CA2872593C - Complex amine absorbent, and device and method for removing one or both of co2 and h2s - Google Patents

Complex amine absorbent, and device and method for removing one or both of co2 and h2s Download PDF

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Publication number
CA2872593C
CA2872593C CA2872593A CA2872593A CA2872593C CA 2872593 C CA2872593 C CA 2872593C CA 2872593 A CA2872593 A CA 2872593A CA 2872593 A CA2872593 A CA 2872593A CA 2872593 C CA2872593 C CA 2872593C
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CA
Canada
Prior art keywords
absorbent
regenerator
amino
amine
absorber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2872593A
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English (en)
French (fr)
Other versions
CA2872593A1 (en
Inventor
Hiroshi Tanaka
Hiromitsu Nagayasu
Takuya Hirata
Tsuyoshi Oishi
Takashi Kamijo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
Original Assignee
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
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Filing date
Publication date
Application filed by Kansai Electric Power Co Inc, Mitsubishi Heavy Industries Ltd filed Critical Kansai Electric Power Co Inc
Publication of CA2872593A1 publication Critical patent/CA2872593A1/en
Application granted granted Critical
Publication of CA2872593C publication Critical patent/CA2872593C/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
CA2872593A 2012-05-11 2013-04-25 Complex amine absorbent, and device and method for removing one or both of co2 and h2s Active CA2872593C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012109948A JP5986796B2 (ja) 2012-05-11 2012-05-11 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
JP2012-109948 2012-05-11
PCT/JP2013/062259 WO2013168588A1 (ja) 2012-05-11 2013-04-25 複合アミン吸収液、ｃｏ2又はｈ2ｓ又はその双方の除去装置及び方法

Publications (2)

Publication Number Publication Date
CA2872593A1 CA2872593A1 (en) 2013-11-14
CA2872593C true CA2872593C (en) 2017-12-12

Family

ID=49550634

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2872593A Active CA2872593C (en) 2012-05-11 2013-04-25 Complex amine absorbent, and device and method for removing one or both of co2 and h2s

Country Status (6)

Country Link
US (1) US10137407B2 (https=)
EP (1) EP2848298B1 (https=)
JP (1) JP5986796B2 (https=)
AU (1) AU2013258901B2 (https=)
CA (1) CA2872593C (https=)
WO (1) WO2013168588A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6841676B2 (ja) 2017-01-31 2021-03-10 三菱重工エンジニアリング株式会社 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
GB201813839D0 (en) * 2018-06-26 2018-10-10 Carbon Clean Solutions Ltd System and process of capturing carbon dioxide from flue gases
CN113457382A (zh) * 2021-07-22 2021-10-01 浙江天地环保科技股份有限公司 一种低粘度的co2捕集混合吸收剂配方
AU2022339829A1 (en) * 2021-08-31 2024-04-11 Yale University Systems and methods for carbon sequestration using enhanced weathering
CN116371146B (zh) * 2023-02-24 2026-02-13 国家能源集团新能源技术研究院有限公司 一种二氧化碳吸收剂及其制备方法与应用
CN116272262A (zh) * 2023-05-11 2023-06-23 上海交通大学 一种三元混合胺型二氧化碳吸收剂及其制备方法和应用

Family Cites Families (26)

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AU506199B2 (en) * 1975-06-26 1979-12-20 Exxon Research And Engineering Company Absorbtion of co2 from gaseous feeds
DE2551717C3 (de) 1975-11-18 1980-11-13 Basf Ag, 6700 Ludwigshafen und ggf. COS aus Gasen
CA1091429A (en) * 1977-01-06 1980-12-16 Guido Sartori Process for removing carbon dioxide containing acidic gases from gaseous mixtures
US4100257A (en) * 1977-02-14 1978-07-11 Exxon Research & Engineering Co. Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures
US4100099A (en) * 1977-03-28 1978-07-11 The Dow Chemical Company Quaternary salt-polyamine inhibitor for sour gas conditioning solutions
JPH0644972B2 (ja) * 1988-03-11 1994-06-15 ユニオン・カーバイド・コーポレーション エチレンアミン促進剤を含有する第三級アルカノールアミン吸収剤及びその使用法
JPH04349921A (ja) * 1991-05-27 1992-12-04 Mitsubishi Heavy Ind Ltd 排煙脱炭吸収剤
JP2809368B2 (ja) * 1993-04-05 1998-10-08 関西電力株式会社 燃焼排ガス中の二酸化炭素の回収方法
JPH06343858A (ja) * 1993-06-08 1994-12-20 Mitsubishi Heavy Ind Ltd 二酸化炭素吸収剤
JPH0751537A (ja) 1993-06-30 1995-02-28 Mitsubishi Heavy Ind Ltd Ｃｏ２ 含有ガス中のｃｏ２ を除去する方法
DE19828977A1 (de) * 1998-06-29 1999-12-30 Basf Ag Verfahren zur Entfernung saurer Gasbestandteile aus Gasen
US6165433A (en) * 1999-06-10 2000-12-26 Praxair Technology, Inc. Carbon dioxide recovery with composite amine blends
JP4690659B2 (ja) 2004-03-15 2011-06-01 三菱重工業株式会社 Ｃｏ２回収装置
US7368476B2 (en) * 2004-04-07 2008-05-06 Pharmacyclics, Inc. Hydroxamates as therapeutic agents
UA93541C2 (ru) * 2006-02-14 2011-02-25 Басф Ce Способ удаления кислых газов из потока текучей среды и способ переоборудования установки для удаления кислых газов из потока текучей среды
AU2007226476B2 (en) * 2006-03-16 2011-03-31 Basf Se Process for contacting two phases whose contact is accompanied by heat evolution
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JP2008013400A (ja) 2006-07-05 2008-01-24 Research Institute Of Innovative Technology For The Earth 排ガス中の二酸化炭素を吸収及び脱離して回収する方法
US7901488B2 (en) * 2006-10-04 2011-03-08 Board Of Regents, The University Of Texas System Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping
JP5215595B2 (ja) * 2007-06-18 2013-06-19 三菱重工業株式会社 吸収液、吸収液を用いたｃｏ２又はｈ２ｓ除去装置及び方法
PL2300127T3 (pl) * 2008-06-23 2015-08-31 Basf Se Absorbent i sposób usuwania kwaśnych gazów ze strumieni płynów, w szczególności z gazów spalinowych
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CN102449124A (zh) * 2009-05-26 2012-05-09 巴斯夫欧洲公司 由流体料流，尤其是由合成气回收二氧化碳的方法
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WO2011121635A1 (ja) 2010-03-29 2011-10-06 株式会社 東芝 酸性ガス吸収剤、酸性ガス除去装置および酸性ガス除去方法
US9266102B2 (en) * 2013-03-29 2016-02-23 The University Of Kentucky Research Foundation Catalysts and methods of increasing mass transfer rate of acid gas scrubbing solvents

Also Published As

Publication number Publication date
AU2013258901B2 (en) 2016-07-14
WO2013168588A1 (ja) 2013-11-14
EP2848298A4 (en) 2016-02-17
JP2013236987A (ja) 2013-11-28
EP2848298B1 (en) 2018-12-26
JP5986796B2 (ja) 2016-09-06
US10137407B2 (en) 2018-11-27
EP2848298A1 (en) 2015-03-18
CA2872593A1 (en) 2013-11-14
US20150132207A1 (en) 2015-05-14
AU2013258901A1 (en) 2014-11-27

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