additif organique par rapport au nombre total de moles des éléments du groupe 6 et des groupes 8 à 10 de la table périodique, ajoutés à un support poreux inorganique composé principalement de silice-alumine qui comprend un oxyde d'un métal du groupe 2 de la table périodique.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2014-046245 | 2014-03-10 | ||
JP2014046245A JP6378902B2 (ja) | 2014-03-10 | 2014-03-10 | 水素化処理触媒、当該触媒の製造方法、並びに当該触媒を用いる炭化水素油の水素化処理方法 |
PCT/JP2015/001018 WO2015136873A1 (fr) | 2014-03-10 | 2015-02-27 | Catalyseur d'hydrotraitement, procédé de production du catalyseur, et procédé d'hydrotraitement pour huile hydrocarbure utilisant le catalyseur |
Publications (2)
Publication Number | Publication Date |
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CA2941844A1 true CA2941844A1 (fr) | 2015-09-17 |
CA2941844C CA2941844C (fr) | 2022-11-01 |
Family
ID=52693013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2941844A Active CA2941844C (fr) | 2014-03-10 | 2015-02-27 | Catalyseur d'hydrotraitement, procede de production du catalyseur, et procede d'hydrotraitement pour huile hydrocarbure utilisant le catalyseur |
Country Status (12)
Country | Link |
---|---|
US (1) | US20170073592A1 (fr) |
EP (1) | EP3116647B1 (fr) |
JP (1) | JP6378902B2 (fr) |
CN (1) | CN106457236B (fr) |
BR (1) | BR112016020914B1 (fr) |
CA (1) | CA2941844C (fr) |
DK (1) | DK3116647T3 (fr) |
ES (1) | ES2702206T3 (fr) |
HU (1) | HUE042533T2 (fr) |
PL (1) | PL3116647T3 (fr) |
TW (1) | TWI642482B (fr) |
WO (1) | WO2015136873A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111318286A (zh) * | 2018-12-13 | 2020-06-23 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3023184B1 (fr) * | 2014-07-04 | 2019-12-27 | IFP Energies Nouvelles | Catalyseur d'hydrotraitement a densite de molybdene elevee et methode de preparation. |
US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
FR3076746B1 (fr) * | 2018-01-15 | 2022-07-01 | Ifp Energies Now | Procede de preparation d'un catalyseur particulier d'hydrogenation selective par malaxage et impregnation |
KR102079120B1 (ko) | 2018-06-18 | 2020-02-19 | 한국과학기술연구원 | 칼슘염에 담지된 금속 촉매, 이의 제조방법 및 이를 이용한 함산소 화합물의 수첨탈산소 반응방법 |
FR3083142A1 (fr) * | 2018-06-27 | 2020-01-03 | IFP Energies Nouvelles | Catalyseur a base de derives du 1,5-pentanediol et son utilisation dans un procede d’hydrotraitement et/ou d’hydrocraquage |
FR3083136A1 (fr) * | 2018-06-27 | 2020-01-03 | IFP Energies Nouvelles | Catalyseur a base d'un ester d'acide butenedioique et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage |
CN111822007B (zh) * | 2019-04-19 | 2022-08-12 | 中国石油化工股份有限公司 | 一种加氢处理催化剂的制备方法 |
CN113019445B (zh) * | 2019-12-25 | 2023-10-10 | 中国石油化工股份有限公司 | 改性加氢处理催化剂载体、催化剂及其制备方法和应用 |
US20220323944A1 (en) * | 2020-02-11 | 2022-10-13 | Hindustan Petroleum Corporation Limited | A composition for dispersed hydrodesulfurization catalyst and process for preparation of the same |
CN112973714B (zh) * | 2021-03-24 | 2023-04-07 | 甘肃农业大学 | 一种制备环戊烯的催化剂及其制备方法和应用 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2806701B2 (ja) * | 1992-06-01 | 1998-09-30 | 出光興産株式会社 | 水素化処理用触媒の製造法とその触媒を用いた重質油の水素化処理方法 |
JP2900771B2 (ja) * | 1992-11-18 | 1999-06-02 | 住友金属鉱山株式会社 | 炭化水素油の水素化処理触媒の製造方法 |
JPH06339635A (ja) * | 1993-06-01 | 1994-12-13 | Japan Energy Corp | 水素化処理触媒の製造方法 |
JPH0731878A (ja) * | 1993-07-20 | 1995-02-03 | Idemitsu Kosan Co Ltd | 触媒担体の製造方法及び該担体から調製した金属担持触媒を用いる重質油の水素化処理方法 |
JP2000008050A (ja) * | 1998-06-19 | 2000-01-11 | Tonen Corp | 水素化処理用触媒およびそれを用いる炭化水素油の水素化処理方法 |
