CA2766279A1 - Hydrophilic porous layer for fuel cells, gas diffusion electrode and manufacturing method thereof, and membrane electrode assembly - Google Patents
Hydrophilic porous layer for fuel cells, gas diffusion electrode and manufacturing method thereof, and membrane electrode assembly Download PDFInfo
- Publication number
- CA2766279A1 CA2766279A1 CA2766279A CA2766279A CA2766279A1 CA 2766279 A1 CA2766279 A1 CA 2766279A1 CA 2766279 A CA2766279 A CA 2766279A CA 2766279 A CA2766279 A CA 2766279A CA 2766279 A1 CA2766279 A1 CA 2766279A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrophilic
- electrically conductive
- water
- conductive material
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 69
- 238000009792 diffusion process Methods 0.000 title claims description 120
- 239000012528 membrane Substances 0.000 title claims description 108
- 238000004519 manufacturing process Methods 0.000 title description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 218
- 239000000463 material Substances 0.000 claims abstract description 209
- 239000004020 conductor Substances 0.000 claims abstract description 153
- 239000003054 catalyst Substances 0.000 claims description 164
- 239000007789 gas Substances 0.000 claims description 124
- 239000011148 porous material Substances 0.000 claims description 62
- 238000000034 method Methods 0.000 claims description 59
- 239000002245 particle Substances 0.000 claims description 43
- 239000002904 solvent Substances 0.000 claims description 34
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 23
- 238000001035 drying Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000011163 secondary particle Substances 0.000 claims description 9
- 239000011164 primary particle Substances 0.000 claims description 6
- 238000010306 acid treatment Methods 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 343
- 239000000976 ink Substances 0.000 description 67
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 66
- 210000004027 cell Anatomy 0.000 description 58
- 239000003792 electrolyte Substances 0.000 description 45
- 239000007788 liquid Substances 0.000 description 42
- 229910052799 carbon Inorganic materials 0.000 description 35
- 239000002585 base Substances 0.000 description 33
- 229920000867 polyelectrolyte Polymers 0.000 description 28
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 230000002940 repellent Effects 0.000 description 17
- 239000005871 repellent Substances 0.000 description 17
- 238000009835 boiling Methods 0.000 description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 239000005518 polymer electrolyte Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 239000011230 binding agent Substances 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 239000002253 acid Substances 0.000 description 13
- 239000003575 carbonaceous material Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000007791 liquid phase Substances 0.000 description 12
- 238000005259 measurement Methods 0.000 description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 12
- 239000004810 polytetrafluoroethylene Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 229910052731 fluorine Inorganic materials 0.000 description 11
- 238000006722 reduction reaction Methods 0.000 description 11
- 238000010276 construction Methods 0.000 description 10
