CA2508043A1 - Procede de preparation de catalyseurs d'epoxydation - Google Patents

Procede de preparation de catalyseurs d'epoxydation Download PDF

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Publication number
CA2508043A1
CA2508043A1 CA002508043A CA2508043A CA2508043A1 CA 2508043 A1 CA2508043 A1 CA 2508043A1 CA 002508043 A CA002508043 A CA 002508043A CA 2508043 A CA2508043 A CA 2508043A CA 2508043 A1 CA2508043 A1 CA 2508043A1
Authority
CA
Canada
Prior art keywords
carrier
process according
catalyst
preparation
hydroperoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002508043A
Other languages
English (en)
Inventor
Johannes Petrus Van Der Linden
Eduardus Petrus Simon Schouten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2508043A1 publication Critical patent/CA2508043A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention se rapporte à un procédé de préparation d'un catalyseur d'époxydation, qui consiste à imprégner un support contenant du silicium avec un flux gazeux constitué d'halogénure de titane, et à un procédé de préparation d'oxyde d'alkylène à l'aide d'un tel catalyseur.
CA002508043A 2002-12-02 2003-11-24 Procede de preparation de catalyseurs d'epoxydation Abandoned CA2508043A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02258296 2002-12-02
EP02258296.9 2002-12-02
PCT/EP2003/050875 WO2004050233A1 (fr) 2002-12-02 2003-11-24 Procede de preparation de catalyseurs d'epoxydation

Publications (1)

Publication Number Publication Date
CA2508043A1 true CA2508043A1 (fr) 2004-06-17

Family

ID=32405785

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002508043A Abandoned CA2508043A1 (fr) 2002-12-02 2003-11-24 Procede de preparation de catalyseurs d'epoxydation

Country Status (8)

Country Link
EP (1) EP1567261A1 (fr)
JP (1) JP2006507932A (fr)
CN (1) CN1720097A (fr)
AU (1) AU2003298312A1 (fr)
BR (1) BR0316825A (fr)
CA (1) CA2508043A1 (fr)
MX (1) MXPA05005699A (fr)
WO (1) WO2004050233A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2008147409A (ru) 2006-05-02 2010-06-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Титановый катализатор, способ его получения и использование в реакциях эпоксидирования
BR112013001173A2 (pt) 2010-07-19 2016-05-31 Shell Int Research "processo de epoxidação para a preparação de óxido de alquileno."
EP2859946A1 (fr) * 2013-10-11 2015-04-15 Repsol, S.A. Procédé de régénération de catalyseurs d'époxydation hétérogènes et leur utilisation pour catalyser des réactions d'époxydation
CN108349918A (zh) 2015-11-09 2018-07-31 国际壳牌研究有限公司 催化剂制备

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8813484D0 (en) * 1988-06-08 1988-07-13 Shell Int Research Process for preparation of oxirane compound
FI87892C (fi) * 1991-07-16 1993-03-10 Neste Oy Foerfarande foer framstaellning av heterogena katalysatorer med oenskad metallhalt
FR2704159B1 (fr) * 1993-04-22 1995-06-09 Atochem Elf Sa Catalyseur solide à base de silice particulaire, comportant du titane, Procédé d'obtention, et utilisation dans l'époxydation d'oléfines.
FI96611C (fi) * 1993-09-10 1996-07-25 Neste Oy Heterogeeninen polymerointikatalyytti ja menetelmä sen valmistamiseksi
ES2213285T3 (es) * 1997-05-05 2004-08-16 Arco Chemical Technology, L.P. Procedimiento de epoxidacion usando una composicion de catalizador heterogeneo mejorada.
US6114552A (en) * 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst

Also Published As

Publication number Publication date
EP1567261A1 (fr) 2005-08-31
WO2004050233A8 (fr) 2004-08-05
JP2006507932A (ja) 2006-03-09
MXPA05005699A (es) 2005-07-26
WO2004050233A1 (fr) 2004-06-17
BR0316825A (pt) 2005-10-18
CN1720097A (zh) 2006-01-11
AU2003298312A1 (en) 2004-06-23

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Legal Events

Date Code Title Description
FZDE Discontinued