CA2871113C - Materiau multicouche resistant a l'oxydation en milieu nucleaire - Google Patents
Materiau multicouche resistant a l'oxydation en milieu nucleaire Download PDFInfo
- Publication number
- CA2871113C CA2871113C CA2871113A CA2871113A CA2871113C CA 2871113 C CA2871113 C CA 2871113C CA 2871113 A CA2871113 A CA 2871113A CA 2871113 A CA2871113 A CA 2871113A CA 2871113 C CA2871113 C CA 2871113C
- Authority
- CA
- Canada
- Prior art keywords
- multilayer
- alloy
- layers
- coating
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 131
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 96
- 230000003647 oxidation Effects 0.000 title claims abstract description 95
- 238000000576 coating method Methods 0.000 claims abstract description 248
- 239000011248 coating agent Substances 0.000 claims abstract description 216
- 239000000758 substrate Substances 0.000 claims abstract description 76
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 58
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 57
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229910052751 metal Inorganic materials 0.000 claims abstract description 43
- 239000002184 metal Substances 0.000 claims abstract description 43
- 229910002058 ternary alloy Inorganic materials 0.000 claims abstract description 32
- 229910000599 Cr alloy Inorganic materials 0.000 claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 claims abstract description 27
- 239000000788 chromium alloy Substances 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 7
- 239000011651 chromium Substances 0.000 claims description 238
- 239000010410 layer Substances 0.000 claims description 204
- 239000010936 titanium Substances 0.000 claims description 98
- 229910052804 chromium Inorganic materials 0.000 claims description 75
- 239000002356 single layer Substances 0.000 claims description 37
- 229910001093 Zr alloy Inorganic materials 0.000 claims description 36
- 229910045601 alloy Inorganic materials 0.000 claims description 25
- 239000000956 alloy Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 23
- 229910052760 oxygen Inorganic materials 0.000 claims description 23
- 239000001301 oxygen Substances 0.000 claims description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 22
- 238000005253 cladding Methods 0.000 claims description 18
- 239000003758 nuclear fuel Substances 0.000 claims description 15
- 239000010955 niobium Substances 0.000 claims description 14
- 230000001186 cumulative effect Effects 0.000 claims description 12
- 230000007797 corrosion Effects 0.000 claims description 11
- 238000005260 corrosion Methods 0.000 claims description 11
- 239000000446 fuel Substances 0.000 claims description 11
- 238000005240 physical vapour deposition Methods 0.000 claims description 11
- 229910052718 tin Inorganic materials 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 10
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 10
- 238000004544 sputter deposition Methods 0.000 claims description 10
- 238000000151 deposition Methods 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 230000008021 deposition Effects 0.000 claims description 7
- 230000006872 improvement Effects 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052729 chemical element Inorganic materials 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- 238000005229 chemical vapour deposition Methods 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 238000005868 electrolysis reaction Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000001465 metallisation Methods 0.000 claims 1
- 238000005289 physical deposition Methods 0.000 claims 1
- 238000001755 magnetron sputter deposition Methods 0.000 abstract description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 78
- 239000001257 hydrogen Substances 0.000 description 22
