CA2632734C - Processing aids for elastomeric compositions - Google Patents
Processing aids for elastomeric compositions Download PDFInfo
- Publication number
- CA2632734C CA2632734C CA 2632734 CA2632734A CA2632734C CA 2632734 C CA2632734 C CA 2632734C CA 2632734 CA2632734 CA 2632734 CA 2632734 A CA2632734 A CA 2632734A CA 2632734 C CA2632734 C CA 2632734C
- Authority
- CA
- Canada
- Prior art keywords
- another embodiment
- rubber
- polymer
- phr
- anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 215
- 239000006057 Non-nutritive feed additive Substances 0.000 title claims abstract description 59
- 229920001971 elastomer Polymers 0.000 claims abstract description 172
- 229920000642 polymer Polymers 0.000 claims abstract description 121
- 239000000806 elastomer Substances 0.000 claims abstract description 84
- 238000000034 method Methods 0.000 claims abstract description 68
- 230000008569 process Effects 0.000 claims abstract description 37
- 150000008064 anhydrides Chemical group 0.000 claims abstract description 17
- -1 innertubes Substances 0.000 claims description 89
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 28
- 230000035699 permeability Effects 0.000 claims description 27
- 229920005555 halobutyl Polymers 0.000 claims description 23
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 241001441571 Hiodontidae Species 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 11
- 229920005604 random copolymer Polymers 0.000 claims description 9
- 230000004888 barrier function Effects 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- SYIUWAVTBADRJG-UHFFFAOYSA-N 2H-pyran-2,6(3H)-dione Chemical class O=C1CC=CC(=O)O1 SYIUWAVTBADRJG-UHFFFAOYSA-N 0.000 claims description 2
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 claims description 2
- CQHADWBXOMARTO-UHFFFAOYSA-N 3-prop-1-enyloxolane-2,5-dione Chemical compound CC=CC1CC(=O)OC1=O CQHADWBXOMARTO-UHFFFAOYSA-N 0.000 claims description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 claims 1
- 210000004712 air sac Anatomy 0.000 claims 1
- 239000005060 rubber Substances 0.000 description 86
- 239000003921 oil Substances 0.000 description 71
- 235000019198 oils Nutrition 0.000 description 71
- 229920001577 copolymer Polymers 0.000 description 67
- 238000012545 processing Methods 0.000 description 61
- 229920005549 butyl rubber Polymers 0.000 description 41
- 229920002367 Polyisobutene Polymers 0.000 description 39
- 239000000178 monomer Substances 0.000 description 35
- 229920001083 polybutene Polymers 0.000 description 35
- 238000009472 formulation Methods 0.000 description 34
- 239000000945 filler Substances 0.000 description 33
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 33
- 229920005652 polyisobutylene succinic anhydride Polymers 0.000 description 30
- 239000000126 substance Substances 0.000 description 30
- 238000012360 testing method Methods 0.000 description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 28
- 239000004927 clay Substances 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 27
- 239000006229 carbon black Substances 0.000 description 26
- 235000019241 carbon black Nutrition 0.000 description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 25
- 229910052717 sulfur Inorganic materials 0.000 description 25
- 239000011593 sulfur Substances 0.000 description 25
- 238000002156 mixing Methods 0.000 description 24
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 21
- 239000005977 Ethylene Substances 0.000 description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
- 229920005557 bromobutyl Polymers 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 21
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 20
- 229920005989 resin Polymers 0.000 description 20
- 239000011347 resin Substances 0.000 description 20
- 229920000265 Polyparaphenylene Polymers 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 238000002844 melting Methods 0.000 description 17
- 230000008018 melting Effects 0.000 description 17
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 16
- 229910052736 halogen Inorganic materials 0.000 description 16
- 230000000704 physical effect Effects 0.000 description 16
- 229920013639 polyalphaolefin Polymers 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- 229920006126 semicrystalline polymer Polymers 0.000 description 15
- 229920000034 Plastomer Polymers 0.000 description 14
- 239000000654 additive Substances 0.000 description 14
- 150000001336 alkenes Chemical class 0.000 description 14
- 150000001993 dienes Chemical class 0.000 description 14
- 238000009826 distribution Methods 0.000 description 14
- 238000004073 vulcanization Methods 0.000 description 14
- 239000011787 zinc oxide Substances 0.000 description 14
- 244000043261 Hevea brasiliensis Species 0.000 description 13
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 13
- 235000021355 Stearic acid Nutrition 0.000 description 13
- 150000002367 halogens Chemical class 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- 229920003052 natural elastomer Polymers 0.000 description 13
