CA2861854C - Multicomponent degradable materials and use - Google Patents
Multicomponent degradable materials and use Download PDFInfo
- Publication number
- CA2861854C CA2861854C CA2861854A CA2861854A CA2861854C CA 2861854 C CA2861854 C CA 2861854C CA 2861854 A CA2861854 A CA 2861854A CA 2861854 A CA2861854 A CA 2861854A CA 2861854 C CA2861854 C CA 2861854C
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- CA
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- Prior art keywords
- degradable
- polymer
- fiber
- pla
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002841 Lewis acid Substances 0.000 description 1
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
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- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
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- PEECTLLHENGOKU-UHFFFAOYSA-N n,n-dimethylpyridin-4-amine Chemical compound CN(C)C1=CC=NC=C1.CN(C)C1=CC=NC=C1 PEECTLLHENGOKU-UHFFFAOYSA-N 0.000 description 1
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- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 1
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- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- 239000005060 rubber Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000383 tetramethylene group Chemical class [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/12—Physical properties biodegradable
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2916—Rod, strand, filament or fiber including boron or compound thereof [not as steel]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
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- Multicomponent Fibers (AREA)
Applications Claiming Priority (3)
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US201161631174P | 2011-12-28 | 2011-12-28 | |
US61/631,174 | 2011-12-28 | ||
PCT/US2012/071147 WO2013101702A1 (en) | 2011-12-28 | 2012-12-21 | Multicomponent degradable materials and use |
Publications (2)
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CA2861854A1 CA2861854A1 (en) | 2013-07-04 |
CA2861854C true CA2861854C (en) | 2020-03-24 |
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CA2861854A Active CA2861854C (en) | 2011-12-28 | 2012-12-21 | Multicomponent degradable materials and use |
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US (1) | US20140374106A1 (es) |
CN (1) | CN104080960A (es) |
AU (2) | AU2012362642A1 (es) |
BR (1) | BR112014016046A8 (es) |
CA (1) | CA2861854C (es) |
MX (1) | MX2014007816A (es) |
WO (1) | WO2013101702A1 (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20112450A1 (it) * | 2011-12-30 | 2013-07-01 | Eni Spa | Apparato e metodo per monitorare l'integrita' strutturale di una condotta |
WO2015061420A1 (en) * | 2013-10-22 | 2015-04-30 | 3M Innovative Properties Company | Well cement composition including multi-component fibers and method of cementing using the same |
WO2015061553A1 (en) * | 2013-10-23 | 2015-04-30 | Schlumberger Canada Limited | Development and characterization of degradable cross-linking in polyvinyl alcohol |
US9567841B2 (en) * | 2014-07-01 | 2017-02-14 | Research Triangle Institute | Cementitious fracture fluid and methods of use thereof |
US11566349B2 (en) | 2015-03-27 | 2023-01-31 | The United States Of America As Represented By The Secretary Of The Army | High strength 3D-printed polymer structures and methods of formation |
US10774612B2 (en) | 2015-04-28 | 2020-09-15 | Thru Tubing Solutions, Inc. | Flow control in subterranean wells |
US9816341B2 (en) | 2015-04-28 | 2017-11-14 | Thru Tubing Solutions, Inc. | Plugging devices and deployment in subterranean wells |
US10655427B2 (en) | 2015-04-28 | 2020-05-19 | Thru Tubing Solutions, Inc. | Flow control in subterranean wells |
US9745820B2 (en) | 2015-04-28 | 2017-08-29 | Thru Tubing Solutions, Inc. | Plugging device deployment in subterranean wells |
US10513653B2 (en) | 2015-04-28 | 2019-12-24 | Thru Tubing Solutions, Inc. | Flow control in subterranean wells |
US10851615B2 (en) | 2015-04-28 | 2020-12-01 | Thru Tubing Solutions, Inc. | Flow control in subterranean wells |
DK201970186A1 (en) * | 2016-09-20 | 2019-04-03 | Fairmount Santrol Inc. | DEGRADABLE BALL SEALERS WITH IMPROVED SOLUBILITY CHARACTERISTICS |
WO2018182444A1 (ru) | 2017-03-31 | 2018-10-04 | Шлюмберже Канада Лимитед | Способ построения плана гидроразрыва пласта и способ гидроразрыва пласта |
CA3053330C (en) * | 2017-06-15 | 2022-04-26 | Halliburton Energy Services, Inc. | Plasticized polyvinyl alcohol diverter materials |
US10808162B2 (en) | 2017-11-17 | 2020-10-20 | Fairmount Santrol Inc. | Crush resistant buoyant ball sealers |
