CA2476971A1 - Low sidestream smoke cigarette with combustible paper having modified ash - Google Patents
Low sidestream smoke cigarette with combustible paper having modified ash Download PDFInfo
- Publication number
- CA2476971A1 CA2476971A1 CA002476971A CA2476971A CA2476971A1 CA 2476971 A1 CA2476971 A1 CA 2476971A1 CA 002476971 A CA002476971 A CA 002476971A CA 2476971 A CA2476971 A CA 2476971A CA 2476971 A1 CA2476971 A1 CA 2476971A1
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- CA
- Canada
- Prior art keywords
- oxide
- sidestream smoke
- cerium
- smoke cigarette
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
Abstract
A low sidestream smoke cigarette comprises a conventional tobacco rod (54), and a combustible treatment paper (56, 58) having a sidestream smoke treatme nt composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non- combustible particulate adjunct for said catalyst. Improvements are made in the treatment composition and/or the addition of metal oxides or carbonates thereto to improve ash characteristics.
Claims (77)
1. In a low sidestream smoke cigarette having a conventional tobacco rod and a combustible treatment paper, said treatment paper having a sidestream smoke treatment composition comprising an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided particulate adjunct for said catalyst, the improvement comprising the use of a solid solution of particulate mixed metal oxides as said catalyst and said adjunct.
2. In a low sidestream smoke cigarette of claim 1, said oxygen storage and donor metal oxide oxidation catalyst for the solid solution being selected from the group consisting of lanthanum oxide, cerium oxide, praseodymium oxide, neodymium oxide and mixtures thereof.
3. In a low sidestream smoke cigarette of claim 1, said adjunct is selected from the group of metal oxides consisting of zirconium oxide, aluminum oxide, magnesium oxides, titanium oxide and mixtures thereof.
4. In a low sidestream smoke cigarette of claim 1, 2 or 3, said solid solution of mixed metal oxides further comprising an oxidation catalyst selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide and mixtures thereof.
5. In a low sidestream smoke cigarette of claim 1, 2, 3 or 4, said solid solution of mixed metal oxides being selected from the group consisting of cerium/lanthinum mixed oxide, cerium/zirconium mixed oxide, cerium/
zirconium/lanthinum mixed oxide, cerium/zirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide and mixtures thereof.
zirconium/lanthinum mixed oxide, cerium/zirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide and mixtures thereof.
6. In a low sidestream smoke cigarette of any one of claims 1 to 5, said solid solution being a high surface area porous particulate.
7. In a low sidestream smoke cigarette of claim 6, said solid solution being a low surface area particulate.
8. In a low sidestream smoke cigarette of claim 6, wherein said catalyst and said adjunct is said high surface area cerium/zirconium mixed oxide.
9. In a low sidestream smoke cigarette of claim 1, wherein a catalyst selected from .the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide and mixtures thereof is either included in said solid solution of cerium/zirconium mixed oxide or is applied to the surface of said high surface area cerium/zirconium mixed oxide.
10. In a low sidestream smoke cigarette of claim 9, wherein said cerium/zirconium mixed oxide has a particle size greater than about 1 µm.
11. In a low sidestream smoke cigarette of claim 10, wherein said cerium/zirconium mixed oxide has a particle size less than about 30 µm.
12. In a low sidestream smoke cigarette of claim 8, wherein said cerium/zirconium mixed oxide have a ratio ranging from about 5:95 to about 95:5.
13. In a low sidestream smoke cigarette of claim 12, wherein said ratio is about 75:25 and said particle size is about 6 µm to 10 µm.
14. In a low sidestream smoke cigarette of claim 1, wherein said treatment composition is incorporated within said treatment paper at a loading rate of about 2.5 g/m2 to about 125 g/m2.
15. In a low sidestream smoke cigarette of claim 1, wherein said treatment composition is coated on said treatment paper.
16. In a low sidestream smoke cigarette of claim 8, wherein said treatment composition includes particulate zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, cerium oxide, tin oxide, iron oxide, manganese oxide, calcium carbonate, zirconium carbonate, magnesium carbonate and mixtures thereof.
17. In a low sidestream smoke cigarette of claim 8, wherein said treatment composition includes particulate zeolite.
18. In a low sidestream smoke cigarette of claim 17, wherein said zeolite is a carrier for an oxidation catalyst selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide, and mixtures thereof.
19. In a low sidestream smoke cigarette of claim 8, wherein said treatment composition includes zirconium oxide.
20. A low sidestream smoke cigarette comprising a conventional tobacco rod and a combustible treatment paper having a sidestream smoke treatment composition, said treatment composition comprising an oxygen storage and donor metal oxide oxidation catalyst, an essentially non-combustible particulate adjunct for said catalyst and a metal oxide or carbonate for modifying ash characteristics.
21. A low sidestream smoke cigarette of claim 20, wherein said adjunct is a high surface area particulate.
22. A low sidestream smoke cigarette of claim 21, wherein said particulate adjunct is a zeolite based material ranging from about 0.1% by weight of total dry weight composition to about 60% by weight of total dry weight composition and preferably less than 25% by weight and most preferably less than 15% by weight.
23. A low sidestream smoke cigarette of claim 21, wherein said ash modifying metal oxide or carbonate is selected from the group consisting of zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, cerium oxide, tin oxide, iron oxide, manganese oxide, calcium carbonate, zirconium carbonate, magnesium carbonate and mixtures thereof.
