CA2870542A1 - Metal hydride alloys having improved activation and high rate performance - Google Patents
Metal hydride alloys having improved activation and high rate performance Download PDFInfo
- Publication number
- CA2870542A1 CA2870542A1 CA2870542A CA2870542A CA2870542A1 CA 2870542 A1 CA2870542 A1 CA 2870542A1 CA 2870542 A CA2870542 A CA 2870542A CA 2870542 A CA2870542 A CA 2870542A CA 2870542 A1 CA2870542 A1 CA 2870542A1
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- CA
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- Prior art keywords
- phase
- alloy
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- modifier element
- alloys
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000956 alloy Substances 0.000 title claims abstract description 138
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 115
- 229910052987 metal hydride Inorganic materials 0.000 title claims abstract description 28
- 150000004681 metal hydrides Chemical class 0.000 title claims abstract description 26
- 230000004913 activation Effects 0.000 title description 13
- 239000003607 modifier Substances 0.000 claims abstract description 47
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 14
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001068 laves phase Inorganic materials 0.000 claims abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 239000012071 phase Substances 0.000 description 98
- 239000000463 material Substances 0.000 description 25
- 239000000203 mixture Substances 0.000 description 17
- 238000003860 storage Methods 0.000 description 17
- 238000009616 inductively coupled plasma Methods 0.000 description 14
- 238000001994 activation Methods 0.000 description 13
- 239000011651 chromium Substances 0.000 description 10
- 238000013461 design Methods 0.000 description 10
- 239000010936 titanium Substances 0.000 description 9
- 230000003247 decreasing effect Effects 0.000 description 7
- 150000004678 hydrides Chemical class 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000003795 desorption Methods 0.000 description 5
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 5
- 239000007792 gaseous phase Substances 0.000 description 5
- -1 AB2 metal hydride Chemical class 0.000 description 4
- 229910020630 Co Ni Inorganic materials 0.000 description 4
- 229910010380 TiNi Inorganic materials 0.000 description 4
- 229910007727 Zr V Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000012458 free base Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 229910007884 Zr7Ni10 Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000004626 scanning electron microscopy Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910020108 MgCu2 Inorganic materials 0.000 description 1
- 229910017708 MgZn2 Inorganic materials 0.000 description 1
- 229910052774 Proactinium Inorganic materials 0.000 description 1
- 229910020997 Sn-Y Inorganic materials 0.000 description 1
- 229910008859 Sn—Y Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- RZJQYRCNDBMIAG-UHFFFAOYSA-N [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] Chemical class [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] RZJQYRCNDBMIAG-UHFFFAOYSA-N 0.000 description 1
- 238000010314 arc-melting process Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002847 impedance measurement Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
- C22C2202/04—Hydrogen absorbing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/450,763 US9272259B2 (en) | 2012-04-19 | 2012-04-19 | Metal hydride alloys having improved activation and high rate performance |
