CA2522217C - Methods of processing nickel-titanium shape memory alloys - Google Patents
Methods of processing nickel-titanium shape memory alloys Download PDFInfo
- Publication number
- CA2522217C CA2522217C CA2522217A CA2522217A CA2522217C CA 2522217 C CA2522217 C CA 2522217C CA 2522217 A CA2522217 A CA 2522217A CA 2522217 A CA2522217 A CA 2522217A CA 2522217 C CA2522217 C CA 2522217C
- Authority
- CA
- Canada
- Prior art keywords
- nickel
- aging
- titanium alloy
- temperature
- austenite transformation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910001000 nickel titanium Inorganic materials 0.000 title claims abstract description 284
- 238000012545 processing Methods 0.000 title claims abstract description 142
- 238000000034 method Methods 0.000 title claims abstract description 108
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 229910001285 shape-memory alloy Inorganic materials 0.000 title description 6
- 230000009466 transformation Effects 0.000 claims abstract description 307
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 270
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 265
- 239000000956 alloy Substances 0.000 claims abstract description 265
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 255
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 130
- 229910010380 TiNi Inorganic materials 0.000 claims abstract description 55
- 239000006104 solid solution Substances 0.000 claims abstract description 35
- 230000032683 aging Effects 0.000 claims description 297
- 239000000203 mixture Substances 0.000 claims description 45
- 239000007787 solid Substances 0.000 claims description 28
- 238000005275 alloying Methods 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 60
- 230000000670 limiting effect Effects 0.000 description 44
- 239000002244 precipitate Substances 0.000 description 13
- 229910000734 martensite Inorganic materials 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- 230000007423 decrease Effects 0.000 description 10
- 238000011282 treatment Methods 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000006911 nucleation Effects 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910004337 Ti-Ni Inorganic materials 0.000 description 3
- 229910011209 Ti—Ni Inorganic materials 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 229910010381 TiNi3 Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000007734 materials engineering Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 238000004881 precipitation hardening Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- LMBUSUIQBONXAS-UHFFFAOYSA-N [Ti].[Fe].[Ni] Chemical compound [Ti].[Fe].[Ni] LMBUSUIQBONXAS-UHFFFAOYSA-N 0.000 description 1
- WCERXPKXJMFQNQ-UHFFFAOYSA-N [Ti].[Ni].[Cu] Chemical compound [Ti].[Ni].[Cu] WCERXPKXJMFQNQ-UHFFFAOYSA-N 0.000 description 1
- ZETVWNYVYYVTAU-UHFFFAOYSA-N [Ti].[Ni].[Hf] Chemical compound [Ti].[Ni].[Hf] ZETVWNYVYYVTAU-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910002059 quaternary alloy Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 238000010313 vacuum arc remelting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/006—Resulting in heat recoverable alloys with a memory effect
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Heat Treatment Of Steel (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Adornments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/427,783 | 2003-05-01 | ||
| US10/427,783 US7192496B2 (en) | 2003-05-01 | 2003-05-01 | Methods of processing nickel-titanium alloys |