24. A low sidestream smoke cigarette of claim 20, wherein said adjunct is a support for a ceria sol to be applied thereto and dried.
25. A low sidestream smoke cigarette of claim 24, wherein said adjunct is high surface area cerium oxide.
26. A low sidestream smoke cigarette of claim 20, wherein said oxygen storage and donor metal oxide oxidation catalyst is selected from a group consisting of transition metal oxides, rare earth metal oxides and mixtures thereof.
27. A low sidestream smoke cigarette of claim 26, wherein said transition metal oxides are selected from the group consisting of oxides of group IVB, VB, VIB, VIIB, VIIIB, IB metals and mixtures thereof.
28. A low sidestream smoke cigarette of claim 27, wherein said rare earth metal oxide is selected from the group consisting of oxides consisting of scandium, yttrium and lanthanide metals and mixtures thereof.
29. A low sidestream smoke cigarette of claim 20 wherein said lanthanide metals oxide are selected from the group consisting of lanthinum oxide, cerium oxide, praseodymium oxide, neodymium oxide and mixtures thereof.
30. A low sidestream smoke cigarette of claim 29, wherein said oxygen storage and donor metal oxide oxidation catalyst and adjunct therefor is a solid solution of mixed metal oxides where the adjuncts are selected from the group consisting of zirconium oxide, aluminium oxide, magnesium oxide, titanium oxide and mixtures thereof.
31. A low sidestream smoke cigarette of the preceding claim 30, wherein said solid solution of mixed metal oxides comprises a catalyst selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide.
32. A low sidestream smoke cigarette of claim 20, wherein said solid solution of mixed metal oxides includes cerium/lanthinum mixed oxides, cerium/zirconium mixed oxides, cerium/lanthinum mixed oxides, cerium/magnesium mixed oxides, cerium/titanium mixed oxides, cerium/
zirconium/lanthinum mixed oxides, cerium/lanthinum mixed oxide, cerium/zirconium mixed oxide, cerium/ zirconium/lanthinum mixed oxide, ceriumlzirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/
praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide.
zirconium/lanthinum mixed oxides, cerium/lanthinum mixed oxide, cerium/zirconium mixed oxide, cerium/ zirconium/lanthinum mixed oxide, ceriumlzirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/
praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide.
33. A low sidestream smoke cigarette of claim 20, wherein said adjunct is selected from the group consisting of clays essentially non-combustible mill fibers, monolithe mineral base materials, essentially non-combustible carbon, zeolytes and mixtures thereof.
34. A low sidestream smoke cigarette of claim 33, wherein said adjuncts are selected from the group consisting of zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, cerium oxide, tin oxide, iron oxide, manganese oxide, calcium carbonate, zirconium carbonate, magnesium carbonate and mixtures thereof, metal oxide fibers and milled porous ceramic fibers and mixtures thereof.
35. In a low sidestream smoke cigarette of claim 29, 30, 31 or 32, said solid solution being a high surface area porous particulate.
36. In a low sidestream smoke cigarette of claim 29, 30, 31 or 32, said solid solution being a low surface area particulate.
37. A low sidestream of smoke cigarette of claim 23, wherein said ash modifying particulate is zirconium oxide.
38. A low sidestream smoke cigarette of claim 29, wherein an oxidation catalyst is used with said oxygen storage and donor metal oxide oxidation catalyst, said oxidation catalyst being selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide, and mixtures thereof.
39. A low sidestream smoke cigarette of claim 22, wherein said zeolite is a Y-type zeolite, ZSM-5 type zeolite or Beta type zeolite.
40. A low sidestream smoke cigarette of clam 29, wherein said oxygen storage and donor metal oxide oxidation catalyst is a porous particulate solid solution of cerium/zirconium which is preferably a mixed oxide high surface area material.
41. A low sidestream smoke cigarette of claim 40, wherein zirconium oxide and/or a zeolite are used in combination with said cerium/zirconium mixed oxide.
42. A low sidestream smoke cigarette of claim 41, wherein an oxidation catalyst is used with said cerium/zirconium metal oxide, zirconium oxide and/or zeolite.
43. A low sidestream smoke cigarette of claim 42, wherein said oxidation catalyst is selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide, and mixtures thereof, said selected oxidation catalyst being either incorporated in said solid solution of cerium/zirconium mixed oxide or applied to surfaces of particulate cerium/zirconium mixed oxide, zirconium oxide and/or zeolite.
44. A low sidestream smoke cigarette of claim 42, wherein said zeolite is a Y-type zeolite.
45. A low sidestream smoke cigarette of claim 20, wherein said treatment composition is applied as a coating to cigarette paper, said coating composition including a metal oxide or carbonate selected from the group consisting of zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, cerium oxide, tin oxide, iron oxide, manganese oxide, calcium carbonate, zirconium carbonate, magnesium carbonate and mixtures thereof.
46. A low sidestream smoke cigarette of claim 20, wherein said combustible treatment paper comprises an inner sheet and an outer sheet, said inner sheet comprises said treatment composition for reducing sidestream smoke, said outer layer comprising a treatment composition for modifying ash characteristics.
47. A low sidestream smoke cigarette of claim 46, wherein said inner paper has greater than 35% by weight of a zeolite material.