- 229910052739 hydrogen Inorganic materials 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 21
- 238000005259 measurement Methods 0.000 description 16
- 238000010791 quenching Methods 0.000 description 14
- 235000012431 wafers Nutrition 0.000 description 14
- 230000000171 quenching effect Effects 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 12
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 12
- 238000004845 hydriding Methods 0.000 description 11
- 239000002131 composite material Substances 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 238000001000 micrograph Methods 0.000 description 7
- 150000004678 hydrides Chemical class 0.000 description 6
- 238000000399 optical microscopy Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 239000002826 coolant Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 206010040844 Skin exfoliation Diseases 0.000 description 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 3
- 229910000423 chromium oxide Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 230000003313 weakening effect Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910020010 Nb—Si Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- -1 free radical hydrides Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012615 high-resolution technique Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000002915 spent fuel radioactive waste Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 1
- QSGNKXDSTRDWKA-UHFFFAOYSA-N zirconium dihydride Chemical compound [ZrH2] QSGNKXDSTRDWKA-UHFFFAOYSA-N 0.000 description 1
- 229910000568 zirconium hydride Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
- C23C14/165—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/02—Fuel elements
- G21C3/04—Constructional details
- G21C3/06—Casings; Jackets
- G21C3/07—Casings; Jackets characterised by their material, e.g. alloys
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/02—Fuel elements
- G21C3/04—Constructional details
- G21C3/16—Details of the construction within the casing
- G21C3/20—Details of the construction within the casing with coating on fuel or on inside of casing; with non-active interlayer between casing and active material with multiple casings or multiple active layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12819—Group VB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- General Chemical & Material Sciences (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1253887 | 2012-04-26 | ||
| FR1253887A FR2989923B1 (fr) | 2012-04-26 | 2012-04-26 | Materiau multicouche resistant a l'oxydation en milieu nucleaire. |
| PCT/FR2013/050849 WO2013160587A1 (fr) | 2012-04-26 | 2013-04-17 | Materiau multicouche resistant a l'oxydation en milieu nucleaire |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2871113A1 CA2871113A1 (fr) | 2013-10-31 |
| CA2871113C true CA2871113C (fr) | 2020-07-14 |
Family
ID=47002949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2871113A Active CA2871113C (fr) | 2012-04-26 | 2013-04-17 | Materiau multicouche resistant a l'oxydation en milieu nucleaire |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9963775B2 (enExample) |
| EP (1) | EP2841264B1 (enExample) |
| JP (1) | JP6370773B2 (enExample) |
| KR (1) | KR102117411B1 (enExample) |
| CN (1) | CN104395069B (enExample) |
| CA (1) | CA2871113C (enExample) |
| FR (1) | FR2989923B1 (enExample) |
| WO (1) | WO2013160587A1 (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614698B (zh) * | 2013-12-18 | 2015-10-21 | 广西大学 | 一种高温抗氧化铌合金复合涂层及其制备方法 |
| US9721676B2 (en) * | 2014-05-27 | 2017-08-01 | Westinghouse Electric Company, Llc | Deposition of a protective coating including metal-containing and chromium-containing layers on zirconium alloy for nuclear power applications |
