CA2886004C - Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming - Google Patents

Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming Download PDF

Info

Publication number
CA2886004C
CA2886004C CA2886004A CA2886004A CA2886004C CA 2886004 C CA2886004 C CA 2886004C CA 2886004 A CA2886004 A CA 2886004A CA 2886004 A CA2886004 A CA 2886004A CA 2886004 C CA2886004 C CA 2886004C
Authority
CA
Canada
Prior art keywords
methane
carbon dioxide
water
source
combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2886004A
Other languages
English (en)
French (fr)
Other versions
CA2886004A1 (en
Inventor
George A. Olah
G.K. Surya Prakash
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Southern California USC
Original Assignee
University of Southern California USC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Southern California USC filed Critical University of Southern California USC
Publication of CA2886004A1 publication Critical patent/CA2886004A1/en
Application granted granted Critical
Publication of CA2886004C publication Critical patent/CA2886004C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516Multisteps
    • C07C29/1518Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/09Preparation of ethers by dehydration of compounds containing hydroxy groups
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2886004A 2012-10-09 2013-09-06 Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming Active CA2886004C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261711610P 2012-10-09 2012-10-09
US61/711,610 2012-10-09
US13/791,778 US8697759B1 (en) 2012-10-09 2013-03-08 Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming
US13/791,778 2013-03-08
PCT/US2013/058469 WO2014058549A1 (en) 2012-10-09 2013-09-06 Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming

Publications (2)

Publication Number Publication Date
CA2886004A1 CA2886004A1 (en) 2014-04-17
CA2886004C true CA2886004C (en) 2018-07-03

Family

ID=50433203

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2886004A Active CA2886004C (en) 2012-10-09 2013-09-06 Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming

Country Status (9)

Country Link
US (1) US8697759B1 (https=)
EP (1) EP2906523B1 (https=)
JP (1) JP6352929B2 (https=)
KR (1) KR101951985B1 (https=)
CN (1) CN104822644B (https=)
AU (1) AU2013330420B2 (https=)
CA (1) CA2886004C (https=)
ES (1) ES2615892T3 (https=)
WO (1) WO2014058549A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016134009A1 (en) 2015-02-18 2016-08-25 University Of Southern California Methanol fuels for internal combustion engines
WO2016144942A1 (en) * 2015-03-09 2016-09-15 Olah George A Common regenerative and environmentally benign methanol fuels for all internal combustion engines for transportation vehicles and other applications
US10364398B2 (en) * 2016-08-30 2019-07-30 Thermochem Recovery International, Inc. Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas
GB2556929A (en) * 2016-11-26 2018-06-13 Avocet Infinite Plc Apparatus and method for producing methanol
GB2556930A (en) * 2016-11-27 2018-06-13 Avocet Infinite Plc Apparatus and method for producing methanol
US11192843B2 (en) * 2018-08-06 2021-12-07 Sabic Global Technologies B.V. Process for producing methanol
CN110013857A (zh) * 2019-04-04 2019-07-16 江苏科技大学 一种焦炉煤气改质催化剂及其制备方法和应用
US11555157B2 (en) 2020-03-10 2023-01-17 Thermochem Recovery International, Inc. System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas
KR102590896B1 (ko) 2020-12-22 2023-10-19 울산대학교 산학협력단 고체 전해질의 제조방법 및 이로부터 제조된 고체 전해질
WO2022191589A1 (ko) * 2021-03-10 2022-09-15 한국기계연구원 바이오 가스의 개질장치
US12098122B2 (en) 2021-03-19 2024-09-24 Saudi Arabian Oil Company Production of acetic acid through cryogenic separation of syngas
US20240246895A1 (en) * 2021-05-19 2024-07-25 Massachusetts Institute Of Technology Abatement of low level methane through the use of catalytic, earth-abundant materials
CN115231522A (zh) * 2022-09-22 2022-10-25 小跃科技(北京)有限公司 一种用于高温裂解二氧化碳的反应釜
CN118950076A (zh) * 2023-05-15 2024-11-15 华东师范大学 一种甲烷氧化耦合二氧化碳加氢制备甲醇的双功能催化剂及其制备方法和应用