48. A low sidestream smoke cigarette of claim 48, wherein said inner paper and outer paper have said treatment composition coated, incorporated or impregnated thereon or therein.
49. A low sidestream smoke cigarette of claim 48, wherein said inner paper has said sidestream smoke reduction composition incorporated therein.
50. A low sidestream smoke cigarette of claim 48, wherein said inner paper has said sidestream smoke reduction composition coated thereon.
51. A low sidestream smoke cigarette of claim 48, wherein said inner paper has said sidestream smoke reduction composition incorporated and coated thereon.
52. A low sidestream smoke cigarette of claim 48, wherein said outer paper has said sidestream smoke reduction composition incorporated thereon.
53. A low sidestream smoke cigarette of claim 48, wherein said outer paper has said sidestream smoke reduction composition coated thereon.
54. A low sidestream smoke cigarette of claim 48, wherein said outer paper has said sidestream smoke reduction composition incorporated and coated thereon.
55. A low sidestream smoke cigarette of claim 46 said inner paper comprising an oxygen storage and donor metal oxide oxidation catalyst with adjunct and a high surface area adsorptive material, the outer layer comprising an oxygen storage and donor metal oxide oxidation catalyst with adjunct and metal oxide for modifying ash characteristics.
56. A low sidestream smoke cigarette of claim 55, wherein said treatment composition for reducing sidestream smoke and said treatment composition for modifying ash are applied as a coatings respectively to said inner sheet and said outer sheet.
57. A low sidestream smoke cigarette of claim 56, wherein said oxygen storage and donor metal oxide oxidation catalyst is a porous particulate high surface area solid solution cerium/zirconium mixed oxide.
58. A low sidestream smoke cigarette of claim 57, wherein said cerium oxide and said zirconium oxide in said solid solution are in a ratio of about 5:95 to about 95:5.
59. A low sidestream smoke cigarette of claim 58, wherein said coating is applied to said inner and outer sheets on either or both sides of each of said sheets.
60. A low sidestream smoke cigarette comprising a conventional tobacco rod and a combustible treatment paper having a sidestream smoke treatment composition, said treatment composition comprising an oxygen storage and donor metal oxide oxidation catalyst, an essentially non-combustible high surface area adjunct for said catalyst incorporated in said treatment paper and a coating of calcium carbonate on an exterior surface of said treatment paper to modify ash characteristics.
61. A low sidestream smoke cigarette of claim 60, wherein said adjunct includes a zeolite based material.
62. A low sidestream smoke cigarette of claim 61, wherein said zeolite based material is in an amount ranging from about 0.1% by weight of total dry weight composition to about 60% by weight of total dry weight composition and preferably less than 25% and most preferably less than 15%.
63. A low sidestream smoke cigarette of claim 60, wherein said oxygen storage and donor metal oxide oxidation catalyst is selected from a group consisting of transition metal oxides, rare earth metal oxides and mixtures thereof.
64. A low sidestream smoke cigarette of claim 61, wherein said transition metal oxides are selected from the group consisting of oxides of group IVB, VB, VIB, VIIB, VIIIB, IB metals and mixtures thereof.
65. A low sidestream smoke cigarette of claim 62, wherein said rare earth metal oxide is selected from the group consisting of oxides consisting of scandium, yttrium, lanthanide metals .and mixtures thereof.
66. A low sidestream smoke cigarette of claim 60, wherein said lanthanide metal oxide is selected from the group consisting of lanthanum oxide, cerium oxide, praseodymium oxide, neodymium oxide and mixtures thereof.
67. A low sidestream smoke cigarette of claim 66, wherein said oxygen storage and donor metal oxide oxidation catalyst and adjunct therefor is a solid solution of mixed metal oxides where the adjuncts are selected from the group consisting of zirconium oxide, aluminium oxide, magnesium oxide, titanium oxide and mixtures thereof.
68. A low sidestream smoke cigarette of the preceding claim 67, wherein said solid solution comprises a metal catalyst selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide and mixtures thereof.
69. A low sidestream smoke cigarette of claim 68, wherein said solid solution of mixed metal oxides includes cerium/lanthinum mixed oxides, cerium/zirconium mixed oxides, cerium/aluminum mixed oxides, cerium/magnesium mixed oxides, cerium/titanium mixed oxides, cerium/
zirconium/lanthinum mixed oxides, cerium/lanthinum mixed oxide, cerium/zirconium mixed oxide, cerium/ zirconium/lanthinum mixed oxide, cerium/zirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/
praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide.
zirconium/lanthinum mixed oxides, cerium/lanthinum mixed oxide, cerium/zirconium mixed oxide, cerium/ zirconium/lanthinum mixed oxide, cerium/zirconium/praseodynium mixed oxide, cerium/zirconium/lanthinum/
praseodynium mixed oxide, cerium/zirconium/neodymium mixed oxide.
70. In a low sidestream smoke cigarette of claim 66, 67, 68 or 69, said solid solution being a high surface area porous particulate.
71. A low sidestream smoke cigarette of claim 66, wherein an oxidation catalyst is used with said oxygen storage and donor metal oxide oxidation catalyst, said oxidation catalyst being selected from the group consisting of palladium, platinum, rhodium, tin oxides, copper oxides, iron oxides, manganese oxides, and mixtures thereof.
72. A low sidestream smoke cigarette of claim 61, wherein said zeolite is a Y-type zeolite, ZSM-5 type zeolite or Beta type zeolite.
