CA2901216C - Enhanced sorbent formulation for removal of mercury from flue gas - Google Patents

Enhanced sorbent formulation for removal of mercury from flue gas Download PDF

Info

Publication number
CA2901216C
CA2901216C CA2901216A CA2901216A CA2901216C CA 2901216 C CA2901216 C CA 2901216C CA 2901216 A CA2901216 A CA 2901216A CA 2901216 A CA2901216 A CA 2901216A CA 2901216 C CA2901216 C CA 2901216C
Authority
CA
Canada
Prior art keywords
ammonium
mercury
halogen
mercury sorbent
sorbent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2901216A
Other languages
English (en)
French (fr)
Other versions
CA2901216A1 (en
Inventor
Richard A. Mimna
Walter G. Tramposch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Calgon Carbon Corp
Original Assignee
Calgon Carbon Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Calgon Carbon Corp filed Critical Calgon Carbon Corp
Publication of CA2901216A1 publication Critical patent/CA2901216A1/en
Application granted granted Critical
Publication of CA2901216C publication Critical patent/CA2901216C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3021—Milling, crushing or grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CA2901216A 2013-02-14 2014-02-04 Enhanced sorbent formulation for removal of mercury from flue gas Active CA2901216C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361764712P 2013-02-14 2013-02-14
US61/764,712 2013-02-14
US13/841,801 2013-03-15
US13/841,801 US9308518B2 (en) 2013-02-14 2013-03-15 Enhanced sorbent formulation for removal of mercury from flue gas
PCT/US2014/014605 WO2014126749A1 (en) 2013-02-14 2014-02-04 Enhanced sorbent formulation for removal of mercury from flue gas

Publications (2)

Publication Number Publication Date
CA2901216A1 CA2901216A1 (en) 2014-08-21
CA2901216C true CA2901216C (en) 2022-05-17

Family

ID=51296525

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2901216A Active CA2901216C (en) 2013-02-14 2014-02-04 Enhanced sorbent formulation for removal of mercury from flue gas

Country Status (8)

