CA2787227C - Common solvent process for producing high molecular weight brominated rubber - Google Patents

Common solvent process for producing high molecular weight brominated rubber Download PDF

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Publication number
CA2787227C
CA2787227C CA2787227A CA2787227A CA2787227C CA 2787227 C CA2787227 C CA 2787227C CA 2787227 A CA2787227 A CA 2787227A CA 2787227 A CA2787227 A CA 2787227A CA 2787227 C CA2787227 C CA 2787227C
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CA
Canada
Prior art keywords
rubber
process according
medium
monomer
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2787227A
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English (en)
French (fr)
Other versions
CA2787227A1 (en
Inventor
Adam Gronowski
Carsten Kreuder
John Lovegrove
Paul Nguyen
David Thompson
Hanns-Ingolf Paul
Rolf Feller
Udo Wiesner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arlanxeo Deutschland GmbH
Original Assignee
Arlanxeo Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of CA2787227A1 publication Critical patent/CA2787227A1/en
Application granted granted Critical
Publication of CA2787227C publication Critical patent/CA2787227C/en
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/12—Incorporating halogen atoms into the molecule
    • C08C19/14—Incorporating halogen atoms into the molecule by reaction with halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/001—Removal of residual monomers by physical means
    • C08F6/003—Removal of residual monomers by physical means from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2787227A 2010-01-20 2011-01-17 Common solvent process for producing high molecular weight brominated rubber Active CA2787227C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10000515 2010-01-20
EP10000515.6 2010-01-20
PCT/EP2011/050529 WO2011089091A1 (en) 2010-01-20 2011-01-17 Common solvent process for producing high molecular weight brominated rubber

Publications (2)

Publication Number Publication Date
CA2787227A1 CA2787227A1 (en) 2011-07-28
CA2787227C true CA2787227C (en) 2018-01-16

Family

ID=42173467

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2787227A Active CA2787227C (en) 2010-01-20 2011-01-17 Common solvent process for producing high molecular weight brominated rubber

Country Status (14)

Country Link
US (1) US9273160B2 (enExample)
EP (1) EP2526123B1 (enExample)
JP (1) JP5703311B2 (enExample)
KR (1) KR101473542B1 (enExample)
CN (1) CN102770461B (enExample)
CA (1) CA2787227C (enExample)
ES (1) ES2492521T3 (enExample)
IN (1) IN2012DN06386A (enExample)
MY (1) MY159846A (enExample)
RU (1) RU2584424C2 (enExample)
SA (1) SA111320111B1 (enExample)
SG (1) SG182530A1 (enExample)
TW (1) TWI513707B (enExample)
WO (1) WO2011089091A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011089092A1 (en) * 2010-01-20 2011-07-28 Lanxess International Sa Common solvent process for producing high molecular weight halogenated rubber
KR101412845B1 (ko) * 2010-03-24 2014-06-27 란세스 인터내쇼날 에스에이 무수 무용매 중합체의 제조 방법
PL2734555T3 (pl) 2011-07-20 2020-11-16 Arlanxeo Deutschland Gmbh Sposób wytwarzania bromowanego kauczuku butylowego
CN103467636B (zh) * 2013-09-29 2015-08-19 浙江信汇合成新材料有限公司 一种溴化丁基橡胶的生产工艺
EP3137519B1 (en) * 2014-04-30 2020-07-29 Arlanxeo Singapore Pte. Ltd. Butyl rubber with new sequence distribution
CN105218719B (zh) * 2014-06-16 2017-06-06 中国石油化工股份有限公司 制备卤化丁基橡胶的方法及由此得到的卤化丁基橡胶
CN107075006B (zh) * 2014-09-30 2020-11-03 埃克森美孚化学专利公司 用于制备具有改善的门尼粘度稳定性的卤化弹性体的方法
SG11202105927SA (en) 2018-12-17 2021-07-29 Arlanxeo Singapore Pte Ltd Process for the production of isoolefin polymers using a tertiary ether
CN113366032B (zh) * 2018-12-21 2024-01-23 阿朗新科新加坡私人有限公司 用于卤化不饱和异烯烃共聚物的湿法中的卤素回收
CA3122591A1 (en) 2018-12-27 2020-07-02 Arlanxeo Singapore Pte. Ltd. Process for producing chlorinated butyl rubber
US12344699B2 (en) 2020-09-18 2025-07-01 Lg Chem, Ltd. Method for halogenating isobutene-isoprene copolymer
CN114432721B (zh) * 2020-11-03 2023-09-15 北京诺维新材科技有限公司 一种聚合物溶液的提浓方法及其应用
CN116601182B (zh) * 2020-12-11 2026-02-27 阿朗新科新加坡私人有限公司 在用于卤化不饱和异烯烃共聚物的方法中使用含k+氧化剂的卤素回收
TWI881025B (zh) * 2021-01-25 2025-04-21 優顯科技股份有限公司 電子裝置及其製造方法