| US13/450,763 | 2012-04-19 | ||
| PCT/US2013/037125 WO2013158850A1 (en) | 2012-04-19 | 2013-04-18 | Metal hydride alloys having improved activation and high rate performance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2870542A1 true CA2870542A1 (en) | 2013-10-24 |
Family
ID=49379240
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2870542A Withdrawn CA2870542A1 (en) | 2012-04-19 | 2013-04-18 | Metal hydride alloys having improved activation and high rate performance |
| CA 2888011 Abandoned CA2888011A1 (en) | 2012-04-19 | 2013-04-18 | Metal hydride alloys having improved activation and high rate performance |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2888011 Abandoned CA2888011A1 (en) | 2012-04-19 | 2013-04-18 | Metal hydride alloys having improved activation and high rate performance |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9272259B2 (enExample) |
| EP (1) | EP2839046B1 (enExample) |
| JP (2) | JP2015520798A (enExample) |
| KR (1) | KR20140148476A (enExample) |
| CN (2) | CN104302795A (enExample) |
| CA (2) | CA2870542A1 (enExample) |
| WO (1) | WO2013158850A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20131921A1 (it) * | 2013-11-20 | 2015-05-21 | Getters Spa | Leghe getter non evaporabili particolarmente adatte per l'assorbimento di idrogeno e monossido di carbonio |
| WO2016130621A1 (en) * | 2015-02-11 | 2016-08-18 | Basf Corporation | Hydrogen storage alloys |
| US9856544B2 (en) | 2015-02-11 | 2018-01-02 | Basf Corporation | Hydrogen storage alloys |
| JP2018511141A (ja) * | 2015-02-11 | 2018-04-19 | ビーエーエスエフ コーポレーション | 水素吸蔵合金 |
| US10109855B2 (en) | 2015-02-11 | 2018-10-23 | Basf Corporation | Hydrogen storage alloys |
| EP3256616A4 (en) * | 2015-02-11 | 2018-10-17 | BASF Corporation | Hydrogen storage alloys |
| US10587012B2 (en) | 2015-03-26 | 2020-03-10 | Basf Corporation | Electrolyte compositions comprising ionic liquids and metal hydride batteries comprising same |
| JP6583616B2 (ja) * | 2015-05-29 | 2019-10-02 | 国立大学法人名古屋大学 | 水素吸蔵量測定方法および水素吸蔵量測定装置 |
| JP6949029B2 (ja) | 2016-01-05 | 2021-10-13 | ビーエーエスエフ コーポレーション | アルカリ充電式電池のためのニッケル水酸化物複合材料 |
| WO2017172290A1 (en) | 2016-03-28 | 2017-10-05 | Basf Corporation | Silicon-based solid electrolyte for rechargeable battery |
| FR3053978B1 (fr) * | 2016-07-12 | 2020-02-21 | Centre National De La Recherche Scientifique (Cnrs) | Matiere active pour electrode negative d’accumulateur alcalin de type nickel hydrure metallique |
| DE102021118143A1 (de) | 2021-07-14 | 2023-01-19 | Vaillant Gmbh | Verfahren und Anordnung zur Erkennung einer Wasserstoffleckage, Computerprogrammprodukt sowie Verwendung eines Absorptionsmittels |
| CN114141916B (zh) * | 2021-11-24 | 2023-08-01 | 福州大学 | 纳米尺寸led芯片阵列及其制备方法 |
| CN115261675B (zh) * | 2022-07-20 | 2022-12-23 | 华南理工大学 | 一种单相或多相AB4型La-Y-Ni基超晶格储氢合金及其制备方法 |
| EP4538224A1 (en) | 2023-10-11 | 2025-04-16 | Cyrus S.A. "Lefkippos" Technology Park of Attica - NCSR | Hydrogen compressing technique |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS583025B2 (ja) * | 1977-10-28 | 1983-01-19 | 松下電器産業株式会社 | 水素貯蔵用金属材料 |
| US4195989A (en) | 1977-10-28 | 1980-04-01 | Matsushita Electric Industrial Co., Ltd. | Hydrogen storage material |
| US5096667A (en) * | 1989-11-24 | 1992-03-17 | Energy Conversion Devices, Inc. | Catalytic hydrogen storage electrode materials for use in electrochemical cells and electrochemical cells incorporating the materials |