| PCT/US2004/010758 WO2004099456A1 (en) | 2003-05-01 | 2004-04-07 | Methods of processing nickel-titanium shape memory alloys |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2522217A1 CA2522217A1 (en) | 2004-11-18 |
| CA2522217C true CA2522217C (en) | 2011-07-19 |
Family
ID=33310255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2522217A Expired - Fee Related CA2522217C (en) | 2003-05-01 | 2004-04-07 | Methods of processing nickel-titanium shape memory alloys |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US7192496B2 (enExample) |
| EP (2) | EP1623050A1 (enExample) |
| JP (2) | JP5535426B2 (enExample) |
| KR (1) | KR101048531B1 (enExample) |
| CN (1) | CN1780924B (enExample) |
| AU (1) | AU2004236647B2 (enExample) |
| BR (1) | BRPI0409953A (enExample) |
| CA (1) | CA2522217C (enExample) |
| HK (1) | HK1201891A1 (enExample) |
| IL (3) | IL171390A (enExample) |
| MX (1) | MXPA05011265A (enExample) |
| NO (1) | NO20055684L (enExample) |
| NZ (1) | NZ543066A (enExample) |
| RU (1) | RU2344196C2 (enExample) |
| TW (1) | TWI295692B (enExample) |
| UA (1) | UA85384C2 (enExample) |
| WO (1) | WO2004099456A1 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004092431A1 (en) * | 2003-04-18 | 2004-10-28 | The University Of Hong Kong | Shape memory material and method of making the same |
| DE202004021289U1 (de) * | 2003-05-14 | 2007-06-06 | Kraus, Kilian | Höhenverstellbares Implantat zum Einsetzen zwischen Wirbelkörpern und Handhabungswerkzeug |
| EP1663330B1 (en) * | 2003-08-08 | 2006-12-27 | Biorthex Inc. | Biocompatible porous ti-ni material |
| DE10357926B3 (de) | 2003-12-11 | 2005-09-01 | Deltacor Gmbh | Längenverstellbares Wirbelsäulen-Implantat |
| WO2006041460A1 (en) * | 2004-10-04 | 2006-04-20 | Saint Louis University | Intramedullary nail device and method for repairing long bone |
| US20070073374A1 (en) * | 2005-09-29 | 2007-03-29 | Anderl Steven F | Endoprostheses including nickel-titanium alloys |
| US9103006B2 (en) * | 2006-09-06 | 2015-08-11 | Cook Medical Technologies Llc | Nickel-titanium alloy including a rare earth element |
| EP2238270A2 (en) * | 2007-12-21 | 2010-10-13 | Cook Incorporated | Radiopaque alloy and medical device made of this alloy |
| US8225478B2 (en) * | 2008-01-30 | 2012-07-24 | The Boeing Company | Memory shape bushings and bearings |
| US20090205826A1 (en) * | 2008-02-19 | 2009-08-20 | Alejandro Rodriguez | Method for Increasing the Fluid Productivity of a Hydraulically Fractured Well |
| RU2374356C1 (ru) * | 2008-04-28 | 2009-11-27 | Закрытое акционерное общество "Промышленный центр МАТЭКС" | Способ термомеханической обработки изделий из сплава на основе никелида титана |
| GB2467584B (en) * | 2009-02-10 | 2010-12-29 | Rolls Royce Plc | An assembly |
| IN2012DN01421A (enExample) * | 2009-08-07 | 2015-06-05 | Innovative Proc Technologies Inc | |
| GB2475340B (en) | 2009-11-17 | 2013-03-27 | Univ Limerick | Nickel-titanium alloy and method of processing the alloy |
| US8216398B2 (en) * | 2010-05-17 | 2012-07-10 | Saint Louis University | Method for controlling phase transformation temperature in metal alloy of a device |
| DE102010026048A1 (de) * | 2010-07-03 | 2012-01-05 | Mtu Aero Engines Gmbh | Nickelbasis-Lotlegierung |
| US8475711B2 (en) | 2010-08-12 | 2013-07-02 | Ati Properties, Inc. | Processing of nickel-titanium alloys |
| GB2495772B (en) | 2011-10-21 | 2014-02-12 | Univ Limerick | Method of forming a sintered nickel-titanium-rare earth (Ni-Ti-RE) alloy |
| JP6199897B2 (ja) | 2012-01-18 | 2017-09-20 | クック・メディカル・テクノロジーズ・リミテッド・ライアビリティ・カンパニーＣｏｏｋ Ｍｅｄｉｃａｌ Ｔｅｃｈｎｏｌｏｇｉｅｓ Ｌｌｃ | ニッケル−チタン−希土類金属（Ｎｉ−Ｔｉ−ＲＥ）焼結合金を製造するための粉末混合物 |