- 229920001194 natural rubber Polymers 0.000 description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 13
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 13
- 239000008117 stearic acid Substances 0.000 description 13
- 229920001519 homopolymer Polymers 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 12
- 230000035882 stress Effects 0.000 description 12
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 11
- 239000002480 mineral oil Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 10
- 239000002114 nanocomposite Substances 0.000 description 10
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 125000000524 functional group Chemical group 0.000 description 9
- 229920002857 polybutadiene Polymers 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- 229920005992 thermoplastic resin Polymers 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- 206010011416 Croup infectious Diseases 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229920001897 terpolymer Polymers 0.000 description 8
- 229920002943 EPDM rubber Polymers 0.000 description 7
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 7
- 229920000459 Nitrile rubber Polymers 0.000 description 7
- 239000004952 Polyamide Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 239000012188 paraffin wax Substances 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 238000010058 rubber compounding Methods 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 6
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 239000006085 branching agent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920001195 polyisoprene Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 description 6
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 230000026030 halogenation Effects 0.000 description 5
- 238000005658 halogenation reaction Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- 229920003051 synthetic elastomer Polymers 0.000 description 5
- 239000005061 synthetic rubber Substances 0.000 description 5
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 239000004711 α-olefin Substances 0.000 description 5
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 4
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 4
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 229940126214 compound 3 Drugs 0.000 description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920001084 poly(chloroprene) Polymers 0.000 description 4
- 229920006380 polyphenylene oxide Polymers 0.000 description 4
- 229920000069 polyphenylene sulfide Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 3
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical class CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 description 3
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005063 High cis polybutadiene Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 239000010692 aromatic oil Substances 0.000 description 3
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 150000001735 carboxylic acids Chemical group 0.000 description 3
- 229920005556 chlorobutyl Polymers 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000011143 downstream manufacturing Methods 0.000 description 3
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- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
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- 229910000271 hectorite Inorganic materials 0.000 description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 3
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
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- 239000011701 zinc Substances 0.000 description 3
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
- GNWUJOLBZOVBAF-UHFFFAOYSA-N 3-methylfuran-2,5-dione;3h-pyran-2,6-dione Chemical compound CC1=CC(=O)OC1=O.O=C1CC=CC(=O)O1 GNWUJOLBZOVBAF-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 238000006596 Alder-ene reaction Methods 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0008—Compositions of the inner liner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C5/00—Inflatable pneumatic tyres or inner tubes
- B60C5/02—Inflatable pneumatic tyres or inner tubes having separate inflatable inserts, e.g. with inner tubes; Means for lubricating, venting, preventing relative movement between tyre and inner tube
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
- C08L19/006—Rubber characterised by functional groups, e.g. telechelic diene polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/36—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with nitrogen-containing compounds, e.g. by nitration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2005/045978 WO2007070063A1 (en) | 2005-12-16 | 2005-12-16 | Processing aids for elastomeric compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2632734A1 CA2632734A1 (en) | 2007-06-21 |
| CA2632734C true CA2632734C (en) | 2011-07-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2632734 Expired - Fee Related CA2632734C (en) | 2005-12-16 | 2005-12-16 | Processing aids for elastomeric compositions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7960454B2 (https=) |
