CA2799986C - Thiobis phenolic antioxidant/polyethylene glycol blends - Google Patents

Thiobis phenolic antioxidant/polyethylene glycol blends Download PDF

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Publication number
CA2799986C
CA2799986C CA2799986A CA2799986A CA2799986C CA 2799986 C CA2799986 C CA 2799986C CA 2799986 A CA2799986 A CA 2799986A CA 2799986 A CA2799986 A CA 2799986A CA 2799986 C CA2799986 C CA 2799986C
Authority
CA
Canada
Prior art keywords
blend
pag
thiobis
phenolic antioxidant
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2799986A
Other languages
English (en)
French (fr)
Other versions
CA2799986A1 (en
Inventor
Antoni Adamczyk
Daniel Emley
Neil Dunchus
Jeffrey M. Cogen
Susan Song
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of CA2799986A1 publication Critical patent/CA2799986A1/en
Application granted granted Critical
Publication of CA2799986C publication Critical patent/CA2799986C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/375—Thiols containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/32—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes natural resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
    • H01B3/427—Polyethers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/22—Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CA2799986A 2010-06-10 2011-06-08 Thiobis phenolic antioxidant/polyethylene glycol blends Expired - Fee Related CA2799986C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US35328610P 2010-06-10 2010-06-10
US61/353,286 2010-06-10
US201161488375P 2011-05-20 2011-05-20
US61/488,375 2011-05-20
PCT/US2011/039546 WO2011156442A1 (en) 2010-06-10 2011-06-08 Thiobis phenolic antioxidant/polyethylene glycol blends

Publications (2)

Publication Number Publication Date
CA2799986A1 CA2799986A1 (en) 2011-12-15
CA2799986C true CA2799986C (en) 2017-03-07

Family

ID=44318171

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2799986A Expired - Fee Related CA2799986C (en) 2010-06-10 2011-06-08 Thiobis phenolic antioxidant/polyethylene glycol blends

Country Status (10)

Country Link
US (2) US8691904B2 (enExample)
EP (1) EP2580276A1 (enExample)
JP (1) JP5784113B2 (enExample)
KR (1) KR101987080B1 (enExample)
CN (1) CN103052677B (enExample)
BR (1) BR112012031115A2 (enExample)
CA (1) CA2799986C (enExample)
MX (1) MX346666B (enExample)
TW (1) TWI523901B (enExample)
WO (1) WO2011156442A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5784113B2 (ja) * 2010-06-10 2015-09-24 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー チオビスフェノール酸化防止剤／ポリエチレングリコールブレンド
JP5848442B2 (ja) * 2011-05-20 2016-01-27 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー チオビスフェノール系酸化防止剤／ポリエチレングリコールのブレンド
CN107245163B (zh) * 2013-09-13 2019-09-24 陶氏环球技术有限责任公司 过氧化物可交联的组合物及其制造方法
KR102628199B1 (ko) * 2018-06-29 2024-01-24 다우 글로벌 테크놀로지스 엘엘씨 폴리(2-알킬-2-옥사졸린)을 갖는 폴리올레핀 제제
CN111471236A (zh) * 2020-04-10 2020-07-31 天津大学 一种聚丙烯电缆绝缘材料及其制备方法、用途
US20240392129A1 (en) 2021-09-30 2024-11-28 Exxonmobil Chemical Patents Inc. Fluoropolymer-free processing aids for ethylene-based polymers
WO2023056208A1 (en) 2021-09-30 2023-04-06 Exxonmobil Chemical Patents Inc. Fluorine-free polymer processing aids including polyethylene glycols
WO2023149984A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. Polyethylene glycol-based polymer processing aids
WO2023154744A1 (en) 2022-02-14 2023-08-17 Exxonmobil Chemical Patents Inc. Polyethylene glycol-based polymer processing aids
US12674049B2 (en) 2024-10-25 2026-07-07 ExxonMobil Technology and Engineering Company Polymer processing aids