| IL96391A (en) * | 1989-11-24 | 1995-05-26 | Energy Conversion Devices Inc | Catalytic hydrogen storage electrode materials for use in electrochemical cells |
| US5536591A (en) | 1990-04-26 | 1996-07-16 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys for nickel metal hydride batteries |
| JP3054477B2 (ja) | 1991-04-10 | 2000-06-19 | 三洋電機株式会社 | 水素吸蔵合金電極 |
| DE69317967T2 (de) * | 1992-09-14 | 1998-12-10 | Kabushiki Kaisha Toshiba, Kawasaki, Kanagawa | Wasserstoffabsorbierende Legierung für Batterien, Verfahren zu ihrer Herstellung und Nickel-Metallhydrid Sekundärbatterie |
| US5512385A (en) | 1994-02-28 | 1996-04-30 | Matsushita Electric Industrial Co., Ltd. | Hydrogen storage alloy and nickel-metal hydride storage battery using the same |
| JP3322486B2 (ja) * | 1994-10-05 | 2002-09-09 | 三洋電機株式会社 | 被毒耐性及び再生回復力にすぐれる水素吸蔵合金 |
| US5951945A (en) * | 1995-06-13 | 1999-09-14 | Mitsubishi Materials Corporation | Hydrogen occluding alloy and electrode made of the alloy |
| JP3307176B2 (ja) * | 1995-07-18 | 2002-07-24 | 松下電器産業株式会社 | 水素吸蔵合金とその製造法およびこれを用いた水素吸蔵合金電極 |
| DE69737799T2 (de) | 1996-02-20 | 2008-03-06 | Matsushita Electric Industrial Co., Ltd., Kadoma | Nickel/Metallhydrid-Speicherzelle und Legierung für negative Elektrode |
| JPH1125964A (ja) * | 1997-06-27 | 1999-01-29 | Hitachi Maxell Ltd | アルカリ蓄電池 |
| US6210498B1 (en) | 1998-04-22 | 2001-04-03 | Energy Conversion Devices, Inc. | Hydrogen storage alloys and methods and improved nickel metal hydride electrodes and batteries using same |
| JP4567935B2 (ja) * | 1999-12-27 | 2010-10-27 | 株式会社東芝 | 水素吸蔵合金、二次電池、ハイブリッドカー及び電気自動車 |
| US6500583B1 (en) * | 2000-07-17 | 2002-12-31 | Energy Conversion Devices, Inc. | Electrochemical hydrogen storage alloys for nickel metal hydride batteries, fuel cells and methods of manufacturing same |
| US6830725B2 (en) * | 2003-04-01 | 2004-12-14 | Texaco Ovonic Battery Systems, Llc | Hydrogen storage alloys having a high porosity surface layer |
| US7108757B2 (en) | 2003-08-08 | 2006-09-19 | Ovonic Hydrogen Systems Llc | Hydrogen storage alloys providing for the reversible storage of hydrogen at low temperatures |
| JP6201307B2 (ja) * | 2012-02-20 | 2017-09-27 | 株式会社Ｇｓユアサ | 水素吸蔵合金、電極、ニッケル水素蓄電池及び水素吸蔵合金の製造方法 |
-
2012
- 2012-04-19 US US13/450,763 patent/US9272259B2/en active Active
-
2013
- 2013-04-18 JP JP2015507166A patent/JP2015520798A/ja active Pending
- 2013-04-18 EP EP13778289.2A patent/EP2839046B1/en active Active
- 2013-04-18 CN CN201380020576.8A patent/CN104302795A/zh active Pending
- 2013-04-18 KR KR1020147031090A patent/KR20140148476A/ko not_active Withdrawn
- 2013-04-18 CA CA2870542A patent/CA2870542A1/en not_active Withdrawn
- 2013-04-18 CA CA 2888011 patent/CA2888011A1/en not_active Abandoned
- 2013-04-18 CN CN201810377416.3A patent/CN108584869A/zh active Pending
- 2013-04-18 WO PCT/US2013/037125 patent/WO2013158850A1/en not_active Ceased
-
2017
- 2017-01-06 JP JP2017001014A patent/JP6747989B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140148476A (ko) | 2014-12-31 |
| JP6747989B2 (ja) | 2020-08-26 |
| CN104302795A (zh) | 2015-01-21 |
| WO2013158850A1 (en) | 2013-10-24 |
| CN108584869A (zh) | 2018-09-28 |
| EP2839046A4 (en) | 2015-11-25 |
| JP2015520798A (ja) | 2015-07-23 |
| JP2017137571A (ja) | 2017-08-10 |
| US20130277607A1 (en) | 2013-10-24 |
| EP2839046A1 (en) | 2015-02-25 |
| EP2839046B1 (en) | 2019-10-02 |
| US9272259B2 (en) | 2016-03-01 |
| CA2888011A1 (en) | 2013-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AZWI | Withdrawn application |
Effective date: 20141205 |