| EP (1) | EP1969016B1 (https=) |
| JP (1) | JP5690471B2 (https=) |
| CN (1) | CN101326199B (https=) |
| AT (1) | ATE466032T1 (https=) |
| CA (1) | CA2632734C (https=) |
| DE (1) | DE602005020997D1 (https=) |
| WO (1) | WO2007070063A1 (https=) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7714043B2 (en) * | 2000-10-18 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Tire innerliners having improved cold temperature properties |
| DE602005020532D1 (de) * | 2005-12-16 | 2010-05-20 | Exxonmobil Chem Patents Inc | Verfahrenshilfsmittel für elastomerzusammensetzungen |
| EP1803771B1 (en) * | 2005-12-28 | 2017-12-06 | Bridgestone Corporation | A rubber composition having good wet-traction properties and a low aromatic-oil content |
| US20070218165A1 (en) * | 2006-03-15 | 2007-09-20 | Wm. Wrigley Jr. Company | Confectionery compositions using nanomaterials |
| CN101742920A (zh) * | 2007-05-25 | 2010-06-16 | Wm.雷格利Jr.公司 | 包含溶液聚合苯乙烯丁二烯无规共聚物弹性体的改善的口香糖 |
| US7985793B2 (en) | 2007-06-29 | 2011-07-26 | Exxonmobil Chemical Patents Inc. | Composites comprising elastomer, layered filler and tackifier |
| KR101615391B1 (ko) * | 2007-10-19 | 2016-04-25 | 란세스 인크. | 3성분 혼합 개질제 시스템을 포함하는 부틸 고무 배합물 |
| US20090151828A1 (en) * | 2007-12-15 | 2009-06-18 | Junling Zhao | Tire with antenna encapsulated with rubber compound containing thermoplastic |
| CN103524804B (zh) | 2007-12-31 | 2017-03-29 | 株式会社普利司通 | 引入橡胶组合物的金属皂及金属皂引入橡胶组合物的方法 |
| JP2011526327A (ja) * | 2008-06-26 | 2011-10-06 | 株式会社ブリヂストン | 金属で官能化されたポリイソブチレン誘導体を含むゴム組成物及びかかる組成物の調製方法 |
| FR2933417B1 (fr) * | 2008-07-04 | 2011-12-30 | Michelin Soc Tech | Bande de roulement de pneumatique |
| US8476352B2 (en) | 2008-08-08 | 2013-07-02 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising hydrocarbon polymer additives having improved impermeability |
| US8389609B2 (en) | 2009-07-01 | 2013-03-05 | Bridgestone Corporation | Multiple-acid-derived metal soaps incorporated in rubber compositions and method for incorporating such soaps in rubber compositions |
| US8809455B2 (en) | 2009-08-27 | 2014-08-19 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions and their use in articles |
| US9803060B2 (en) | 2009-09-10 | 2017-10-31 | Bridgestone Corporation | Compositions and method for making hollow nanoparticles from metal soaps |
| US9475910B2 (en) * | 2009-10-26 | 2016-10-25 | Exxonmobil Chemical Patents Inc. | Elastomer nanocomposites with incorporated process oils |
| CN102695603B (zh) * | 2009-11-19 | 2015-03-25 | 埃克森美孚化学专利公司 | 充气内衬的制备方法 |
| US9573347B2 (en) * | 2009-12-15 | 2017-02-21 | Teknor Apex Company | Thermoplastic elastomer with desirable grip especially during wet conditions |
| CN102372894B (zh) * | 2010-08-13 | 2013-01-23 | 上海锦湖日丽塑料有限公司 | 一种抗静电的热塑性弹性体组合物及其制备方法 |
| CN102372893B (zh) * | 2010-08-13 | 2013-01-02 | 上海锦湖日丽塑料有限公司 | 一种苯乙烯类热塑性弹性体组合物及其制备方法 |
| US8454778B2 (en) * | 2010-11-15 | 2013-06-04 | Ramendra Nath Majumdar | Pneumatic tire with barrier layer and method of making the same |
| FR2970256B1 (fr) * | 2010-11-30 | 2013-01-11 | Michelin Soc Tech | Pneumatique comportant une sous-couche de bande de roulement a base de caoutchouc nitrile. |
| US8802755B2 (en) | 2011-01-18 | 2014-08-12 | Bridgestone Corporation | Rubber compositions including metal phosphate esters |
| US9090753B2 (en) * | 2011-08-11 | 2015-07-28 | Bridgestone Corporation | Rubber composition and pneumatic tire using the rubber composition |
| KR101771375B1 (ko) | 2011-10-05 | 2017-08-24 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 타이어 경화 블래더 |
| ES2401813B2 (es) * | 2011-10-11 | 2013-08-12 | Industrias Químicas Del Ebro, S.A. | Carga reforzante de caucho. |
| RU2589714C2 (ru) | 2011-12-19 | 2016-07-10 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерные композиции и их применение в изделиях |
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-
2005
- 2005-12-16 CA CA 2632734 patent/CA2632734C/en not_active Expired - Fee Related
- 2005-12-16 WO PCT/US2005/045978 patent/WO2007070063A1/en not_active Ceased
- 2005-12-16 CN CN2005800523111A patent/CN101326199B/zh not_active Expired - Fee Related
- 2005-12-16 AT AT05854651T patent/ATE466032T1/de not_active IP Right Cessation
- 2005-12-16 JP JP2008545557A patent/JP5690471B2/ja not_active Expired - Fee Related
- 2005-12-16 EP EP20050854651 patent/EP1969016B1/en not_active Expired - Lifetime
- 2005-12-16 US US12/093,786 patent/US7960454B2/en active Active
- 2005-12-16 DE DE200560020997 patent/DE602005020997D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN101326199A (zh) | 2008-12-17 |
| JP5690471B2 (ja) | 2015-03-25 |
| US20080281021A1 (en) | 2008-11-13 |
| CN101326199B (zh) | 2011-11-16 |
| US7960454B2 (en) | 2011-06-14 |
| WO2007070063A1 (en) | 2007-06-21 |
| EP1969016B1 (en) | 2010-04-28 |
| CA2632734A1 (en) | 2007-06-21 |
| JP2009520050A (ja) | 2009-05-21 |
| DE602005020997D1 (de) | 2010-06-10 |
| ATE466032T1 (de) | 2010-05-15 |
| EP1969016A1 (en) | 2008-09-17 |
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