| US20130239565A1 (en) * | 2012-03-16 | 2013-09-19 | GM Global Technology Operations LLC | Spatially graded sma actuators |
| US9279171B2 (en) | 2013-03-15 | 2016-03-08 | Ati Properties, Inc. | Thermo-mechanical processing of nickel-titanium alloys |
| CN104099544A (zh) * | 2013-04-07 | 2014-10-15 | 北京有色金属研究总院 | 形状记忆合金获得全程记忆效应的方法 |
| CN103422038B (zh) * | 2013-09-04 | 2015-04-08 | 上海康晟特种合金有限公司 | 用于高温铜合金挤压机的内衬模套的热处理方法 |
| CN105517504B (zh) | 2013-09-06 | 2020-08-04 | 奥姆科公司 | 正畸矫治器以及制造和使用该正畸矫治器的方法 |
| US9982330B2 (en) | 2013-11-27 | 2018-05-29 | University Of Florida Research Foundation, Inc. | Nickel titanium alloys, methods of manufacture thereof and article comprising the same |
| WO2015126419A1 (en) * | 2014-02-24 | 2015-08-27 | Halliburton Energy Services, Inc. | Propping subterranean formation fractures using memory particulates |
| FR3033487B1 (fr) * | 2015-03-11 | 2021-01-08 | Soprane | Perfectionnements aux aiguilles hyper elastiques |
| WO2018076010A1 (en) | 2016-10-21 | 2018-04-26 | Confluent Medical Technologies, Inc. | Materials having superelastic properties including related methods of fabrication and design for medical devices |
| CN110465662B (zh) * | 2019-08-09 | 2021-01-19 | 华南理工大学 | 一种原位调控镍钛合金功能特性的4d打印方法及应用 |
| CN113235028B (zh) * | 2021-04-06 | 2022-06-14 | 华南理工大学 | 一种高马氏体相变温度的镍钛形状记忆合金的训练方法 |
| CN113308656B (zh) * | 2021-05-28 | 2022-05-03 | 中国石油大学(北京) | 增材制造超弹镍钛合金的后处理方法及其应用 |
| CN115233122A (zh) * | 2022-07-27 | 2022-10-25 | 天津大学 | 一种NiTi合金双程形状记忆效应的训练方法及其产品 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4283233A (en) * | 1980-03-07 | 1981-08-11 | The United States Of America As Represented By The Secretary Of The Navy | Method of modifying the transition temperature range of TiNi base shape memory alloys |
| JPS58151445A (ja) * | 1982-02-27 | 1983-09-08 | Tohoku Metal Ind Ltd | 可逆形状記憶効果を有するチタンニツケル合金およびその製造方法 |
| US4533411A (en) * | 1983-11-15 | 1985-08-06 | Raychem Corporation | Method of processing nickel-titanium-base shape-memory alloys and structure |
| US4654092A (en) * | 1983-11-15 | 1987-03-31 | Raychem Corporation | Nickel-titanium-base shape-memory alloy composite structure |
| US4631094A (en) * | 1984-11-06 | 1986-12-23 | Raychem Corporation | Method of processing a nickel/titanium-based shape memory alloy and article produced therefrom |
| US4770725A (en) * | 1984-11-06 | 1988-09-13 | Raychem Corporation | Nickel/titanium/niobium shape memory alloy & article |
| SU1431353A1 (ru) * | 1987-10-31 | 1995-06-09 | Московский авиационный технологический институт им.К.Э.Циолковского | Способ термической обработки сплавов на основе никелида титана |
| EP0753080A1 (en) * | 1994-03-31 | 1997-01-15 | Petrus Antonius Besselink | Ni-Ti-Nb ALLOY PROCESSING METHOD AND ARTICLES FORMED FROM THE ALLOY |
| US5624508A (en) * | 1995-05-02 | 1997-04-29 | Flomenblit; Josef | Manufacture of a two-way shape memory alloy and device |
| US5882444A (en) * | 1995-05-02 | 1999-03-16 | Litana Ltd. | Manufacture of two-way shape memory devices |
| JP2899682B2 (ja) | 1996-03-22 | 1999-06-02 | 科学技術庁金属材料技術研究所長 | Ｔｉ−Ｎｉ系形状記憶合金とその製造方法 |
| US5843244A (en) * | 1996-06-13 | 1998-12-01 | Nitinol Devices And Components | Shape memory alloy treatment |
| CN1170834A (zh) * | 1996-07-16 | 1998-01-21 | 中国科学院固体物理研究所 | 具有反常记忆效应钛镍弹簧及制备 |
| FR2758338B1 (fr) * | 1997-01-16 | 1999-04-09 | Memometal Ind | Procede de fabrication d'une piece superelastique en alliage de nickel et de titane |
| DE69729807T2 (de) * | 1997-04-25 | 2005-07-14 | Litana Ltd. | Herstellung von zweiwegformgedächtnisteilen |
| RU2201470C2 (ru) * | 1997-04-25 | 2003-03-27 | Литана Лтд. | Способ получения сплава с двойной памятью формы и способ изготовления устройств из этого сплава |
