CA2701144A1 - Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials - Google Patents
Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials Download PDFInfo
- Publication number
- CA2701144A1 CA2701144A1 CA2701144A CA2701144A CA2701144A1 CA 2701144 A1 CA2701144 A1 CA 2701144A1 CA 2701144 A CA2701144 A CA 2701144A CA 2701144 A CA2701144 A CA 2701144A CA 2701144 A1 CA2701144 A1 CA 2701144A1
- Authority
- CA
- Canada
- Prior art keywords
- compound
- present
- process according
- gaseous
- oxidation state
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 121
- 230000008569 process Effects 0.000 title claims abstract description 114
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title description 26
- 239000000463 material Substances 0.000 title description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 243
- 239000002245 particle Substances 0.000 claims abstract description 31
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 15
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 3
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 3
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 95
- 230000003647 oxidation Effects 0.000 claims description 63
- 238000007254 oxidation reaction Methods 0.000 claims description 63
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 52
- 239000003638 chemical reducing agent Substances 0.000 claims description 46
- 125000004437 phosphorous atom Chemical group 0.000 claims description 41
- 239000007787 solid Substances 0.000 claims description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 239000004020 conductor Substances 0.000 claims description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 22
- 235000011007 phosphoric acid Nutrition 0.000 claims description 22
- 238000001354 calcination Methods 0.000 claims description 21
- 239000002243 precursor Substances 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 13
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 5
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 229910019670 (NH4)H2PO4 Inorganic materials 0.000 claims description 3
- 229910003953 H3PO2 Inorganic materials 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 239000002322 conducting polymer Substances 0.000 claims description 3
- 229920001940 conductive polymer Polymers 0.000 claims description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- 229910019928 (NH4)2HPO3 Inorganic materials 0.000 claims 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 53
- 229910001868 water Inorganic materials 0.000 description 53
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 46
- 229940124024 weight reducing agent Drugs 0.000 description 42
- 239000000843 powder Substances 0.000 description 39
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 37
- 235000013350 formula milk Nutrition 0.000 description 33
- 229910001367 Li3V2(PO4)3 Inorganic materials 0.000 description 31
- 239000000243 solution Substances 0.000 description 31
- XNQULTQRGBXLIA-UHFFFAOYSA-O phosphonic anhydride Chemical compound O[P+](O)=O XNQULTQRGBXLIA-UHFFFAOYSA-O 0.000 description 30
- 229910052757 nitrogen Inorganic materials 0.000 description 23
- 229910003206 NH4VO3 Inorganic materials 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000000634 powder X-ray diffraction Methods 0.000 description 18
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 17
- GNTDGMZSJNCJKK-UHFFFAOYSA-N Vanadium(V) oxide Inorganic materials O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 16
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 14
- 229910013594 LiOAc Inorganic materials 0.000 description 13
- 238000004626 scanning electron microscopy Methods 0.000 description 13