- 230000005611 electricity Effects 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000012808 vapor phase Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000011737 fluorine Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- -1 Ketchen Black Chemical compound 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 210000000170 cell membrane Anatomy 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
- 239000006230 acetylene black Substances 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 229920000557 Nafion® Polymers 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 239000004917 carbon fiber Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000007792 gaseous phase Substances 0.000 description 5
- 238000005087 graphitization Methods 0.000 description 5
- 229920000554 ionomer Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000002033 PVDF binder Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 125000001153 fluoro group Chemical group F* 0.000 description 4
- 239000002737 fuel gas Substances 0.000 description 4
- 150000002739 metals Chemical group 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 101100365516 Mus musculus Psat1 gene Proteins 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000007731 hot pressing Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000010023 transfer printing Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 229940083957 1,2-butanediol Drugs 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 206010011878 Deafness Diseases 0.000 description 2
- 229920003935 Flemion® Polymers 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910021383 artificial graphite Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 239000006231 channel black Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000006233 lamp black Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 239000002116 nanohorn Substances 0.000 description 2
- 229910021382 natural graphite Inorganic materials 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 2
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 2
- 239000006234 thermal black Substances 0.000 description 2
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- PAKNPEMFWIUWQV-UHFFFAOYSA-N 1,2-difluoro-2-(2-fluorophenyl)ethenesulfonic acid Chemical compound OS(=O)(=O)C(F)=C(F)C1=CC=CC=C1F PAKNPEMFWIUWQV-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920003934 Aciplex® Polymers 0.000 description 1
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 206010016275 Fear Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- MAHPNPYYQAIOJN-UHFFFAOYSA-N azimsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C2=NN(C)N=N2)C)=N1 MAHPNPYYQAIOJN-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000006023 eutectic alloy Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Composite Materials (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009153012 | 2009-06-26 | ||
| JP2009-153012 | 2009-06-26 | ||
| PCT/JP2010/060825 WO2010150870A1 (ja) | 2009-06-26 | 2010-06-25 | 燃料電池用親水性多孔質層、ガス拡散電極およびその製造方法、ならびに膜電極接合体 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2766279A1 true CA2766279A1 (en) | 2010-12-29 |
Family
ID=43386639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2766279A Abandoned CA2766279A1 (en) | 2009-06-26 | 2010-06-25 | Hydrophilic porous layer for fuel cells, gas diffusion electrode and manufacturing method thereof, and membrane electrode assembly |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20120100461A1 (https=) |
| EP (1) | EP2448047A1 (https=) |
| JP (1) | JP5488254B2 (https=) |
| CN (1) | CN102804466B (https=) |
| CA (1) | CA2766279A1 (https=) |