73. A low sidestream smoke cigarette of clam 72, wherein said oxygen storage and donor metal oxide oxidation catalyst is a porous particulate cerium/zirconium mixed oxide high surface area material.
74. A low sidestream smoke cigarette of claim 73, wherein an oxidation catalyst is used with said cerium/zirconium mixed oxide, zirconium oxide and/or zeolite.
75. A low sidestream smoke cigarette of claim 74, wherein said oxidation catalyst is selected from the group consisting of palladium, platinum, rhodium, tin oxide, copper oxide, iron oxide, manganese oxide, and mixtures thereof, said selected oxidation catalyst being either incorporated in said solid solution of cerium/zirconium mixed oxide or applied to surfaces of particulate cerium/zirconium mixed oxide, zirconium oxide and/or zeolite.
76. A low sidestream smoke cigarette of claim 75, wherein said zeolite is a Y-type zeolite.
77. A low sidestream smoke cigarette of claim 60, wherein a binder for said calcium carbonate coating is selected from the group consisting of polyvinylalcohol, starches, CMC, casein, soya, binding clays, inorganic binders and mixtures thereof.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36413702P | 2002-03-15 | 2002-03-15 | |
US60/364,137 | 2002-03-15 | ||
PCT/CA2003/000353 WO2003077687A2 (en) | 2002-03-15 | 2003-03-14 | Low sidestream smoke cigarette with combustible paper having modified ash characteristics |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2476971A1 true CA2476971A1 (en) | 2003-09-25 |
CA2476971C CA2476971C (en) | 2012-02-28 |
Family
ID=28041877
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2476971A Expired - Fee Related CA2476971C (en) | 2002-03-15 | 2003-03-14 | Low sidestream smoke cigarette with combustible paper having modified ash |
Country Status (19)
Country | Link |
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US (2) | US20040020504A1 (en) |
EP (1) | EP1489928B1 (en) |
JP (2) | JP4520745B2 (en) |
KR (1) | KR100964873B1 (en) |
CN (2) | CN101623127B (en) |
AU (2) | AU2003215454B2 (en) |
BR (1) | BR0308465B1 (en) |
CA (1) | CA2476971C (en) |
ES (1) | ES2586552T3 (en) |
HK (2) | HK1086728A1 (en) |
MX (1) | MXPA04008980A (en) |
MY (1) | MY143467A (en) |
NO (1) | NO20044395L (en) |
NZ (2) | NZ552999A (en) |
RU (1) | RU2305480C2 (en) |
SG (1) | SG158740A1 (en) |
TW (1) | TWI270350B (en) |
WO (1) | WO2003077687A2 (en) |
ZA (1) | ZA200407357B (en) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU9156801A (en) | 2000-09-18 | 2002-04-02 | Rothmans Benson | Low sidestream smoke cigarette with non-combustible treatment material |
US6789548B2 (en) * | 2000-11-10 | 2004-09-14 | Vector Tobacco Ltd. | Method of making a smoking composition |
MXPA04008980A (en) * | 2002-03-15 | 2004-11-26 | Rothmans Benson & Hedges | Low sidestream smoke cigarette with combustible paper having modified ash characteristics. |
JP4637099B2 (en) * | 2003-06-13 | 2011-02-23 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Cigarette wrapper with catalyst filler and method of making the same |
WO2004110188A2 (en) * | 2003-06-13 | 2004-12-23 | Philip Morris Products S.A. | Shredded paper with catalytic filler in tobacco cut filler and methods of making same |
US20050005947A1 (en) * | 2003-07-11 | 2005-01-13 | Schweitzer-Mauduit International, Inc. | Smoking articles having reduced carbon monoxide delivery |
US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
US20050268925A1 (en) * | 2004-06-03 | 2005-12-08 | Brown & Williamson Tobacco Corporation | Application of mesoporous molecular sieves as selective smoke filtration additives |
US8151806B2 (en) * | 2005-02-07 | 2012-04-10 | Schweitzer-Mauduit International, Inc. | Smoking articles having reduced analyte levels and process for making same |
GB0514959D0 (en) * | 2005-07-21 | 2005-08-24 | British American Tobacco Co | Smoking article |
US9255361B2 (en) * | 2006-03-31 | 2016-02-09 | Philip Morris Usa Inc. | In situ formation of catalytic cigarette paper |
EP2031990B1 (en) * | 2006-06-01 | 2017-07-26 | Schweitzer-Mauduit International, Inc. | Free air burning smoking articles with reduced ignition proclivity characteristics |
JP2010518861A (en) * | 2007-02-23 | 2010-06-03 | シュヴァイツア マードゥイット インターナショナルインコーポレイテッド | Wrapping material for smokers with reduced diffusivity leading to reduced ignition propensity |
DE102007034633A1 (en) * | 2007-04-05 | 2009-01-29 | Nano-X Gmbh | Coating material with a catalytic activity and use of the coating material |
