CA2865634A1 - Methods for perforating graphene using an activated gas stream and perforated graphene produced therefrom - Google Patents
Methods for perforating graphene using an activated gas stream and perforated graphene produced therefrom Download PDFInfo
- Publication number
- CA2865634A1 CA2865634A1 CA2865634A CA2865634A CA2865634A1 CA 2865634 A1 CA2865634 A1 CA 2865634A1 CA 2865634 A CA2865634 A CA 2865634A CA 2865634 A CA2865634 A CA 2865634A CA 2865634 A1 CA2865634 A1 CA 2865634A1
- Authority
- CA
- Canada
- Prior art keywords
- graphene
- graphene sheet
- activated gas
- gas stream
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 140
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 138
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000007789 gas Substances 0.000 claims abstract description 54
- 239000002131 composite material Substances 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 abstract description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052786 argon Inorganic materials 0.000 abstract description 5
- 239000001307 helium Substances 0.000 abstract description 3
- 229910052734 helium Inorganic materials 0.000 abstract description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 chlorine ions Chemical class 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002064 nanoplatelet Substances 0.000 description 1
- 239000002074 nanoribbon Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/847—Surface modifications, e.g. functionalization, coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/888—Shaping or removal of materials, e.g. etching
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261613938P | 2012-03-21 | 2012-03-21 | |
| US61/613,938 | 2012-03-21 | ||
| PCT/US2013/030344 WO2013142133A1 (en) | 2012-03-21 | 2013-03-12 | Methods for perforating graphene using an activated gas stream and perforated graphene produced therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2865634A1 true CA2865634A1 (en) | 2013-09-26 |
Family
ID=48040413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2865634A Abandoned CA2865634A1 (en) | 2012-03-21 | 2013-03-12 | Methods for perforating graphene using an activated gas stream and perforated graphene produced therefrom |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9567224B2 (enExample) |
| EP (1) | EP2828196A1 (enExample) |
| JP (1) | JP6246785B2 (enExample) |
| KR (1) | KR20140146131A (enExample) |
| CN (1) | CN104245577A (enExample) |
| AU (1) | AU2013235643B2 (enExample) |
| CA (1) | CA2865634A1 (enExample) |
| IL (1) | IL234684A0 (enExample) |
| IN (1) | IN2014DN07732A (enExample) |
| SG (1) | SG11201405346RA (enExample) |
| WO (1) | WO2013142133A1 (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9475709B2 (en) | 2010-08-25 | 2016-10-25 | Lockheed Martin Corporation | Perforated graphene deionization or desalination |
| US9193587B2 (en) | 2011-07-13 | 2015-11-24 | Lockheed Martin Corporation | System and method for water purification and desalination |
| US9028663B2 (en) * | 2012-03-21 | 2015-05-12 | Lockheed Martin Corporation | Molecular separation device |
| US9095823B2 (en) | 2012-03-29 | 2015-08-04 | Lockheed Martin Corporation | Tunable layered membrane configuration for filtration and selective isolation and recovery devices |
| US9463421B2 (en) | 2012-03-29 | 2016-10-11 | Lockheed Martin Corporation | Planar filtration and selective isolation and recovery device |
| US10017852B2 (en) | 2016-04-14 | 2018-07-10 | Lockheed Martin Corporation | Method for treating graphene sheets for large-scale transfer using free-float method |
| US10376845B2 (en) | 2016-04-14 | 2019-08-13 | Lockheed Martin Corporation | Membranes with tunable selectivity |