| WO (1) | WO2010150870A1 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012053303A1 (ja) * | 2010-10-22 | 2012-04-26 | 日産自動車株式会社 | 固体高分子型燃料電池用電極触媒 |
| US9044566B2 (en) * | 2013-03-01 | 2015-06-02 | Reaction Systems, Llc | Advanced supported liquid membranes for carbon dioxide control in extravehicular activity applications |
| US10573901B2 (en) * | 2013-04-25 | 2020-02-25 | Tanaka Kikinzoku Kogyo K.K. | Catalyst and manufacturing method thereof, and electrode catalyst layer using the catalyst |
| CN105142784A (zh) | 2013-04-25 | 2015-12-09 | 日产自动车株式会社 | 催化剂以及使用该催化剂的电极催化剂层、膜电极接合体及燃料电池 |
| CN105453321B (zh) | 2013-05-16 | 2018-07-31 | 联合工艺公司 | 具有拥有最大水域团簇尺寸的水合离子交换膜的液流电池 |
| JP2015032415A (ja) * | 2013-08-01 | 2015-02-16 | 本田技研工業株式会社 | 電解質膜・電極構造体 |
| EP2869382B1 (en) * | 2013-10-30 | 2018-12-12 | Basf Se | Improved membrane electrode assemblies |
| US10367218B2 (en) | 2014-10-29 | 2019-07-30 | Nissan Motor Co., Ltd. | Electrode catalyst layer for fuel cell, method for producing the same, and membrane electrode assembly and fuel cell using the catalyst layer |
| JP6571961B2 (ja) * | 2015-03-25 | 2019-09-04 | 株式会社東芝 | 燃料電池用電極、燃料電池用膜電極複合体および燃料電池 |
| US20180261866A1 (en) * | 2015-09-09 | 2018-09-13 | Nissan Motor Co., Ltd. | Fuel cell electrode catalyst layer and manufacturing method therefor, and membrane electrode assembly, fuel cell, and vehicle using catalyst layer |
| GB2556836B (en) * | 2015-09-17 | 2021-09-22 | Figaro Eng | Electrochemical gas sensor |
| DE102017204096A1 (de) * | 2017-03-13 | 2018-09-13 | Siemens Aktiengesellschaft | Herstellung von Gasdiffusionselektroden mit Ionentransport-Harzen zur elektrochemischen Reduktion von CO2 zu chemischen Wertstoffen |
| US11056698B2 (en) | 2018-08-02 | 2021-07-06 | Raytheon Technologies Corporation | Redox flow battery with electrolyte balancing and compatibility enabling features |
| WO2020031479A1 (ja) * | 2018-08-09 | 2020-02-13 | 三井金属鉱業株式会社 | 燃料電池用電極触媒層及びそれを用いた固体高分子形燃料電池 |
| CN111240376B (zh) * | 2018-11-29 | 2021-06-01 | 中国科学院大连化学物理研究所 | 一种被动式气压调节装置 |
| DE102019208171A1 (de) | 2019-06-05 | 2020-12-10 | Robert Bosch Gmbh | Brennstoffzelleneinheit |
| US11271226B1 (en) | 2020-12-11 | 2022-03-08 | Raytheon Technologies Corporation | Redox flow battery with improved efficiency |
| JP7563156B2 (ja) * | 2020-12-16 | 2024-10-08 | Toppanホールディングス株式会社 | 固体高分子形燃料電池用触媒インク |
| WO2024155622A1 (en) * | 2023-01-17 | 2024-07-25 | The Johns Hopkins University | Controlling water activity to promote selective electrochemical reactions |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3162851B2 (ja) * | 1993-01-05 | 2001-05-08 | 三洋電機株式会社 | 電極/高分子電解質膜接合体の製造方法 |
| JPH07176310A (ja) * | 1993-12-20 | 1995-07-14 | Sanyo Electric Co Ltd | 電極及びその電極とイオン交換膜との接合体 |
| JP3555209B2 (ja) * | 1994-12-21 | 2004-08-18 | トヨタ自動車株式会社 | 燃料電池の発電層およびその製造方法 |
| CN1230933C (zh) * | 1996-12-27 | 2005-12-07 | 日本电池株式会社 | 气体扩散电极、固体聚合物电解质膜、及其生产方法和固体聚合物电解质燃料电池 |
| JP3903562B2 (ja) * | 1996-12-27 | 2007-04-11 | 株式会社ジーエス・ユアサコーポレーション | ガス拡散電極及び固体高分子電解質膜並びにそれらの製造方法、並びにそれを用いた固体高分子電解質型燃料電池 |
| JP3577402B2 (ja) * | 1997-07-28 | 2004-10-13 | 株式会社東芝 | 固体高分子型燃料電池 |
| JP2001345106A (ja) * | 2000-03-31 | 2001-12-14 | Japan Storage Battery Co Ltd | 燃料電池用電極およびその製造方法 |
| JP3594533B2 (ja) * | 2000-05-30 | 2004-12-02 | 三洋電機株式会社 | 燃料電池 |
| JP2002164056A (ja) * | 2000-11-22 | 2002-06-07 | Aisin Seiki Co Ltd | 固体高分子電解質型燃料電池及び電極、及びその電極の製造方法 |
| US6916575B2 (en) * | 2001-03-08 | 2005-07-12 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte type fuel cell |