KR101519821B1 (en) * | 2007-07-03 | 2015-05-13 | 슈바이쳐-모뒤 인터내셔널, 인크. | Smoking articles having reduced ignition proclivity characteristics |
EP2023418A1 (en) * | 2007-08-09 | 2009-02-11 | Sony Corporation | Memory device |
JP2009191393A (en) * | 2008-02-13 | 2009-08-27 | Rengo Co Ltd | Cigarette paper |
TW201026242A (en) * | 2008-11-06 | 2010-07-16 | Japan Tobacco Inc | Smoking article and manufacturing method for the same, and method for manufacturing carbon monoxide reducer |
US9155772B2 (en) | 2008-12-08 | 2015-10-13 | Philip Morris Usa Inc. | Soft, chewable and orally dissolvable and/or disintegrable products |
US9167835B2 (en) | 2008-12-30 | 2015-10-27 | Philip Morris Usa Inc. | Dissolvable films impregnated with encapsulated tobacco, tea, coffee, botanicals, and flavors for oral products |
US9167847B2 (en) | 2009-03-16 | 2015-10-27 | Philip Morris Usa Inc. | Production of coated tobacco particles suitable for usage in a smokeless tobacoo product |
GB2469842A (en) * | 2009-04-29 | 2010-11-03 | British American Tobacco Co | Aerosol generating material for a smoking article |
EP2452579B1 (en) * | 2009-07-07 | 2014-12-24 | Japan Tobacco, Inc. | Method and apparatus for producing cigarette wrapping paper |
ES2671717T3 (en) * | 2010-03-26 | 2018-06-08 | Philip Morris Products S.A. | Smoking article with heat-resistant sheet material |
JP2011251946A (en) * | 2010-06-03 | 2011-12-15 | Soda Aromatic Co Ltd | Incense or its analogue |
EP2906057A1 (en) | 2012-10-11 | 2015-08-19 | Schweitzer-Mauduit International, Inc. | Wrapper having reduced ignition proclivity characteristics |
CN105377061B (en) * | 2013-07-19 | 2020-12-29 | 菲利普莫里斯生产公司 | Smoking article with particle-containing wrapper |
CA2951767A1 (en) * | 2013-07-19 | 2015-01-22 | Philip Morris Products S.A. | Hydrophobic paper |
EP3103851B1 (en) * | 2014-02-06 | 2022-05-18 | Asahi Kasei Kogyo Co., Ltd. | Polishing abrasive particle, production method therefor, polishing method, polishing device, and slurry |
CN104687250B (en) * | 2014-12-31 | 2018-09-11 | 东莞市车宝节能科技有限公司 | A kind of filtration core, the filter-tip and preparation method thereof containing filtration core |
DE102015107829B4 (en) * | 2015-05-19 | 2017-06-14 | Delfortgroup Ag | Wrapping paper, process for its preparation and cigarette with a wrapping paper |
WO2017216671A1 (en) * | 2016-06-14 | 2017-12-21 | Philip Morris Products S.A. | Coated plug wrap to enhance filter hardness |
US11252995B2 (en) * | 2017-04-18 | 2022-02-22 | Philip Morris Products S.A. | Apparatus and method for the production of sheet like tobacco material |
EP3453268B1 (en) | 2017-09-07 | 2019-12-11 | Philip Morris Products S.a.s. | Aerosol-generating article with improved outermost wrapper |
US10815427B2 (en) | 2017-11-17 | 2020-10-27 | Branislav R. Simonovic | Fire-retardant for an insulation product |
EP3495554A1 (en) * | 2017-12-07 | 2019-06-12 | Philip Morris Products S.a.s. | Smoking article paper wrapper with amorphous magnesium carbonate |
PL3984383T3 (en) | 2020-10-15 | 2024-02-12 | Jt International Sa | A smoking article with a heated segment comprising a tobacco product |
Family Cites Families (115)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1581451A (en) * | 1925-10-06 | 1926-04-20 | Frank C Hewitt | Fire-safe cigarette |
US2496265A (en) * | 1944-07-25 | 1950-02-07 | Standard Oil Dev Co | Hydrocarbon synthesis process |
US2495700A (en) * | 1944-10-09 | 1950-01-31 | Koppers Co Inc | Silica-alumina-nickel dehydrogenation catalyst |
US2436733A (en) * | 1944-12-28 | 1948-02-24 | Standard Oil Dev Co | Zinc oxide-bismuth oxide catalyst |
US2499733A (en) * | 1947-07-23 | 1950-03-07 | Rubbio Antonio Di | Cigarette holder |
US2541837A (en) * | 1949-02-12 | 1951-02-13 | Schroff Joseph | Safety cigarette holder |
US2666437A (en) * | 1950-06-10 | 1954-01-19 | Lattof Alphonse | Cigarette extinguisher |
IT541844A (en) * | 1953-12-04 | |||
US3193493A (en) * | 1960-10-17 | 1965-07-06 | Socony Mobil Oil Co Inc | Catalytic cracking process with a catalyst composition comprising an aluminosilicate containing beryllium |
NL293155A (en) * | 1963-03-04 | |||
US3266973A (en) * | 1963-07-25 | 1966-08-16 | Richard P Crowley | Method of preparing adsorbent filter paper containing crystalline zeolite particles, and paper thereof |
US3250280A (en) * | 1964-03-03 | 1966-05-10 | Hu Yow-Jiun | Smoking apparatus |
US3140253A (en) * | 1964-05-01 | 1964-07-07 | Socony Mobil Oil Co Inc | Catalytic hydrocarbon conversion with a crystalline zeolite composite catalyst |