| US10980919B2 (en) | 2016-04-14 | 2021-04-20 | Lockheed Martin Corporation | Methods for in vivo and in vitro use of graphene and other two-dimensional materials |
| US9610546B2 (en) | 2014-03-12 | 2017-04-04 | Lockheed Martin Corporation | Separation membranes formed from perforated graphene and methods for use thereof |
| US9834809B2 (en) | 2014-02-28 | 2017-12-05 | Lockheed Martin Corporation | Syringe for obtaining nano-sized materials for selective assays and related methods of use |
| US9067811B1 (en) * | 2012-05-25 | 2015-06-30 | Lockheed Martin Corporation | System, method, and control for graphenoid desalination |
| US10653824B2 (en) | 2012-05-25 | 2020-05-19 | Lockheed Martin Corporation | Two-dimensional materials and uses thereof |
| US9744617B2 (en) | 2014-01-31 | 2017-08-29 | Lockheed Martin Corporation | Methods for perforating multi-layer graphene through ion bombardment |
| TWI493549B (zh) * | 2013-03-05 | 2015-07-21 | Nat Univ Tsing Hua | 電阻式隨機存取記憶體 |
| US9592475B2 (en) | 2013-03-12 | 2017-03-14 | Lockheed Martin Corporation | Method for forming perforated graphene with uniform aperture size |
| US9505192B2 (en) | 2013-03-13 | 2016-11-29 | Lockheed Martin Corporation | Nanoporous membranes and methods for making the same |
| US9480952B2 (en) | 2013-03-14 | 2016-11-01 | Lockheed Martin Corporation | Methods for chemical reaction perforation of atomically thin materials |
| US9572918B2 (en) | 2013-06-21 | 2017-02-21 | Lockheed Martin Corporation | Graphene-based filter for isolating a substance from blood |
| AU2015210875A1 (en) | 2014-01-31 | 2016-09-15 | Lockheed Martin Corporation | Processes for forming composite structures with a two-dimensional material using a porous, non-sacrificial supporting layer |
| KR20160142820A (ko) | 2014-01-31 | 2016-12-13 | 록히드 마틴 코포레이션 | 브로드 이온 필드를 사용한 2차원 물질 천공 |
| US20150258525A1 (en) * | 2014-03-12 | 2015-09-17 | Lockheed Martin Corporation | Graphene-based molecular sieves and methods for production thereof |
| CN106232205A (zh) | 2014-03-12 | 2016-12-14 | 洛克希德马丁公司 | 由有孔石墨烯形成的分离膜 |
| AU2015285551A1 (en) * | 2014-06-30 | 2017-01-12 | Kotobuki Tsushou Co., Ltd. | Method for perforating carbon nanomaterial, and method for producing filter molded article |
| CN107073408A (zh) | 2014-09-02 | 2017-08-18 | 洛克希德马丁公司 | 基于二维膜材料的血液透析膜和血液过滤膜及其应用方法 |
| US9421739B2 (en) * | 2015-01-05 | 2016-08-23 | The Boeing Company | Graphene aerospace composites |
| US10266677B2 (en) | 2015-01-05 | 2019-04-23 | The Boeing Company | Graphene-augmented composite materials |
| CN104925794B (zh) * | 2015-06-11 | 2016-05-04 | 青岛大学 | 一种以纳米孔石墨烯为基底生长三维氮掺杂石墨烯的方法 |
| KR20180036989A (ko) * | 2015-08-05 | 2018-04-10 | 록히드 마틴 코포레이션 | 그래핀계 물질의 천공 시트 |
| CN107921402A (zh) * | 2015-08-05 | 2018-04-17 | 洛克希德马丁公司 | 石墨烯基材料的穿孔片 |
| CA2994549A1 (en) | 2015-08-05 | 2017-02-09 | Lockheed Martin Corporation | Perforatable sheets of graphene-based material |
| CA2994664A1 (en) * | 2015-08-06 | 2017-02-09 | Lockheed Martin Corporation | Nanoparticle modification and perforation of graphene |
| CN105514121B (zh) * | 2016-01-26 | 2019-03-15 | 武汉华星光电技术有限公司 | 一种tft阵列基板及其制作方法 |
| EP3442697A4 (en) | 2016-04-14 | 2020-03-18 | Lockheed Martin Corporation | SELECTIVE INTERFACE REDUCTION OF GRAPH DEFECTS |
| WO2017180138A1 (en) * | 2016-04-14 | 2017-10-19 | Lockheed Martin Corporation | Healing of thin graphenic-based membranes via charged particle irradiation |
| KR20190018410A (ko) | 2016-04-14 | 2019-02-22 | 록히드 마틴 코포레이션 | 흐름 통로들을 갖는 2차원 막 구조들 |
| JP2019519756A (ja) | 2016-04-14 | 2019-07-11 | ロッキード・マーチン・コーポレーション | 欠陥形成または欠陥修復をその場で監視して制御する方法 |
| WO2018043634A1 (ja) | 2016-08-31 | 2018-03-08 | 国立大学法人大阪大学 | 自己触媒能を有する炭素系水素貯蔵材料、その製造方法、その化合物を用いる水素の吸蔵方法及び水素の放出方法、及び水素吸蔵用デバイス |
| KR101934568B1 (ko) * | 2016-11-25 | 2019-01-02 | 한국과학기술연구원 | 나노다공성 그래핀 막의 제조 방법 |
| KR101835596B1 (ko) * | 2017-03-20 | 2018-03-08 | 삼화콘덴서공업 주식회사 | 고용량 에너지 저장 커패시터 |