| CN1084800C (zh) * | 1997-04-25 | 2002-05-15 | 利塔那有限公司 | 双程形状记忆合金及器件的制造方法 |
| US6106642A (en) * | 1998-02-19 | 2000-08-22 | Boston Scientific Limited | Process for the improved ductility of nitinol |
| US6149742A (en) * | 1998-05-26 | 2000-11-21 | Lockheed Martin Corporation | Process for conditioning shape memory alloys |
| JP3782289B2 (ja) * | 2000-07-06 | 2006-06-07 | トキコーポレーション株式会社 | 形状記憶合金の処理方法および形状記憶合金 |
| US6416564B1 (en) | 2001-03-08 | 2002-07-09 | Ati Properties, Inc. | Method for producing large diameter ingots of nickel base alloys |
-
2003
- 2003-05-01 US US10/427,783 patent/US7192496B2/en not_active Expired - Fee Related
-
2004
- 2004-04-07 KR KR1020057020630A patent/KR101048531B1/ko not_active Expired - Fee Related
- 2004-04-07 BR BRPI0409953-2A patent/BRPI0409953A/pt not_active Application Discontinuation
- 2004-04-07 WO PCT/US2004/010758 patent/WO2004099456A1/en not_active Ceased
- 2004-04-07 CA CA2522217A patent/CA2522217C/en not_active Expired - Fee Related
- 2004-04-07 CN CN2004800117842A patent/CN1780924B/zh not_active Expired - Fee Related
- 2004-04-07 AU AU2004236647A patent/AU2004236647B2/en not_active Ceased
- 2004-04-07 JP JP2006509794A patent/JP5535426B2/ja not_active Expired - Fee Related
- 2004-04-07 UA UAA200511376A patent/UA85384C2/ru unknown
- 2004-04-07 EP EP04749864A patent/EP1623050A1/en not_active Withdrawn
- 2004-04-07 RU RU2005137319/02A patent/RU2344196C2/ru not_active IP Right Cessation
- 2004-04-07 MX MXPA05011265A patent/MXPA05011265A/es active IP Right Grant
- 2004-04-07 NZ NZ543066A patent/NZ543066A/xx not_active IP Right Cessation
- 2004-04-07 EP EP14184480.3A patent/EP2818565A1/en not_active Withdrawn
- 2004-04-30 TW TW093112375A patent/TWI295692B/zh active
-
2005
- 2005-10-11 IL IL171390A patent/IL171390A/en not_active IP Right Cessation
- 2005-12-01 NO NO20055684A patent/NO20055684L/no not_active Application Discontinuation
-
2006
- 2006-03-22 HK HK15102262.0A patent/HK1201891A1/en unknown
-
2007
- 2007-02-19 US US11/676,348 patent/US7628874B2/en not_active Expired - Fee Related
-
2010
- 2010-01-06 IL IL203162A patent/IL203162A/en not_active IP Right Cessation
- 2010-01-06 IL IL203166A patent/IL203166A/en not_active IP Right Cessation
-
2013
- 2013-07-12 JP JP2013146206A patent/JP2014015681A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060004970A (ko) | 2006-01-16 |
| JP2014015681A (ja) | 2014-01-30 |
| EP2818565A1 (en) | 2014-12-31 |
| AU2004236647A1 (en) | 2004-11-18 |
| IL171390A (en) | 2011-03-31 |
| NO20055684L (no) | 2005-12-01 |
| JP2006525430A (ja) | 2006-11-09 |
| BRPI0409953A (pt) | 2006-04-25 |
| IL203162A (en) | 2011-09-27 |
| WO2004099456A1 (en) | 2004-11-18 |
| IL203166A0 (en) | 2011-08-01 |
| KR101048531B1 (ko) | 2011-07-11 |
| NZ543066A (en) | 2009-02-28 |
| EP1623050A1 (en) | 2006-02-08 |
| CA2522217A1 (en) | 2004-11-18 |
| HK1089793A1 (en) | 2006-12-08 |
| IL203166A (en) | 2011-09-27 |
| TWI295692B (en) | 2008-04-11 |
| HK1201891A1 (en) | 2015-09-11 |
| AU2004236647B2 (en) | 2009-10-22 |
| RU2344196C2 (ru) | 2009-01-20 |
| US20040216816A1 (en) | 2004-11-04 |
| CN1780924A (zh) | 2006-05-31 |
| JP5535426B2 (ja) | 2014-07-02 |
| US7628874B2 (en) | 2009-12-08 |
| MXPA05011265A (es) | 2006-01-24 |
| IL203162A0 (en) | 2011-08-01 |
| UA85384C2 (ru) | 2009-01-26 |
| CN1780924B (zh) | 2010-12-15 |
| TW200513541A (en) | 2005-04-16 |
| US7192496B2 (en) | 2007-03-20 |
| US20070163688A1 (en) | 2007-07-19 |
| RU2005137319A (ru) | 2006-04-27 |
Similar Documents
| Publication | Publication Date | Title |
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