- 229910012453 Li3Fe2(PO4)3 Inorganic materials 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000001694 spray drying Methods 0.000 description 12
- 239000011541 reaction mixture Substances 0.000 description 11
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- -1 oxide Chemical compound 0.000 description 9
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 8
- 239000000306 component Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 6
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 6
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 6
- 230000001603 reducing effect Effects 0.000 description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000008103 glucose Substances 0.000 description 5
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 5
- 229910052808 lithium carbonate Inorganic materials 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 229910003227 N2H4 Inorganic materials 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000004108 freeze drying Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 229960004592 isopropanol Drugs 0.000 description 3
- 229910052756 noble gas Inorganic materials 0.000 description 3
- 150000002835 noble gases Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 229910000352 vanadyl sulfate Inorganic materials 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- YWJVFBOUPMWANA-UHFFFAOYSA-H [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O YWJVFBOUPMWANA-UHFFFAOYSA-H 0.000 description 2
- 230000002730 additional effect Effects 0.000 description 2
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 2
- 150000001793 charged compounds Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002707 nanocrystalline material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- JBJWASZNUJCEKT-UHFFFAOYSA-M sodium;hydroxide;hydrate Chemical compound O.[OH-].[Na+] JBJWASZNUJCEKT-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 2
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229910012682 Li3M2(PO4)3 Inorganic materials 0.000 description 1
- 229910011304 Li3V2 Inorganic materials 0.000 description 1
- 229910020657 Na3V2(PO4)3 Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000013681 dietary sucrose Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000012493 hydrazine sulfate Substances 0.000 description 1
- 229910000377 hydrazine sulfate Inorganic materials 0.000 description 1
- LIAWOTKNAVAKCX-UHFFFAOYSA-N hydrazine;dihydrochloride Chemical compound Cl.Cl.NN LIAWOTKNAVAKCX-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- DUSYNUCUMASASA-UHFFFAOYSA-N oxygen(2-);vanadium(4+) Chemical compound [O-2].[O-2].[V+4] DUSYNUCUMASASA-UHFFFAOYSA-N 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920005569 poly(vinylidene fluoride-co-hexafluoropropylene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229940058401 polytetrafluoroethylene Drugs 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000012002 vanadium phosphate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US97664007P | 2007-10-01 | 2007-10-01 | |
| US60/976,640 | 2007-10-01 | ||
| US2463108P | 2008-01-30 | 2008-01-30 | |
| US61/024,631 | 2008-01-30 | ||
| PCT/EP2008/062427 WO2009043729A2 (en) | 2007-10-01 | 2008-09-18 | Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2701144A1 true CA2701144A1 (en) | 2009-04-09 |
Family
ID=40457750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2701144A Abandoned CA2701144A1 (en) | 2007-10-01 | 2008-09-18 | Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US20100301281A1 (enExample) |
| EP (1) | EP2207751B1 (enExample) |
| JP (1) | JP5702145B2 (enExample) |
| KR (1) | KR101540133B1 (enExample) |
