CA2863694C - Methods for making catalyst compositions and polymer products produced therefrom - Google Patents

Methods for making catalyst compositions and polymer products produced therefrom Download PDF

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Publication number
CA2863694C
CA2863694C CA2863694A CA2863694A CA2863694C CA 2863694 C CA2863694 C CA 2863694C CA 2863694 A CA2863694 A CA 2863694A CA 2863694 A CA2863694 A CA 2863694A CA 2863694 C CA2863694 C CA 2863694C
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Prior art keywords
polyethylene
titanium
catalyst
reacted product
mmol
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CA2863694A
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English (en)
French (fr)
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CA2863694A1 (en
Inventor
Wesley R. Mariott
Kevin J. Cann
John H. Moorhouse
Mark G. Goode
Thomas Oswald
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Univation Technologies LLC
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Univation Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2863694A 2012-03-05 2013-02-18 Methods for making catalyst compositions and polymer products produced therefrom Active CA2863694C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261606601P 2012-03-05 2012-03-05
US61/606,601 2012-03-05
PCT/US2013/026584 WO2013133956A2 (en) 2012-03-05 2013-02-18 Methods for making catalyst compositions and polymer products produced therefrom

Publications (2)

Publication Number Publication Date
CA2863694A1 CA2863694A1 (en) 2013-09-12
CA2863694C true CA2863694C (en) 2020-11-03

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Family Applications (1)

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CA2863694A Active CA2863694C (en) 2012-03-05 2013-02-18 Methods for making catalyst compositions and polymer products produced therefrom

Country Status (11)

Country Link
US (2) US9487601B2 (de)
EP (1) EP2800766B1 (de)
JP (1) JP6181672B2 (de)
KR (1) KR102053117B1 (de)
CN (1) CN104159933B (de)
BR (1) BR112014020839B1 (de)
CA (1) CA2863694C (de)
ES (1) ES2752139T3 (de)
RU (1) RU2640048C2 (de)
SG (2) SG11201404696VA (de)
WO (1) WO2013133956A2 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5827180B2 (ja) * 2012-06-18 2015-12-02 富士フイルム株式会社 インプリント用硬化性組成物と基板の密着用組成物およびこれを用いた半導体デバイス
CN105189637B (zh) 2013-05-22 2018-02-06 陶氏环球技术有限责任公司 含有具高熔融强度低密度乙烯基聚合物的组合物和由其形成的膜
JP6527519B2 (ja) * 2013-09-05 2019-06-05 ユニベーション・テクノロジーズ・エルエルシー 増加した分子量分布を持つポリエチレン
US10155831B2 (en) 2013-09-05 2018-12-18 Univation Technologies, Llc Process control for long chain branching control in polyethylene production
KR102402009B1 (ko) * 2014-07-31 2022-05-24 베르살리스 에스.피.에이. α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법
KR101950462B1 (ko) 2016-02-24 2019-02-20 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
US11459413B2 (en) 2016-09-27 2022-10-04 Univation Technologies, Llc Process control for long chain branching control in polyethylene production
WO2018064048A1 (en) * 2016-09-27 2018-04-05 Univation Technologies, Llc Method for long chain branching control in polyethylene production
KR102351569B1 (ko) 2017-12-18 2022-01-14 주식회사 엘지화학 폴리에틸렌 수지 필름
WO2019124817A1 (ko) * 2017-12-18 2019-06-27 주식회사 엘지화학 폴리에틸렌 수지 필름
KR102363189B1 (ko) 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
WO2020083386A1 (zh) * 2018-10-26 2020-04-30 中国石油化工股份有限公司 含介孔材料的聚烯烃催化剂组分及其制备方法和应用
ES2995043T3 (en) 2018-11-05 2025-02-05 Kloner S L Co-extruded multilayer structure and method for obtaining thereof
WO2021126448A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Broad orthogonal distribution polyethylenes for films
EP4077422B1 (de) 2019-12-17 2025-09-10 ExxonMobil Chemical Patents Inc. Polyethylene mit breiter orthogonaler verteilung für filme
EP4084955B1 (de) * 2019-12-31 2024-02-14 Dow Global Technologies LLC Polyethylenzusammensetzungen
EP4101869B1 (de) 2020-08-12 2025-11-05 Lg Chem, Ltd. Verfahren zur herstellung eines metallocen-trägerkatalysators, metallocen-trägerkatalysator und verfahren zur herstellung eines polyolefins damit
US20240117085A1 (en) * 2021-02-01 2024-04-11 China Petroleum & Chemical Corporation Ethylene polymer and preparation method therefor
KR20240117136A (ko) * 2021-12-16 2024-07-31 다우 글로벌 테크놀로지스 엘엘씨 다층 필름

