CA2734155A1 - Method of making a cleaning solution from hydrogel cleaning concentrate and packaged cleaning concentrate - Google Patents
Method of making a cleaning solution from hydrogel cleaning concentrate and packaged cleaning concentrate Download PDFInfo
- Publication number
- CA2734155A1 CA2734155A1 CA2734155A CA2734155A CA2734155A1 CA 2734155 A1 CA2734155 A1 CA 2734155A1 CA 2734155 A CA2734155 A CA 2734155A CA 2734155 A CA2734155 A CA 2734155A CA 2734155 A1 CA2734155 A1 CA 2734155A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrogel
- cleaning
- cleaning concentrate
- concentrate
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 342
- 239000000017 hydrogel Substances 0.000 title claims abstract description 243
- 239000012141 concentrate Substances 0.000 title claims abstract description 216
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 claims abstract description 57
- 239000011324 bead Substances 0.000 claims description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 87
- 239000000203 mixture Substances 0.000 claims description 83
- 239000000463 material Substances 0.000 claims description 61
- 239000004094 surface-active agent Substances 0.000 claims description 53
- 239000002798 polar solvent Substances 0.000 claims description 52
- 239000002243 precursor Substances 0.000 claims description 52
- 239000000178 monomer Substances 0.000 claims description 44
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 39
- 125000002947 alkylene group Chemical group 0.000 claims description 38
- 239000002253 acid Substances 0.000 claims description 26
- -1 poly(alkylene) Polymers 0.000 claims description 26
- 229920000642 polymer Polymers 0.000 claims description 22
- 229920003176 water-insoluble polymer Polymers 0.000 claims description 20
- 230000005855 radiation Effects 0.000 claims description 18
- 102000004190 Enzymes Human genes 0.000 claims description 14
- 108090000790 Enzymes Proteins 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 12
- 239000004599 antimicrobial Substances 0.000 claims description 10
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- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000003205 fragrance Substances 0.000 claims description 7
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- 238000010526 radical polymerization reaction Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 229920001484 poly(alkylene) Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 description 63
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 32
- 239000007788 liquid Substances 0.000 description 23
- 230000000845 anti-microbial effect Effects 0.000 description 16
- 239000000126 substance Substances 0.000 description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 12
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 12
- 229940088598 enzyme Drugs 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- 238000010790 dilution Methods 0.000 description 10
- 239000012895 dilution Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 9
- 239000002736 nonionic surfactant Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 125000002091 cationic group Chemical group 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- 150000001875 compounds Chemical class 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 239000000645 desinfectant Substances 0.000 description 5
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- 235000021419 vinegar Nutrition 0.000 description 5
- 239000000052 vinegar Substances 0.000 description 5
- GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical group CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 4
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