US3395096A (en) * | 1966-06-07 | 1968-07-30 | Exxon Research Engineering Co | Selective conversion process |
US3860529A (en) * | 1968-01-24 | 1975-01-14 | Union Carbide Corp | Stabilized tetragonal zirconia fibers and textiles |
US3502087A (en) * | 1968-07-05 | 1970-03-24 | Ernest J Romano | Cigarette filter |
US3572348A (en) * | 1968-08-01 | 1971-03-23 | Liggett & Myers Inc | Tobacco composition |
US3547808A (en) * | 1968-10-11 | 1970-12-15 | Union Oil Co | Conversion process and catalyst |
US3555317A (en) * | 1969-05-01 | 1971-01-12 | Motion Rotators Inc | Electric motor and clutch |
BE791758A (en) * | 1971-11-24 | 1973-05-22 | Olin Corp | CARBON-CHARGED ENVELOPE FOR SMOKING ARTICLE AND SMOKING ARTICLE WITH SUCH A ENVELOPE |
GB1445975A (en) * | 1972-08-30 | 1976-08-11 | Ici Ltd | Friction material |
US4044778A (en) * | 1973-09-10 | 1977-08-30 | Cohn Charles C | Cigarettes |
GB1524211A (en) * | 1975-01-09 | 1978-09-06 | British American Tobacco Co | Smoking articles |
US4126141A (en) * | 1975-03-26 | 1978-11-21 | Montclair Research Corporation | Filter and cigarette including a filter |
US4181532A (en) * | 1975-10-22 | 1980-01-01 | United Kingdom Atomic Energy Authority | Production of colloidal dispersions |
US4108151A (en) * | 1975-12-10 | 1978-08-22 | Olin Corporation | Gamma alumina filled paper wrapper for smoking articles |
US4637990A (en) * | 1978-08-28 | 1987-01-20 | Torobin Leonard B | Hollow porous microspheres as substrates and containers for catalysts and method of making same |
US4248251A (en) * | 1979-02-21 | 1981-02-03 | Liggett Group Inc. | Tobacco composition |
US4225636A (en) * | 1979-03-08 | 1980-09-30 | Olin Corporation | High porosity carbon coated cigarette papers |
US5213779A (en) * | 1980-07-31 | 1993-05-25 | Gas Desulfurization Corporation | Process for optimizing the removal of NOX and SOX from gases utilizing lanthanide compounds |
US4452259A (en) * | 1981-07-10 | 1984-06-05 | Loews Theatres, Inc. | Smoking articles having a reduced free burn time |
US4457833A (en) * | 1981-08-27 | 1984-07-03 | Ashland Oil, Inc. | Process and catalyst for the conversion of carbo-metallic containing oils |
US4440868A (en) * | 1981-12-07 | 1984-04-03 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
US4433697A (en) * | 1982-04-07 | 1984-02-28 | Olin Corporation | Wrapper for smoking articles and method |
US4450847A (en) * | 1982-04-07 | 1984-05-29 | Olin Corporation | Wrapper for smoking articles and method |
US4420002A (en) * | 1982-04-07 | 1983-12-13 | Olin Corp. | Wrapper for smoking articles and method |
US4499318A (en) * | 1983-04-22 | 1985-02-12 | Exxon Research & Engineering Co. | Modified zeolite catalyst composition and process for alkylating toluene with methanol to form styrene |
GB8313604D0 (en) * | 1983-05-17 | 1983-06-22 | British American Tobacco Co | Cigarette |
US4585014A (en) * | 1983-08-01 | 1986-04-29 | Fry Arnold H | Fire inhibiting tubular safety shield for a cigarette type smoking device and combination thereof |
GB2157541B (en) * | 1984-03-30 | 1988-09-21 | Dynic Corp | Device for decreasing side stream smoke of tobacco products |
US4637992A (en) * | 1984-12-17 | 1987-01-20 | Shell Oil Company | Intercalated clay compositions |
US4938238A (en) * | 1985-08-26 | 1990-07-03 | R. J. Reynolds Tobacco Company | Smoking article with improved wrapper |
US4685477A (en) * | 1985-12-18 | 1987-08-11 | Valdez Loredana G | Cigar or cigarette holder |
US4796980A (en) * | 1986-04-02 | 1989-01-10 | Canon Kabushiki Kaisha | Ferroelectric liquid crystal optical modulation device with regions within pixels to initiate nucleation and inversion |
US4739775A (en) * | 1986-09-26 | 1988-04-26 | Kimberly-Clark Corporation | Wrapper constructions for self-extinguishing and reduced ignition proclivity smoking articles |
US5008090A (en) * | 1987-06-15 | 1991-04-16 | Allied-Signal Inc. | Catalytic process for minimizing the H2 S emissions from automotive exhaust |
US5112781A (en) * | 1987-06-19 | 1992-05-12 | Manville Corporation | Process for producing zirconium based granules and zirconium oxide fibers |
US4927622A (en) * | 1987-06-19 | 1990-05-22 | Manville Corporation | Process for producing zirconium based granules |
JP2720155B2 (en) * | 1987-08-05 | 1998-02-25 | 美どり 伊藤 | Cigarette |
DE3802645A1 (en) * | 1988-01-29 | 1989-08-10 | Reemtsma H F & Ph | QUICK OR SELF-EXTINGUISHING CIGARETTE |
US5137034A (en) * | 1988-05-16 | 1992-08-11 | R. J. Reynolds Tobacco Company | Smoking article with improved means for delivering flavorants |