| JP3778506B2 (ja) | 2002-11-08 | 2006-05-24 | 本田技研工業株式会社 | 固体高分子型燃料電池用の電極 |
| JP2004296435A (ja) * | 2003-03-13 | 2004-10-21 | Toray Ind Inc | 電極触媒層およびその製造方法ならびにそれを用いた固体高分子型燃料電池 |
| JP4917737B2 (ja) * | 2003-11-12 | 2012-04-18 | 日産自動車株式会社 | 燃料電池用電解質膜および燃料電池 |
| US7157178B2 (en) * | 2003-11-24 | 2007-01-02 | General Motors Corporation | Proton exchange membrane fuel cell |
| CN1323455C (zh) * | 2004-10-10 | 2007-06-27 | 上海河森电气有限公司 | 一种电化学发电装置中导电与气体扩散层材料的制造方法 |
| JP4910305B2 (ja) * | 2005-05-12 | 2012-04-04 | 株式会社Gsユアサ | 固体高分子形燃料電池用触媒層およびそれを備えた固体高分子形燃料電池。 |
| JP5326185B2 (ja) * | 2005-09-28 | 2013-10-30 | 日産自動車株式会社 | ガス拡散電極用材料及びその製造方法 |
| JP5011867B2 (ja) * | 2006-07-21 | 2012-08-29 | トヨタ自動車株式会社 | 燃料電池用の膜電極接合体の製造方法 |
| JP2008027810A (ja) * | 2006-07-24 | 2008-02-07 | Toyota Motor Corp | 燃料電池、燃料電池用膜−電極接合体、および、燃料電池の製造方法 |
| US20080206615A1 (en) * | 2007-02-22 | 2008-08-28 | Paul Nicotera | Gas diffusion layer with controlled diffusivity over active area |
| JP2008270163A (ja) * | 2007-03-23 | 2008-11-06 | Toshiba Corp | 燃料電池 |
| JP5066998B2 (ja) * | 2007-04-25 | 2012-11-07 | 旭硝子株式会社 | 固体高分子形燃料電池用膜電極接合体 |
-
2010
- 2010-06-25 JP JP2010144940A patent/JP5488254B2/ja not_active Expired - Fee Related
- 2010-06-25 CN CN201080028661.5A patent/CN102804466B/zh not_active Expired - Fee Related
- 2010-06-25 US US13/380,709 patent/US20120100461A1/en not_active Abandoned
- 2010-06-25 WO PCT/JP2010/060825 patent/WO2010150870A1/ja not_active Ceased
- 2010-06-25 CA CA2766279A patent/CA2766279A1/en not_active Abandoned
- 2010-06-25 EP EP10792188A patent/EP2448047A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP2448047A1 (en) | 2012-05-02 |
| JP2011029170A (ja) | 2011-02-10 |
| CN102804466A (zh) | 2012-11-28 |
| US20120100461A1 (en) | 2012-04-26 |
| JP5488254B2 (ja) | 2014-05-14 |
| CN102804466B (zh) | 2015-12-16 |
| WO2010150870A1 (ja) | 2010-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20120100461A1 (en) | Hydrophilic porous layer for fuel cells, gas diffusion electrode and manufacturing method thereof, and membrane electrode assembly | |
| CA2766022C (en) | Gas diffusion electrode and production method for same; membrane electrode assembly and production method for same | |
| CN104094460B (zh) | 燃料电池用电极催化剂层 | |
| KR102368761B1 (ko) | 촉매 | |
| CA2866706C (en) | Electrolyte film-electrode assembly | |
| US20160079605A1 (en) | Catalyst and electrode catalyst layer, membrane electrode assembly, and fuel cell using the catalyst | |
| Kannan et al. | Nanostructured gas diffusion and catalyst layers for proton exchange membrane fuel cells | |
| JP2008186798A (ja) | 電解質膜−電極接合体 | |
| CN106922203A (zh) | 燃料电池用电极催化剂及其制造方法、含有该催化剂的燃料电池用电极催化剂层以及使用该催化剂或催化剂层的燃料电池用膜电极接合体及燃料电池 | |
| JP2016091605A (ja) | 燃料電池用電極触媒層の製造方法 | |
| WO2016067878A1 (ja) | 燃料電池用電極触媒層、その製造方法ならびに当該触媒層を用いる膜電極接合体および燃料電池 | |
| JP2006339124A (ja) | 燃料電池用膜電極接合体およびこれを用いた固体高分子型燃料電池 | |
| JP5884550B2 (ja) | アノードガス拡散層 | |
| JP2020057516A (ja) | 電極層ならびに当該電極層を用いた膜電極接合体および燃料電池 | |
| JP2005243295A (ja) | ガス拡散層、およびこれを用いた燃料電池用mea | |
| JP5544689B2 (ja) | 燃料電池用保水層およびその製造方法並びに電解質膜−電極接合体 | |
| JP2006012449A (ja) | 膜電極接合体およびこれを用いた固体高分子型燃料電池 | |
| JP5458774B2 (ja) | 電解質膜−電極接合体 | |
| JP6661954B2 (ja) | 触媒および電解質を含む構造体の評価方法、ならびに当該評価方法を用いる燃料電池の製造方法 | |
| JP2007165188A (ja) | 高分子型燃料電池の膜−電極接合体 | |
| KR20250172369A (ko) | 연료 전지용 전극 촉매층 및 연료 전지용 전극 촉매층의 제조 방법 | |
| WO2014174973A1 (ja) | ガス拡散電極体、その製造方法ならびにこれを用いる燃料電池用膜電極接合体および燃料電池 | |
| JP2011070926A (ja) | 電解質膜−電極接合体 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Dead |
Effective date: 20170627 |