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- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical class CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
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- 239000011148 porous material Substances 0.000 description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229940075554 sorbate Drugs 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical group C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 2
- 108010065511 Amylases Proteins 0.000 description 2
- 229940123208 Biguanide Drugs 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical class C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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- 241001043922 Pensacola Species 0.000 description 2
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- 240000004760 Pimpinella anisum Species 0.000 description 2
- 235000012550 Pimpinella anisum Nutrition 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920002413 Polyhexanide Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
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- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8050608P | 2008-07-14 | 2008-07-14 | |
| US61/080,506 | 2008-07-14 | ||
| PCT/US2009/047145 WO2010008712A1 (en) | 2008-07-14 | 2009-06-12 | Method of making a cleaning solution from hydrogel cleaning concentrate and packaged cleaning concentrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2734155A1 true CA2734155A1 (en) | 2010-01-21 |
Family
ID=40908622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2734155A Abandoned CA2734155A1 (en) | 2008-07-14 | 2009-06-12 | Method of making a cleaning solution from hydrogel cleaning concentrate and packaged cleaning concentrate |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8846595B2 (enExample) |
| EP (1) | EP2318499B1 (enExample) |
| JP (1) | JP5508414B2 (enExample) |
| KR (1) | KR101595142B1 (enExample) |
| CN (1) | CN102119208B (enExample) |
| BR (1) | BRPI0910366A2 (enExample) |
| CA (1) | CA2734155A1 (enExample) |
| MX (1) | MX2011000430A (enExample) |
| WO (1) | WO2010008712A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201006076D0 (en) * | 2010-04-12 | 2010-05-26 | Xeros Ltd | Novel cleaning apparatus and method |
| WO2013081863A1 (en) * | 2011-11-16 | 2013-06-06 | Oms Investments, Inc. | Peroxy salt compositions and uses thereof |
| KR101444423B1 (ko) * | 2012-10-05 | 2014-09-24 | 주식회사 엘지생활건강 | 세정용 수화겔 조성물 및 이를 포함하는 다공성 기재 |
| CN105838509B (zh) * | 2015-01-16 | 2018-04-24 | 3M创新有限公司 | 酶溶液、含酶无纺布及其制备方法和应用 |
| CN105081911B (zh) * | 2015-06-19 | 2017-06-16 | 苏州金螳螂园林绿化景观有限公司 | 一种对铺设在红土地上的石材进行保洁的方法 |
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| JPS523832A (en) | 1975-05-16 | 1977-01-12 | Japan Synthetic Rubber Co Ltd | Gel fragrant deodorant |
| US4203851A (en) * | 1978-06-16 | 1980-05-20 | Colgate-Palmolive Company | Fabric softening compositions and methods for manufacture thereof |
| US4659496A (en) * | 1986-01-31 | 1987-04-21 | Amway Corporation | Dispensing pouch containing premeasured laundering compositions |
| US4929400A (en) * | 1986-04-28 | 1990-05-29 | California Institute Of Technology | Production of monodisperse, polymeric microspheres |
| GB8620845D0 (en) | 1986-08-28 | 1986-10-08 | Reckitt & Colmann Prod Ltd | Treatment of textile surfaces |
| JPS63317597A (ja) * | 1987-06-19 | 1988-12-26 | Sanyo Chem Ind Ltd | 徐溶化剤および組成物 |
| EP0390813B1 (en) | 1987-11-12 | 1993-11-03 | Kone Oy | Method and store for storing paper rolls |
| US4973416A (en) * | 1988-10-14 | 1990-11-27 | The Procter & Gamble Company | Liquid laundry detergent in water-soluble package |
| US4946617A (en) * | 1988-11-15 | 1990-08-07 | Nordico, Inc. | Substantially dry cleaning wipe capable of rendering a cleaned surface static free |
| US5126381A (en) * | 1988-12-19 | 1992-06-30 | Dow Corning Corporation | Bead processor |
