CA2928600C - Polymerization initiating system and method to produce highly reactive olefin functional polymers - Google Patents

Polymerization initiating system and method to produce highly reactive olefin functional polymers Download PDF

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Publication number
CA2928600C
CA2928600C CA2928600A CA2928600A CA2928600C CA 2928600 C CA2928600 C CA 2928600C CA 2928600 A CA2928600 A CA 2928600A CA 2928600 A CA2928600 A CA 2928600A CA 2928600 C CA2928600 C CA 2928600C
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Prior art keywords
catalyst
isobutene
group
initiator
ether
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CA2928600A
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English (en)
French (fr)
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CA2928600A1 (en
Inventor
Rudolf Faust
Jacob Emert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Infineum International Ltd
University of Massachusetts Amherst
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Infineum International Ltd
University of Massachusetts Amherst
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Publication of CA2928600A1 publication Critical patent/CA2928600A1/en
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Publication of CA2928600C publication Critical patent/CA2928600C/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
CA2928600A 2015-05-13 2016-05-02 Polymerization initiating system and method to produce highly reactive olefin functional polymers Active CA2928600C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/710,763 US9771442B2 (en) 2015-05-13 2015-05-13 Polymerization initiating system and method to produce highly reactive olefin functional polymers
US14/710,763 2015-05-13

Publications (2)

Publication Number Publication Date
CA2928600A1 CA2928600A1 (en) 2016-11-13
CA2928600C true CA2928600C (en) 2021-07-06

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2928600A Active CA2928600C (en) 2015-05-13 2016-05-02 Polymerization initiating system and method to produce highly reactive olefin functional polymers

Country Status (8)

Country Link
US (1) US9771442B2 (https=)
EP (1) EP3098246B1 (https=)
JP (1) JP6647133B2 (https=)
KR (1) KR102294441B1 (https=)
CN (1) CN106146691B (https=)
CA (1) CA2928600C (https=)
ES (1) ES2732887T3 (https=)
SG (1) SG10201603112QA (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
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US9631038B2 (en) 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
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US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
CN111171197B (zh) * 2020-02-11 2022-08-02 北京石油化工学院 一种利用双官能团引发剂制备高活性聚异丁烯的方法及应用
CN115703855A (zh) * 2021-08-13 2023-02-17 南京中科康润新材料科技有限公司 用于c4液化石油气阳离子聚合的催化剂体系及聚丁烯生产方法

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Also Published As

Publication number Publication date
EP3098246A1 (en) 2016-11-30
US9771442B2 (en) 2017-09-26
CN106146691B (zh) 2021-01-08
ES2732887T3 (es) 2019-11-26
KR102294441B1 (ko) 2021-08-25
SG10201603112QA (en) 2016-12-29
JP6647133B2 (ja) 2020-02-14
EP3098246B1 (en) 2019-04-03
KR20160134525A (ko) 2016-11-23
CA2928600A1 (en) 2016-11-13
JP2016210990A (ja) 2016-12-15
CN106146691A (zh) 2016-11-23
US20160333123A1 (en) 2016-11-17

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