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993457A (en) 1973-07-30 1976-11-23 Exxon Research And Engineering Company Concurrent production of methanol and synthetic natural gas
US4098339A (en) 1976-06-21 1978-07-04 Mobil Oil Corporation Utilization of low BTU natural gas
GB1545329A (en) 1976-06-21 1979-05-10 Mobil Oil Corp Utilization of low btu natural gas to produce methanol or liquid hydrocarbons
NZ194405A (en) 1979-08-02 1982-05-25 Dut Pty Ltd Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock
CA1241667A (en) 1984-04-25 1988-09-06 Martin F.M. Post Process for the preparation of hydrocarbons
JPS61516A (ja) * 1984-06-12 1986-01-06 Toyo Rokougiyou Kk 雰囲気ガス発生装置
US4618732A (en) 1985-05-20 1986-10-21 Gesser Hyman D Direct conversion of natural gas to methanol by controlled oxidation
JPS63252904A (ja) * 1987-01-28 1988-10-20 Toyo Rokougiyou Kk 雰囲気ガス製造方法
FR2684313B1 (fr) * 1991-12-03 1994-01-28 Institut Francais Petrole Procede et dispositif pour la fabrication de gaz de synthese et application.
US5342702A (en) 1993-01-05 1994-08-30 Integrated Energy Development Corp. Synergistic process for the production of carbon dioxide using a cogeneration reactor
IT1272532B (it) 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
US5599638A (en) 1993-10-12 1997-02-04 California Institute Of Technology Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane
US5767165A (en) 1995-03-16 1998-06-16 Steinberg; Meyer Method for converting natural gas and carbon dioxide to methanol and reducing CO2 emissions
US7132183B2 (en) 2002-06-27 2006-11-07 Intellergy Corporation Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
JP4309627B2 (ja) 2002-09-06 2009-08-05 東洋エンジニアリング株式会社 ジメチルエーテルの製造方法
JP5145213B2 (ja) 2005-04-15 2013-02-13 ユニヴァーシティー オブ サザン カリフォルニア 二酸化炭素のメタノール、ジメチルエーテルおよび派生生成物への効率的且つ選択的変換法
CA2604574C (en) 2005-04-15 2013-11-19 University Of Southern California Selective oxidative conversion of methane to methanol, dimethyl ether and derived products
US7608743B2 (en) 2005-04-15 2009-10-27 University Of Southern California Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products
AU2005335085A1 (en) 2005-08-01 2007-02-08 Bp P.L.C. An integrated process for the co-production of methanol and demethyl ether from syngas containing nitrogen
US7795175B2 (en) 2006-08-10 2010-09-14 University Of Southern California Nano-structure supported solid regenerative polyamine and polyamine polyol absorbents for the separation of carbon dioxide from gas mixtures including the air
US7378561B2 (en) * 2006-08-10 2008-05-27 University Of Southern California Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material
US7906559B2 (en) 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
CA2757577A1 (en) * 2009-04-10 2010-10-14 University Of Southern California Rendering petroleum oil as an environmentally carbon dioxide neutral source material for fuels, derived products and as a regenerative carbon source
JP2012523422A (ja) * 2009-04-10 2012-10-04 ユニバーシティ オブ サザン カリフォルニア 天然ガスを環境的に二酸化炭素ニュートラルな燃料および再生可能炭素源とすること
JP2012523420A (ja) * 2009-04-10 2012-10-04 ユニバーシティ オブ サザン カリフォルニア 石炭を環境的に二酸化炭素ニュートラルな燃料および再生可能炭素源とすること
AU2010362120A1 (en) 2010-10-06 2013-04-18 Silicon Fire Ag Method and installation for synthesising hydrocarbon

Also Published As

Publication number Publication date
CA2886004A1 (en) 2014-04-17
KR101951985B1 (ko) 2019-02-25
WO2014058549A1 (en) 2014-04-17
US20140100391A1 (en) 2014-04-10
KR20150093652A (ko) 2015-08-18
US8697759B1 (en) 2014-04-15
JP2015533827A (ja) 2015-11-26
ES2615892T3 (es) 2017-06-08
JP6352929B2 (ja) 2018-07-04
EP2906523A1 (en) 2015-08-19
EP2906523B1 (en) 2016-11-16
CN104822644B (zh) 2017-10-10
CN104822644A (zh) 2015-08-05
AU2013330420A1 (en) 2015-04-09
AU2013330420B2 (en) 2016-10-27

Similar Documents

Publication Publication Date Title
CA2886004C (en) Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming
Dalena et al. Methanol production and applications: an overview
Basile et al. Methanol: science and engineering
US8198338B2 (en) Process for producing liquid fuel from carbon dioxide and water
CN101679168B (zh) 使用甲烷或天然气的双转化的二氧化碳至二甲醚的转化
AU2010234506B2 (en) Rendering natural gas as an environmentally carbon dioxide neutral fuel and a regenerative carbon source
CN104395232A (zh) 用于生产合成气混合物的方法
KR20240037308A (ko) 수소 및/또는 합성가스 운반체로서의 액체 연료의 생산 및 사용
Sepahi et al. Methanol production from syngas
US20260048985A1 (en) Production of syngas from carbon dioxide through methanol
RU2676688C2 (ru) Способ и установка для получения диметилового эфира из синтез-газа
Rahmani et al. A comparative study of two different membranes applied for auto-thermal methanol synthesis process
Centi et al. Advances in catalysts and processes for methanol synthesis from CO2

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20170913

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 11TH ANNIV.) - STANDARD

Year of fee payment: 11

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20240830

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT

Effective date: 20240830

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20240830

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 12TH ANNIV.) - STANDARD

Year of fee payment: 12

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250829

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250909