| US5002681A (en) | 1989-03-03 | 1991-03-26 | The Procter & Gamble Company | Jumbo particulate fabric softner composition |
| GB9107100D0 (en) * | 1991-04-04 | 1991-05-22 | Unilever Plc | Detergent containing article |
| AU655282B2 (en) | 1991-06-14 | 1994-12-15 | Rhone-Poulenc Agro | New aqueous formulations |
| US5514379A (en) * | 1992-08-07 | 1996-05-07 | The General Hospital Corporation | Hydrogel compositions and methods of use |
| US5506279A (en) * | 1993-10-13 | 1996-04-09 | Minnesota Mining And Manufacturing Company | Acrylamido functional disubstituted acetyl aryl ketone photoinitiators |
| US6090763A (en) * | 1994-02-28 | 2000-07-18 | Stewart; Howard Franklin | Hydrogel soap |
| US5603955A (en) * | 1994-07-18 | 1997-02-18 | University Of Cincinnati | Enhanced loading of solutes into polymer gels |
| JP2700535B2 (ja) * | 1995-02-17 | 1998-01-21 | 三洋化成工業株式会社 | 自動芳香洗浄剤基材 |
| HUP9802188A3 (en) * | 1995-03-29 | 2000-03-28 | Unilever Nv | Liquid cleanser compositions for cosmetical purposes |
| US6040286A (en) * | 1995-12-26 | 2000-03-21 | Huff; Karen L. | Through-the-washer-dryer pouch-type detergent bag and method of use |
| WO1999013045A1 (de) * | 1997-09-11 | 1999-03-18 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung teilchenförmiger wasch- oder reinigungsmittel |
| US6245728B1 (en) * | 1996-10-17 | 2001-06-12 | The Clorox Company | Low odor, hard surface cleaner with enhanced soil removal |
| US6800278B1 (en) * | 1996-10-28 | 2004-10-05 | Ballard Medical Products, Inc. | Inherently antimicrobial quaternary amine hydrogel wound dressings |
| JPH11256199A (ja) * | 1998-03-06 | 1999-09-21 | Lion Corp | カートリッジ洗浄剤及びその製造方法 |
| DE19831703A1 (de) * | 1998-07-15 | 2000-01-20 | Henkel Kgaa | Portionierte Wasch- und Reinigungsmittelzusammensetzung |
| US6861067B2 (en) * | 1998-09-17 | 2005-03-01 | Sherwood Services Ag | Hydrogel wound dressing and the method of making and using the same |
| US6250511B1 (en) * | 1999-11-05 | 2001-06-26 | Albert R. Kelly | Recharge insert for cleaning, sanitizing or disinfectant fluid spray system |
| US6995128B2 (en) * | 2000-03-24 | 2006-02-07 | The Clorox Co. | Mixed surfactant cleaning compositions with reduced streaking |
| AU2001256248A1 (en) * | 2000-04-14 | 2001-10-30 | Unilever Plc | Water soluble package and liquid contents thereof |
| US6831051B2 (en) * | 2000-04-28 | 2004-12-14 | The Procter & Gamble Company | Pouched compositions |
| AU2001263062A1 (en) * | 2000-05-11 | 2001-11-20 | The Procter And Gamble Company | Highly concentrated fabric softener compositions and articles containing such compositions |
| AUPQ984400A0 (en) * | 2000-09-01 | 2000-09-28 | Novapharm Research (Australia) Pty Ltd | Surfactant sytem |
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| AU2002235694B2 (en) * | 2001-02-28 | 2007-06-14 | Covalon Technologies Inc. | Method of making anti-microbial polymeric surfaces |
| DE10128894A1 (de) * | 2001-06-15 | 2002-12-19 | Basf Ag | Verfahren zur schmutzablösungsfördernden Behandlung von Oberflächen textiler und nicht-textiler Materialien |
| GB0114921D0 (en) | 2001-06-19 | 2001-08-08 | Ciba Spec Chem Water Treat Ltd | Particles containing fabric conditioner |
| US7005143B2 (en) * | 2002-04-12 | 2006-02-28 | 3M Innovative Properties Company | Gel materials, medical articles, and methods |
| RU2320677C2 (ru) * | 2002-06-11 | 2008-03-27 | Басф Акциенгезелльшафт | Сложный (мет)акриловый эфир полиалкоксилированного триметилолпропана (варианты) и его применение для получения абсорбирующих водосодержащие жидкости полимеров |
| US6729786B1 (en) * | 2003-03-14 | 2004-05-04 | Mediflex Hospital Products, Inc. | Liquid applicator for coloring a liquid |