WO2019122195A1 (en) * | 2017-12-21 | 2019-06-27 | Beaulieu International Group Nv | Biodegradable fabric and use of such fabric |
JPWO2020138252A1 (ja) * | 2018-12-27 | 2021-11-18 | 三菱ケミカル株式会社 | ダイバーティングエージェント及びこれを用いた坑井の亀裂の閉塞方法 |
CN110157403B (zh) * | 2019-05-08 | 2020-09-29 | 中国石油大学(北京) | 一种低渗透油藏驱油剂 |
EP3990686B1 (en) | 2019-06-26 | 2024-01-03 | 3M Innovative Properties Company | Method of making a nonwoven fiber web, and a nonwoven fiber web |
CN114401703A (zh) * | 2019-09-25 | 2022-04-26 | 3M创新有限公司 | 伤口敷料材料及其制造和使用方法 |
US11945154B2 (en) * | 2019-11-18 | 2024-04-02 | Pablo Gabriel de León | Printer and printing method for space and pressure suits using additive manufacturing |
CN111269582B (zh) * | 2020-03-31 | 2022-11-08 | 宁波普莱斯帝金属制品有限公司 | 一种木粉/聚乳酸可降解复合材料的制备方法 |
CN111234321B (zh) * | 2020-03-31 | 2021-11-12 | 深圳市富恒新材料股份有限公司 | 一种可快速降解的淀粉/聚乳酸复合材料的制备方法 |
US11767462B2 (en) * | 2020-05-22 | 2023-09-26 | Kuraray Co., Ltd. | Polyvinyl alcohol-based particulate compositions |
US20230190988A1 (en) * | 2020-06-12 | 2023-06-22 | 3M Innovative Properties Company | Wound Dressing Material and Methods of Making and Using the Same |
CN111961323B (zh) * | 2020-08-28 | 2022-11-22 | 上海浦景化工技术股份有限公司 | 一种适用于低温井的可降解材料及其制备方法与应用 |
US20230372578A1 (en) * | 2020-09-23 | 2023-11-23 | 3M Innovative Properties Company | Wound Dressing Material and Methods of Making and Using the Same |
CN114130123B (zh) * | 2021-12-01 | 2023-03-28 | 江苏舒源空调制造有限公司 | 一种抗菌防霉空气净化材料及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5814404A (en) * | 1994-06-03 | 1998-09-29 | Minnesota Mining And Manufacturing Company | Degradable multilayer melt blown microfibers |
US6579814B1 (en) * | 1994-12-30 | 2003-06-17 | 3M Innovative Properties Company | Dispersible compositions and articles of sheath-core microfibers and method of disposal for such compositions and articles |
JP3499053B2 (ja) * | 1995-07-26 | 2004-02-23 | ユニチカ株式会社 | 生分解性ポリエステル繊維 |
US5698322A (en) * | 1996-12-02 | 1997-12-16 | Kimberly-Clark Worldwide, Inc. | Multicomponent fiber |
US20020168912A1 (en) * | 2001-05-10 | 2002-11-14 | Bond Eric Bryan | Multicomponent fibers comprising starch and biodegradable polymers |
EP1464737B1 (en) * | 2001-06-15 | 2009-08-05 | Kuraray Co., Ltd. | Composite fiber |
US6782781B2 (en) * | 2001-07-23 | 2004-08-31 | Scandus Trading Company, Llc | Saw blade for reciprocating saw apparatus |
CN1239523C (zh) * | 2002-12-26 | 2006-02-01 | 中国石油化工股份有限公司北京燕山分公司研究院 | 脱除聚合物溶液中挥发性组分的方法 |
AU2003241790A1 (en) * | 2003-05-27 | 2005-01-21 | Asahi Kasei Kabushiki Kaisha | Biodegradable resin film or sheet and process for producing the same |
US7380600B2 (en) * | 2004-09-01 | 2008-06-03 | Schlumberger Technology Corporation | Degradable material assisted diversion or isolation |
US7267170B2 (en) * | 2005-01-31 | 2007-09-11 | Halliburton Energy Services, Inc. | Self-degrading fibers and associated methods of use and manufacture |
US20100029161A1 (en) * | 2005-06-24 | 2010-02-04 | North Carolina State University | Microdenier fibers and fabrics incorporating elastomers or particulate additives |
US8230936B2 (en) * | 2005-08-31 | 2012-07-31 | Schlumberger Technology Corporation | Methods of forming acid particle based packers for wellbores |
CN101139752B (zh) * | 2006-09-06 | 2014-07-16 | 远东新世纪股份有限公司 | 具有生物可分解性的热融着复合纤维 |
US20110028062A1 (en) * | 2008-02-14 | 2011-02-03 | Chester Stephen O | Bicomponent fibers, textile sheets and use thereof |
KR101404296B1 (ko) * | 2010-06-07 | 2014-06-09 | (주)엘지하우시스 | 직물 표면을 갖는 pla 바닥재 |
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2012
- 2012-12-21 WO PCT/US2012/071147 patent/WO2013101702A1/en active Application Filing
- 2012-12-21 MX MX2014007816A patent/MX2014007816A/es unknown
- 2012-12-21 CN CN201280068242.3A patent/CN104080960A/zh active Pending
- 2012-12-21 CA CA2861854A patent/CA2861854C/en active Active
- 2012-12-21 US US14/369,451 patent/US20140374106A1/en not_active Abandoned
- 2012-12-21 BR BR112014016046A patent/BR112014016046A8/pt not_active IP Right Cessation
- 2012-12-21 AU AU2012362642A patent/AU2012362642A1/en not_active Abandoned
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2017
- 2017-08-21 AU AU2017218922A patent/AU2017218922A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
WO2013101702A1 (en) | 2013-07-04 |
CN104080960A (zh) | 2014-10-01 |
BR112014016046A2 (pt) | 2017-06-13 |
AU2017218922A1 (en) | 2017-09-07 |
US20140374106A1 (en) | 2014-12-25 |
BR112014016046A8 (pt) | 2017-07-04 |
CA2861854A1 (en) | 2013-07-04 |
MX2014007816A (es) | 2014-09-01 |
AU2012362642A1 (en) | 2014-07-03 |
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