| CN (1) | CN102123943B (enExample) |
| CA (1) | CA2701144A1 (enExample) |
| TW (1) | TWI401207B (enExample) |
| WO (1) | WO2009043729A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108963235A (zh) * | 2018-08-01 | 2018-12-07 | 武汉理工大学 | 石墨烯增强碳包覆磷酸钛锰钠微米球电极材料及其制备方法和应用 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201010944A (en) | 2008-04-17 | 2010-03-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
| TW200951066A (en) * | 2008-04-17 | 2009-12-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
| TW201038469A (en) | 2009-03-17 | 2010-11-01 | Basf Se | Synthesis of lithium-iron-phosphates |
| US9209461B2 (en) | 2009-06-24 | 2015-12-08 | Basf Se | Process for the preparation of LiFePO4-carbon composites |
| KR101939415B1 (ko) * | 2010-09-27 | 2019-01-16 | 니폰 가가쿠 고교 가부시키가이샤 | 인산바나듐리튬 탄소 복합체의 제조 방법 |
| WO2012124990A2 (ko) * | 2011-03-16 | 2012-09-20 | 한화케미칼 주식회사 | 로타리 킬른을 이용한 전극물질의 하소 방법 |
| CN102569797B (zh) * | 2012-01-20 | 2015-04-29 | 中国科学院宁波材料技术与工程研究所 | 一种新型磷酸盐基正极复合材料及其制备方法和用途 |
| CN102544497A (zh) * | 2012-03-08 | 2012-07-04 | 苏州大学 | 用于锂离子二次电池的正极材料及其制备方法、锂离子二次电池正极和锂离子二次电池 |
| FR2989378B1 (fr) | 2012-04-16 | 2015-10-02 | Commissariat Energie Atomique | Polymere comme materiau d'electrode pour des batteries secondaires au lithium. |
| FR3012450B1 (fr) | 2013-10-30 | 2017-10-13 | Commissariat Energie Atomique | Materiau d'electrode pour batterie organique |
| CN105118968B (zh) * | 2015-09-29 | 2018-10-16 | 中南大学 | 一种巢状v2o3包覆磷酸钒锂的锂离子正极材料 |
| CN105470479B (zh) * | 2015-11-26 | 2017-12-01 | 中南大学 | 一种改性的磷酸锰锂复合正极材料及其制备方法 |
| CN106784597A (zh) * | 2016-12-19 | 2017-05-31 | 苏州格瑞动力电源科技有限公司 | 一种锂离子电池电极片的制备方法 |
| US11909046B2 (en) | 2017-03-07 | 2024-02-20 | The Research Foundation For The State University Of New York | Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions |
| US11251430B2 (en) | 2018-03-05 | 2022-02-15 | The Research Foundation For The State University Of New York | ϵ-VOPO4 cathode for lithium ion batteries |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4567158A (en) * | 1983-12-28 | 1986-01-28 | Monsanto Company | Process for preparing phosphorus-vanadium mixed oxide oxidation catalysts |
| US5102836A (en) * | 1990-06-06 | 1992-04-07 | Center For Innovative Technology | Ceramic materials with low thermal conductivity and low coefficients of thermal expansion |
| US5910382A (en) * | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
| US6203946B1 (en) * | 1998-12-03 | 2001-03-20 | Valence Technology, Inc. | Lithium-containing phosphates, method of preparation, and uses thereof |
| US5871866A (en) * | 1996-09-23 | 1999-02-16 | Valence Technology, Inc. | Lithium-containing phosphates, method of preparation, and use thereof |
| JP2949229B1 (ja) * | 1998-09-16 | 1999-09-13 | 大阪大学長 | 燐酸リチウム・バナジウム複合化合物及び同複合化合物からなるリチウムイオン二次電池用正極材料 |
| US6528033B1 (en) * | 2000-01-18 | 2003-03-04 | Valence Technology, Inc. | Method of making lithium-containing materials |
| US7001690B2 (en) * | 2000-01-18 | 2006-02-21 | Valence Technology, Inc. | Lithium-based active materials and preparation thereof |
| US6777132B2 (en) * | 2000-04-27 | 2004-08-17 | Valence Technology, Inc. | Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials |
| FR2852148B1 (fr) | 2003-03-07 | 2014-04-11 | Batscap Sa | Materiau pour electrode composite, procede pour sa preparation |
| US20040202935A1 (en) * | 2003-04-08 | 2004-10-14 | Jeremy Barker | Cathode active material with increased alkali/metal content and method of making same |
| CN100336247C (zh) * | 2004-03-30 | 2007-09-05 | 中国科学院物理研究所 | 一种锂离子电池的磷酸盐正极材料的制备方法 |
| JP4794833B2 (ja) * | 2004-07-21 | 2011-10-19 | 日本コークス工業株式会社 | リチウムイオン二次電池用正極材料、その製造方法、及びリチウムイオン二次電池 |