| CN114051430A (zh) * | 2019-07-24 | 2022-02-15 | 国立大学法人大阪大学 | 烷烃脱氢催化剂、以及使用该催化剂的氢制造方法 |
| CN110451496B (zh) * | 2019-09-17 | 2021-04-20 | 北京石墨烯研究院 | 一种连续放量制备粉体石墨烯的方法 |
| AU2021258335A1 (en) | 2020-02-21 | 2022-09-29 | Paul J. LILLY | Above room temperature Type II superconductor |
| KR102654642B1 (ko) * | 2021-05-24 | 2024-04-04 | (주)에스그래핀 | 기능기의 탈부착을 이용한 그래핀 나노홀의 형성방법 및 이에 의해 형성된 그래핀 나노홀을 가지는 그래핀 시트 |
| EP4570363A1 (en) | 2023-12-13 | 2025-06-18 | Université de Fribourg | Method for treating a graphene membrane and membrane obtained by the method |
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| US9744617B2 (en) | 2014-01-31 | 2017-08-29 | Lockheed Martin Corporation | Methods for perforating multi-layer graphene through ion bombardment |
| US9067811B1 (en) | 2012-05-25 | 2015-06-30 | Lockheed Martin Corporation | System, method, and control for graphenoid desalination |
| US20150258498A1 (en) | 2014-03-12 | 2015-09-17 | Lockheed Martin Corporation | Graphene-based molecular separation and sequestration device and methods for harvest and recovery |
| US9592475B2 (en) | 2013-03-12 | 2017-03-14 | Lockheed Martin Corporation | Method for forming perforated graphene with uniform aperture size |
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| US9480952B2 (en) | 2013-03-14 | 2016-11-01 | Lockheed Martin Corporation | Methods for chemical reaction perforation of atomically thin materials |
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| US9572918B2 (en) | 2013-06-21 | 2017-02-21 | Lockheed Martin Corporation | Graphene-based filter for isolating a substance from blood |
| US20150075667A1 (en) | 2013-09-19 | 2015-03-19 | Lockheed Martin Corporation | Carbon macrotubes and methods for making the same |
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| KR20160142820A (ko) | 2014-01-31 | 2016-12-13 | 록히드 마틴 코포레이션 | 브로드 이온 필드를 사용한 2차원 물질 천공 |
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| US20150258502A1 (en) | 2014-03-12 | 2015-09-17 | Lockheed Martin Corporation | Coating of a porous substrate for disposition of graphene and other two-dimensional materials thereon |
| US20150268150A1 (en) | 2014-03-24 | 2015-09-24 | Lockheed Martin Corporation | Large area membrane evaluation apparatuses and methods for use thereof |
| CN106457159A (zh) | 2014-05-08 | 2017-02-22 | 洛克希德马丁公司 | 堆叠的二维材料以及生产包含该材料的结构的方法 |
-
2013
- 2013-03-12 EP EP13713275.9A patent/EP2828196A1/en not_active Withdrawn
- 2013-03-12 JP JP2015501729A patent/JP6246785B2/ja not_active Expired - Fee Related
- 2013-03-12 CN CN201380013988.9A patent/CN104245577A/zh active Pending
- 2013-03-12 KR KR1020147029287A patent/KR20140146131A/ko not_active Withdrawn
- 2013-03-12 SG SG11201405346RA patent/SG11201405346RA/en unknown
- 2013-03-12 AU AU2013235643A patent/AU2013235643B2/en not_active Ceased
- 2013-03-12 WO PCT/US2013/030344 patent/WO2013142133A1/en not_active Ceased
- 2013-03-12 IN IN7732DEN2014 patent/IN2014DN07732A/en unknown
- 2013-03-12 CA CA2865634A patent/CA2865634A1/en not_active Abandoned
- 2013-03-12 US US13/795,276 patent/US9567224B2/en not_active Expired - Fee Related
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2014
- 2014-09-16 IL IL234684A patent/IL234684A0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20130249147A1 (en) | 2013-09-26 |
| AU2013235643A1 (en) | 2014-10-16 |
| IN2014DN07732A (enExample) | 2015-05-15 |
| JP6246785B2 (ja) | 2017-12-13 |
| IL234684A0 (en) | 2014-11-30 |
| SG11201405346RA (en) | 2014-10-30 |
| CN104245577A (zh) | 2014-12-24 |
| EP2828196A1 (en) | 2015-01-28 |
| KR20140146131A (ko) | 2014-12-24 |
| JP2015516357A (ja) | 2015-06-11 |
| WO2013142133A1 (en) | 2013-09-26 |
| AU2013235643B2 (en) | 2015-12-17 |
| US9567224B2 (en) | 2017-02-14 |
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