Family Cites Families (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2082153A5 (fr) 1970-03-05 1971-12-10 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
DE2553179A1 (de) 1975-11-27 1977-06-08 Hoechst Ag Verfahren zur herstellung eines katalysators
NL7702323A (nl) 1977-03-04 1978-09-06 Stamicarbon Katalysator voor de bereiding van polyalkenen.
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
DE3015587A1 (de) 1980-04-23 1981-10-29 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von acylcyaniden
US4481301A (en) 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4500648A (en) 1983-04-25 1985-02-19 Exxon Research & Engineering Co. Long chain branching in polyolefins from ziegler-natta catalysts
US4540753A (en) 1983-06-15 1985-09-10 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4626520A (en) 1984-08-06 1986-12-02 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4558024A (en) 1984-08-06 1985-12-10 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE3600610A1 (de) 1986-01-11 1987-07-16 Basf Ag Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreaktoren
BR8704367A (pt) 1986-08-25 1988-04-19 Toa Nenryo Kogyo Kk Processo para a producao de uma borracha de copolimero de etileno-propileno e borracha de copolimero de etileno-propileno
JPS6354408A (ja) * 1986-08-25 1988-03-08 Toa Nenryo Kogyo Kk エチレン・プロピレン共重合体ゴムを製造する方法
FR2618786B1 (fr) 1987-07-31 1989-12-01 Bp Chimie Sa Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5145821A (en) 1990-05-09 1992-09-08 Quantum Chemical Corporation Silica supported polymerization catalyst system
CA1329801C (en) * 1987-09-21 1994-05-24 Charles K. Buehler Modified silica based catalyst
US4803251A (en) 1987-11-04 1989-02-07 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4925821A (en) 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5008204A (en) 1988-02-02 1991-04-16 Exxon Chemical Patents Inc. Method for determining the compositional distribution of a crystalline copolymer
US5008228A (en) 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
RO109545B1 (ro) * 1990-03-30 1995-03-30 Bp Chem Int Ltd Catalizator pentru polimerizarea sau copolimerizarea olefinelor si procedeu de obtinere si utilizare a acestuia
FR2660926B1 (fr) 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5238892A (en) 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
DE69307472T2 (de) 1992-11-10 1997-05-15 Mitsubishi Chem Corp Verfahren zur Herstellung von Alpha-Olefinpolymeren
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5422325A (en) 1993-09-17 1995-06-06 Exxon Chemical Patents Inc. Supported polymerization catalysts, their production and use
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
EP0729477B1 (de) 1993-11-19 1999-10-27 Exxon Chemical Patents Inc. Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
FI95276C (fi) 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
EP0746574B2 (de) 1994-02-14 2005-04-13 Univation Technologies LLC Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
IT1269931B (it) 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5629253A (en) 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
IT1269837B (it) 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US5468702A (en) 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
GB9417211D0 (en) 1994-08-25 1994-10-12 Solicitor For The Affairs Of H Nucleotide sequencing method
KR100368194B1 (ko) 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
US5529965A (en) 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US7153909B2 (en) * 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US5625015A (en) 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
US5714424A (en) 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts
IT1274253B (it) 1995-02-21 1997-07-15 Himont Inc Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine
IT1275412B (it) 1995-06-01 1997-08-05 Enichem Spa Procedimento per la preparazione di ossidi misti silice-allumina porosi in forma sferica
