CA2454346A1 - Method of surface oxidizing zirconium and zirconium alloys and resulting product - Google Patents
Method of surface oxidizing zirconium and zirconium alloys and resulting product Download PDFInfo
- Publication number
- CA2454346A1 CA2454346A1 CA002454346A CA2454346A CA2454346A1 CA 2454346 A1 CA2454346 A1 CA 2454346A1 CA 002454346 A CA002454346 A CA 002454346A CA 2454346 A CA2454346 A CA 2454346A CA 2454346 A1 CA2454346 A1 CA 2454346A1
- Authority
- CA
- Canada
- Prior art keywords
- zirconium
- prosthesis
- black
- coating
- blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract description 144
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract description 141
- 229910001093 Zr alloy Inorganic materials 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims description 71
- 230000001590 oxidative effect Effects 0.000 title claims description 13
- 238000000576 coating method Methods 0.000 claims abstract description 106
- 239000011248 coating agent Substances 0.000 claims abstract description 86
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- 230000003746 surface roughness Effects 0.000 claims abstract description 41
- 239000000956 alloy Substances 0.000 claims abstract description 15
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229920000620 organic polymer Polymers 0.000 claims description 12
- 210000001519 tissue Anatomy 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000011324 bead Substances 0.000 claims description 8
- 230000001788 irregular Effects 0.000 claims description 7
- 238000002513 implantation Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
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- 230000003647 oxidation Effects 0.000 description 31
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 210000001624 hip Anatomy 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 210000001124 body fluid Anatomy 0.000 description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
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- 210000002303 tibia Anatomy 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000952 Be alloy Inorganic materials 0.000 description 1
- 208000006386 Bone Resorption Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RZJQYRCNDBMIAG-UHFFFAOYSA-N [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] Chemical class [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] RZJQYRCNDBMIAG-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
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- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
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- 238000003379 elimination reaction Methods 0.000 description 1
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- 238000010952 in-situ formation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
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- 230000000926 neurological effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
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- 239000012457 nonaqueous media Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
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Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Transplantation (AREA)
- Public Health (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Cardiology (AREA)
- Vascular Medicine (AREA)
- Heart & Thoracic Surgery (AREA)
- Biomedical Technology (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Prostheses (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/909,612 | 2001-07-20 | ||
| US09/909,612 US6585772B2 (en) | 1997-03-27 | 2001-07-20 | Method of surface oxidizing zirconium and zirconium alloys and resulting product |
| PCT/US2002/023086 WO2003008657A1 (en) | 2001-07-20 | 2002-07-19 | Method of surface oxidizing zirconium and zirconium alloys and resulting product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2454346A1 true CA2454346A1 (en) | 2003-01-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002454346A Abandoned CA2454346A1 (en) | 2001-07-20 | 2002-07-19 | Method of surface oxidizing zirconium and zirconium alloys and resulting product |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6585772B2 (enExample) |
| EP (1) | EP1409760A1 (enExample) |
| JP (1) | JP4719416B2 (enExample) |
| KR (1) | KR20040043162A (enExample) |
| CN (1) | CN1553967A (enExample) |