US4852590A (en) * | 1988-07-07 | 1989-08-01 | Robert Ferka | Insertable cigarette smoke baffle for holders |
US4900712A (en) * | 1988-09-30 | 1990-02-13 | Prototech Company | Catalytic washcoat and method of preparation of the same |
US5040551A (en) * | 1988-11-01 | 1991-08-20 | Catalytica, Inc. | Optimizing the oxidation of carbon monoxide |
US4937212A (en) * | 1988-12-19 | 1990-06-26 | Minnesota Mining And Manufacturing Company | Zirconium oxide fibers and process for their preparation |
US4998542A (en) * | 1989-02-23 | 1991-03-12 | Philip Morris Incorporated | Wrapper for smoking articles and method for preparing same |
JPH07123069B2 (en) * | 1989-05-18 | 1995-12-25 | 松下電器産業株式会社 | Heating element |
US5709228A (en) | 1989-06-02 | 1998-01-20 | Rothmans, Benson & Hedges, Inc. | Cigarette with decreased sidestream smoke |
US5094222A (en) * | 1989-11-17 | 1992-03-10 | Matsushita Electric Industrial Co., Ltd. | Catalytic composite and a cooker having the same |
US5232889A (en) * | 1989-11-27 | 1993-08-03 | Rhone-Poulenc Chimie | Supported catalysts |
DE3942236A1 (en) * | 1989-12-21 | 1991-06-27 | Bosch Siemens Hausgeraete | CATALYTIC COATING AGENT, METHOD FOR THE PRODUCTION THEREOF AND COOKING, BAKING, FRYING OR GRILLING EQUIPMENT OR PARTS AVAILABLE WITH THE COATING AGENT |
US5013352A (en) | 1990-03-30 | 1991-05-07 | Dowelanco | Substituted pyridyl-cyclohexanediones and their herbicidal uses |
US5109876A (en) * | 1990-04-19 | 1992-05-05 | R. J. Reynolds Tobacco Company | Cigarette paper and cigarette incorporating same |
US5170807A (en) * | 1990-07-20 | 1992-12-15 | Kimberly Clark Corporation | Method of producing a non-burning outer wrapper for use with smoking products |
US5281445A (en) * | 1990-07-30 | 1994-01-25 | Phillips Petroleum Company | Coating of components of sulfur absorbants |
US5105837A (en) * | 1990-08-28 | 1992-04-21 | R. J. Reynolds Tobacco Company | Smoking article with improved wrapper |
US5105838A (en) * | 1990-10-23 | 1992-04-21 | R.J. Reynolds Tobacco Company | Cigarette |
US5191906A (en) * | 1990-10-30 | 1993-03-09 | Philip Morris Incorporated | Process for making wrappers for smoking articles which modify the burn rate of the smoking article |
CA2057962C (en) | 1991-01-05 | 1999-08-10 | Larry Bowen | Novel smoking product |
JPH0679965B2 (en) * | 1991-04-12 | 1994-10-12 | 株式会社コロイドリサーチ | Method for producing zirconia sol and method for producing zirconia molded body |
US5263999A (en) * | 1991-09-10 | 1993-11-23 | Philip Morris Incorporated | Smoking article wrapper for controlling burn rate and method for making same |
US5200382A (en) * | 1991-11-15 | 1993-04-06 | Exxon Research And Engineering Company | Catalyst comprising thin shell of catalytically active material bonded onto an inert core |
US5176899A (en) * | 1991-11-25 | 1993-01-05 | Montgomery Robert E | Antimicrobial dentifrice |
US5431887A (en) * | 1992-05-19 | 1995-07-11 | Prototech Company | Flame arresting and contaminant-adsorbing filter apparatus and method in the catalytic abatement of broiler emissions |
US20020044901A1 (en) * | 1993-04-19 | 2002-04-18 | William G. Wilson | Desulfurization of gases with cerium oxide microdomains |
EP0624393B1 (en) * | 1993-05-10 | 2001-08-16 | Sakai Chemical Industry Co., Ltd., | Catalyst for catalytic reduction of nitrogen oxides |
US5386838A (en) * | 1993-07-09 | 1995-02-07 | Kimberly-Clark Corporation | High surface area iron-magnesium smoke suppressive compositions |
US5592955A (en) * | 1994-02-07 | 1997-01-14 | Philip Morris Incorporated | Cigarette with insulating shell and method for making same |
FR2720295B1 (en) * | 1994-05-27 | 1996-07-12 | Rhone Poulenc Chimie | Dispersible compound based on a rare earth, colloidal suspension obtained from this compound, their methods of preparation and use in the manufacture of catalysts. |
GB9501146D0 (en) | 1995-01-20 | 1995-03-08 | Rothmans Benson & Hedges | A device for controlling free-burn rate of a cigarette |
JP2883298B2 (en) * | 1995-08-09 | 1999-04-19 | 三島製紙株式会社 | Water dispersible sheet for tobacco and tobacco using the same |
JP2947735B2 (en) * | 1995-08-09 | 1999-09-13 | 三島製紙株式会社 | Water dispersible sheet and tobacco using the same |
US6040265A (en) * | 1996-02-21 | 2000-03-21 | Asec Manufacturing General Partnership | Methods of making highly dispersed substantially uniform cerium and zirconium mixed-metal-oxide composite supports for exhaust conversion catalysts |
