CA2838907A1 - Process for the preparation of formic acid by reacting carbon dioxide with hydrogen - Google Patents
Process for the preparation of formic acid by reacting carbon dioxide with hydrogen Download PDFInfo
- Publication number
- CA2838907A1 CA2838907A1 CA2838907A CA2838907A CA2838907A1 CA 2838907 A1 CA2838907 A1 CA 2838907A1 CA 2838907 A CA2838907 A CA 2838907A CA 2838907 A CA2838907 A CA 2838907A CA 2838907 A1 CA2838907 A1 CA 2838907A1
- Authority
- CA
- Canada
- Prior art keywords
- phase
- formic acid
- tertiary amine
- mixture
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
- B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11173130 | 2011-07-07 | ||
EP11173130.3 | 2011-07-07 | ||
PCT/EP2012/062518 WO2013004577A1 (de) | 2011-07-07 | 2012-06-27 | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2838907A1 true CA2838907A1 (en) | 2013-01-10 |
Family
ID=46397263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2838907A Abandoned CA2838907A1 (en) | 2011-07-07 | 2012-06-27 | Process for the preparation of formic acid by reacting carbon dioxide with hydrogen |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP2729438A1 (ja) |
JP (1) | JP2014522823A (ja) |
KR (1) | KR20140044891A (ja) |
CN (1) | CN103649036A (ja) |
BR (1) | BR112013033528A2 (ja) |
CA (1) | CA2838907A1 (ja) |
RU (1) | RU2014104137A (ja) |
WO (1) | WO2013004577A1 (ja) |
ZA (1) | ZA201400863B (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8946462B2 (en) | 2011-11-10 | 2015-02-03 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
EP3710420A4 (en) * | 2017-11-15 | 2021-08-04 | Solvay SA | FORMIC ACID PRODUCTION PROCESS |
EP4089177A1 (en) | 2021-05-14 | 2022-11-16 | Cebal - Centro De Biotecnologia Agrícola E Agro-Alimentar Do Alentejo | Process for the production of formic acid using e. coli strains |
CN117138775B (zh) * | 2023-07-24 | 2024-04-30 | 昆明贵金属研究所 | 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1220222A (en) | 1982-05-22 | 1987-04-07 | David J. Drury | Production of formate salts |
GB8307611D0 (en) | 1983-03-18 | 1983-04-27 | Bp Chem Int Ltd | Formic acid |
GB8401005D0 (en) * | 1984-01-14 | 1984-02-15 | Bp Chem Int Ltd | Formate salts |
GB8424672D0 (en) | 1984-09-29 | 1984-11-07 | Bp Chem Int Ltd | Production of formic acid |
NZ227890A (en) * | 1988-02-17 | 1992-02-25 | Bp Chemical Ltd | Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen |
DE68920933T2 (de) * | 1988-08-20 | 1995-05-24 | Bp Chem Int Ltd | Produktion von Formiat-Salzen von Stickstoffbasen. |
DE102004040789A1 (de) * | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
JP2010521533A (ja) * | 2007-03-23 | 2010-06-24 | ビーエーエスエフ ソシエタス・ヨーロピア | 蟻酸の製造方法 |
CN102574762B (zh) | 2009-06-26 | 2014-08-13 | 巴斯夫欧洲公司 | 生产甲酸的方法 |
UA104324C2 (ru) * | 2009-06-26 | 2014-01-27 | Басф Се | Способ получения муравьиной кислоты |
-
2012
- 2012-06-27 EP EP12730532.4A patent/EP2729438A1/de not_active Withdrawn
- 2012-06-27 JP JP2014517690A patent/JP2014522823A/ja active Pending
- 2012-06-27 KR KR1020147002909A patent/KR20140044891A/ko not_active Application Discontinuation
- 2012-06-27 CA CA2838907A patent/CA2838907A1/en not_active Abandoned
- 2012-06-27 WO PCT/EP2012/062518 patent/WO2013004577A1/de active Application Filing
- 2012-06-27 RU RU2014104137/04A patent/RU2014104137A/ru not_active Application Discontinuation
- 2012-06-27 BR BR112013033528A patent/BR112013033528A2/pt not_active IP Right Cessation
- 2012-06-27 CN CN201280033657.7A patent/CN103649036A/zh active Pending
-
2014
- 2014-02-05 ZA ZA2014/00863A patent/ZA201400863B/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2013004577A1 (de) | 2013-01-10 |
EP2729438A1 (de) | 2014-05-14 |
CN103649036A (zh) | 2014-03-19 |
RU2014104137A (ru) | 2015-08-20 |
JP2014522823A (ja) | 2014-09-08 |
KR20140044891A (ko) | 2014-04-15 |
ZA201400863B (en) | 2015-12-23 |
BR112013033528A2 (pt) | 2017-02-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Dead |
Effective date: 20160629 |