US6489410B1 (en) * 1995-06-07 2002-12-03 W. R. Grace & Co.-Conn. Supported catalyst composition for polymerization of olefins
CA2223258A1 (en) 1995-07-06 1997-01-23 Exxon Chemical Patents, Inc. Method for producing prepolymerized, supported metallocene catalyst systems
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
USRE38429E1 (en) 1996-03-12 2004-02-17 Tyco Plastics Services Ag Stretch wrap films
US5749202A (en) 1996-03-12 1998-05-12 Tenneco Packaging Stretch wrap films
US5902684A (en) 1996-03-12 1999-05-11 Tenneco Packaging Inc. Multilayered Metallocene stretch wrap films
US5752362A (en) 1996-03-12 1998-05-19 Tenneco Packaging Stretch wrap films
US5998017A (en) 1996-03-12 1999-12-07 Tenneco Packaging Stretch wrap films
US5814399A (en) 1996-03-12 1998-09-29 Tenneco Packaging Stretch wrap films
US5723402A (en) 1996-05-30 1998-03-03 Pq Corporation Silicas with specific contents of cations as supports for olefin polymerization catalysts
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
US6093480A (en) 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US5907942A (en) 1997-05-21 1999-06-01 Tenneco Packaging Stretch wrap films
US5907943A (en) 1997-06-11 1999-06-01 Tenneco Packaging Inc. Stretch wrap films
US5922441A (en) 1997-06-11 1999-07-13 Tenneco Packaging Inc. Stretch wrap films
US6423420B1 (en) 1997-08-11 2002-07-23 Exxonmobil Chemical Patents Inc. Oriented coextruded films
US6083611A (en) 1997-11-12 2000-07-04 Tenneco Packaging, Inc. Roll wrap film
US6448348B1 (en) 1998-10-16 2002-09-10 Saudi Basic Industries Corporation Process for polymerizing olefins with supported Ziegler-Natta catalyst systems
US6265055B1 (en) 1999-10-13 2001-07-24 David Simpson Multilayer stretch cling film
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
EP1209179B1 (de) 2000-03-31 2005-11-02 Mitsui Chemicals, Inc. Verfahren zur herstellung einer polyolefinzusammensetzung
JP2003212918A (ja) * 2002-01-29 2003-07-30 Japan Polyolefins Co Ltd エチレン系重合体製造用触媒、エチレン系重合体の製造方法、エチレン系重合体、およびエチレン系重合体の物性制御方法
US7235607B2 (en) 2002-09-05 2007-06-26 Exxonmobil Chemical Patents Inc. Shrink film
DE60335634D1 (de) 2002-09-05 2011-02-17 Exxonmobil Chem Patents Inc Stretchfoliewickelverfahren
WO2004050722A1 (en) 2002-11-29 2004-06-17 Borealis Technology Oy Ziegler natta catalyst system and polymerisation process using said zn catalyst system for producing ethylene copolymers having a broad molecular weight distribution
CN1898090B (zh) 2003-12-18 2010-04-28 陶氏环球技术公司 具有超级耐冲击性和在高应变率下改进的耐灾害性破坏性能的膜
US20070213204A1 (en) 2006-03-10 2007-09-13 Novolen Technology Holdings C.V. Ziegler-Natta catalyst with in situ-generated donor
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
CA2650826A1 (en) 2006-06-27 2007-08-01 Univation Technologies, Llc Improved polymerization processes using metallocene catalysts, their polymer products and end uses
JP5392015B2 (ja) * 2008-11-11 2014-01-22 住友化学株式会社 エチレン−α−オレフィン共重合体及び成形体
BRPI0923985B1 (pt) 2009-03-31 2019-10-08 Dow Global Technologies Llc Película multicamada e artigo fabricado
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
KR20130026531A (ko) 2010-02-22 2013-03-13 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법

Also Published As

Publication number Publication date
JP6181672B2 (ja) 2017-08-16
CN104159933B (zh) 2017-09-12
BR112014020839B1 (pt) 2020-09-29
US20150011719A1 (en) 2015-01-08
EP2800766B1 (de) 2019-09-04
US20170029542A1 (en) 2017-02-02
RU2014140098A (ru) 2016-04-20
KR20140138823A (ko) 2014-12-04
EP2800766A2 (de) 2014-11-12
JP2015509553A (ja) 2015-03-30
RU2640048C2 (ru) 2017-12-26
ES2752139T3 (es) 2020-04-03
SG11201404696VA (en) 2014-12-30
US9487601B2 (en) 2016-11-08
CN104159933A (zh) 2014-11-19
WO2013133956A2 (en) 2013-09-12
KR102053117B1 (ko) 2019-12-06
WO2013133956A3 (en) 2013-12-19
SG10201700111XA (en) 2017-03-30
US9975974B2 (en) 2018-05-22
CA2863694A1 (en) 2013-09-12

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