Country Link
US (1) US9308518B2 (cg-RX-API-DMAC7.html)
EP (1) EP2956230B8 (cg-RX-API-DMAC7.html)
JP (1) JP6166387B2 (cg-RX-API-DMAC7.html)
KR (1) KR102081571B1 (cg-RX-API-DMAC7.html)
CN (1) CN105120982B (cg-RX-API-DMAC7.html)
CA (1) CA2901216C (cg-RX-API-DMAC7.html)
PL (1) PL2956230T3 (cg-RX-API-DMAC7.html)
WO (1) WO2014126749A1 (cg-RX-API-DMAC7.html)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10828596B2 (en) 2003-04-23 2020-11-10 Midwest Energy Emissions Corp. Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams
US11179673B2 (en) 2003-04-23 2021-11-23 Midwwest Energy Emission Corp. Sorbents for the oxidation and removal of mercury
US7435286B2 (en) 2004-08-30 2008-10-14 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US10343114B2 (en) 2004-08-30 2019-07-09 Midwest Energy Emissions Corp Sorbents for the oxidation and removal of mercury
US9011805B2 (en) 2012-04-23 2015-04-21 Energy & Environmental Research Center Foundation Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream
US20130330257A1 (en) 2012-06-11 2013-12-12 Calgon Carbon Corporation Sorbents for removal of mercury
EP2964376A2 (en) 2013-03-06 2016-01-13 Energy & Environmental Research Center Foundation Activated carbon sorbent including nitrogen and methods of using the same
US10130930B2 (en) 2013-03-06 2018-11-20 Midwest Energy Emissions Corp Sorbent comprising carbon and nitrogen and methods of using the same
US9889451B2 (en) 2013-08-16 2018-02-13 ADA-ES, Inc. Method to reduce mercury, acid gas, and particulate emissions
CA2979332C (en) 2015-03-16 2022-11-22 University Of Wyoming Methods and compositions for the removal of mercury from gases
HK1250365A1 (zh) * 2015-05-20 2018-12-14 Calgon Carbon Corporation 用於去除汞的吸附剂
FR3037258B1 (fr) * 2015-06-15 2020-10-16 Eurotab Composition absorbante d'humidite comprenant un agent sequestrant
US10220369B2 (en) 2015-08-11 2019-03-05 Calgon Carbon Corporation Enhanced sorbent formulation for removal of mercury from flue gas
US9764280B2 (en) 2015-08-21 2017-09-19 Ecolab Usa Inc. Complexation and removal of mercury from flue gas desulfurization systems
CR20180165A (es) 2015-08-21 2018-06-14 Ecolab Usa Inc Complejación y eliminación del mercurio de sistema de desulfuración de gas de combustión
US10569221B2 (en) 2015-08-21 2020-02-25 Ecolab Usa Inc. Complexation and removal of mercury from flue gas desulfurization systems
CN105561924A (zh) * 2016-01-29 2016-05-11 北京市劳动保护科学研究所 烟气汞的改性活性炭吸附剂及其捕集管的制备方法与应用
CN105903429A (zh) * 2016-06-16 2016-08-31 马鞍山市顺达环保设备有限公司 一种脱除烟气中汞的吸附剂
CN106582244B (zh) * 2016-12-21 2019-07-09 贵州大学 一种湿法脱除含汞、含硫烟气中硫和汞的方法
KR102511171B1 (ko) * 2017-02-13 2023-03-20 칼곤 카본 코포레이션 클로라민 및 염소 제거 물질 및 이의 제조 방법
EP3648871A1 (en) 2017-07-06 2020-05-13 Ecolab USA, Inc. Enhanced injection of mercury oxidants
EP3668639A1 (en) * 2017-08-16 2020-06-24 Cabot Corporation Sorbents comprising activated carbon and ammonium phosphates
EP3752277A4 (en) 2018-02-13 2021-11-17 Calgon Carbon Corporation PROCESS FOR OXIDIZING CHEMICAL SORBANTS AND SORBANTS MANUFACTURED THEREOF
JP2019178796A (ja) * 2018-03-30 2019-10-17 Ｊｘ金属株式会社 水銀の管理方法
CN112266098B (zh) * 2020-10-12 2023-03-24 东华理工大学 一种利用助剂提升吸咐剂吸附性能的方法
CN116272864B (zh) * 2023-02-24 2024-08-30 苏州西热节能环保技术有限公司 一种用于脱除烟气中汞、三氧化硫的吸附剂及其制备方法
WO2025117567A1 (en) * 2023-11-27 2025-06-05 Calgon Carbon Corporation Sorbents for removal of mercury and other contaminants