| AU (1) | AU2002330894B2 (enExample) |
| CA (1) | CA2454346A1 (enExample) |
| WO (1) | WO2003008657A1 (enExample) |
Families Citing this family (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998042390A1 (en) * | 1997-03-27 | 1998-10-01 | Smith & Nephew, Inc. | Method of surface oxidizing zirconium alloys and resulting product |
| US6585772B2 (en) * | 1997-03-27 | 2003-07-01 | Smith & Nephew, Inc. | Method of surface oxidizing zirconium and zirconium alloys and resulting product |
| US7101391B2 (en) | 2000-09-18 | 2006-09-05 | Inflow Dynamics Inc. | Primarily niobium stent |
| US7402173B2 (en) | 2000-09-18 | 2008-07-22 | Boston Scientific Scimed, Inc. | Metal stent with surface layer of noble metal oxide and method of fabrication |
| US7597715B2 (en) | 2005-04-21 | 2009-10-06 | Biomet Manufacturing Corp. | Method and apparatus for use of porous implants |
| US20020120340A1 (en) | 2001-02-23 | 2002-08-29 | Metzger Robert G. | Knee joint prosthesis |
| US8123814B2 (en) | 2001-02-23 | 2012-02-28 | Biomet Manufacturing Corp. | Method and appartus for acetabular reconstruction |
| US7497874B1 (en) | 2001-02-23 | 2009-03-03 | Biomet Manufacturing Corp. | Knee joint prosthesis |
| US20030153979A1 (en) * | 2002-02-11 | 2003-08-14 | Dean Hughes | Posterior stabilized knee system prosthetic devices employing diffusion-hardened surfaces |
| US20040034432A1 (en) * | 2002-02-11 | 2004-02-19 | Dean Hughes | Mobile bearing tibial base prosthetic devices employing oxidized zirconium surfaces |
| US20030209517A1 (en) * | 2002-05-08 | 2003-11-13 | Mcgehee Brian | Post oxidation mass finishing techniques for prosthetic devices having textured diffusion-hardened surfaces |
| US7048767B2 (en) * | 2002-06-11 | 2006-05-23 | Spire Corporation | Nano-crystalline, homo-metallic, protective coatings |
| EP1534175B1 (en) | 2002-08-19 | 2011-10-12 | Crucible Intellectual Property, LLC | Medical implants made of amorphous alloys |
| AU2003300822A1 (en) | 2002-12-04 | 2004-06-23 | California Institute Of Technology | BULK AMORPHOUS REFRACTORY GLASSES BASED ON THE Ni-(-Cu-)-Ti(-Zr)-A1 ALLOY SYSTEM |
| US20040122524A1 (en) * | 2002-12-18 | 2004-06-24 | Smith & Nephew, Inc. | Bi-polar hip prosthetic devices employing diffusion-hardened surfaces |
| DE10304756B4 (de) | 2003-02-05 | 2005-04-07 | W.C. Heraeus Gmbh | Sauerstoffangereicherter Niob-Draht |
| US20040167632A1 (en) | 2003-02-24 | 2004-08-26 | Depuy Products, Inc. | Metallic implants having roughened surfaces and methods for producing the same |
| AU2004200704B2 (en) * | 2003-02-24 | 2010-03-25 | Depuy Products, Inc. | Metallic implants having roughened surfaces and method for producing the same |
| EP1648348B1 (en) * | 2003-07-24 | 2015-06-17 | Tecomet Inc. | Assembled non-random foams |
| US20050025805A1 (en) * | 2003-07-28 | 2005-02-03 | Adam Heller | Osmium compounds for reduction of adverse inflammation |
| DE102004032128B4 (de) | 2003-10-17 | 2010-10-14 | W.C. Heraeus Gmbh | Metallischer Werkstoff, Herstellverfahren und Verwendung |
| US6974625B2 (en) * | 2003-12-16 | 2005-12-13 | Smith & Nephew, Inc. | Oxidized zirconium on a porous structure for bone implant use |
| US20050164041A1 (en) * | 2004-01-23 | 2005-07-28 | Dunsmore David V. | Medical device having a smooth, hardened surface |
| US7473278B2 (en) * | 2004-09-16 | 2009-01-06 | Smith & Nephew, Inc. | Method of surface oxidizing zirconium and zirconium alloys and resulting product |
| CN1329085C (zh) * | 2004-10-27 | 2007-08-01 | 中国科学院上海硅酸盐研究所 | 硅酸二钙/氧化锆复合承载骨替换材料及制备方法 |
| US20060111779A1 (en) * | 2004-11-22 | 2006-05-25 | Orthopedic Development Corporation, A Florida Corporation | Minimally invasive facet joint fusion |
| US8021392B2 (en) | 2004-11-22 | 2011-09-20 | Minsurg International, Inc. | Methods and surgical kits for minimally-invasive facet joint fusion |
| DE102004061679A1 (de) * | 2004-12-22 | 2006-07-06 | Schaeffler Kg | Ausrückvorrichtung |
| US8021432B2 (en) | 2005-12-05 | 2011-09-20 | Biomet Manufacturing Corp. | Apparatus for use of porous implants |
| US8266780B2 (en) | 2005-04-21 | 2012-09-18 | Biomet Manufacturing Corp. | Method and apparatus for use of porous implants |
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| US6585772B2 (en) | 2003-07-01 |
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| EP1409760A1 (en) | 2004-04-21 |
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