JP3782893B2 (ja) * | 1998-06-23 | 2006-06-07 | 東燃ゼネラル石油株式会社 | 水素化処理用触媒および該水素化処理用触媒を使用する炭化水素油の水素化処理方法 |
CA2302969A1 (fr) | 1999-04-02 | 2000-10-02 | Akzo Nobel Nv | Procede permettant d'effectuer l'hydrodesulfuration (hds) haute intensite de charges de depart composees d'hydrocarbures |
JP2001104790A (ja) * | 1999-10-07 | 2001-04-17 | Tonengeneral Sekiyu Kk | 水素化処理用触媒およびそれを用いる炭化水素油の水素化処理方法 |
JP2001310133A (ja) * | 2000-04-28 | 2001-11-06 | Sumitomo Metal Mining Co Ltd | 炭化水素油の水素化脱硫脱窒素用触媒およびその製造方法 |
TWI240750B (en) * | 2001-06-27 | 2005-10-01 | Japan Energy Corp | Method for manufacturing hydrorefining catalyst |
CN1181165C (zh) * | 2001-12-30 | 2004-12-22 | 中国石化集团齐鲁石油化工公司 | 一种选择性加氢催化剂 |
JP2005013848A (ja) * | 2003-06-25 | 2005-01-20 | Petroleum Energy Center | 水素化処理触媒用担体、炭化水素油の水素化処理触媒及びそれを用いた水素化処理方法 |
FR2880822B1 (fr) * | 2005-01-20 | 2007-05-11 | Total France Sa | Catalyseur d'hydrotraitement, son procede de preparation et son utilisation |
US8877671B2 (en) * | 2005-12-14 | 2014-11-04 | Advanced Refining Technologies Llc | Method of making hydroprocessing catalyst |
US8563456B2 (en) * | 2008-10-03 | 2013-10-22 | Chevron U.S.A. Inc. | Hydrodemetallization catalyst and process |
US9187702B2 (en) * | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
US9254478B2 (en) * | 2009-08-24 | 2016-02-09 | Albemarle Corporation | Solutions and catalysts comprising group VI metal, group VIII metal, phosphorus and an additive |
JP5635752B2 (ja) * | 2009-09-25 | 2014-12-03 | 日本ケッチェン株式会社 | 水素化処理触媒の製造方法、並びに当該触媒を用いる炭化水素油の水素化処理方法 |
CN103480410B (zh) * | 2012-06-12 | 2016-08-24 | 中国石油化工股份有限公司 | 具有加氢催化作用的催化剂及其制备方法和应用以及加氢处理方法 |
-
2014
- 2014-03-10 JP JP2014046245A patent/JP6378902B2/ja active Active
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2015
- 2015-02-27 CN CN201580013046.XA patent/CN106457236B/zh active Active
- 2015-02-27 WO PCT/JP2015/001018 patent/WO2015136873A1/fr active Application Filing
- 2015-02-27 HU HUE15710931A patent/HUE042533T2/hu unknown
- 2015-02-27 EP EP15710931.5A patent/EP3116647B1/fr active Active
- 2015-02-27 BR BR112016020914-1A patent/BR112016020914B1/pt active IP Right Grant
- 2015-02-27 PL PL15710931T patent/PL3116647T3/pl unknown
- 2015-02-27 DK DK15710931.5T patent/DK3116647T3/en active
- 2015-02-27 CA CA2941844A patent/CA2941844C/fr active Active
- 2015-02-27 ES ES15710931T patent/ES2702206T3/es active Active
- 2015-02-27 US US15/124,756 patent/US20170073592A1/en not_active Abandoned
- 2015-03-10 TW TW104107550A patent/TWI642482B/zh active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111318286A (zh) * | 2018-12-13 | 2020-06-23 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
CN111318286B (zh) * | 2018-12-13 | 2023-08-01 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其制备方法 |
Also Published As
Publication number | Publication date |
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ES2702206T3 (es) | 2019-02-27 |
JP6378902B2 (ja) | 2018-08-22 |
BR112016020914B1 (pt) | 2021-07-06 |
EP3116647B1 (fr) | 2018-10-03 |
CA2941844C (fr) | 2022-11-01 |
US20170073592A1 (en) | 2017-03-16 |
JP2015167936A (ja) | 2015-09-28 |
WO2015136873A1 (fr) | 2015-09-17 |
TWI642482B (zh) | 2018-12-01 |
EP3116647A1 (fr) | 2017-01-18 |
PL3116647T3 (pl) | 2019-05-31 |
CN106457236B (zh) | 2020-07-21 |
HUE042533T2 (hu) | 2019-07-29 |
TW201545815A (zh) | 2015-12-16 |
CN106457236A (zh) | 2017-02-22 |
DK3116647T3 (en) | 2019-01-07 |
BR112016020914A2 (pt) | 2017-08-15 |
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