| US8062792B2 (en) * | 2005-04-26 | 2011-11-22 | Uchicago Argonne Llc | Processes for making dense, spherical active materials for lithium-ion cells |
| TWI254031B (en) * | 2005-05-10 | 2006-05-01 | Aquire Energy Co Ltd | Manufacturing method of LixMyPO4 compound with olivine structure |
| CN101268572B (zh) * | 2005-09-21 | 2011-08-03 | 国立大学法人九州大学 | 制造正极活性材料的方法和使用其的非水电解质电池 |
| CN100420076C (zh) * | 2005-12-19 | 2008-09-17 | 南开大学 | 溶胶凝胶法合成锂离子电池正极材料磷酸钒锂的方法 |
| US8491861B2 (en) * | 2006-05-26 | 2013-07-23 | Eltron Research, Inc. | Synthetic process for preparation of high surface area electroactive compounds for battery applications |
| JP4926607B2 (ja) * | 2006-08-23 | 2012-05-09 | 住友大阪セメント株式会社 | 電極材料の製造方法及び正極材料並びに電池 |
| CN101636351B (zh) * | 2007-02-28 | 2011-12-14 | 株式会社三德 | 具有橄榄石型结构的化合物、非水电解质二次电池用正极、非水电解质二次电池 |
| JP5182626B2 (ja) * | 2007-06-29 | 2013-04-17 | 株式会社Ｇｓユアサ | 正極活物質および非水電解質電池 |
| TW200951066A (en) * | 2008-04-17 | 2009-12-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
| TW201038469A (en) * | 2009-03-17 | 2010-11-01 | Basf Se | Synthesis of lithium-iron-phosphates |
-
2008
- 2008-09-18 EP EP08804368.2A patent/EP2207751B1/en not_active Not-in-force
- 2008-09-18 US US12/681,193 patent/US20100301281A1/en not_active Abandoned
- 2008-09-18 CN CN2008801186284A patent/CN102123943B/zh not_active Expired - Fee Related
- 2008-09-18 KR KR1020107009706A patent/KR101540133B1/ko not_active Expired - Fee Related
- 2008-09-18 CA CA2701144A patent/CA2701144A1/en not_active Abandoned
- 2008-09-18 WO PCT/EP2008/062427 patent/WO2009043729A2/en not_active Ceased
- 2008-09-18 JP JP2010527394A patent/JP5702145B2/ja not_active Expired - Fee Related
- 2008-09-25 TW TW097136971A patent/TWI401207B/zh not_active IP Right Cessation
-
2013
- 2013-04-02 US US13/855,001 patent/US8808576B2/en not_active Expired - Fee Related
- 2013-04-02 US US13/854,996 patent/US8808575B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108963235A (zh) * | 2018-08-01 | 2018-12-07 | 武汉理工大学 | 石墨烯增强碳包覆磷酸钛锰钠微米球电极材料及其制备方法和应用 |
| CN108963235B (zh) * | 2018-08-01 | 2021-07-23 | 武汉理工大学 | 石墨烯增强碳包覆磷酸钛锰钠微米球电极材料及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200930660A (en) | 2009-07-16 |
| US20100301281A1 (en) | 2010-12-02 |
| JP5702145B2 (ja) | 2015-04-15 |
| CN102123943A (zh) | 2011-07-13 |
| US20130214212A1 (en) | 2013-08-22 |
| EP2207751A2 (en) | 2010-07-21 |
| US8808575B2 (en) | 2014-08-19 |
| WO2009043729A3 (en) | 2009-10-29 |
| KR101540133B1 (ko) | 2015-07-28 |
| US8808576B2 (en) | 2014-08-19 |
| EP2207751B1 (en) | 2013-07-03 |
| TWI401207B (zh) | 2013-07-11 |
| WO2009043729A2 (en) | 2009-04-09 |
| US20130214201A1 (en) | 2013-08-22 |
| KR20100091954A (ko) | 2010-08-19 |
| JP2010540393A (ja) | 2010-12-24 |
| CN102123943B (zh) | 2013-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2207751B1 (en) | Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials | |
| EP2212247B1 (en) | Process for the preparation of crystalline lithium-, vanadium- and phosphate-comprising materials | |
| EP2285740B1 (en) | Process for the preparation of crystalline lithium-, iron- and phosphate-comprising materials | |
| EP2282971B1 (en) | Process for the preparation of crystalline lithium-, iron- and phosphate-comprising materials | |
| US9156693B2 (en) | Synthesis of lithium-metal-phosphates under hydrothermal conditions | |
| US9209461B2 (en) | Process for the preparation of LiFePO4-carbon composites | |
| EP2340228B1 (en) | Synthesis of lifepo4 under hydrothermal conditions | |
| EP2408712B1 (en) | Synthesis of lithium-iron-phosphates under hydrothermal conditions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20130916 |
|
| FZDE | Discontinued |
Effective date: 20160919 |