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE588531C (de) 1931-06-30 1933-11-20 Auergesellschaft Gmbh Masse zur Bindung von in der Luft enthaltenen Quecksilberdaempfen
US1984164A (en) 1931-06-30 1934-12-11 Degea Ag Process and apparatus for purifying air vitiated with mercury vapors
US3194629A (en) 1962-02-23 1965-07-13 Pittsburgh Activated Carbon Co Method of removing mercury vapor from gases
JPS4953592A (cg-RX-API-DMAC7.html) 1972-09-29 1974-05-24
JPS4953591A (cg-RX-API-DMAC7.html) 1972-09-29 1974-05-24
NL7710632A (nl) 1977-09-29 1979-04-02 Akzo Nv Werkwijze voor de verwijdering van kwik uit kwikdamp bevattende gassen.
AU559284B2 (en) 1982-07-08 1987-03-05 Takeda Chemical Industries Ltd. Adsorption of mercury vapour
DE3229396C2 (de) 1982-08-06 1985-10-31 Bergwerksverband Gmbh, 4300 Essen Verfahren zur Herstellung von mit Elementarschwefel imprägnierten kohlenstoffhaltigen Adsorptionsmitteln
US4708853A (en) 1983-11-03 1987-11-24 Calgon Carbon Corporation Mercury adsorbent carbon molecular sieves and process for removing mercury vapor from gas streams
DE3714844A1 (de) 1987-05-05 1988-12-01 Kernforschungsz Karlsruhe Verfahren zur abscheidung von quecksilber und organischen stoffen aus rauchgasen einer verbrennungsanlage
US5202301A (en) 1989-11-22 1993-04-13 Calgon Carbon Corporation Product/process/application for removal of mercury from liquid hydrocarbon
CA2036746A1 (en) 1990-07-31 1992-02-01 Peter Z. Kubin Process and apparatus for absorption/adsorption material injection
US5435980A (en) 1991-11-04 1995-07-25 Niro A/S Method of improving the Hg-removing capability of a flue gas cleaning process
CA2114331C (en) 1993-06-10 2000-03-28 Bernard J. Lerner Removal of mercury and cadmium and their compounds from incinerator flue gases
US6589318B2 (en) 1999-09-29 2003-07-08 Merck & Co., Inc. Adsorption powder for removing mercury from high temperature, high moisture gas streams
US6638347B2 (en) 1999-09-29 2003-10-28 Merck & Co., Inc. Carbon-based adsorption powder containing cupric chloride
US6719828B1 (en) 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
US6808692B2 (en) 2002-02-14 2004-10-26 Oehr Klaus H Enhanced mercury control in coal-fired power plants
US6960329B2 (en) 2002-03-12 2005-11-01 Foster Wheeler Energy Corporation Method and apparatus for removing mercury species from hot flue gas
US20030206843A1 (en) * 2002-05-06 2003-11-06 Nelson Sidney G. Methods and compositions to sequester combustion-gas mercury in fly ash and concrete
US6878358B2 (en) 2002-07-22 2005-04-12 Bayer Aktiengesellschaft Process for removing mercury from flue gases
DE10233173B4 (de) 2002-07-22 2006-03-23 Bayer Industry Services Gmbh & Co. Ohg Verfahren zur Abscheidung von Quecksilber aus Rauchgasen
US20040074391A1 (en) 2002-10-16 2004-04-22 Vincent Durante Filter system
US6818043B1 (en) 2003-01-23 2004-11-16 Electric Power Research Institute, Inc. Vapor-phase contaminant removal by injection of fine sorbent slurries
US7435286B2 (en) 2004-08-30 2008-10-14 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US8652235B2 (en) 2004-08-30 2014-02-18 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US8069797B2 (en) 2003-06-03 2011-12-06 Alstom Technology Ltd. Control of mercury emissions from solid fuel combustion
US6848374B2 (en) 2003-06-03 2005-02-01 Alstom Technology Ltd Control of mercury emissions from solid fuel combustion
JP4113090B2 (ja) 2003-10-22 2008-07-02 株式会社日本触媒 排ガス処理方法
US7514052B2 (en) 2004-01-06 2009-04-07 General Electric Company Method for removal of mercury emissions from coal combustion
WO2005092476A1 (en) 2004-03-22 2005-10-06 The Babcock & Wilcox Company Dynamic halogenation of sorbents for the removal of mercury from flue gases
