CA2838907A1 - Procede de production d'acide formique par reaction de dioxyde de carbone avec de l'hydrogene - Google Patents

Procede de production d'acide formique par reaction de dioxyde de carbone avec de l'hydrogene Download PDF

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Publication number
CA2838907A1
CA2838907A1 CA2838907A CA2838907A CA2838907A1 CA 2838907 A1 CA2838907 A1 CA 2838907A1 CA 2838907 A CA2838907 A CA 2838907A CA 2838907 A CA2838907 A CA 2838907A CA 2838907 A1 CA2838907 A1 CA 2838907A1
Authority
CA
Canada
Prior art keywords
phase
formic acid
tertiary amine
mixture
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2838907A
Other languages
English (en)
Inventor
Thomas Schaub
Donata Maria Fries
Rocco Paciello
Peter Bassler
Martin Schafer
Stefan Rittinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2838907A1 publication Critical patent/CA2838907A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2838907A 2011-07-07 2012-06-27 Procede de production d'acide formique par reaction de dioxyde de carbone avec de l'hydrogene Abandoned CA2838907A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11173130.3 2011-07-07
EP11173130 2011-07-07
PCT/EP2012/062518 WO2013004577A1 (fr) 2011-07-07 2012-06-27 Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène

Publications (1)

Publication Number Publication Date
CA2838907A1 true CA2838907A1 (fr) 2013-01-10

Family

ID=46397263

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2838907A Abandoned CA2838907A1 (fr) 2011-07-07 2012-06-27 Procede de production d'acide formique par reaction de dioxyde de carbone avec de l'hydrogene

Country Status (9)

Country Link
EP (1) EP2729438A1 (fr)
JP (1) JP2014522823A (fr)
KR (1) KR20140044891A (fr)
CN (1) CN103649036A (fr)
BR (1) BR112013033528A2 (fr)
CA (1) CA2838907A1 (fr)
RU (1) RU2014104137A (fr)
WO (1) WO2013004577A1 (fr)
ZA (1) ZA201400863B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8946462B2 (en) 2011-11-10 2015-02-03 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US9428438B2 (en) 2012-11-27 2016-08-30 Basf Se Process for preparing formic acid
WO2019096190A1 (fr) * 2017-11-15 2019-05-23 Solvay Sa Procédé de production d'acide formique
EP4089177A1 (fr) 2021-05-14 2022-11-16 Cebal - Centro De Biotecnologia Agrícola E Agro-Alimentar Do Alentejo Procédé de production d'acide formique utilisant des souches de e. coli
CN117138775B (zh) * 2023-07-24 2024-04-30 昆明贵金属研究所 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1220222A (fr) 1982-05-22 1987-04-07 David J. Drury Production des sels de formates
GB8307611D0 (en) 1983-03-18 1983-04-27 Bp Chem Int Ltd Formic acid
GB8401005D0 (en) * 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
NZ227890A (en) * 1988-02-17 1992-02-25 Bp Chemical Ltd Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen
EP0357243B1 (fr) * 1988-08-20 1995-02-01 BP Chemicals Limited Production de sels formiques de bases azotées
DE102004040789A1 (de) 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure
EP2139837A1 (fr) * 2007-03-23 2010-01-06 Basf Se Procédé de production d'acide formique
UA104324C2 (ru) * 2009-06-26 2014-01-27 Басф Се Способ получения муравьиной кислоты
PL2445860T3 (pl) 2009-06-26 2013-10-31 Basf Se Sposób wytwarzania kwasu mrówkowego

Also Published As

Publication number Publication date
BR112013033528A2 (pt) 2017-02-07
KR20140044891A (ko) 2014-04-15
JP2014522823A (ja) 2014-09-08
ZA201400863B (en) 2015-12-23
EP2729438A1 (fr) 2014-05-14
RU2014104137A (ru) 2015-08-20
WO2013004577A1 (fr) 2013-01-10
CN103649036A (zh) 2014-03-19

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Legal Events

Date Code Title Description
FZDE Dead

Effective date: 20160629