| FR3025929B1 (fr) | 2014-09-17 | 2016-10-21 | Commissariat Energie Atomique | Gaines de combustible nucleaire, procedes de fabrication et utilisation contre l'oxydation. |
| US9844923B2 (en) * | 2015-08-14 | 2017-12-19 | Westinghouse Electric Company Llc | Corrosion and wear resistant coating on zirconium alloy cladding |
| US20180294062A1 (en) * | 2015-10-06 | 2018-10-11 | The Penn State Research Foundation | Ceramic coating for corrosion resistance of nuclear fuel cladding |
| EP3181718A1 (en) * | 2015-12-15 | 2017-06-21 | Areva NP | Cladding for a fuel rod for a light water reactor |
| EP3488445B1 (en) * | 2016-07-22 | 2021-07-21 | Westinghouse Electric Company Llc | Cold spray chromium coating for nuclear fuel rods |
| HUE051186T2 (hu) | 2016-09-28 | 2021-03-01 | Commissariat Energie Atomique | Nukleáris komponens fém szubsztráttal, eljárás annak elõállítására DLI-MOCVD módszerrel és alkalmazásai oxidáció/hidridképzõdés szabályozására |
| FR3056815B1 (fr) * | 2016-09-28 | 2021-01-29 | Commissariat Energie Atomique | Composant nucleaire a substrat metallique et utilisations contre l'oxydation/hydruration. |
| JP6735914B2 (ja) * | 2016-09-28 | 2020-08-05 | コミサーリャ ア レナジー アトミック エー オー エナジー アルタナティブＣｏｍｍｉｓｓａｒｉａｔ Ａ Ｌ’Ｅｎｅｒｇｉｅ Ａｔｏｍｉｑｕｅ Ｅｔ Ａｕｘ Ｅｎｅｒｇｉｅｓ Ａｌｔｅｒｎａｔｉｖｅｓ | 準安定クロム被覆を有する原子炉コンポーネント、ｄｌｉ−ｍｏｃｖｄによる製造方法および酸化／水素化に対する使用 |
| US11715572B2 (en) | 2016-09-28 | 2023-08-01 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Composite nuclear component, DLI-MOCVD method for producing same, and uses for controlling oxidation/hydridation |
| EP3519605B1 (fr) | 2016-09-28 | 2020-08-05 | Commissariat à l'Énergie Atomique et aux Énergies Alternatives | Composant nucléaire avec revetement de crc amorphe, procédé de fabrication par dli-mocvd et utilisation contre l'oxydation/hydruration |
| JP7130629B2 (ja) * | 2016-10-03 | 2022-09-05 | ウエスチングハウス・エレクトリック・カンパニー・エルエルシー | 原子燃料棒の事故耐性二重被膜の形成方法 |
| CN106739265A (zh) * | 2016-11-24 | 2017-05-31 | 苏州华意铭铄激光科技有限公司 | 一种耐高温防护复合金属制品 |
| CN106739266A (zh) * | 2016-11-24 | 2017-05-31 | 苏州华意铭铄激光科技有限公司 | 一种抗老化防护复合金属制品 |
| US11133114B2 (en) | 2017-02-13 | 2021-09-28 | Terrapower Llc | Steel-vanadium alloy cladding for fuel element |
| US11031145B2 (en) | 2017-03-06 | 2021-06-08 | Westinghouse Electric Company Llc | Method of manufacturing a reinforced nuclear fuel cladding using an intermediate thermal deposition layer |
| KR101941673B1 (ko) * | 2017-04-18 | 2019-01-23 | 가천대학교 산학협력단 | 다층구조 핵연료 피복관 및 다층구조 핵연료 피복관의 제조방법 |
| JP6850209B2 (ja) * | 2017-06-23 | 2021-03-31 | 日立Ｇｅニュークリア・エナジー株式会社 | 接合部材、それを用いた接合構造体及び接合部材の製造方法 |
| CN107301883A (zh) * | 2017-07-28 | 2017-10-27 | 中国原子能科学研究院 | 一种钠冷快堆燃料中去除氢和氚的装置 |
| EP3502321A1 (en) | 2017-12-20 | 2019-06-26 | Westinghouse Electric Sweden AB | Method of forming a coated component made of zirconium or zirconium-based alloy |
| EP3680917B1 (en) | 2019-01-14 | 2023-10-04 | Westinghouse Electric Sweden AB | A cladding tube for a fuel rod for nuclear reactors |
| CN110055496B (zh) * | 2019-04-04 | 2021-05-04 | 中国核动力研究设计院 | 一种在核用锆合金基底表面制备Cr涂层的制备工艺 |
| CN110129752A (zh) * | 2019-05-24 | 2019-08-16 | 山东省科学院激光研究所 | 锆合金管材表面处理方法及装置 |
| JP2023523331A (ja) * | 2020-04-27 | 2023-06-02 | ウェスティングハウス エレクトリック カンパニー エルエルシー | めっきされた金属基材及びその製造方法 |
| EP3907742B1 (en) | 2020-05-07 | 2023-06-21 | Westinghouse Electric Sweden AB | A cladding tube for a fuel rod for a nuclear reactor, a fuel rod, and a fuel assembly |
| CN111636082A (zh) * | 2020-06-16 | 2020-09-08 | 西安稀有金属材料研究院有限公司 | 一种电化学制备核燃料包壳元件事故容错Cr涂层的方法 |
| CN114232052B (zh) * | 2020-09-09 | 2023-03-10 | 北京师范大学 | 一种锆合金包壳表面抗高温腐蚀的复合涂层制备方法 |
| JP2023552098A (ja) * | 2020-11-25 | 2023-12-14 | ウエスチングハウス・エレクトリック・カンパニー・エルエルシー | クロム合金被膜付き原子燃料棒 |
| NL2027163B1 (en) | 2020-12-18 | 2022-07-15 | Drylock Tech Nv | Absorbent article with improved bottom distribution assembly |
| JP7489570B2 (ja) * | 2020-12-25 | 2024-05-24 | 三菱重工業株式会社 | 燃料被覆管の製造方法 |
