CA2725802A1 - Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction - Google Patents

Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction Download PDF

Info

Publication number
CA2725802A1
CA2725802A1 CA2725802A CA2725802A CA2725802A1 CA 2725802 A1 CA2725802 A1 CA 2725802A1 CA 2725802 A CA2725802 A CA 2725802A CA 2725802 A CA2725802 A CA 2725802A CA 2725802 A1 CA2725802 A1 CA 2725802A1
Authority
CA
Canada
Prior art keywords
gas
heat transfer
mixed gas
catalyst
areas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2725802A
Other languages
English (en)
French (fr)
Inventor
Richard F. Abrams
John Robert Harold
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Babcock Power Environmental Inc
Original Assignee
Babcock Power Environmental Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Power Environmental Inc filed Critical Babcock Power Environmental Inc
Publication of CA2725802A1 publication Critical patent/CA2725802A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/208Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20723Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20776Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/502Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Chimneys And Flues (AREA)
  • Treating Waste Gases (AREA)
CA2725802A 2008-05-27 2009-05-26 Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction Abandoned CA2725802A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US5631008P 2008-05-27 2008-05-27
US61/056,310 2008-05-27
US12/355,231 US7758831B2 (en) 2004-09-30 2009-01-16 Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction
US12/355,231 2009-01-16
PCT/US2009/045107 WO2010036409A1 (en) 2008-05-27 2009-05-26 Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction

Publications (1)

Publication Number Publication Date
CA2725802A1 true CA2725802A1 (en) 2010-04-01

Family

ID=42060035

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2725802A Abandoned CA2725802A1 (en) 2008-05-27 2009-05-26 Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction

Country Status (7)

Country Link
US (1) US7758831B2 (https=)
EP (1) EP2285471A4 (https=)
JP (1) JP2011521783A (https=)
KR (1) KR20110021839A (https=)
CN (1) CN102065979A (https=)
CA (1) CA2725802A1 (https=)
WO (1) WO2010036409A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108298459A (zh) * 2018-03-20 2018-07-20 长沙理工大学 升降式scr催化剂现场再生装备

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8124017B2 (en) 2004-09-30 2012-02-28 Babcock Power Environmental Inc. Systems and methods for high efficiency regenerative selective catalytic reduction
AT507773B1 (de) 2009-07-15 2010-08-15 Scheuch Gmbh Verfahren und vorrichtung zur entstickung von rauchgasen
US7931881B2 (en) * 2009-09-25 2011-04-26 Babcock Power Environmental Inc. Integrated boiler and air pollution control systems
AT508921B1 (de) * 2010-04-02 2011-05-15 Scheuch Gmbh Verfahren und vorrichtung zur entstickung von rauchgasen
CN203316005U (zh) * 2013-01-18 2013-12-04 北京神雾环境能源科技集团股份有限公司 催化净化和换热系统
AT515887A1 (de) 2014-05-20 2015-12-15 Ge Jenbacher Gmbh & Co Og Verfahren zum Anfahren eines Thermoreaktors
CN104324612B (zh) * 2014-11-13 2016-05-04 安徽同兴环保工程股份有限公司 低温烟气专用单仓加热再生脱硝系统及脱硝方法
DE102015108014B3 (de) * 2015-05-20 2016-11-24 Chemisch Thermische Prozesstechnik Gmbh Verfahren und Anlage zur Reinigung von mit Stickoxiden beladenen Abgasen
AT517670B1 (de) * 2015-09-04 2023-03-15 Innio Jenbacher Gmbh & Co Og Abgasnachbehandlungsvorrichtung
JP6616737B2 (ja) * 2016-05-31 2019-12-04 日立造船株式会社 排ガス脱硝装置、焼却炉および排ガス脱硝方法
DE102016121301A1 (de) 2016-11-08 2018-05-09 Thyssenkrupp Ag Anlage und Verfahren zur Reinigung eines Abgases einer Bearbeitungsvorrichtung der Zement-, Kalk- oder Mineralsindustrie
CN106512686B (zh) * 2016-11-24 2019-03-08 华中科技大学 一种有机污染土壤热解析尾气处理系统
KR101719793B1 (ko) * 2017-01-13 2017-04-05 주식회사 대성제이테크 백 필터를 이용한 저중심용 집진장치
DE102017101507B4 (de) * 2017-01-26 2022-10-13 Chemisch Thermische Prozesstechnik Gmbh Verfahren und Vorrichtung zur Abgasreinigung
KR102641549B1 (ko) * 2021-07-06 2024-02-27 (주) 환경과에너지 축열식 촉매 산화 장치
KR102820876B1 (ko) * 2021-12-28 2025-06-17 주식회사 엔바이온 Nh3 혼합 소스를 환원제로 사용한 선택적 촉매 환원 또는/및 무촉매 환원 기능을 갖는 축열식 탈질 연소 설비
WO2023018036A1 (ko) * 2021-08-09 2023-02-16 주식회사 엔바이온 선택적 촉매 환원 및 무촉매 환원 기능을 갖는 축열식 산화 장치
KR102594138B1 (ko) * 2021-08-09 2023-10-26 주식회사 엔바이온 선택적 촉매 환원 및 무촉매 환원 기능을 갖는 축열식 산화 장치