DE19614540A1 (en) * | 1996-04-12 | 1997-10-16 | Degussa | Diesel catalyst |
FR2748740B1 (en) * | 1996-05-15 | 1998-08-21 | Rhone Poulenc Chimie | COMPOSITION BASED ON CERIUM OXIDE AND ZIRCONIUM OXIDE WITH HIGH SPECIFIC SURFACE AND HIGH OXYGEN STORAGE CAPACITY, METHOD OF PREPARATION AND USE IN CATALYSIS |
JPH10121333A (en) * | 1996-06-28 | 1998-05-12 | Minolta Co Ltd | Production of fiber |
US5935889A (en) * | 1996-10-04 | 1999-08-10 | Abb Lummus Global Inc. | Catalyst and method of preparation |
RU2180180C2 (en) * | 1996-10-15 | 2002-03-10 | Ротманс, Бенсон Энд Хеджиз Инк. | Apparatus for reducing the release of side-stream smoke and cigarette charring rate |
US5759663A (en) * | 1996-10-31 | 1998-06-02 | Thorpe Products Company | Hard-faced insulating refractory fiber linings |
US5730840A (en) * | 1996-11-14 | 1998-03-24 | Schwietzer-Mauduit Inernational, Inc. | Cigarette paper with improved ash characteristics |
US5944025A (en) * | 1996-12-30 | 1999-08-31 | Brown & Williamson Tobacco Company | Smokeless method and article utilizing catalytic heat source for controlling products of combustion |
US5878754A (en) * | 1997-03-10 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article |
US5878753A (en) * | 1997-03-11 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article without affecting smoking characteristics |
TW536395B (en) * | 1998-04-16 | 2003-06-11 | Rothmans Benson & Hedges | Cigarette sidestream smoke treatment material |
CN1095350C (en) * | 1999-11-19 | 2002-12-04 | 长沙卷烟厂 | Flue-cured tobacco type cigarette with low smoke by-pass and method for reducing smoke by-pass of cigarette |
GB9928853D0 (en) * | 1999-12-07 | 2000-02-02 | British American Tobacco Co | Improvements relating to smoking articles |
KR100520795B1 (en) * | 1999-12-27 | 2005-10-12 | 니뽄 다바코 산교 가부시키가이샤 | Wrapping paper for cigarette reduced in scattering property of ash therefrom |
KR100831535B1 (en) * | 2000-03-23 | 2008-05-22 | 필립모리스 프로덕츠 인코포레이티드 | Electrical smoking system and method |
US6419998B1 (en) * | 2000-06-19 | 2002-07-16 | Mcgrath Thomas | Method for deposition of metal catalysts on inert supports |
CN1248605C (en) * | 2000-09-08 | 2006-04-05 | 日本烟草产业株式会社 | Method and device for producing low flame propagation cigarette |
AU9156801A (en) * | 2000-09-18 | 2002-04-02 | Rothmans Benson | Low sidestream smoke cigarette with non-combustible treatment material |
JP3958685B2 (en) * | 2000-11-13 | 2007-08-15 | シュヴァイツア マードゥイット インターナショナルインコーポレイテッド | Method for producing smoking article having reduced ignitability and product produced by the method |
US6536442B2 (en) * | 2000-12-11 | 2003-03-25 | Brown & Williamson Tobacco Corporation | Lighter integral with a smoking article |
ATE538670T1 (en) * | 2001-01-15 | 2012-01-15 | Japan Tobacco Inc | LOW FIRE SPREAD CIGARETTE |
US20020179105A1 (en) * | 2001-02-26 | 2002-12-05 | Zawadzki Michael A. | Reduced ignition propensity smoking article |
US20020179106A1 (en) * | 2001-03-28 | 2002-12-05 | Zawadzki Michael A. | Reduced ignition propensity smoking article with a polysaccharide treated wrapper |
EP1392135A1 (en) * | 2001-05-11 | 2004-03-03 | Philip Morris Products Inc. | Cigarette paper with selected attenuator bands |
US6854469B1 (en) * | 2001-06-27 | 2005-02-15 | Lloyd Harmon Hancock | Method for producing a reduced ignition propensity smoking article |
MXPA04002376A (en) * | 2001-09-13 | 2005-04-11 | Rothmans Benson & Hedges | Zirconium/metal oxide fibres. |
JP4471654B2 (en) * | 2001-09-14 | 2010-06-02 | ロスマンズ、ベンソン アンド ヘッジズ インコーポレイテッド | Method for producing rare earth metal oxide-coated microporous material |
US6779530B2 (en) * | 2002-01-23 | 2004-08-24 | Schweitzer-Mauduit International, Inc. | Smoking articles with reduced ignition proclivity characteristics |
MXPA04008980A (en) * | 2002-03-15 | 2004-11-26 | Rothmans Benson & Hedges | Low sidestream smoke cigarette with combustible paper having modified ash characteristics. |
CN1662157A (en) * | 2002-04-22 | 2005-08-31 | 乐富门·本森及赫奇斯有限公司 | Low ignition propensity cigarette having oxygen donor metal oxide in the cigarette wrapper |
US20040134631A1 (en) * | 2003-01-15 | 2004-07-15 | Crooks Evon Llewellyn | Smoking article wrapping materials comprising ultrafine particles |
WO2005025342A1 (en) * | 2003-09-15 | 2005-03-24 | Rothmans, Benson & Hedges Inc. | Treatment of mainstream smoke constituents by use of oxygen storage and donor metal oxide oxidation catalyst |
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