| CN113088884A (zh) * | 2021-03-09 | 2021-07-09 | 哈尔滨工业大学 | 一种在锆包壳上制备具有高温抗氧化性能的铬涂层的方法 |
| US20230323519A1 (en) * | 2022-04-11 | 2023-10-12 | Michael T. Clarke | Formation of surface oxide coatings for zirconium and zirconium based alloys |
| US20240145104A1 (en) * | 2022-11-02 | 2024-05-02 | Westinghouse Electric Company Llc | Use of oxidation resistant coatings to increase thin walled cladding tensile strength to increase uranium loadings |
| CN118086848B (zh) * | 2024-03-07 | 2024-10-08 | 重庆文理学院 | 一种核用锆合金表面抗高温氧化复合涂层及其制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1493040A (fr) * | 1966-07-12 | 1967-08-25 | Commissariat Energie Atomique | Procédé de protection du zirconium et de ses alliages par un revêtement de chrome |
| FR1527055A (fr) * | 1967-04-17 | 1968-05-31 | Ugine Kuhlmann | Perfectionnements relatifs à la protection du zirconium et de ses alliages |
| US4029545A (en) * | 1974-11-11 | 1977-06-14 | General Electric Company | Nuclear fuel elements having a composite cladding |
| US4268586A (en) | 1975-06-26 | 1981-05-19 | General Electric Company | Corrosion resistant zirconium alloy structural components and process |
| JPS5917602B2 (ja) * | 1975-12-17 | 1984-04-23 | 株式会社日立製作所 | サデンリユウハンソウホゴケイデンソウチ ノ ジドウテンケンホウシキ |
| ES8200501A1 (es) * | 1979-11-26 | 1981-11-01 | Gen Electric | Metodo para producir un recipiente con destino a reactores nucleares de fision. |
| JPS62182269A (ja) * | 1986-02-03 | 1987-08-10 | ザ・バブコツク・アンド・ウイルコツクス・カンパニ− | クロムによるジルコニウム合金のイオン打込み |
| US4880597A (en) * | 1987-08-05 | 1989-11-14 | Combustion Engineering, Inc. | Alloy coated fuel cladding |
| JPH04204196A (ja) * | 1990-11-30 | 1992-07-24 | Nippon Nuclear Fuel Dev Co Ltd | 核燃料要素 |
| JP2937580B2 (ja) * | 1991-10-16 | 1999-08-23 | 功二 橋本 | 高耐食アモルファス合金 |
| JPH05171418A (ja) * | 1991-12-26 | 1993-07-09 | Hitachi Ltd | 高Ｆｅ，Ｎｉ，Ｃｒ添加ジルコニウム合金 |
| DE19520843A1 (de) * | 1995-06-08 | 1996-12-12 | Leybold Ag | Scheibe aus durchscheinendem Werkstoff sowie Verfahren zu ihrer Herstellung |
| FR2849620A1 (fr) * | 2003-01-07 | 2004-07-09 | Metatherm Sa | Revetement multicouche pour proteger une piece contre la corrosion, procede pour la realisation d'un tel revetement et piece comportant un tel revetement |
| WO2006038826A1 (fr) * | 2004-03-02 | 2006-04-13 | Anatoly Nikolaevich Paderov | Procede d'application d'un revetement a couches multiples aux articles metalliques |
| KR20060022769A (ko) * | 2004-09-08 | 2006-03-13 | 박혜련 | 표면층 형성에 의한 핵연료용 내식성 지르코늄합금 피복관의 제조방법 |
| JP2006219740A (ja) * | 2005-02-14 | 2006-08-24 | Chokoon Zairyo Kenkyusho:Kk | 耐酸化性に優れた二オブ基合金耐熱部材 |
| KR101038106B1 (ko) * | 2009-04-15 | 2011-06-01 | 한국수력원자력 주식회사 | 고속로용 핵연료 피복관 상에 기능성 다층 박막을 저온에서 증착하는 방법 |
-
2012
- 2012-04-26 FR FR1253887A patent/FR2989923B1/fr active Active
-
2013
- 2013-04-17 CA CA2871113A patent/CA2871113C/fr active Active
- 2013-04-17 JP JP2015507576A patent/JP6370773B2/ja active Active
- 2013-04-17 EP EP13722497.8A patent/EP2841264B1/fr active Active
- 2013-04-17 KR KR1020147033318A patent/KR102117411B1/ko active Active
- 2013-04-17 CN CN201380032329.XA patent/CN104395069B/zh active Active
- 2013-04-17 WO PCT/FR2013/050849 patent/WO2013160587A1/fr not_active Ceased
-
2014
- 2014-10-27 US US14/524,174 patent/US9963775B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2871113A1 (fr) | 2013-10-31 |
| FR2989923B1 (fr) | 2014-05-16 |
| EP2841264A1 (fr) | 2015-03-04 |
| KR102117411B1 (ko) | 2020-06-01 |
| EP2841264C0 (fr) | 2024-01-24 |
| JP2015523231A (ja) | 2015-08-13 |
| CN104395069B (zh) | 2016-12-28 |
| CN104395069A (zh) | 2015-03-04 |
| EP2841264B1 (fr) | 2024-01-24 |
| US9963775B2 (en) | 2018-05-08 |
| US20150050521A1 (en) | 2015-02-19 |
| KR20150010963A (ko) | 2015-01-29 |
| FR2989923A1 (fr) | 2013-11-01 |
| JP6370773B2 (ja) | 2018-08-08 |
| WO2013160587A1 (fr) | 2013-10-31 |
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