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2938654B1 (de) * 1979-09-25 1980-09-18 Didier Eng Verfahren zur Vernichtung von Ammoniak in Abwaessern
DE3508553A1 (de) * 1985-03-11 1986-09-11 Hüls AG, 4370 Marl Verfahren und vorrichtung zum katalytischen umsetzen von gasen
DE3533199A1 (de) * 1985-09-18 1987-03-26 Kraftanlagen Ag Verfahren und anlage zur reinigung der abgase von feuerungsanlagen
DE3604045C1 (de) * 1986-02-08 1987-01-29 Steag Ag Verfahren zum Abscheiden von Stickstoffoxiden aus Rauchgasen
JPH01501454A (ja) * 1986-10-17 1989-05-25 インスティテュト カタリザ シビルスコゴ オトデレニア アカデミイ ナウク エスエスエスエル 排ガスの触媒による清浄方法
JPS6372327A (ja) 1987-08-28 1988-04-02 Kogyo Kaihatsu Kenkyusho ガス中のアンモニアおよび炭化水素系化合物除去方法
DE4027329A1 (de) 1990-08-29 1992-03-12 Siemens Ag Katalysator-anordnung zur stickoxidminderung in einem rauchgas
DE4038054A1 (de) 1990-11-29 1992-06-04 Man Technologie Gmbh Verfahren und vorrichtung zur selektiven katalytischen no(pfeil abwaerts)x(pfeil abwaerts)-reduktion in sauerstoffhaltigen abgasen
JPH04326924A (ja) * 1991-04-25 1992-11-16 Matsushita Electric Ind Co Ltd 間欠式触媒浄化装置および浄化方法
US6183707B1 (en) * 1992-06-08 2001-02-06 Biothermica International Inc. Incineration of waste gases containing contaminant aerosols
US5364259A (en) * 1993-03-10 1994-11-15 Monsanto Enviro-Chem Systems, Inc. Process and apparatus for gas phase reaction in a regenerative incinerator
AT399828B (de) * 1993-07-23 1995-07-25 Kvt Verfahrenstech Gmbh Verfahren und anlage zur reinigung von abgasen
US6228329B1 (en) * 1994-03-04 2001-05-08 Durr Environmental Two chamber regenerative thermal or catalytic oxidizer with purging circuit
BR9607399A (pt) * 1995-02-13 1998-11-17 Salem Engelhard Processo para purificar ar contaminado com emissões produzidas por um processo de manufatura de madeira e oxidante catalítico regenerativo
US5658541A (en) * 1995-03-16 1997-08-19 Monsato Company Process for removal of divalent sulfur compounds from waste gases
DE19519868A1 (de) * 1995-05-31 1996-12-05 Duerr Gmbh & Co Einrichtung zur thermischen Abluftreinigung
US5919425A (en) * 1995-09-21 1999-07-06 Engelhard Corporation Catalyzed packing material for regenerative catalytic oxidation
US6039927A (en) * 1997-11-04 2000-03-21 Greco; Richard Valve system for regenerative thermal oxidizers
SE518812C2 (sv) * 1998-03-17 2002-11-26 Bjoern Heed Katalytisk regenerativ anordning för rening av gaser
US6935105B1 (en) * 1998-11-06 2005-08-30 Ceryx Asset Recovery Llc Integrated apparatus for removing pollutants from a fluid stream in a lean-burn environment with heat recovery
JP3771758B2 (ja) * 1999-10-18 2006-04-26 三菱重工業株式会社 閉鎖空間用coガス含有有害ガス処理装置
JP2003117352A (ja) * 2001-10-09 2003-04-22 Babcock Hitachi Kk 排ガスの浄化方法および装置
US6673325B2 (en) * 2002-04-29 2004-01-06 Biothermica Technologies Inc. Incineration of waste organic aerosols
US7017592B2 (en) * 2002-12-10 2006-03-28 Pro-Environmental Inc. Regenerative fume-incinerator with on-line burn-out and wash-down system
US7490464B2 (en) * 2003-11-04 2009-02-17 Basf Catalysts Llc Emissions treatment system with NSR and SCR catalysts
US7198769B2 (en) * 2003-12-02 2007-04-03 Cichanowicz J Edward Multi-stage process for SCR of NOx
US7438876B2 (en) * 2003-12-02 2008-10-21 Cichanowicz J Edward Multi-stage heat absorbing reactor and process for SCR of NOx and for oxidation of elemental mercury
US7294321B2 (en) * 2004-09-30 2007-11-13 Babcock Power Enviormental Inc. Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction
EP2069049A2 (en) * 2006-08-22 2009-06-17 Babcock Power Inc. Thermal decomposition of urea in a side stream of combustion flue gas using a regenerative heat exchanger
US20080317652A1 (en) * 2007-01-09 2008-12-25 Robert Bono Emission control system internal to a boiler