Family Cites Families (17)

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US3018275A (en) * 1958-12-30 1962-01-23 Exxon Research Engineering Co Halogenation of low unsaturation rubbery polymers in the presence of oxidizing agen
US3257349A (en) 1963-09-17 1966-06-21 Exxon Research Engineering Co Purifying recycle streams in integrated process for preparing halogenated butyl rubber and butyl rubber latex
US3361725A (en) * 1965-06-02 1968-01-02 Exxon Research Engineering Co Process for preparation of solution butyl rubbers using a major amount of air2x and a minor amount of airx2 as catalyst
CA1019095A (en) 1973-06-25 1977-10-11 Lev N. Vladykin Method for preparing butyl rubber
IT1134567B (it) 1980-12-03 1986-08-13 Ente Giprokautchuk L Reattore per la polimerizzazione di idrocarburi in soluzione od in sospensione
US5021509A (en) 1989-09-01 1991-06-04 Exxon Chemical Patents Inc. Butyl rubber compositions having improved adhesion to polyester
US5077345A (en) 1990-03-01 1991-12-31 Exxon Chemical Patents Inc. Halogenation of polymers with improved neutralization
IT1270944B (it) * 1993-02-10 1997-05-26 Pressindustria A G Procedimento continuo e impianto di alogenazione di elastomeri.
DE4437931A1 (de) 1994-10-24 1996-04-25 Bayer Ag Verfahren zur Bromierung von Alkylkautschuken
CA2174794C (en) * 1996-04-23 2009-09-22 Gabor Kaszas Improved polymer bromination process in solution
CA2174795C (en) 1996-04-23 2009-11-03 Gabor Kaszas Improved polymer bromination process
US5681901A (en) * 1996-07-24 1997-10-28 Exxon Chemical Patents Inc. Process for halogenating isomonoolefin copolymers
CA2252295C (en) 1998-10-30 2007-07-17 Bayer Inc. Improved process for preparation of butyl rubber utilizing activated alkylaluminum halides
TWI229089B (en) * 2000-12-12 2005-03-11 Bayer Ag Halogenated, high molecular weight, gel-free isobutene copolymers with elevated double bond contents
RU2212416C2 (ru) * 2001-01-17 2003-09-20 Открытое акционерное общество "Нижнекамскнефтехим" Способ получения бромбутилкаучука
CA2604409C (en) * 2006-12-22 2015-04-07 Lanxess Inc. Butyl rubber ionomer nanocomposites
KR101281343B1 (ko) 2008-07-15 2013-07-02 란세스 인터내쇼날 에스에이 고분자량 할로부틸 고무를 제조하기 위한 공통 용매 방법

Also Published As

Publication number Publication date
TW201139465A (en) 2011-11-16
US20130131281A1 (en) 2013-05-23
IN2012DN06386A (enExample) 2015-10-02
CN102770461A (zh) 2012-11-07
CN102770461B (zh) 2014-11-05
KR20120107137A (ko) 2012-09-28
ES2492521T3 (es) 2014-09-09
RU2584424C2 (ru) 2016-05-20
JP2013517361A (ja) 2013-05-16
TWI513707B (zh) 2015-12-21
WO2011089091A1 (en) 2011-07-28
CA2787227A1 (en) 2011-07-28
KR101473542B1 (ko) 2014-12-16
RU2012135379A (ru) 2014-02-27
MY159846A (en) 2017-02-15
US9273160B2 (en) 2016-03-01
JP5703311B2 (ja) 2015-04-15
SG182530A1 (en) 2012-08-30
EP2526123B1 (en) 2014-05-21
EP2526123A1 (en) 2012-11-28
SA111320111B1 (ar) 2014-01-17

Similar Documents

Publication Publication Date Title
US9273160B2 (en) Common solvent process for producing high molecular weight brominated rubber
CA2787228C (en) Common solvent process for producing high molecular weight halogenated rubber
CA2730624C (en) Common solvent process for producing high molecular weight halobutyl rubber
CA2787122C (en) Process for production of halobutyl ionomers
EP2526127B1 (en) Process for production of polymer nanocomposites

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