| US7022656B2 (en) * | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| DE10358372A1 (de) * | 2003-04-03 | 2004-10-14 | Basf Ag | Gemische von Verbindungen mit mindestens zwei Doppelbindungen und deren Verwendung |
| MXPA05010333A (es) * | 2003-04-03 | 2005-11-17 | Basf Ag | Mezclas de (met) acrilatos de trimetilolpropano polialcoxilado. |
| CA2527316C (en) * | 2003-06-03 | 2011-08-16 | The Procter & Gamble Company | Detergent pouch |
| US7325688B1 (en) * | 2003-09-26 | 2008-02-05 | Gowan Milling Company, L.L.C. | Pressurized water-soluble pouch |
| CN1870887A (zh) | 2003-10-24 | 2006-11-29 | 诺瓦制药研究（澳大利亚）有限公司 | 化霜水盘片剂 |
| JP2005187511A (ja) * | 2003-12-24 | 2005-07-14 | Lion Corp | 液体組成物、及び洗浄方法 |
| EP1607412A1 (en) * | 2004-06-07 | 2005-12-21 | First Water Limited | Hydrogel Composites |
| US7318871B2 (en) * | 2004-06-16 | 2008-01-15 | The Clorox Company | Vehicular cleaning concentrate |
| US9028852B2 (en) * | 2004-09-07 | 2015-05-12 | 3M Innovative Properties Company | Cationic antiseptic compositions and methods of use |
| US8198326B2 (en) * | 2004-09-07 | 2012-06-12 | 3M Innovative Properties Company | Phenolic antiseptic compositions and methods of use |
| WO2006028582A1 (en) | 2004-09-07 | 2006-03-16 | Nordico Market Development Inc. | Sleeve for recharging a cleaning, sanitizing or disinfectant fluid spray system |
| US20060051384A1 (en) * | 2004-09-07 | 2006-03-09 | 3M Innovative Properties Company | Antiseptic compositions and methods of use |
| EP1714605B1 (en) | 2005-04-21 | 2011-06-08 | Reckitt Benckiser (UK) Limited | Device and method |
| US20060242754A1 (en) * | 2005-04-27 | 2006-11-02 | Coppock Christopher A | Flush valve cleaner dispenser system |
| EP1898769A1 (en) * | 2005-06-14 | 2008-03-19 | 3M Innovative Properties Company | Liquid dispensing floor mop |
| US7612029B2 (en) * | 2006-04-11 | 2009-11-03 | The Clorox Company | Controlled release using gels in a melamine foam |
| US20090270305A1 (en) | 2006-06-01 | 2009-10-29 | Johnson Mitchell T | Cleaning composition |
| JP5368300B2 (ja) * | 2006-06-08 | 2013-12-18 | スリーエム イノベイティブ プロパティズ カンパニー | ポリマービーズおよびポリマービーズの製造方法 |
| CN101460689A (zh) | 2006-06-08 | 2009-06-17 | 3M创新有限公司 | 用于涂敷地板的涂覆器及其方法 |
| US7939578B2 (en) * | 2007-02-23 | 2011-05-10 | 3M Innovative Properties Company | Polymeric fibers and methods of making |
| BRPI0820704A2 (pt) | 2007-12-12 | 2015-06-16 | 3M Innovative Proferties Company | Métodos de fabricação de materiais poliméricos moldados |
| GB201212096D0 (en) * | 2012-07-06 | 2012-08-22 | Xeros Ltd | Improved cleaning formulation and method |
-
2009
- 2009-06-12 BR BRPI0910366A patent/BRPI0910366A2/pt not_active IP Right Cessation
- 2009-06-12 WO PCT/US2009/047145 patent/WO2010008712A1/en not_active Ceased
- 2009-06-12 US US12/992,139 patent/US8846595B2/en not_active Expired - Fee Related
- 2009-06-12 JP JP2011518761A patent/JP5508414B2/ja not_active Expired - Fee Related
- 2009-06-12 EP EP09789798A patent/EP2318499B1/en not_active Not-in-force
- 2009-06-12 MX MX2011000430A patent/MX2011000430A/es active IP Right Grant
- 2009-06-12 KR KR1020117003137A patent/KR101595142B1/ko not_active Expired - Fee Related
- 2009-06-12 CA CA2734155A patent/CA2734155A1/en not_active Abandoned
- 2009-06-12 CN CN200980131168.3A patent/CN102119208B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN102119208A (zh) | 2011-07-06 |
| BRPI0910366A2 (pt) | 2015-10-13 |
| MX2011000430A (es) | 2011-03-15 |
| US20110082068A1 (en) | 2011-04-07 |
| EP2318499B1 (en) | 2013-03-06 |
| JP2011528061A (ja) | 2011-11-10 |
| CN102119208B (zh) | 2013-02-13 |
| EP2318499A1 (en) | 2011-05-11 |
| JP5508414B2 (ja) | 2014-05-28 |
| WO2010008712A1 (en) | 2010-01-21 |
| KR20110051193A (ko) | 2011-05-17 |
| KR101595142B1 (ko) | 2016-02-17 |
| US8846595B2 (en) | 2014-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20140327 |
|
| FZDE | Discontinued |
Effective date: 20161028 |