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108298459A (zh) * 2018-03-20 2018-07-20 长沙理工大学 升降式scr催化剂现场再生装备
CN108298459B (zh) * 2018-03-20 2023-06-30 长沙理工大学 升降式scr催化剂现场再生装备

Also Published As

Publication number Publication date
JP2011521783A (ja) 2011-07-28
WO2010036409A1 (en) 2010-04-01
EP2285471A4 (en) 2011-09-28
EP2285471A1 (en) 2011-02-23
US20090130011A1 (en) 2009-05-21
KR20110021839A (ko) 2011-03-04
US7758831B2 (en) 2010-07-20
CN102065979A (zh) 2011-05-18

Similar Documents

Publication Publication Date Title
US7758831B2 (en) Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction
US7494625B2 (en) Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction
US7931881B2 (en) Integrated boiler and air pollution control systems
US8318115B2 (en) Systems and methods for high efficiency regenerative selective catalytic reduction
CN112221348B (zh) 一种处理VOCs协同脱硝的一体化RTO装置及工艺
EP1064080B1 (en) Reducing NOx in exhaust gases
CN108057343A (zh) 一种蓄热式选择性还原脱硝设备及脱硝工艺
CN101036850A (zh) 防止氨逃逸的锅炉低温烟气scr联合吸附脱附催化床
CN209848679U (zh) 烧结机烟气低温scr脱硝装置
CN211913346U (zh) 一种低温干法脱硫-催化脱硝一体化设备
US20160310893A1 (en) Constant direction regenerative selective catalytic reduction
CN215654569U (zh) 一种烧结球团烟气的活性炭脱硫及scr脱硝耦合系统
CN111298645A (zh) 基于活性炭纤维的垃圾焚烧烟气脱硝脱二噁英装置及方法
KR102820876B1 (ko) Nh3 혼합 소스를 환원제로 사용한 선택적 촉매 환원 또는/및 무촉매 환원 기능을 갖는 축열식 탈질 연소 설비
CN223628421U (zh) 一种免氨脱硝协同co脱除系统
KR102594138B1 (ko) 선택적 촉매 환원 및 무촉매 환원 기능을 갖는 축열식 산화 장치
CN219128854U (zh) 一种低成本焦炉烟道气干式超净协同脱除多污染物装置
HK1159013A (en) Systems and methods for removing materials from flue gas via regenerative selective catalytic reduction
CN211988024U (zh) 一种基于活性炭纤维的垃圾焚烧烟气脱硝脱二噁英装置
CN120189789A (zh) 用于生物质焚烧烟气脱除氮氧化物的系统及方法
KR20250091572A (ko) 질소 산화물 저감 시스템
CN113663471A (zh) 烧结球团烟气的活性炭脱硫及scr脱硝耦合系统及方法
JPH07213845A (ja) 温度スイング方式アンモニア回収装置

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20140526

FZDE Dead

Effective date: 20170228