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US331809A (en) 1885-12-08 Eobeet bueans motheewell
BE607527A (enExample) 1960-08-29 1900-01-01
GB1052968A (enExample) * 1963-12-14
DE1211389B (de) * 1964-04-10 1966-02-24 Hoechst Ag Stabilisieren von polymeren Homo- oder Copolymerisaten von Alkylenoxyden
US4088622A (en) * 1976-06-25 1978-05-09 The United States Of America As Represented By The Secretary Of The Navy Molded drag reduction coatings
US4101445A (en) 1976-09-22 1978-07-18 Union Carbide Corporation Preparation of modified and activated chromocene catalysts for ethylene polymerization
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
JPS5628231A (en) * 1979-08-16 1981-03-19 Nippon Yunikaa Kk Polyolefin composition for electrical insulation
US4440671A (en) 1982-03-31 1984-04-03 Union Carbide Corporation Compositions of hydrocarbon-substituted diphenyl amines and high molecular weight polyethylene glycols; and the use thereof as water-tree retardants for polymers
US4508842A (en) 1983-03-29 1985-04-02 Union Carbide Corporation Ethylene polymerization using supported vanadium catalyst
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4857600A (en) 1988-05-23 1989-08-15 Union Carbide Corporation Process for grafting diacid anhydrides
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5371145A (en) 1993-06-08 1994-12-06 Union Carbide Chemicals & Plastics Technology Corporation High density, high molecular weight polyethylene
US5342907A (en) 1993-06-28 1994-08-30 Union Carbide Chemicals & Plastics Technology Corporation Ethylene/propylene copolymer rubbers
US5332793A (en) 1993-06-28 1994-07-26 Union Carbide Chemicals & Plastics Technology Corporation Ethylene/propylene copolymer rubbers
US5410003A (en) 1994-03-31 1995-04-25 Union Carbide Chemicals & Plastics Technology Corporation Process for production of homogeneous polyethylenes
US5405901A (en) 1994-07-06 1995-04-11 Union Carbide Chemicals & Plastics Technology Corporation Process of producing ethylene polymer blends in gas phase
ZA973884B (en) 1996-05-23 1998-11-06 Du Pont Merck Pharma Tetrahydropteridines and pyridylpiperazines for treatment of neurological disorders
US6404890B1 (en) 1998-04-08 2002-06-11 Citibank, Na Generating RSA moduli including a predetermined portion
US6180706B1 (en) 1998-06-16 2001-01-30 Union Carbide Chemicals & Plastics Technology Corporation Crosslinkable high pressure low density polyethylene composition
TWI224607B (en) 1998-06-16 2004-12-01 Union Carbide Chem Plastic Tree resistant cable
US6496629B2 (en) 1999-05-28 2002-12-17 Tycom (Us) Inc. Undersea telecommunications cable
JP2001019811A (ja) 1999-07-06 2001-01-23 Nippon Unicar Co Ltd 非ブルーミング性ポリオレフィン系樹脂組成物及び成形品
US6714707B2 (en) 2002-01-24 2004-03-30 Alcatel Optical cable housing an optical unit surrounded by a plurality of gel layers
US20050148715A1 (en) 2002-01-28 2005-07-07 Caronia Paul J. Water tree resistant cable
EP1571175B1 (en) * 2002-11-29 2015-08-12 Zeon Corporation Process for producing polyether polymer composition, polyether polymer composition, and solid electrolyte film
GB0508350D0 (en) 2005-04-26 2005-06-01 Great Lakes Chemical Europ Stabilized crosslinked polyolefin compositions
DK1731564T3 (da) * 2005-06-08 2010-06-14 Borealis Tech Oy Sammensætning til hæmning af vandtræ
WO2007097511A1 (en) * 2006-02-24 2007-08-30 Lg Chem, Ltd. Cross-linked polyethylene having excellent inhibition of sweat-out and insulation properties
KR100727207B1 (ko) * 2006-02-24 2007-06-13 주식회사 엘지화학 스웨트-아웃 억제 및 전기 절연특성이 우수한 가교 폴리에틸렌 조성물
EP2516544B1 (en) * 2009-12-21 2016-12-21 Union Carbide Chemicals & Plastics Technology LLC Medium voltage cable insulation
JP5784113B2 (ja) * 2010-06-10 2015-09-24 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー チオビスフェノール酸化防止剤／ポリエチレングリコールブレンド

Also Published As

Publication number Publication date
TW201211127A (en) 2012-03-16
TWI523901B (zh) 2016-03-01
MX346666B (es) 2017-03-28
EP2580276A1 (en) 2013-04-17
MX2012014296A (es) 2013-02-12
JP5784113B2 (ja) 2015-09-24
CA2799986A1 (en) 2011-12-15
BR112012031115A2 (pt) 2016-11-01
CN103052677A (zh) 2013-04-17
KR101987080B1 (ko) 2019-06-10
KR20130088826A (ko) 2013-08-08
CN103052677B (zh) 2016-03-16
US9187629B2 (en) 2015-11-17
JP2013528249A (ja) 2013-07-08
US8691904B2 (en) 2014-04-08
WO2011156442A1 (en) 2011-12-15
US20130068498A1 (en) 2013-03-21
US20140134436A1 (en) 2014-05-15

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