US20050260114A1 (en) 2004-05-18 2005-11-24 Higgins Brian S Method for flue-gas reduction of pollutants in combustion processes
US20060051270A1 (en) 2004-09-03 2006-03-09 Robert Brunette Removal of volatile metals from gas by solid sorbent capture
US20060090646A1 (en) 2004-11-04 2006-05-04 Questair Technologies Inc. Adsorbent material for selective adsorption of carbon monoxide and unsaturated hydrocarbons
US7399456B2 (en) * 2005-02-25 2008-07-15 Conocophillips Company Process for the removal of heavy metals from gases, and compositions therefor and therewith
US20060205592A1 (en) 2005-03-14 2006-09-14 Chien-Chung Chao Catalytic adsorbents for mercury removal from flue gas and methods of manufacture therefor
US7704920B2 (en) 2005-11-30 2010-04-27 Basf Catalysts Llc Pollutant emission control sorbents and methods of manufacture
US7468170B2 (en) 2005-12-21 2008-12-23 Douglas C Comrie Nitrogenous sorbent for coal combustion
US20070234902A1 (en) 2006-03-29 2007-10-11 Fair David L Method for mercury removal from flue gas streams
US7767007B2 (en) 2006-12-08 2010-08-03 Praxair Technology, Inc. Mercury adsorbents compatible as cement additives
JP5094468B2 (ja) 2007-03-01 2012-12-12 日本エンバイロケミカルズ株式会社 ガス中の水銀蒸気除去法
US8080088B1 (en) 2007-03-05 2011-12-20 Srivats Srinivasachar Flue gas mercury control
DE102007020422B4 (de) 2007-04-27 2010-10-21 Rwe Power Ag Verfahren zur trockenen Reinigung von mit Quecksilber beladenen Abgasen
US8312822B2 (en) 2007-07-02 2012-11-20 Energy & Environmental Research Center Foundation Mercury control using moderate-temperature dissociation of halogen compounds
US8906823B2 (en) 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
CN102131562B (zh) * 2009-05-08 2015-01-07 克拉基斯技术控股公司 用于从燃气中去除重金属的方法及组合物
JP2011031212A (ja) 2009-08-05 2011-02-17 Mitsubishi Heavy Ind Ltd 排ガスの水銀除去システム及び水銀除去方法
US20110048231A1 (en) 2009-08-28 2011-03-03 Sinha Rabindra K Composition and Method for Reducing Mercury Emitted into the Atmosphere
JP5740070B2 (ja) 2009-09-28 2015-06-24 カルゴン カーボン コーポレーション 燃焼排ガスから水銀を取り除く吸着剤
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
MX2012011676A (es) 2010-04-07 2013-01-29 Calgon Carbon Corp Metodo para el retiro de mercurio de gases de combustion.
US9555420B2 (en) 2010-04-08 2017-01-31 Nalco Company Gas stream treatment process
BR112013004469A2 (pt) 2010-08-30 2016-06-07 Albemarle Corp carvão ativado sorvente para remover mercúrio de emissões produzidas durante combustão de combustível, aditivo não halogenado e processo par aumentar a estabilidade térmica de carvão ativado
CN102553522A (zh) * 2010-12-30 2012-07-11 四川清源环境工程有限公司 一种用于燃煤烟气汞脱除的氧化性吸附剂
US20130330257A1 (en) 2012-06-11 2013-12-12 Calgon Carbon Corporation Sorbents for removal of mercury
CN102764581A (zh) * 2012-07-26 2012-11-07 艾淑艳 湿法脱汞系统及其脱汞工艺

Also Published As

Publication number Publication date
CN105120982B (zh) 2017-07-07
EP2956230A1 (en) 2015-12-23
US9308518B2 (en) 2016-04-12
CA2901216A1 (en) 2014-08-21
EP2956230B8 (en) 2020-03-04
PL2956230T3 (pl) 2021-05-31
US20140224121A1 (en) 2014-08-14
WO2014126749A1 (en) 2014-08-21
JP2016508444A (ja) 2016-03-22
KR20150119906A (ko) 2015-10-26
EP2956230A4 (en) 2016-10-19
EP2956230B1 (en) 2020-01-01
JP6166387B2 (ja) 2017-07-19
KR102081571B1 (ko) 2020-02-26
CN105120982A (zh) 2015-12-02

Similar Documents

Publication Publication Date Title
CA2901216C (en) Enhanced sorbent formulation for removal of mercury from flue gas
US8450238B2 (en) Sorbent formulation for removal of mercury from flue gas
US11857942B2 (en) Sorbents for removal of mercury
AU2020250222A1 (en) Sorbents for removal of mercury
HK1246730B (zh) 用於除汞的吸附剂

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20190204