CA2877576C - Process for the conversion of oxygenates to olefins - Google Patents

Process for the conversion of oxygenates to olefins Download PDF

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Publication number
CA2877576C
CA2877576C CA2877576A CA2877576A CA2877576C CA 2877576 C CA2877576 C CA 2877576C CA 2877576 A CA2877576 A CA 2877576A CA 2877576 A CA2877576 A CA 2877576A CA 2877576 C CA2877576 C CA 2877576C
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CA
Canada
Prior art keywords
process according
catalyst
further preferably
range
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2877576A
Other languages
English (en)
French (fr)
Other versions
CA2877576A1 (en
Inventor
Kirsten SPANNHOFF
Florina Corina Patcas
Ekkehard Schwab
Alexander Weck
Kerem Bay
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
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Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2877576A1 publication Critical patent/CA2877576A1/en
Application granted granted Critical
Publication of CA2877576C publication Critical patent/CA2877576C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2877576A 2012-06-29 2013-06-26 Process for the conversion of oxygenates to olefins Expired - Fee Related CA2877576C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12174295 2012-06-29
EP12174295.1 2012-06-29
PCT/EP2013/063435 WO2014001411A2 (de) 2012-06-29 2013-06-26 Verfahren für die umwandlung von oxygenaten zu olefinen

Publications (2)

Publication Number Publication Date
CA2877576A1 CA2877576A1 (en) 2014-01-03
CA2877576C true CA2877576C (en) 2020-10-27

Family

ID=48745924

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2877576A Expired - Fee Related CA2877576C (en) 2012-06-29 2013-06-26 Process for the conversion of oxygenates to olefins

Country Status (9)

Country Link
EP (1) EP2866935B1 (enExample)
JP (2) JP2015526401A (enExample)
CN (2) CN104582840A (enExample)
AU (1) AU2013283348B2 (enExample)
BR (1) BR112014031392A2 (enExample)
CA (1) CA2877576C (enExample)
MX (1) MX2014015731A (enExample)
RU (1) RU2015102197A (enExample)
WO (1) WO2014001411A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
DE2830787B2 (de) 1978-07-13 1981-02-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von stickstoffhaltigen kirstallinen Metallsilikaten mit Zeolithstniktur
DE3006471A1 (de) 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
US4692423A (en) 1985-12-04 1987-09-08 Mobil Oil Corporation Method for preparing structured catalytic solids
ATE168585T1 (de) 1993-04-23 1998-08-15 Exxon Chemical Patents Inc Kristalline molekularsiebe enthaltende schichten und verfahren zu ihrer herstellung
US5925800A (en) 1996-12-31 1999-07-20 Exxon Chemical Patents Inc. Conversion of oxygenates to hydrocarbons with monolith supported non-zeolitic molecular sieve catalysts
US6926882B2 (en) * 2000-01-05 2005-08-09 Exxonmobil Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation
US8530714B2 (en) * 2005-11-14 2013-09-10 Jgc Corporation Method for production of lower olefin
JP4823655B2 (ja) * 2005-11-21 2011-11-24 出光興産株式会社 キシレン類の製造方法
TWI406707B (zh) * 2006-08-30 2013-09-01 Jgc Corp 含鹼土類金屬化合物之沸石催化劑及其調製方法與再生方法、以及低級烴之製造方法
JP5388436B2 (ja) * 2007-10-23 2014-01-15 出光興産株式会社 軽質オレフィン類の製造方法
JP2009255014A (ja) * 2008-04-21 2009-11-05 Mitsubishi Chemicals Corp メタノールからオレフィンを製造するための触媒
EP2446964A4 (en) * 2009-06-22 2015-04-29 Jgc Corp CATALYST FOR PRODUCING LOW OLEFINS AND METHOD FOR PRODUCING LOW OLEFINS THEREWITH

Also Published As

Publication number Publication date
AU2013283348B2 (en) 2017-03-02
CA2877576A1 (en) 2014-01-03
JP2019069967A (ja) 2019-05-09
RU2015102197A (ru) 2016-08-20
AU2013283348A1 (en) 2015-01-22
WO2014001411A2 (de) 2014-01-03
BR112014031392A2 (pt) 2017-06-27
EP2866935A2 (de) 2015-05-06
CN104582840A (zh) 2015-04-29
MX2014015731A (es) 2015-09-04
CN109942360A (zh) 2019-06-28
EP2866935B1 (de) 2018-10-10
WO2014001411A3 (de) 2014-02-27
JP2015526401A (ja) 2015-09-10

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Effective date: 20180626

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Effective date: 20210628